DE894897C - Disinfectants and preservatives - Google Patents

Disinfectants and preservatives

Info

Publication number
DE894897C
DE894897C DEB18069A DEB0018069A DE894897C DE 894897 C DE894897 C DE 894897C DE B18069 A DEB18069 A DE B18069A DE B0018069 A DEB0018069 A DE B0018069A DE 894897 C DE894897 C DE 894897C
Authority
DE
Germany
Prior art keywords
parts
preservatives
product
disinfectants
action
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB18069A
Other languages
German (de)
Inventor
Oskar Dr Flieg
Josef Dr Mittermair
Conrad Dr Schoeller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DEB18069A priority Critical patent/DE894897C/en
Application granted granted Critical
Publication of DE894897C publication Critical patent/DE894897C/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04Sulfonic acids; Derivatives thereof
    • A01N41/06Sulfonic acid amides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02Amines; Quaternary ammonium compounds
    • A01N33/04Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)

Description

Desinfektions- und Konservierungsmittel Im Patent Boa 346 sind Desinfektions- und Konservierungsmittel beschrieben, die durch einen Gehaltan Polymeri.sationsprodukten des Ät!hylenimins oder seiner polymerissationsfähigen Homologen, und Substitutionsprodukte gekennzeichnet sind.Disinfectants and preservatives In the Boa 346 patent, disinfectants and preservatives are described, which are characterized by a content of polymerization products of ethylene imine or its polymerisable homologues, and substitution products Marked are.

Es wurde nun gefunden, daß sich für .die gleichen Zwecke ebenso und zum Teil noch besser diejenigen Produkte eignen, die .man erhält, indem man i, 2-Alkylenimine auf Salze von basischen organischen Stickstoffverbindungen einwirken läßt, die am Stickstoff mindestens i Wasserstoffatom tragen.It has now been found that for the same purposes and In some cases, those products are even better which are obtained by using i, 2-alkylenimines can act on salts of basic organic nitrogen compounds, which am Nitrogen carry at least one hydrogen atom.

Besonders geeignet sind die Einwirkungsprodukte von Äthylenimin auf Salze solcher Stickstoffverbindun:gen:, die einen .aromatischen, oder aliphatischen Rest mit mindestens 6 Kohlenstoffatomen enthalten, also z. B. auf Salze des p-Phenylendiamins, der Tol@uylendi.amine, der Aminosal,icyl,säuren, der Aminobenzoesäuren und Aminophenole, des p-Am.inobenzolsulfamids und seiner Derivate, ferner die Polyäthyleniminderivate des Stearyl-, Oleyl-oder Do,decylamins, des Dodecyläthylendiamins, des Ste;a;rylbiguani,d@ins, des Stearoyltriäthylentetramins und seiner Umsetzungsprodukte mit Chloressigsäure.The products of action of ethyleneimine are particularly suitable Salts of such nitrogen compounds: which are aromatic or aliphatic Contain a remainder with at least 6 carbon atoms, so z. B. on salts of p-phenylenediamine, the Tol@uylendi.amine, the aminosal, icyl, acids, the aminobenzoic acids and aminophenols, des p-Am.inobenzolsulfamids and its derivatives, also the polyethyleneimine derivatives of stearyl, oleyl or do, decylamine, dodecylethylenediamine, ste; a; rylbiguani, d @ ins, of stearoyltriethylenetetramine and its reaction products with chloroacetic acid.

Die durch Umsetzen von Ät.hylenimin mit den genannten Salzen von Stickstoffverbindungen hergestellten Produkte können also solche oder in Form der freien Basen oder .der in Üblicher Weise hergestellten quaternären Ammoniumsalze verwendet werden. Man kann sie für sich oder z. B. zusammen mit anderen Desinfektions- und, Konservierungsmitteln, mit Salbengrundlagen, Fetten, Wirkstoffen oder kapillanakti@ven Verbindungen zu Pudern bzw. Pasten, Cremes, Reinigungs- oder kosmetischen Mitteln verarbeiten, Appretur- oder Gerbmitteln zusetzen oder .zu Schädlingsbekämpfungsmitteln verarbeiten. Beispiel i Man versetzt eine durch Verskleistern von 5oo g Kartoffelmehl ,mit io 1 Wasser erhaltene Appreturmasse mit 25 g Marseiller Seife und,mit 5 g eines Produktes, das durch Einwirkung von 8o Mol Äthylenimin .auf i Mol Stearyl,aminacetat erhalten wurde. Die Masse bleibt lange Zeit schimmelfrei. Beispiel 2 Einem Pflanzenschleim oder Gelatine und Glycerin enthaltenden kosmetischen Präparat setzt man o,i 1/o ,des Einwirkungsproduktes von 2o Mol Äthylen.imin auf i Mol Oktodecylaminacetat zu. Dias Präparat ist gegen bakterielle Einflüsse widerstandsfähiger b.zw. lagerbeständiger als ohne -diesen Zusatz. -Beispiel 3 2o Teile des Einwirkungsproduktes von io Mol Athylenimin auf i Mol des salzsauren Salzes der p-Aminabernzoesäure werden mit 4 Teilendes Einwirkungsproduktes von 15 Mol Äthylenoxyd auf i Mol Ölsäureäthanol.amid und 76 Teilen Wasser vermischt. 2°/aige Lösungen dieses Präparats eignen sich u. a. zum Reinigen und Desinfizieren von Milchflaschen.By reacting Ät.hylenimin with the mentioned salts of nitrogen compounds Manufactured products can be such or in the form of free bases or produced in the usual way quaternary ammonium salts are used will. You can use them for yourself or z. B. together with other disinfection and, Preservatives, with ointment bases, fats, active ingredients or capillary-active substances Connections to powders or pastes, creams, cleaning agents or cosmetic agents process, add finishing or tanning agents or pesticides to process. Example i One is added by pasting 500 g of potato flour , with 10 1 of water obtained finishing mass with 25 g of Marseille soap and, with 5 g of one Product obtained by the action of 80 moles of ethylene imine on 1 mole of stearyl amine acetate was obtained. The mass remains mold-free for a long time. Example 2 A plant slime or cosmetic preparation containing gelatin and glycerol is added o, i 1 / o , the product of action of 20 moles of ethylene imine on 1 mole of octodecylamine acetate to. The preparation is more resistant to bacterial influences. more stable than without this addition. Example 3 2o parts of the product of action of 10 mol Ethylenimine to 1 mole of the hydrochloric acid salt of p-aminabernzoic acid are mixed with 4 Dividing action product of 15 moles of ethylene oxide to 1 mole of oleic acid ethanol amide and 76 parts of water mixed. 2% solutions of this preparation are, among other things, suitable. a. for cleaning and disinfecting milk bottles.

Beispiel 4 Man löst in 75 Teilen Wasser io Teile des Einwirkungsprodluktes von 5 bis io Mol Äthylenimin auf i Mol ödes salzsauren Salzes von p-Aminobenzolsulfamiid und 15 Teile des Einwirkungsproduktes von 8 Mol Äthylenoxyd auf i Mol Kokosfettalkohol. Man erhält eine viskose Lösung, welche, mit Wasser im Verhältnis i : ioo verdünnt, zum Reinigen und Desinfizieren von ärztlichen Instrumenten Verwendung finden kann. Beispiel 5 Man mischt 4o Teile Vaseline mit 5 Teilen des Kondensationsproduktes von Ölsäure mit Diiäthanolarnin, 45 Teilen eines Polyäthylengly'koläthers vom ungefähren Molekulargewicht 2700 und io Teilen des Einwirkungsproduktes von 40 Mol Äthyleni.min auf i Mol CHleylaminacetat. Das Präparat eignet sich als .bakterizides Melkfett.EXAMPLE 4 In 75 parts of water, 10 parts of the product of action of 5 to 10 moles of ethyleneimine to 1 mole of dehydrated hydrochloric acid salt of p-aminobenzene sulfamide and 15 parts of the product of action of 8 moles of ethylene oxide to 1 mole of coconut fatty alcohol are dissolved. A viscous solution is obtained which, diluted with water in the ratio i: 100, can be used for cleaning and disinfecting medical instruments. EXAMPLE 5 40 parts of petroleum jelly are mixed with 5 parts of the condensation product of oleic acid with diethanolamine, 45 parts of a polyethylene glycol ether of approximate molecular weight 2700 and 10 parts of the product of 40 mol of ethylene min to 1 mol of chleylamine acetate. The preparation is suitable as a bactericidal milking fat.

Claims (1)

PATENTANSPRUCH: Des,infektions- und Konservierungsmittel in Weiterb.il,dung des Patents 802 346, gekennzeichnet durch einen Gehalt an den durch-Umsetzen von i, 2-Alkyleniminen mit Salzen von basischen stickstoffhaltigen organischen Verbindungen erhältlichen Produkten bzw. den entsprechenden freien-Basen oder den .daraus in üblicher Weise hergestellten quaternärenAmmoniumsalzen. PATENT CLAIM: Des, infectious and preservative in further development of the patent 802 346, characterized by a content of the products obtainable by reacting i, 2-alkylenimines with salts of basic nitrogen-containing organic compounds or the corresponding free bases or the quaternary ammonium salts prepared therefrom in the customary manner.
DEB18069A 1951-12-07 1951-12-07 Disinfectants and preservatives Expired DE894897C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB18069A DE894897C (en) 1951-12-07 1951-12-07 Disinfectants and preservatives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB18069A DE894897C (en) 1951-12-07 1951-12-07 Disinfectants and preservatives

Publications (1)

Publication Number Publication Date
DE894897C true DE894897C (en) 1953-10-29

Family

ID=6959580

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB18069A Expired DE894897C (en) 1951-12-07 1951-12-07 Disinfectants and preservatives

Country Status (1)

Country Link
DE (1) DE894897C (en)

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