DE864855C - Process for mercerizing - Google Patents
Process for mercerizingInfo
- Publication number
- DE864855C DE864855C DEB7617D DEB0007617D DE864855C DE 864855 C DE864855 C DE 864855C DE B7617 D DEB7617 D DE B7617D DE B0007617 D DEB0007617 D DE B0007617D DE 864855 C DE864855 C DE 864855C
- Authority
- DE
- Germany
- Prior art keywords
- mercerizing
- carbon atoms
- alkylolamines
- glycols
- mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 150000002334 glycols Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- MVVQNBYRSDXHRF-UHFFFAOYSA-N 2-[2-hydroxyethyl(2-methylpropyl)amino]ethanol Chemical compound CC(C)CN(CCO)CCO MVVQNBYRSDXHRF-UHFFFAOYSA-N 0.000 description 3
- 238000009992 mercerising Methods 0.000 description 3
- 238000005517 mercerization Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- GVNHOISKXMSMPX-UHFFFAOYSA-N 2-[butyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCN(CCO)CCO GVNHOISKXMSMPX-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- -1 alkyl diethanolamines Chemical class 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 241000567769 Isurus oxyrinchus Species 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatment Of Fiber Materials (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Verfahren zum Mercerisieren Es wurde gefunden, daß Mercerisierlaugen, die Alkylolamine mit mindestens einem mehr als 2 Kohlenstoffatome enthaltenden Rest und außerdem zur Erzielung klarer Lösungen ausreichende Mengen von Glykolen, vorzugsweise solchen mit mehr als 3 Kohlenstoffatomen im Molekül, enthalten, eine hervorr agende Netzwirkung für .Baumwolle besitzen und daher zur Durchführung der Mercerisation, beispielsweise von Rohbaumwolle, ganz vorzüglich geeignet sind. Man kann vorteilhaft die Alkylolamine und Glykole zunächst miteinander vermischen und diese fertigen Gemische dann der Mercerisierlauge zusetzen. Andererseits können beide Arten von Verbindungen auch getrennt, gleichzeitig oder nacheinander den Mercerisierlaugen zugesetzt werden.Process for mercerizing It has been found that mercerizing liquors, the alkylolamines with at least one radical containing more than 2 carbon atoms and also sufficient amounts of glycols, preferably to achieve clear solutions those with more than 3 carbon atoms in the molecule, an excellent one Have a net effect for cotton and therefore to carry out the mercerization, for example of raw cotton, are extremely suitable. One can be beneficial First mix the alkylolamines and glycols with one another and prepare them Then add mixtures to the mercerizing liquor. On the other hand, both types of Connections also separately, simultaneously or in succession to the mercerising liquors can be added.
Vorzüglich geeignet sind beispielsweise einerseits die Alkyldiäthanolamine, insbesondere solche, die im Molekül einen organischen-Rest mit mehr als 2 Iiohlenstoffatomen aufweisen, wie iso- oder n-Butyldiäthanolamin und andererseits Propylenglykol oder Butylenglykol.On the one hand, the alkyl diethanolamines, for example, are particularly suitable, especially those which have an organic radical with more than 2 Iiohlenstoffatomen in the molecule have, such as iso- or n-butyl diethanolamine and on the other hand propylene glycol or Butylene glycol.
Die Mengenverhältnisse beider Arten von Verbindungen können weitgehend abgeändert werden; beispielsweise kann man 5 bis q.o Teile des Alkylolamins mit 95 bis 6o Teilen des Glykols mischen. Es ist bereits bekannt, Mercerisierlaugen zwecks Erhöhung der Netzfähigkeit Gemische aus Phenolen und mehrwertigen Alkoholen der aliphatischen, araliphatischen oder alicyclischen Reihe, welche mindestens i Kohlenstoffatom mehr als Hydroxylgruppen enthalten, oder Gemische aus Phenolen und stickstoffhaltigen organischen Basen zuzusetzen. Diesen Gemischen sind die neuen Mercerisiernetzmittelgemische aus Glykolen und Alkylolaminen mit mindestens einem mehr als 2 Kohlenstoffatome enthaltenden Rest durch ihre bessere bziv. schnellere Netzwirkung überlegen. Beispiel i Man vermischt n-Butyldiäthanolamin mit Propylenglykol im Gewichtsverhältnis 35: 65. In einer Mercerisierlauge von 3o bis 32'° Be löst man je Liter iö g des genannten Gemisches.The proportions of the two types of compounds can be largely changed; for example, 5 to qo parts of the alkylolamine can be mixed with 95 to 60 parts of the glycol. It is already known that mercerizing liquors can be added to mixtures of phenols and polyhydric alcohols of the aliphatic, araliphatic or alicyclic series, which contain at least one carbon atom more than hydroxyl groups, or mixtures of phenols and nitrogen-containing organic bases, in order to increase the wetting ability. These mixtures are the new mercerizing wetting agent mixtures of glycols and alkylolamines with at least one radical containing more than 2 carbon atoms by their better bziv. superior to faster meshing. Example I is mixed n-butyldiethanolamine with propylene glycol in the weight ratio 35: 65. In a mercerization of 3o to 32 '° Be to per liter dissolves IÖ g of said mixture.
Die so erhaltene Mercerisierlauge übt auf Rohmakogarn eine außerordentlich schnelle Mercerisierwirkung aus. Beispiel 2 Man vermischt iso-Butyldiäthanolamin mit i, 2-oder i, 3-Butylenglykol im Gewichtsverhältnis 25 :75. In einer Mercerisierlauge von 32° Be löst man ie Liter io z der zenannten Mischunz. Die erhaltene Lauge läßt sich mit besonderem Vorteil für die Stückmercerisation verwenden, wobei sehr schöne Glanzwirkungen erzielt werden. In dieser Weise mercerisierte Stücke lassen sich in sehr befriedigender Weise färben.The mercerizing liquor obtained in this way has an extraordinary effect on raw mako yarn rapid mercerising effect. Example 2 Isobutyl diethanolamine is mixed with i, 2- or i, 3-butylene glycol in a weight ratio of 25:75. In a mercerising liquor from 32 ° Be one resolves the liter io z of the zen named mixed ounce. The lye obtained leaves Use with particular advantage for piece mercerization, with very beautiful Gloss effects can be achieved. Pieces mercerized in this way can be color in a very satisfactory way.
Man kann die Mercerisierlauge auch herstellen, indem man das iso-Butyldiäthanolamin und das Butylenglykol getrennt, gleichzeitig oder nacheinander in beliebiger Reihenfolge in die Lauge unter Rühren einträgt.The mercerizing liquor can also be produced by using the isobutyl diethanolamine and the butylene glycol separately, simultaneously or sequentially in any order enters the liquor with stirring.
Claims (1)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB7617D DE864855C (en) | 1936-06-14 | 1936-06-14 | Process for mercerizing |
| GB19051/36A GB475675A (en) | 1936-06-14 | 1936-07-09 | Improvements in and relating to mercerising liquors |
| FR822052D FR822052A (en) | 1936-06-14 | 1937-05-21 | Process for preparing mercerizing liquors |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB7617D DE864855C (en) | 1936-06-14 | 1936-06-14 | Process for mercerizing |
| GB19051/36A GB475675A (en) | 1936-06-14 | 1936-07-09 | Improvements in and relating to mercerising liquors |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE864855C true DE864855C (en) | 1953-01-29 |
Family
ID=25964870
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB7617D Expired DE864855C (en) | 1936-06-14 | 1936-06-14 | Process for mercerizing |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE864855C (en) |
| FR (1) | FR822052A (en) |
| GB (1) | GB475675A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE593048C (en) * | 1926-10-29 | Chem Fab Vormals Sandoz | Process to increase the wetting ability of mercerising liquors | |
| AT133113B (en) * | 1926-10-29 | 1933-05-10 | Chem Fab Vormals Sandoz | Process for increasing the wetting ability of alkalizing liquids. |
| AT137298B (en) * | 1926-10-29 | 1934-04-25 | Chem Fab Vormals Sandoz | Process for increasing the wetting ability of alkalizing liquids. |
-
1936
- 1936-06-14 DE DEB7617D patent/DE864855C/en not_active Expired
- 1936-07-09 GB GB19051/36A patent/GB475675A/en not_active Expired
-
1937
- 1937-05-21 FR FR822052D patent/FR822052A/en not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE593048C (en) * | 1926-10-29 | Chem Fab Vormals Sandoz | Process to increase the wetting ability of mercerising liquors | |
| AT133113B (en) * | 1926-10-29 | 1933-05-10 | Chem Fab Vormals Sandoz | Process for increasing the wetting ability of alkalizing liquids. |
| AT137298B (en) * | 1926-10-29 | 1934-04-25 | Chem Fab Vormals Sandoz | Process for increasing the wetting ability of alkalizing liquids. |
Also Published As
| Publication number | Publication date |
|---|---|
| FR822052A (en) | 1937-12-20 |
| GB475675A (en) | 1937-11-24 |
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