DE19735865C1 - Aqueous formulation useful as hair conditioner, treatment or leave-on lotion - Google Patents

Aqueous formulation useful as hair conditioner, treatment or leave-on lotion

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Publication number
DE19735865C1
DE19735865C1 DE1997135865 DE19735865A DE19735865C1 DE 19735865 C1 DE19735865 C1 DE 19735865C1 DE 1997135865 DE1997135865 DE 1997135865 DE 19735865 A DE19735865 A DE 19735865A DE 19735865 C1 DE19735865 C1 DE 19735865C1
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Prior art keywords
hair
formulation
aqueous
cationic
permanently
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Expired - Fee Related
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DE1997135865
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German (de)
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Dieter Heinz
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KPSS-Kao Professional Salon Services GmbH
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Goldwell AG
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/004Preparations used to protect coloured hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/416Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/892Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/893Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/96Cosmetics or similar toilet preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toilet preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426Polymers characterized by specific structures/properties characterized by the charge cationic

Abstract

An aqueous formulation containing (a) quaternary ammonium compound(s) with 10-22 carbon (C) alk(en)yl group(s), (b) green tea extract and (c) a cationic polymer is used for increasing the stability of the color and/or set of colored and/or permanently waved hair.

Description

Die vorliegende Erfindung betrifft die Verwendung eines Haarbehandlungsmittels auf wäßriger Basis, das dem menschlichen Haar erhöhte Stabilität verleiht und bei dauergewelltem und gefärbtem Haar eine verbesserte Haltbarkeit der Dauerwellung und Färbung bewirkt. The present invention relates to the use of a hair treatment composition on aqueous basis, which gives human hair, increased stability and permanent waved and dyed hair results in improved durability of the permanent waving and coloring.

Mittel zum Konditionieren von menschlichen Haaren sind seit langem bekannt. Means for conditioning human hair have long been known. Sie enthalten in der Regel quaternäre Ammoniumverbindungen, die mindestens eine langkettige Alkyl- oder Alkenylgruppe aufweisen, und gegebenenfalls auch Polymere. They typically contain quaternary ammonium compounds having at least one long chain alkyl or alkenyl group, and optionally also polymers.

Solche Mittel werden üblicherweise als wäßrige Dispersionen bzw. Emulsionen, Mikroemulsionen, Gele oder auch in Aerosolform konfektioniert und als Haarspülungen, Kuren etc. eingesetzt. Such agents are typically formulated as aqueous dispersions or emulsions, microemulsions, gels or also in aerosol form and used as hair rinses, treatments, etc..

Eine Übersicht über die bekannten Haarnachbehandlungsmittel und ihre Zusammensetzung findet sich in der Monographie von K. Schrader, Grundlagen und Rezepturen der Kosmetika, 2. Aufl. (1989), S. 722 bis 781, insbesondere S. 728 bis 737. An overview of the known hair-treatment agent and its composition can be found in the monograph by K. Schrader, bases and Formulations of Cosmetics, 2nd ed. (1989), pp 722-781, in particular pp 728-737.

Trotz dieser bekannten Zusammensetzungen besteht aber noch ein Bedürfnis nach Haarbehandlungsmitteln, die insbesondere dauergewelltem und gefärbtem Haar verbesserte Stabilität von Form und Farbe verleihen. Despite these known compositions, however, there still lend a need for hair treatment compositions, in particular, permed and dyed hair improved stability of form and color.

Es wurde nunmehr gefunden, daß dauergewelltem und/oder gefärbtem Haar bei topischer Behandlung mit einem wäßrigen Haarbehandlungsmittel eine verbesserte Farbstabilität verleihen werden kann, wenn man ein Haarbehandlungsmittel verwendet, das eine Kombination aus mindestens einer quaternären Ammoniumverbindung mit mindestens einer Alkyl- bzw. Alkenylgruppe mit 10 bis 22 Kohlenstoffatomen, Grünen Tee- Extrakt, und ein kationisches Polymer enthält. It has now been found that permanent waved and / or dyed hair upon topical treatment improved color stability can be provide with an aqueous hair treatment composition when using a hair treatment composition, comprising a combination of at least one quaternary ammonium compound having at least one alkyl or alkenyl group having 10 to 22 carbon atoms, Green tea extract, and a cationic polymer.

Aus der DE 33 20 539 A1 ist bereits ein Haarkosmetikum bekannt, das Flavanol-Derivate, ua auch Grünen Tee-Extrakt, enthält. From DE 33 20 539 A1 a hair cosmetic, the flavanol derivatives is already known, including also contains green tea extract. Durch dessen Anwendung sollen dem Haar eine ausgezeichnete Frisierbarkeit und Halt der Frisur sowie ein zweckentsprechender Grad an Glätte oder Weichheit verliehen werden. excellent manageability and hold of the hairstyle as well, an appropriate degree of smoothness or softness are to be imparted to the hair by its application.

Der Einsatz von Grünem Tee-Extrakt in Dauerwellmitteln auf Basis von Thioglycolaten und in Haarfärbemitteln ist ebenfalls beschrieben; The use of green tea extract in permanent waving compositions based on thioglycolates and in hair dye is also described; jedoch geht daraus keinerlei Hinweis auf die erfindungsgemäße Verwendung spezieller Kombinationen mit Grünem Tee-Extrakt zur Nachbehandlung dauergewellten bzw. gefärbten, also vorgeschädigten Haaren, zur Verbesserung der Farbstabilität bzw. Formbeständigkeit derselben hervor. However, it is permed or colored to post-treatment, so pre-damaged hair no reference to the inventive use of particular combinations with green tea extract, to improve color stability or dimensional stability thereof taken.

Die erfindungsgemäß verwendeten Zusammensetzungen enthalten, wie gesagt, mindestens eine quaternäre Ammoniumverbindung mit einer oder zwei Alkyl- bzw. Alkenylgruppen mit 10 bis 22 Kohlenstoffatomen, insbesondere in einer Menge von 0,1 bis 10, vorzugsweise 0,25 bis 7,5, besonders bevorzugt 0,5 bis 5 Gew.-%, der Gesamtzusammensetzung. The compositions according to the invention contain, as mentioned, at least one quaternary ammonium compound with one or two alkyl or alkenyl groups having 10 to 22 carbon atoms, in particular in an amount of 0.1 to 10, preferably 0.25 to 7.5, more preferably 0.5 to 5 wt .-%, of the total composition.

Geeignete langkettige quaternäre Ammoniumverbindungen, die allein oder im Gemisch miteinander eingesetzt werden können, sind insbesondere Cetyltrimethylammoniumchlorid, Dimethyldicetylammoniumchlorid, Trimethylcetylammoniumbromid, Stearyltrimethylammoniumchlorid, Dimethylstearylbenzylammoniumchlorid, Benzyltetradecyldimethylammoniumchlorid, Dimethyl-dihydriertes-Talgammoniumchlorid, Laurylpyridiniumchlorid, Lauryldimethylbenzylammoniumchlorid, Lauryltrimethylammoniumchlorid, Tris-(oligooxyethyl)alkylammoniumphosphat, Cetylpyridiniumchlorid, etc. Suitable long-chain quaternary ammonium compounds which may be used alone or in admixture are in particular cetyl trimethyl ammonium chloride, Dimethyldicetylammoniumchlorid, trimethylcetylammonium bromide, stearyltrimethylammonium chloride, dimethylstearylbenzylammonium chloride Benzyltetradecyldimethylammoniumchlorid, dimethyl dihydrogenated-tallow ammonium chloride, lauryl pyridinium chloride, lauryldimethylbenzylammonium chloride, lauryl trimethyl ammonium chloride, tris- (oligooxyethyl) alkyl ammonium phosphate, cetyl pyridinium chloride, Etc.

Grundsätzlich sind alle quaternären Ammoniumverbindungen geeignet, die im CTFA International Cosmetic Ingredient Dictionary unter der Bezeichnung "Quaternium" aufgeführt sind. Basically, all quaternary ammonium compounds are suitable that are listed in the CTFA International Cosmetic Ingredient Dictionary under the name "Quaternium".

Der erfindungsgemäß eingesetzte pulvrige Tee-Extrakt wird aus Blättern, Blattknospen und zarten Stielen des Teestrauchs, Camellia sinensis bzw. Camellia oleifera, durch wäßrige bzw. wäßrig-alkoholische Extraktion und anschließende Sprühtrocknung erhalten. The powdery tea extract used in the invention is obtained from the leaves, leaf buds and tender stems of the tea shrub, Camellia sinensis or Camellia oleifera, by aqueous or aqueous-alcoholic extraction and subsequent spray drying.

Bei grünem Tee handelt es sich um die aus den Arten Thea sinensis bzw. Thea assamica gewonnenen, im Gegensatz zum schwarzen Tee nicht fermentierten Produkte. When green tea is extracted from the types Thea sinensis or Thea assamica, unlike black tea is not fermented products.

Eine Übersicht über die biologische und pharmakologische Wirkung grünen Tees sowie seine Inhaltsstoffe findet sich z. An overview of the biological and pharmacological activity of green tea and its ingredients can be found,. B. in einem Artikel von A. Pistorius, SÖFW-Journal, 122. Jahrgang, No. As in an article by A. Pistorius, SFW-Journal, 122. Year, issue no 7/1996, S. 468-471, auf den Bezug genommen wird. 7/1996, pp 468-471, which is incorporated by reference.

Der Gehalt an Extrakt aus grünem Tee in den erfindungsgemäß verwendeten Zusammensetzungen ist variabel. The content of green tea extract in the present invention compositions used is variable. Er liegt vorzugsweise bei 0,1 bis 10, vorzugsweise 0,25 bis 5, insbesondere 0,5 bis 2,5 Gew.-%, berechnet auf die Gesamtzusammensetzung des Mittels und den pulverförmigen Extrakt. It is preferably 0.1 to 10, preferably 0.25 to 5, in particular 0.5 to 2.5 wt .-%, calculated to the total composition and the pulverulent extract.

Der dritte essentielle Bestandteil in den erfindungsgemäß verwendeten Zusammensetzungen ist ein kationisches Polymer, vorzugsweise in einer Menge von 0,1 bis 2,5, insbesondere 0,25 bis 1,5 Gew.-% der Gesamtzusammensetzung. The third essential ingredient in the compositions used according to the invention is a cationic polymer, preferably in an amount of 0.1 to 2.5, in particular 0.25 to 1.5 wt .-% of the total composition. Besonders bevorzugt sind hierbei die unter der CTFA-Bezeichnung "Polyquaternium" bekannten kationischen (Co-)Polymeren. Particularly preferred here are those known under the CTFA name "Polyquaternium" cationic (co) polymers are.

Geeignete kationische Polymere sind neben den altbekannten quaternären Cellulosederivaten des Typs "Polymer® JR" insbesondere quaternisierte Homo- und Copolymere des Dimethyldiallylammoniumchlorids, wie sie unter dem Handelsnamen "Merquat®" im Handel sind, quaternäre Vinylpyrrolidon-Copolymere, insbesondere mit Dialkylaminoalkyl(meth)- acrylaten, wie sie unter dem Namen "Gafquat®" bekannt sind, Copolymerisate aus Vinylpyrrolidon und Vinylimidazoliniummethochlorid, die unter dem Handelsnamen "Luviquat®" angeboten werden, Polyamino-Polyamid-Derivate, beispielsweise Copolymere von Adipinsäure-Dimethylaminohydroxypropyldiethylentriamin, wie sie unter dem Namen "Cartaretine® F" vertrieben werden, sowie auch bisquaternäre langkettige Ammoniumverbindungen der in der US-A 4 157 388 beschriebenen Harnstoff Struktur, die unter dem Handelsnamen "Mirapol® A15" im Handel sind. Suitable cationic polymers are, in addition to the well-known quaternary cellulose derivatives of the type "Polymer® JR" particularly quaternized homo- and copolymers of dimethyldiallylammonium chloride such as those under the trade name "Merquat" in the trade, quaternary vinyl pyrrolidone copolymers, especially with dialkyl aminoalkyl (meth) - acrylates, such as those known under the name "Gafquat.RTM", copolymers of vinylpyrrolidone and Vinylimidazoliniummethochlorid offered under the trade name "Luviquat®" polyamino-polyamide derivatives, for example copolymers of adipic acid dimethylaminohydroxypropyl as under the name " Cartaretine® F "are distributed as well as bisquaternary long-chain ammonium compounds of the urea structure described in US-A 4,157,388, sold under the trade name" are Mirapol® A15 "in the trade.

Verwiesen wird in diesem Zusammenhang auch auf die in den DE 25 21 960 A1, 28 11 010, 30 44 738 A1 und 32 17 059 A1 genannten kationaktiven Polymeren sowie die in der EP 0 337 354 A1 auf den Seiten 3 bis 7 beschriebenen Produkte. Reference is made in this context to those mentioned in the DE 25 21 960 A1, 28 11 010 30 44 738 A1 and 32 17 059 A1 cationic polymers as well as the products described in EP 0337354 A1 on pages 3 to 7th Es können auch Mischungen verschiedener kationischer Polymerer eingesetzt werden. It can also be used mixtures of various cationic polymers.

Gut geeignete kationische Polymere sind auch die in der EP 0 640 643 A1 geoffenbarten Pfropfcopolymerisate aus Organopolysiloxanen und Polyethyloxazolin. Highly suitable cationic polymers are also disclosed in the EP 0 640 643 A1 graft copolymers of organopolysiloxanes and polyethyl oxazoline.

Ein besonders bevorzugtes Pfropfcopolymerisat der dargestellten Art weist ein Gesamtmolekulargewicht von etwa 50000 bis etwa 500000, vorzugsweise etwa 80000 bis etwa 300000, insbesondere etwa 100000 Dalton auf, wobei das Molgewicht des Oxazolin- Segments etwa 2500 bis etwa 7500, vorzugsweise etwa 4000 bis etwa 6000, insbesondere etwa 5000 Dalton-Segment beträgt, dh dessen Molanteil bei 20 Einheiten/Molekül liegt. A particularly preferred graft copolymer of the type illustrated has a total molecular weight of about 50,000 to about 500,000, preferably about 80,000 to about 300,000, especially about 100,000 daltons, wherein the molecular weight of the oxazoline segment is from about 2500 to about 7500, preferably about 4000 to about 6000, more preferably about 5000 daltons segment is, that its mole fraction is 20 units / molecule. Der bevorzugte Si-Gehalt beträgt, entsprechend der Elementaranalyse, etwa 50%. The preferred Si content is, according to the elemental analysis, about 50%. Besonders geeignet sind die unter den Bezeichnungen A-1, A-2 und A3 auf den Seiten 12 bis 13 der EP 0 640 643 A1 beschriebenen Organopolysiloxane. Particularly suitable under the designations A1, A-2 and organopolysiloxanes described on pages 12 to 13 of EP 0 640 643 A1 A3.

Die erfindungsgemäß verwendete Haarbehandlungsmittel können natürlich zusätzlich, die in solchen Mitteln üblichen Bestandteile enthalten; The hair treatment agent used in the invention can also, of course, contain the usual ingredients in such compositions; es wird, zur Vermeidung von Wiederholungen wiederum auf K. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2. Aufl. (1989), S. 722-771, verwiesen. it is, to avoid repetition, in turn, 2nd ed to K. Schrader, "Fundamentals and formulations of cosmetics." (1989), pp 722-771, directed.

Geeignete Zusatzstoffe sind beispielsweise weitere synthetische oder nichtionische, anionische und/oder amphotere Polymere, beispielsweise solchen vom Typ "Amphomer". Suitable additives are for example synthetic or more nonionic, anionic and / or amphoteric polymers, for example those of the type "Amphomer".

Gemäß einer weiteren Ausführungsform der Erfindung kann das verwendete Haarbehandlungsmittel noch mindestens eine Verbindung, ausgewählt aus der Gruppe 1- Methoxypropanol(-2), 1-Ethoxypropanol(-2), Diethylenglykolmonomethyl- oder -ethylether, Dipropylenglykolmonomethyl- oder -ethylether, Benzylalkohol, Benzyloxyethanol, Phenylethylalkohol, Phenoxyethanol und/oder Zimtalkohol, vorzugsweise in einer Menge von 0,1 bis 20, insbesondere 0,5 bis 15, vor allem 1 bis 12,5 und 2,5 bis 10 Gew.-%, berechnet auf die Geamtzusammensetzung des Mittels enthalten. According to another embodiment of the invention, the hair treatment agent used may be at least one compound selected from the group 1-methoxypropanol (-2), 1-ethoxypropanol (-2), diethylene glycol monomethyl or monoethyl ether, Dipropylenglykolmonomethyl- or monoethyl ether, benzyl alcohol, benzyloxyethanol , phenylethyl alcohol, phenoxyethanol and / or cinnamyl alcohol, preferably in an amount of 0.1 to 20, especially 0.5 to 15, especially from 1 to 12.5 and 2.5 to 10 wt .-%, calculated on the Geamtzusammensetzung of means included. Bevorzugte Verbindungen aus dieser Gruppe sind Ethoxydiglykol und Benzyloxyethanol. Preferred compounds from this group are ethoxydiglycol and benzyloxyethanol.

Weitere Zusatzstoffe, deren Art und Menge natürlich von der Applikationsform des Mittels abhängig ist, sind Fette, Fettalkohole, Emulgatoren, pH-Regulatoren, Lösungs- und Verdünnungsmittel, Lösungsvermittler, Konservierungsmittel, Parfums, etc. Other additives whose type and amount is of course dependent on the form of administration of the agent are fats, fatty alcohols, emulsifiers, pH regulators, solvents and diluents, solubilizers, preservatives, perfumes, etc.

Geeignete Fette und Öle, zu denen auch Wachse zählen, sind insbesondere natürliche Öle wie Avocadoöl, Cocosöl, Palmöl, Sesamöl, Erdnußöl, Spermöl, Sonnenblumenöl, Mandelöl, Pfirsichkernöl, Weizenkeimöl, Macadamianußöl, Nachtkerzenöl, Jojobaöl, Ricinusöl, oder auch Oliven- bzw. Sojaöl, Lanolin und dessen Derivate, ebenso Mineralöle wie Paraffinöl und Vaseline. Suitable fats and oils, which include waxes include, in particular natural oils such as avocado oil, coconut oil, palm oil, sesame oil, peanut oil, whale oil, sunflower oil, almond oil, peach kernel oil, wheat germ oil, macadamia nut oil, evening primrose oil, jojoba oil, castor oil, or also olive oil soya oil, lanolin and its derivatives, also mineral oils such as paraffin oil and petrolatum.

Synthetische Öle und Wachse sind beispielsweise Silikonöle, Polyethylengykole, etc. Weitere geeignete hydrophobe Komponenten sind insbesondere Fettalkohole, vorzugsweise solche mit etwa 8 bis 22 Kohlenstoffatomen im Molekül wie Myristyl-, Cetyl-, Stearylalkohol, Wachsalkohole und Fettsäureester wie Isopropylmyristat, -palmitat, -stearat und -isostearat, Oleyloleat, Isocetylstearat, Hexyllaurat, Dibutyladipat, Dioctyladipat, Myristylmyristat, Oleylerucat, Polyethlenglykol- und Polyglycerylfettsäureester wie PEG-7-glycerylcocoat, Cetylpalmitat, etc. Synthetic oils and waxes are, for example, silicone oils, polyethylene glycols, etc. Other suitable hydrophobic components are in particular fatty alcohols, preferably those palmitate with about 8 to 22 carbon atoms in the molecule such as myristyl, cetyl, stearyl alcohol, wax alcohols and fatty acid ester such as isopropyl myristate, stearate and -isostearat, oleyl oleate, isocetyl stearate, hexyl laurate, dibutyl adipate, dioctyl adipate, myristyl myristate, oleyl erucate, Polyethlenglykol- and polyglyceryl fatty acid esters such as PEG-7 glyceryl cocoate, cetyl palmitate, etc.

Diese hydrophoben Komponenten sind in der erfindungsgemäß verwendeten Zusammensetzungen vorzugsweise in einer Gesamtmenge von etwa 0,5 bis etwa 10, insbesondere etwa 1 bis 7,5, vorallem etwa 1,5 bis 5 Gew.-%, berechnet auf die Gesamtzusammensetzung, enthalten. These hydrophobic components are used in the invention compositions preferably in a total amount of about 0.5 to about 10, preferably about 1 to 7.5, especially about 1.5 to 5 wt .-%, calculated to the total composition.

Ebenso können neben den oben erwähnten quaternären langkettigen Ammoniumverbindungen auch andere oberflächenaktive Stoffe, insbesondere amphotere (zwitterionische) und/oder nichtionische Tenside, deren einschlägige Verwendung natürlich an sich bekannt ist, eingesetzt werden. Also, besides the above-mentioned long-chain quaternary ammonium compounds, other surfactants, especially amphoteric (zwitterionic) and / or nonionic surfactants whose pertinent use is of course known per se, can be used.

Eine beispielhafte Zusammenfassung der Herstellung solcher Mittel findet sich ebenfalls in der bereits erwähnten Monographie von K. Schrader, S. 798 bis 818, insbesondere S. 804 ff. An exemplary summary of the production of such agents can be found also in the abovementioned monograph by K. Schrader, pp 798-818, in particular page 804 et seq.

Die erfindungsgemäß verwendeten haarkonditionierenden Mittel liegen vorzugsweise als wäßrige Emulsion, Mikroemulsion, Dispersion oder opakes oder transparentes Gel vor, und können auch als Aerosole konfektioniert werden. The hair conditioning agent used in the invention are preferably present as aqueous emulsion, microemulsion, dispersion or opaque or transparent gel before, and can also be formulated as aerosols. Solche Zusammensetzungen und ihre Herstellung sind dem Fachmann grundsätzlich bekannt und bedürfen daher keiner näheren Erläuterung. Such compositions and their preparation are known in the art in principle and hence require no further explanation.

Der pH-Wert der erfindungsgemäßen Haarbehandlungsmittel ist nicht kritisch; The pH of the hair treatment compositions of the invention is not critical; er kann vorzugsweise bei 3 bis etwa 8, insbesondere zwischen 4 und 6, 5, liegen. it can preferably 3 to about 8, in particular between 4 and 6, 5, lie.

Die folgenden Beispiele dienen der Illustration der Erfindung. The following examples serve to illustrate the invention.

Beispiel 1 example 1

In eine Haar-Aufbaukur der Zusammensetzung In a hair-revitalizing composition

Cetrimoniumchlorid cetrimonium 2,5 (Gew.-%) 2.5 (wt .-%)
Di-C 12 -C 15 -alkyldimoniumchlorid Di-C 12 -C 15 -alkyldimoniumchlorid 0,6 (Gew.-%) 0.6 (wt .-%)
Behensäure behenic 6,0 (Gew.-%) 6.0 (wt .-%)
Benzyloxyethanol benzyloxyethanol 3,5 (Gew.-%) 3.5 (wt .-%)
Ethoxydiglykol ethoxydiglycol 5,0 (Gew.-%) 5.0 (wt .-%)
Hydroxyethylcellulose hydroxyethyl 0,5 (Gew.-%) 0.5 (wt .-%)
Polyquaternium-4 Polyquaternium-4 0,2 (Gew.-%) 0.2 (wt .-%)
Glycerin glycerin 35,0 (Gew.-%) 35.0 (wt .-%)
Isopropylpalmitat isopropyl palmitate 0,5 (Gew.-%) 0.5 (wt .-%)
PEG-30 Steareth-4 PEG-30 Steareth-4 1,0 (Gew.-%) 1.0 (wt .-%)
Stearinsäure stearic acid 2,0 (Gew.-%) 2.0 (wt .-%)
Dimethicone Dimethicone 5,0 (Gew.-%) 5.0 (wt .-%)
Dimethicone Methylether Dimethicone methyl ether 1,0 (Gew.-%) 1.0 (wt .-%)
Parfum Perfume 0,3 (Gew.-%) 0.3 (wt .-%)
Natriumhydroxid sodium hydroxide 0,5 (Gew.-%) 0.5 (wt .-%)
Wasser water ad 100,0 (Gew.-%) 100.0 (wt .-%)

wurden, unter entsprechender Verringerung des Wassergehalts, 0,5 Gew.-% Grüner Tee- Extrakt eingearbeitet. were, with a corresponding reduction of the water content, 0.5 wt .-% incorporated Green tea extract.

Beide Zusammensetzungen wurden im Halbseitenversuch auf je eine Hälfte dauergewellten Haares aufgebracht und nach dem Einarbeiten und Trocknen die Eigenschaften beider Haarhälften verglichen. Both compositions were applied in a half side test on each half permed hair and compared the properties of both halves of hair after incorporation and drying.

Die mit der erfindungsgemäßen Zusammensetzung behandelte Haarhälfte wies gegenüber der mit der bekannten Haar-Aufbaukur behandelten Haarhälfte eine deutlich verbesserte, über längere Zeit anhaltende Formbeständigkeit auf. The group treated with the inventive composition hair half pointed towards the group treated with the known hair-revitalizing hair half a significantly improved over long periods of time lasting dimensional stability.

Beispiel 2 example 2

In eine Emulsion der Zusammensetzung In an emulsion of the composition

Cetrimoniumchlorid cetrimonium 3,0 (Gew.-%) 3.0 (wt .-%)
Talgtrimoniumchlorid tallowtrimonium chloride 0,3 (Gew.-%) 0.3 (wt .-%)
Benzyloxyethanol benzyloxyethanol 2,0 (Gew.-%) 2.0 (wt .-%)
Ethoxydiglykol ethoxydiglycol 10,0 (Gew.-%) 10.0 (wt .-%)
Behensäure behenic 6,0 (Gew.-%) 6.0 (wt .-%)
Glykolsäure glycolic acid 0,7 (Gew.-%) 0.7 (wt .-%)
Hydroxyethylcellulose hydroxyethyl 0,4 (Gew.-%) 0.4 (wt .-%)
Isostearylpentaerythrylglycerylether Isostearylpentaerythrylglycerylether 0,3 (Gew.-%) 0.3 (wt .-%)
Glycerin glycerin 30,0 (Gew.-%) 30.0 (wt .-%)
Polyquaternium-7 Polyquaternium-7 0,3 (Gew.-%) 0.3 (wt .-%)
PEG-20 Steareth-4 PEG-20 Steareth-4 1,5 (Gew.-%) 1.5 (wt .-%)
Trideceth-12 Trideceth-12 0,4 (Gew.-%) 0.4 (wt .-%)
Stearinsäure stearic acid 2,0 (Gew.-%) 2.0 (wt .-%)
Parfum Perfume 0,5 (Gew.-%) 0.5 (wt .-%)
Dimethiconol Dimethiconol 0,4 (Gew.-%) 0.4 (wt .-%)
Amodimethicone amodimethicone 0,3 (Gew.-%) 0.3 (wt .-%)
Natriumhydroxid sodium hydroxide 1,2 (Gew.-%) 1.2 (wt .-%)
Weizenkeimöl Wheat germ oil 0,3 (Gew.-%) 0.3 (wt .-%)
Wasser water ad 100,0 (Gew.-%) 100.0 (wt .-%)

wurden 0,2 Gew.-% Grüner Tee-Extrakt unter entsprechender Verringerung des Wassergehalts eingearbeitet. 0.2 wt .-% green tea extract were incorporated with corresponding reduction of the water content.

Analog dem in Beispiel 1 beschriebenen Verfahren wurden beide Zusammensetzungen im Halbseitenversuch an gefärbtem Haar verglichen. Both compositions were compared to dyed hair in a half side test analogous to that described in Example 1.

Die mit der erfindungsgemäßen Zusammensetzung behandelte Haarhälfte wies einen deutlich verbesserten Glanz und eine verbesserte Farbintensität auf, die auch über längere Zeit anhielt. The group treated with the inventive composition hair half had a significantly improved gloss and improved color intensity, which continued for a long time.

Beispiel 3 example 3 Leave-on Lotion Leave-on lotion
Distearyldimethylammoniumchlorid distearyldimethylammonium 0,6 (Gew.-%) 0.6 (wt .-%)
Amodimethicone amodimethicone 2,0(Gew.-%) 2.0 (wt .-%)
Aminosäuren (L-Arginin + D-Glucosamin.HCl) Amino acids (L-arginine + D-Glucosamin.HCl) 0,5(Gew.-%) 0.5 (wt .-%)
Polyquaternium-11 Polyquaternium-11 0,3(Gew.-%) 0.3 (wt .-%)
Pyrrolidon-2-carbonsäure, Natriumsalz Pyrrolidone-2-carboxylic acid, sodium salt 0,2(Gew.-%) 0.2 (wt .-%)
Citronensäure citric acid 0,2(Gew.-%) 0.2 (wt .-%)
Milchsäure lactic acid 0,1(Gew.-%) 0.1 (wt .-%)
Glyoxylsäure glyoxylic 0,5(Gew.-%) 0.5 (wt .-%)
Grüner Tee-Extrakt Green tea extract 0,5(Gew.-%) 0.5 (wt .-%)
PEG-40 Hydriertes Ricinusöl PEG-40 hydrogenated castor oil 0,3(Gew.-%) 0.3 (wt .-%)
Panthenol panthenol 1,0(Gew.-%) 1.0 (wt .-%)
Tocopherolacetat tocopherol 0,1(Gew.-%) 0.1 (wt .-%)
Parfum Perfume 0,3(Gew.-%) 0.3 (wt .-%)
Konservierungsmittel preservative 0,3(Gew.-%) 0.3 (wt .-%)
Wasser water ad 100,0(Gew.-%) 100.0 (wt .-%)

Diese Zusammensetzung gibt gefärbtem und dauergewelltem Haar eine langdauernde Färbung und verlängert die Haltbarkeit der Frisur. This composition is dyed and permed hair a long-lasting coloration, and extends the shelf life of the hairstyle.

Claims (3)

  1. 1. Verwendung eines Mittels auf wäßriger Basis, enthaltend 1. Use of a composition on aqueous basis, comprising
    • a) mindestens eine quaternäre Ammoniumverbindung mit mindestens einer Alkyl- bzw. Alkenylgruppe mit 10 bis 22 Kohlenstoffatomen; a) at least one quaternary ammonium compound having at least one alkyl or alkenyl group having 10 to 22 carbon atoms;
    • b) Grünen Tee-Extrakt; b) green tea extract; und and
    • c) ein kationisches Polymer c) a cationic polymer
    zur Verbesserung der Farbstabilität und/oder Formbeständigkeit von gefärbten und/oder dauergewellten Haaren. to improve color stability and / or dimensional stability of dyed and / or permed hair.
  2. 2. Verwendung eines Mittels nach Anspruch 1, enthaltend 0,1 bis 10 Gew.-% Grünen Tee- Extrakt, berechnet als Trockenmasse auf die Gesamtzusammensetzung des Mittels. 2. Use of an agent according to claim 1 containing 0.1 to 10 wt .-% Green tea extract, calculated as dry matter on the total composition.
  3. 3. Verwendung eines Mittels nach Anspruch 1 und/oder 2, enthaltend 0,25 bis 5,0 Gew.-% Grünen Tee-Extrakt, berechnet als Trockenmasse auf die Gesamtzusammensetzung des Mittels. 3. Use of an agent according to claim 1 and / or 2, containing 0.25 to 5.0 wt .-% green tea extract, calculated as dry matter on the total composition.
DE1997135865 1997-08-19 1997-08-19 Aqueous formulation useful as hair conditioner, treatment or leave-on lotion Expired - Fee Related DE19735865C1 (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10133203A1 (en) * 2001-07-07 2003-01-16 Beiersdorf Ag Topical compositions containing catechins and/or their gallate esters, useful e.g. for treating or preventing dry skin or inflammatory conditions of the skin, e.g. eczema, polymorphic light dermatosis or psoriasis
EP1321131A2 (en) * 2001-12-22 2003-06-25 Henkel Kommanditgesellschaft auf Aktien Colour protection
FR2841467A1 (en) * 2002-06-28 2004-01-02 Oreal Cosmetic composition comprising a quaternary silicone, a cation, two cationic polymers and cosmetic treatment process
EP1787686A1 (en) * 2005-11-16 2007-05-23 L'Oréal Composition and process for coloring hair
EP1787682A1 (en) * 2005-11-16 2007-05-23 L'Oréal Process for inhibiting dyed hair fibers from losing their color during shampooing
FR2915376A1 (en) * 2007-04-30 2008-10-31 Oreal Use of a multi-carbo multi-site moieties coupling agent to protect the color vis-a-vis the washing keratin fibers artificially dyed; staining methods
US7727288B2 (en) 2005-11-16 2010-06-01 L'oreal Process for styling dyed hair and inhibiting its color loss during shampooing
US7871599B2 (en) 2002-07-05 2011-01-18 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Hair treatment compositions containing xanthine and alpha hydroxy acid
FR2964319A1 (en) * 2010-09-06 2012-03-09 Oreal cosmetic composition comprising at least one cationic polymer and at least two surfactants
DE102012215968A1 (en) 2012-09-10 2013-06-06 Henkel Ag & Co. Kgaa Use of condensation product made of hydrolyzed protein and carboxylic acid, as stabilizing agent for artificially generated hair dye, for reducing fading of artificially generated hair dye after hair treatment, and in hair treatment agent
EP2609903A1 (en) * 2011-12-29 2013-07-03 KPSS-Kao Professional Salon Services GmbH Method of treating artificially coloured hair

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DE3320539A1 (en) * 1982-06-07 1983-12-08 Kao Corp hair cosmetics
DE3442175A1 (en) * 1984-11-17 1986-05-28 Henkel Kgaa Conditioning hair care products

Patent Citations (2)

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DE3320539A1 (en) * 1982-06-07 1983-12-08 Kao Corp hair cosmetics
DE3442175A1 (en) * 1984-11-17 1986-05-28 Henkel Kgaa Conditioning hair care products

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10133203A1 (en) * 2001-07-07 2003-01-16 Beiersdorf Ag Topical compositions containing catechins and/or their gallate esters, useful e.g. for treating or preventing dry skin or inflammatory conditions of the skin, e.g. eczema, polymorphic light dermatosis or psoriasis
EP1321131A2 (en) * 2001-12-22 2003-06-25 Henkel Kommanditgesellschaft auf Aktien Colour protection
EP1321131A3 (en) * 2001-12-22 2004-09-01 Henkel Kommanditgesellschaft auf Aktien Colour protection
FR2841467A1 (en) * 2002-06-28 2004-01-02 Oreal Cosmetic composition comprising a quaternary silicone, a cation, two cationic polymers and cosmetic treatment process
EP1378227A1 (en) * 2002-06-28 2004-01-07 L'oreal Cosmetic composition comprising a quaternary silicone, a cationic surfactant and two cationic polymers, as well as cosmetic treatment process
US7871599B2 (en) 2002-07-05 2011-01-18 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Hair treatment compositions containing xanthine and alpha hydroxy acid
US8236743B2 (en) 2005-11-16 2012-08-07 L'oréal Process for inhibiting dyed hair fibers from losing their color during shampooing
US8648023B2 (en) 2005-11-16 2014-02-11 L'oréal Process for inhibiting dyed hair fibers from losing their color during shampooing
US7449029B2 (en) 2005-11-16 2008-11-11 L'oreal Composition and process for color hair
US7727288B2 (en) 2005-11-16 2010-06-01 L'oreal Process for styling dyed hair and inhibiting its color loss during shampooing
EP1787686A1 (en) * 2005-11-16 2007-05-23 L'Oréal Composition and process for coloring hair
EP1787682A1 (en) * 2005-11-16 2007-05-23 L'Oréal Process for inhibiting dyed hair fibers from losing their color during shampooing
FR2915376A1 (en) * 2007-04-30 2008-10-31 Oreal Use of a multi-carbo multi-site moieties coupling agent to protect the color vis-a-vis the washing keratin fibers artificially dyed; staining methods
EP1997473A3 (en) * 2007-04-30 2015-04-15 L'Oréal Use of a multi-carbosite, multi-group coupling agent for protecting the colour of artificially dyed keratin fibres with respect to washing; dyeing processes
CN103079537A (en) * 2010-09-06 2013-05-01 莱雅公司 Cosmetic composition comprising at least one cationic polymer and at least two cationic surfactants
WO2012032055A1 (en) * 2010-09-06 2012-03-15 L'oreal Cosmetic composition comprising at least one cationic polymer and at least two cationic surfactants
FR2964319A1 (en) * 2010-09-06 2012-03-09 Oreal cosmetic composition comprising at least one cationic polymer and at least two surfactants
EP2609903A1 (en) * 2011-12-29 2013-07-03 KPSS-Kao Professional Salon Services GmbH Method of treating artificially coloured hair
WO2013098210A1 (en) * 2011-12-29 2013-07-04 Kao Germany Gmbh Method of treating artificially coloured hair
DE102012215968A1 (en) 2012-09-10 2013-06-06 Henkel Ag & Co. Kgaa Use of condensation product made of hydrolyzed protein and carboxylic acid, as stabilizing agent for artificially generated hair dye, for reducing fading of artificially generated hair dye after hair treatment, and in hair treatment agent

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