DE910884C - Process for the treatment of cellulose-containing textiles - Google Patents
Process for the treatment of cellulose-containing textilesInfo
- Publication number
- DE910884C DE910884C DEZ693D DEZ0000693D DE910884C DE 910884 C DE910884 C DE 910884C DE Z693 D DEZ693 D DE Z693D DE Z0000693 D DEZ0000693 D DE Z0000693D DE 910884 C DE910884 C DE 910884C
- Authority
- DE
- Germany
- Prior art keywords
- parts
- copper oxide
- treatment
- ammonia
- cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 12
- 239000004753 textile Substances 0.000 title claims description 9
- 229920002678 cellulose Polymers 0.000 title claims description 4
- 239000001913 cellulose Substances 0.000 title claims description 4
- DBNPDRYVYQWGFW-UHFFFAOYSA-N N.[Cu]=O Chemical compound N.[Cu]=O DBNPDRYVYQWGFW-UHFFFAOYSA-N 0.000 claims description 23
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 15
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000000344 soap Substances 0.000 claims description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- NSEQHAPSDIEVCD-UHFFFAOYSA-N N.[Zn+2] Chemical class N.[Zn+2] NSEQHAPSDIEVCD-UHFFFAOYSA-N 0.000 claims description 3
- -1 aliphatic fatty acids Chemical class 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 2
- 125000001477 organic nitrogen group Chemical group 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 9
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
- 239000008149 soap solution Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 229920000875 Dissolving pulp Polymers 0.000 description 1
- 241000784732 Lycaena phlaeas Species 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
- ATUAEKLEUALEBS-UHFFFAOYSA-N copper;azane Chemical compound N.N.[Cu+2] ATUAEKLEUALEBS-UHFFFAOYSA-N 0.000 description 1
- ZURAKLKIKYCUJU-UHFFFAOYSA-N copper;azane Chemical compound N.[Cu+2] ZURAKLKIKYCUJU-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
- D06M11/62—Complexes of metal oxides or complexes of metal salts with ammonia or with organic amines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Verfahren zur Behandlung cellulosehaltiger Textilien Es ist bereits bekannt, Textilien, die aus Cellulose bestehen, mit Kupferoxydammoniaklösungen zu behandeln, sei es, indem man die Kupferoxydammoniaklösung aufträgt oder das textile Gebilde durch solche Lösungen durchführt. Infolge der Eigenschaft der Kupferoxydammoniaklösungen, Cellulose rasch zu lösen, lassen sich durch die gekennzeichnete Behandlung mannigfaltige Wirkungen erzielen. In Sonderheit bezweckt man mit der Behandlung ein Schließen bzw. Verkleben der textilen Oberfläche, um das Gewebe wasserabstoßend zu machen. Die Behandlung mit Kupferoxydammoniak hat daher bei der Herstellung von Wagenplanen, Zelten oder ähnlichen Erzeugnissen zunehmend an Bedeutung gewonnen.Method of treating cellulosic textiles It is already known to textiles made of cellulose with copper oxide ammonia solutions treat, be it by applying the copper oxide ammonia solution or the textile Performs structures through such solutions. Due to the property of the copper oxide ammonia solutions, Rapidly dissolving cellulose can be varied by the treatment indicated Achieve effects. In particular, the aim of the treatment is closing or gluing the textile surface to make the fabric water-repellent. The treatment with copper oxide ammonia has therefore in the manufacture of tarpaulin, Tents or similar products are becoming increasingly important.
Es wurde nun gefunden, daß sich durch das vorliegende Verfahren diese bekannte Behandlungsweise in technisch wertvoller Weise und in bisher unbekanntem Maße erweitern läßt. Man erhält bei gleichartiger Verwendungsweise Erzeugnisse, welche sich gegenüber dem Bekannten durch Fülle, Weichheit und Elastizität auszeichnen, ohne daß die wasserabweisende Wirkung darunter leidet, wenn man den Kupferoxydammoniaklösungen verfahrensgemäß Lösungen komplexer Kupfer- bzw. Zinkammoniumverbindungen niederer aliphatischer Fettsäuren, - sogenannter Vorlauffettsäuren und l oder Lösungen von mehrwertigen 3#,letallseifen höherer Fettsäuren, in anorganischen oder organischen stickstoffhaltigen Basen zusetzt.It has now been found that this known method of treatment in a technically valuable manner and in a previously unknown manner Can expand dimensions. If the method of use is the same, one obtains products which are characterized by their fullness, softness and elasticity compared to the familiar, without the water-repellent effect suffering if one uses the copper oxide ammonia solutions according to the method, solutions of complex copper or zinc ammonium compounds of lower more aliphatic Fatty acids, - so-called pre-run fatty acids and l or solutions of polyvalent 3 #, lethal soaps of higher fatty acids, in inorganic or organic nitrogenous bases are added.
Demgegenüber hat die Behandlung von Textilien mit gewöhnlichen Kupferoxydammoniaklösungen den Nachteil, da,ß das Gewebe hart und sperrig wird, so, daß die geschlossene Oberfläche leicht bricht.In contrast, the treatment of textiles with common copper oxide ammonia solutions the disadvantage that the fabric becomes hard and bulky, so that the closed surface breaks easily.
Die- chemisch wohldefinierten komplexen Metallverbindungen niederer aliphatischer Fettsäuren sowie die Seifen mehrwertiger Metalle, die sich in anorganischen oder organischen Stickstoffhasen lösen, sind in Wasser allein praktisch unlöslich. Die wäßrigen ammoniakalischen oder pyridinhaltigen Lösungen dieser Metallverbindungen hinterlassen beim Verdunsten die näher gekennzeichneten Komplexverbindungen bzw. Metallseifen, die an sich in Wasser schwer bzw. unlöslich sind. Es ist daher schon als ein technisch wertvoller Fortschritt zu bezeichnen, daß es gemäß vorliegendem Verfahren möglich ist. den Kupferoxydammoniaklösungen diese Verbindungen zuzusetzen, wobei die zuzusetzende Menge in weiten Grenzen schwanken kann, ohne daß störende Ausfällungen entstehen. Das Verfahren gestattet aber auch, das textile Gewebe zuerst mit den Komplex- bzw. Metallverbindungen zu behandeln und nachträglich die gewohnte Behandlung mit Kupferoxydammoniaklösung vorzunehmen. Es gestattet ferner, in gleicher Weise umgekehrt zunächst ein Gewebe in gewohnter Weise mit Kupferoxydammonial: zu behandeln und es anschließend im Sinn des beanspruchten Verfahrens zu behandeln. Außerdem kann man gleichzeitig Komplexverbindungen und Metallseifen den Behandlungsbädern zusetzen.The chemically well-defined complex metal compounds of lower aliphatic fatty acids as well as the soaps of polyvalent metals, which are in inorganic or organic nitrogen phases are practically insoluble in water alone. The aqueous ammoniacal or pyridine-containing solutions of these metal compounds When evaporating, leave behind the complex compounds or Metal soaps that are difficult or insoluble in water. So it is to be described as a technically valuable advance that it is in accordance with the present Procedure is possible. to add these compounds to the copper oxide ammonia solutions, the amount to be added can vary within wide limits without disturbing Precipitations arise. The process also allows the textile fabric first to treat with the complex or metal compounds and subsequently the usual Treatment with copper oxide ammonia solution. It also allows in the same Conversely, first assign a fabric in the usual way with copper oxydammonial: to treat and then treat it in the sense of the claimed method. In addition, complex compounds and metal soaps can be added to the treatment baths at the same time to add.
Nachdem es darüber hinaus bekannt ist, Metallseifen. die in Ammoniak bzw. Pyridin oder Triäthanolamin löslich sind, in technischem Maßstab herzustellen, kann man das Verfahren auch derart ausüben, daß man der Kupferoxydammoniaklösung die feste Metallseife als solche zusetzt und darin auflöst. Das Verfahren wird durch folgende Beispiele näher gekennzeichnet. Beispiel i iooTeilenKupferoxydammonialclösung,die 3o gll Kupferoxydammoniak enthält, setzt man 1o Teile einer komplexen Zinkammoniumverbindung-gemäß folgender Zusammensetzung zu: 15 Teile Zinkchlorid, 5o Teile Ammoniak konzentriert, 32 Teile Wasser, 3o Teile sogenannter Vorlauffettsäuren. Beispiel 2 ioo Teilen Kupferoxydammoniaklösung, die 2o g%1 Kupferoxydammoniak enthält, setzt man 15 Teile einer komplexen Kupferammoniumverhindung zu, die wie folgt zusammengesetzt ist: 18 Teile Kupferacetat, 75 Teile Ammoniak konzentriert, 1 8 Teile Wasser, 3o Teile Vorlauffettsäure. Beispiel 3 ioo Teilen Kupferoxydammoniaklösung (i : i) setzt man 2o Teile einer ammoniakalischen Metall-Seifenlösung zu, die wie folgt zusammengesetzt ist: 15 Teile vorlauffcttsaures Zink, go Teile Wasser. 35 Teile Ammoniak konzentriert.After it is also known, metallic soaps. those in ammonia or pyridine or triethanolamine are soluble, to be produced on an industrial scale, you can also practice the process in such a way that the copper oxide ammonia solution the solid metal soap as such adds and dissolves in it. The procedure is through the following examples are identified in more detail. Example iooShare copper oxide ammonium solution that Contains 30 gll copper oxide ammonium, one adds 10 parts of a complex zinc ammonium compound according to the following composition: 15 parts zinc chloride, 50 parts concentrated ammonia, 32 parts of water, 3o parts of so-called pre-run fatty acids. Example 2 100 parts of copper oxide ammonia solution, which contains 20 g% 1 copper ammonium ammonia, 15 parts of a complex copper ammonium compound are used to, which is composed as follows: 18 parts of copper acetate, 75 parts of ammonia concentrated, 18 parts of water, 3o parts of initial fatty acid. Example 3 ioo parts Copper oxide ammonia solution (i: i) is used to add 20 parts of an ammoniacal metal soap solution to, which is composed as follows: 15 parts of zinc preliquor, go parts Water. 35 parts concentrated ammonia.
Beispiel 4 ioo Teilen Kupferoxydammoniaklösung, die 30 gll Kupferoxydammoniak enthält, setzt man :2o Teile einer pyridinigen Metallseifenlösung zu, die wie folgt zusammengesetzt ist: 15 Teile vorlauffettsaures Zink, 2o Teile Wasser, 35 Teile Pyridin technisch.EXAMPLE 4 100 parts of copper oxide ammonia solution containing 30 μl of copper oxide ammonia are added: 2o parts of a pyridine metal soap solution which is composed as follows: 15 parts of zinc precursor, 2o parts of water, 35 parts of technical pyridine.
Beispiels ioo Teilen Kupferoxydammoniaklösung, die 30 gr/1 Kupferoxydammoniak enthält, setzt man 2o `feile einer alkylolaminhaltigen Metallseifenlösung zu, die wie folgt zusammengesetzt ist: 15 Teile vorlauffettsaures Zink, 35 Teile Wasser. 35 Teile Triäthanolamin, 5 Teile Spiritus.For example, 100 parts of copper oxide ammonia solution containing 30 g / l of copper oxide ammonia is added to 20 parts of an alkylolamine-containing metal soap solution, which is composed as follows: 15 parts of zinc precursor, 35 parts of water. 35 parts triethanolamine, 5 parts alcohol.
Beispiel 6 ioo Teilen Kupferoxydammoniaklösung, die 3o g11 Kupferoxydammoniak enthält, setzt man 5 Teile vorlauffettsaures Zink zu und rührt bis zur Lösung.Example 6 100 parts of copper oxide ammonia solution, the 3o g11 copper oxide ammonia contains, 5 parts of pre-run fatty acid zinc are added and the mixture is stirred until it dissolves.
Beispiel? ioo Teilen Kupferoxydammoniaklösung, die 20 g/1 Kupferoxvdammoniak enthält, setzt man 2o Teile einer #fetallseifenlösung nachstehender Zusammensetzung zu: 15 Teile kokosfettsaures Zink, 9o Teile Wasser, 6o Teile Ammoniak konzentriert, 2o Teile Spiritus.Example? 100 parts of copper oxide ammonia solution, which contains 20 g / l of copper oxide ammonia, are added to 2o parts of a metal soap solution of the following composition: 15 parts of coconut fatty acid zinc, 90 parts of water, 60 parts of concentrated ammonia, 2o parts of alcohol.
In Flotten, die wahlweise je nach dem gewünschten Effekt eine Zusammensetzung gemäß der Beispiele 1 bis 7 haben, werden cellulosehaltige Textilien nach an sich bekannten Verfahren behandelt und auf übliche Weise fertiggestellt.In liquors, which optionally have a composition depending on the desired effect according to Examples 1 to 7, cellulose-containing textiles are per se Treated known methods and completed in the usual way.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ693D DE910884C (en) | 1941-08-26 | 1941-08-26 | Process for the treatment of cellulose-containing textiles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ693D DE910884C (en) | 1941-08-26 | 1941-08-26 | Process for the treatment of cellulose-containing textiles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE910884C true DE910884C (en) | 1954-05-06 |
Family
ID=7617857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEZ693D Expired DE910884C (en) | 1941-08-26 | 1941-08-26 | Process for the treatment of cellulose-containing textiles |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE910884C (en) |
-
1941
- 1941-08-26 DE DEZ693D patent/DE910884C/en not_active Expired
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