DE904099C - Leather fatliquor - Google Patents

Leather fatliquor

Info

Publication number
DE904099C
DE904099C DEB7409D DEB0007409D DE904099C DE 904099 C DE904099 C DE 904099C DE B7409 D DEB7409 D DE B7409D DE B0007409 D DEB0007409 D DE B0007409D DE 904099 C DE904099 C DE 904099C
Authority
DE
Germany
Prior art keywords
leather
leather fatliquor
fatliquor
acid number
oxidation products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB7409D
Other languages
German (de)
Inventor
Dr Michael Aschenbrenner
Dr Michael Jahrstorfer
Dr Gerhard Otto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DEB7409D priority Critical patent/DE904099C/en
Application granted granted Critical
Publication of DE904099C publication Critical patent/DE904099C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
    • C14C9/02Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes using fatty or oily materials, e.g. fat liquoring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Description

Lederfettungsmittel Gegenstand des Patents 896 697 sind Lederfettungsmittel mit einem, Gehalt an Stoffgemischen, welche durch teilweise Oxydation von -sehr hochmolekularen. a.liphatischen, praktisch gesättigten Kohlenwasserstoffenbis zu einer Säurezahl wesentlich unterhalb derjenigen, die sich unter Annahme einer Carboxyl.gruppe je Durchschnittsmolekül des Ausgang;sstoffes errechnet, erhalten werden.Leather fatliquor The subject of patent 896 697 is leather fatliquor with a content of mixtures of substances, which by partial oxidation of -very high molecular weight. a.liphatic, practically saturated hydrocarbons up to an acid number significantly below that which is calculated assuming one carboxyl group per average molecule of the starting material.

Es wurde nun gefunden, diaß man die mit solchen Enzeugn.issen hergestellten Lederfettungsmitteli noch verbessern, kann, wenn. man, ihnen Oxyd:at;ion@sprodukte von bei gewöhnlicher Temperatur flüssigen gesättigten oder teilweise ungesättigten höhermolekuliaren Kohlenwasserstoffen oder ihren Chlorierungspradukten zusetzt. Die Kohlenwasserstoffe können. z. B. durch Hydrieren von Kohlenoxyd erhalten. sein.It has now been found that one produced with such products Leather oiling agents can improve, if. man, them Oxyd: at; ion @ products of saturated or partially unsaturated ones that are liquid at ordinary temperature adding higher molecular hydrocarbons or their chlorination products. The hydrocarbons can. z. B. obtained by hydrogenation of carbon oxide. be.

Durch den Zusatz dieser Oxydationsprodukte erhält man Ledenfettungsmittel, die in dass Leder besonders leicht eindringen. Sie machen das Leder gut wasserabweisend und verleihen ihm einen vollen, geschmeidigen Griff.By adding these oxidation products, leather fat-giving agents are obtained, which penetrate the leather particularly easily. They make the leather well water repellent and give it a full, supple grip.

Beispiel i ioo kg abgeweliktes Fablleder werden. im Heiß-1u@ftifaß ibei 6o° mit ig kg eines I.ede:rfettu:ngsmi ttels gewalkt, das durch Zuisam,menschmelzen. von gleichen Teilen von Tran, @Degras und einer Mischung aus 25"/o eines bis zur Säurezahl, 4o oxydierten, hochschmelzenden Paraffins aus der Kohlenoxy.dhydrierung und 75% eines zwischen Zoo bis 35o° siedenden, bis zur Säurezahl 35 oxydierten Koh ,lenwasserstoffgemi.sches hergestellt wurde. Man erhält ein hochwertiges Fahlleder von. gutem Griff und guter Wasserabweisung, wie man es sonst nur durch entsprechenden Zusatz eines guten Talgs zur Fettschmiere erhält. Beispiele ioo kg abgewelktes Blankleder wenden ,mit einer Mischung .aus o,6 kg des im Bespiel i erwähnten Oxydationspro.dul,ts, von hochschmelzendem Paraffin (Säurezahl 4o), 2,4 kg eines bis zur Säurezahl 40 oxydierten Chlorierungsprodukts von flüssigen Paraffinen aus der Kohlenoxydhydrierung (Siede-Bereich 22o bis 32o°), i,4 kg Tran und i,6 kg Degras von Hand geschmiert. Dann walkt ,man es i Stunde im Heißluftfaß bei etiwa 55°. Man erhält ein im Griff, in der wasserahweisenden Wirkung und in allen sonstigen Eigenschaften einwandfreies Blankleder.Example ioo kg of worn-out leather will become. in the hot 1u @ ftifaß Ibei 60 ° with ig kg of an I.ede: rfettu: ngsmi ttels tumbled, that through Zuisam, human melting. of equal parts of Tran, @Degras and a mixture from 25 "/ o a high-melting paraffin from carbo-oxyhydrogenation, which is oxidized up to the acid number 4o and 75% of a Koh which boils between zoo and 35o ° and is oxidized to an acid number of 35 , Hydrogen Mixture was produced. A high quality pale leather is obtained from. good grip and good water repellency, as otherwise only possible with the appropriate Good sebum is added to the grease. Examples 100 kg of withered leather turn, with a mixture of 0.6 kg of the oxidation process mentioned in example i, of high-melting paraffin (acid number 4o), 2.4 kg of one up to acid number 40 oxidized chlorination product of liquid paraffins from carbohydrate hydrogenation (Boiling range 22o to 32o °), 1.4 kg of Tran and 1.6 kg of Degras lubricated by hand. Then you mill it for an hour in a hot air barrel at around 55 °. You get a grip Impeccable in the water-repellent effect and in all other properties Bare leather.

Claims (1)

PATENTANSPRUCH: Lederfettungsmittel nach Patent 896697, dadurch gekennzeichnet, daß das Lederfettungsmittel neben den im Hauptpatent beschriebenen Oxydationsprodukten Oxydationsprodukte von bei gewöhnlicher Temperatur flüssigen, gegebenenfalls chlorierten gesättigten oder teilweise ungesättigten höhermolekularen Kohlenwasserstoffen enthält.PATENT CLAIM: Leather fatliquor according to patent 896697, characterized in that the leather fatliquor contains, in addition to the oxidation products described in the main patent, oxidation products of optionally chlorinated saturated or partially unsaturated higher molecular weight hydrocarbons which are liquid at ordinary temperature.
DEB7409D 1943-08-14 1943-08-14 Leather fatliquor Expired DE904099C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB7409D DE904099C (en) 1943-08-14 1943-08-14 Leather fatliquor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB7409D DE904099C (en) 1943-08-14 1943-08-14 Leather fatliquor

Publications (1)

Publication Number Publication Date
DE904099C true DE904099C (en) 1954-02-15

Family

ID=6955346

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB7409D Expired DE904099C (en) 1943-08-14 1943-08-14 Leather fatliquor

Country Status (1)

Country Link
DE (1) DE904099C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2231753A1 (en) * 1973-06-01 1974-12-27 Basf Ag

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2231753A1 (en) * 1973-06-01 1974-12-27 Basf Ag

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