DE894898C - Disinfectants - Google Patents

Disinfectants

Info

Publication number
DE894898C
DE894898C DEF2690D DEF0002690D DE894898C DE 894898 C DE894898 C DE 894898C DE F2690 D DEF2690 D DE F2690D DE F0002690 D DEF0002690 D DE F0002690D DE 894898 C DE894898 C DE 894898C
Authority
DE
Germany
Prior art keywords
disinfectants
chloride
urea
ammonium
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEF2690D
Other languages
German (de)
Inventor
Friedrich Dr Leuchs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Priority to DEF2690D priority Critical patent/DE894898C/en
Application granted granted Critical
Publication of DE894898C publication Critical patent/DE894898C/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Paper (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

Desinfektionsmittel Es wurde gefunden, daß die quaternären Ammoniumverbindungen, die mindestens einen höheren aliphatischen Kohlenwasserstoffrest imMolekül enthalten und in denen das quaternäre Stickstoffatom über wenigstens zwei Kohlenstoffatome an die Harnstoffgruppierung einer Alkylharnstoff- bzw. Acylharlistoff-, -thioharnstoff- oder -guanididgruppe gebunden und im übrigen durch Alkyl- bzw. Aralkylreste besetzt ist, guteDesinfektionsmittelsind. DieneuenVerbindungen zeigen neben einer guten allgemeinen Desinfektionswirkung besonders gegenüber Tuberkelbazillen Desinfektionseigenschaften.Disinfectants It has been found that the quaternary ammonium compounds, which contain at least one higher aliphatic hydrocarbon radical in the molecule and in which the quaternary nitrogen atom has at least two carbon atoms to the urea grouping of an alkylurea or acylharlistoff, -thiourea- or -guanididgruppe bound and otherwise occupied by alkyl or aralkyl radicals are good disinfectants. The new connections show next to a good one general disinfectant effect especially against tubercle bacilli disinfectant properties.

In ihrer Wirkung gegen Tuberkelbazillen sind sie den als Desinfektionsmitteln bekannten hochmolekularen Aminen und Ammoniumverbindungen überlegen. i'/,ige Lösungen des salzsauren Dodecylguanidins (USA.-Patentschrift 2213474, Beispieli), ferner i0/,ige Lösungen von Dodecyl-dimethylbenzyl-ammoniumchlorid oder von Dodecyl-dimethyl-3,4-dichlorbenzyl-ammoniumchlorid töten Tuberkelbazillen im Laufe von 2 Stunden nicht ab, während dies bei il/,igen Lösungen von Dodezyl-dimethyl-(3, 4-dichlorbenzylmethyl)-ursidoacetyl-ammoniumchlorid (Beispiel 4 der vorliegenden Erfindung) stets der Fall ist. Die Wirkung gegen Coli und Staphylococcen der Lösungen der angeführten Stoffe ist dagegen praktisch ziemlich gleichwertig.In their action against tubercle bacilli, they are used as disinfectants superior to known high molecular weight amines and ammonium compounds. i '/, ige solutions of hydrochloric acid dodecylguanidine (US Pat. No. 2213474, Examplei), furthermore 10% solutions of dodecyl-dimethylbenzyl-ammonium chloride or of dodecyl-dimethyl-3,4-dichlorobenzyl-ammonium chloride do not kill tubercle bacilli within 2 hours, while this does so with il /, igen Solutions of dodecyl dimethyl (3, 4-dichlorobenzylmethyl) ursidoacetyl ammonium chloride (Example 4 of the present invention) is always the case. The effect against coli and staphylococcal of the solutions of the substances mentioned is, on the other hand, practically quite equivalent to.

Insbesondere haben sich die folgenden Verbindungen als wertvoll erwiesen: Dodecyldimethyl-ureidoacetylammoniumchlorid, Myristyl-dimathylb,-nzviureido- acetyl-arninoniumchlorid,- -Dodecyldimetliyl-p-chlor- benzylureidoacetyl animoniumchlorid,Dodecvldimethyl (3, 4-dichlorbenzylmethyl)-ureidoacetyl-ammonium- chlorid, Dodecyldimethyl - benzylureidopropionyl- ammoniumchlorid, Myristyl-dimethyl-m-oxyphenyl- ureidoacetyl-ammoniumchlorid, Cetyl-dimethyl-ben- zylureidoacetyl-ammoniumbromid, Benzyl-dimethyl- dodecylureidoacetyl-ammoniumbromid, Benzyl-dime- thyl-dodecylureidoacetyl-ammoniumchlorid, Myristyl- dimethyl-benzylthioureidoacetyl-ammoniumchlorid, Dodecyl-dimethylguanido-acetylarnmoniumchlorid, Dodecylureidoacetyl - (p - chlorbenzyldimethyl) - am- moniumchlorid, Guanidopropyl-myristyl-dimethyl- ammoniumbromid. Die Darstellung der neuen Verbindungen kann in üblicher Weise erfolgen.In particular, the following compounds have proven to be valuable: Dodecyldimethyl-ureidoacetylammonium chloride, myristyl-dimathylb, -nzviureido- acetyl-arninoniumchlorid, - -Dodecyldimetliyl-p -chlor- benzylureidoacetyl ammonium chloride, dodecvldimethyl (3, 4-dichlorobenzylmethyl) -ureidoacetyl-ammonium- chloride, dodecyldimethyl - benzylureidopropionyl- ammonium chloride, myristyl-dimethyl-m-oxyphenyl- ureidoacetylammonium chloride, cetyldimethylben- zylureidoacetyl ammonium bromide, benzyl dimethyl dodecylureidoacetylammonium bromide, benzyldime- ethyl dodecylureidoacetyl ammonium chloride, myristyl dimethyl-benzylthioureidoacetyl-ammonium chloride, Dodecyl-dimethylguanido-acetylammonium chloride, Dodecylureidoacetyl - (p - chlorobenzyldimethyl) - am- monium chloride, guanidopropyl myristyl dimethyl ammonium bromide. The new compounds can be presented in the usual way.

Claims (1)

PATFNTANSPRUCH-' Desinfektionsmittel, bestehend aus oder enthaltend eine quaternäre Ammoniumverbindung, die mindestens einen höheren aliphatischen Kohlenwasserstoffrest im Molekül enthält und in der das quaternäre Stickstoffatom über wenigstens zwei KohIenstoffatome an die Harnstoffgruppierung einer Alkylharnstoff- bzw. Acylhamstoff-, -thioharnstoff- oder -guanididgruppe gebunden und im übrigen durch Alkyl- bzw. Aralkylreste besetzt ist.PATFNTANSPRUCH- 'Disinfectants, consisting of or containing a quaternary ammonium compound containing at least one higher aliphatic hydrocarbon radical contains in the molecule and in which the quaternary nitrogen atom has at least two Carbon atoms on the urea grouping of an alkyl urea or acyl urea, -thiourea or -guanididgruppe bound and otherwise by alkyl or aralkyl radicals is busy.
DEF2690D 1941-01-16 1941-01-16 Disinfectants Expired DE894898C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEF2690D DE894898C (en) 1941-01-16 1941-01-16 Disinfectants

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF2690D DE894898C (en) 1941-01-16 1941-01-16 Disinfectants

Publications (1)

Publication Number Publication Date
DE894898C true DE894898C (en) 1953-10-29

Family

ID=7083405

Family Applications (1)

Application Number Title Priority Date Filing Date
DEF2690D Expired DE894898C (en) 1941-01-16 1941-01-16 Disinfectants

Country Status (1)

Country Link
DE (1) DE894898C (en)

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