DE917505C - Process for the preparation of resinous condensation products - Google Patents

Process for the preparation of resinous condensation products

Info

Publication number
DE917505C
DE917505C DEB7348D DEB0007348D DE917505C DE 917505 C DE917505 C DE 917505C DE B7348 D DEB7348 D DE B7348D DE B0007348 D DEB0007348 D DE B0007348D DE 917505 C DE917505 C DE 917505C
Authority
DE
Germany
Prior art keywords
condensation products
preparation
resinous condensation
resinous
ammonia
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB7348D
Other languages
German (de)
Inventor
Dr Hans Bueren
Dr Friedrich Christmann
Dr Heinz Lemme
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DEI58939D external-priority patent/DE727116C/en
Application filed by BASF SE filed Critical BASF SE
Priority to DEB7348D priority Critical patent/DE917505C/en
Application granted granted Critical
Publication of DE917505C publication Critical patent/DE917505C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F240/00—Copolymers of hydrocarbons and mineral oils, e.g. petroleum resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/22—Alkylation reaction products with aromatic type compounds, e.g. Friedel-crafts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/101—Condensation polymers of aldehydes or ketones and phenols, e.g. Also polyoxyalkylene ether derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Verfahren zur Herstellung harzartiger Kondensationsprodukte Zusatz zum Patent 32'7 116 Gegenstand des Hauptpatents ist ein Verfahren zur Herstellung von harzartigen Verbindungen, das darin besteht, daß man ungesättigte Kohlenstoffverbindungen auf einen Kohlenstoffring enthaltende harzartige Stoffe in Gegenwart von Lösungsmitteln, die im wesentlichen aus Chlorkohlenwasserstoffen oder chlorierten Äthern bestehen, unter Vermittlung von Borfluorid oder einer mit Fluorverbindungen behandelten Bleicherde einwirken läßt.Process for the production of resinous condensation products Additive to Patent 32'7 116 The main patent relates to a method of manufacture of resinous compounds, which consists in being unsaturated carbon compounds resinous substances containing a carbon ring in the presence of solvents, which essentially consist of chlorinated hydrocarbons or chlorinated ethers, with the mediation of boron fluoride or a bleaching earth treated with fluorine compounds can act.

Im Zusatzpatent 915 505 wird vorgeschlagen, statt der im Hauptpatent genannten Chlorkohlenwasserstoffe die entsprechenden Verbindungen der übrigen Halogene, insbesondere von Brom und Jod, zu verwenden. Die Abtrennung der Lösungsmittel aus dem Endprodukt geschieht nach dem Verfahren des Hauptpatents durch Destillation und Erhitzen des Reaktionsproduktes im Vakuum.In the additional patent 915 505 it is proposed to use the corresponding compounds of the other halogens, in particular bromine and iodine, instead of the chlorinated hydrocarbons mentioned in the main patent. The solvent is separated from the end product according to the process of the main patent by distillation and heating of the reaction product in vacuo.

Es wurde nun gefunden, daß man besonders hochmolekulare Produkte erhalten kann, wenn man in die durch Einwirkung von ungesättigten Kohlenwasserstoffen auf harzartige Stoffe erhaltene zähflüssige Masse Ammoniak einleitet und hierauf das Lösungsmittel abdestilliert. Dabei entweicht das in der Masse enthaltene Borfluorid als Molekülverbindung mit Ammoniak. Unter dem Einfluß des Ammoniaks bleibt das Molekulargewicht der Kondensationsprodukte, das bei der bisher üblichen Entfernung des Lösungsmittels durch Destillation vermindert wurde, erhalten, was dann von besonderer Bedeutung ist, wenn die gewonnenen harzartigen Verbindungen auf Isoliermassen oder ähnliche Stoffe verarbeitet werden sollen.It has now been found that particularly high molecular weight products are obtained can if you get into the by the action of unsaturated hydrocarbons on Resin-like substances obtained viscous mass ammonia introduces and then the Solvent distilled off. The boron fluoride contained in the mass escapes as a molecular compound with ammonia. The molecular weight remains under the influence of ammonia the condensation products that occur during the previously customary removal of the solvent reduced by distillation was received, what then was special It is important if the resin-like compounds obtained on insulating masses or similar substances are to be processed.

Beispiel 45 Gewichtsteile Polystyrol (mittleres Molgewicht etwa 12o ooo) und 55 Gewichtsteile Butylen werden in 3oo Gewichtsteilen Äthylenchlorid gelöst und bei Zimmertemperatur einige Stunden mit Borfluorid behandelt. In die entstandene zähflüssige Masse leitet man Ammoniak ein und destilliert hierauf das Äthylenchlorid ab, wobei das in der Masse enthaltene Borfluorid als Molekülverbindung mit Ammoniak entweicht. Durch Trocknen des Reaktionsproduktes im Vakuum bei etwa zoo° erhält man .ein walzbares Produkt, das in der Wärme elastisch ist.Example 45 parts by weight of polystyrene (average molecular weight about 12o ooo) and 55 parts by weight of butylene are dissolved in 300 parts by weight of ethylene chloride and treated with boron fluoride for a few hours at room temperature. In the resulting viscous mass is passed in ammonia and then the ethylene chloride is distilled from, the boron fluoride contained in the mass as a molecular compound with ammonia escapes. Obtained by drying the reaction product in vacuo at about zoo ° a rollable product that is elastic when exposed to heat.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung harzartiger Verbindungen, dadurch gekennzeichnet, daß in die nach dem Verfahren des Patents 727 116 oder des Zusatzpatents gz5 5o5 erhaltenen zähflüssigen Massen Ammoniak eingeleitet und anschließend das Lösungsmittel abdestilliert wird. PATENT CLAIM: Process for the production of resinous compounds, characterized in that the viscous masses of ammonia obtained by the process of patent 727 116 or the additional patent gz5 505 are introduced and the solvent is then distilled off.
DEB7348D 1937-08-28 1937-12-21 Process for the preparation of resinous condensation products Expired DE917505C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB7348D DE917505C (en) 1937-08-28 1937-12-21 Process for the preparation of resinous condensation products

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEI58939D DE727116C (en) 1937-08-28 1937-08-28 Process for the preparation of resinous condensation products
DEB7348D DE917505C (en) 1937-08-28 1937-12-21 Process for the preparation of resinous condensation products

Publications (1)

Publication Number Publication Date
DE917505C true DE917505C (en) 1954-09-06

Family

ID=25964864

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB7348D Expired DE917505C (en) 1937-08-28 1937-12-21 Process for the preparation of resinous condensation products

Country Status (1)

Country Link
DE (1) DE917505C (en)

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