DE863549C - Process for the production of condensation products - Google Patents

Process for the production of condensation products

Info

Publication number
DE863549C
DE863549C DEC2406D DEC0002406D DE863549C DE 863549 C DE863549 C DE 863549C DE C2406 D DEC2406 D DE C2406D DE C0002406 D DEC0002406 D DE C0002406D DE 863549 C DE863549 C DE 863549C
Authority
DE
Germany
Prior art keywords
condensation products
production
parts
oleic acid
chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEC2406D
Other languages
German (de)
Inventor
Walter Dr Brunner
Werner Dr Zerweck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cassella Farbwerke Mainkur AG
Original Assignee
Cassella Farbwerke Mainkur AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cassella Farbwerke Mainkur AG filed Critical Cassella Farbwerke Mainkur AG
Priority to DEC2406D priority Critical patent/DE863549C/en
Application granted granted Critical
Publication of DE863549C publication Critical patent/DE863549C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paints Or Removers (AREA)

Description

Verfahren zur Herstellung von Kondensationsprodukten Es wurde gefunden, daß man wertvolle Kondensationsprodukte verhält, wenn man Halogenide von ungesättigten höheren Carbonsäuren, insbesondere von Ölsäure, der Einwirkung von kondeinsierend wirkenden Metallhalogeniden mit oder ohne Zusatz von Kohlenwasserstoffei unterwirft.Process for the production of condensation products It has been found that one behaves valuable condensation products when one halides of unsaturated higher carboxylic acids, especially of oleic acid, the action of condensing acting metal halides with or without the addition of hydrocarbons.

Als Ausgangskörper seien neben den Halogeniden derölsäure beispielsweise die der Eläostearinsäure, Linolsäure, Ricinensäure und des Tallöls genannt. Als kondensierend wirkendes Metallhalogenid kommt vor allem Aluminiumchlorid, als Kohlenwasserstoff Benzol und seine Substitutionsprodukte, wie Chlorbenzol, Toluol, Xylol iu. dgl., in Betracht. Je nach den Reaktionsbedingungen, insbesondere bez"uglich Temperatur !und Dauer, erhält man nach vorliegendem Verfahren Kondensationsprodukte von der Art selbsttrocknender Öle, Lackharze, Weichmacher oder auch gummiartiger Erzeugnisse.In addition to the halides, oleic acid may be used as starting bodies, for example called those of elaostearic acid, linoleic acid, ricinic acid and tall oil. as metal halide with a condensing effect is mainly aluminum chloride, as a hydrocarbon Benzene and its substitution products, such as chlorobenzene, toluene, xylene iu. like., into consideration. Depending on the reaction conditions, especially with regard to the temperature ! and duration, condensation products are obtained from the Type of self-drying oils, lacquer resins, plasticizers or rubber-like products.

Die vorliegenden Reaktionsprodukte sind meist in den üblichen organischen Lösungsmitteln, wie Benzin, Äther, Aceton, Methylenchlorid, Butylacetat, Benzol und seinen Subs,titutionsprodukten, Tetrahydronaphthalin u. dgl. löslich; in Alkoholen sind sie wenig, in Alkalien nicht löslich. je nach den Eigenschaften sind sie für mannigfache Verwendungs7w:ecke geeignet, wie z. B. zur Herstellung von Macken, Tals .auch für Kitte und im der Textilindustrie, vor :allem für solche. Zwecke, für die bisher Leinöl verwendet wurde. Be ispi.,e.l 1- _ . . t41 Teile Ölsäure werden in das Chlarid über- "geführt -und hei -5 bis i o' mit 8o Teilen Aluminium- chlorid =unter -Rühren versetzt. Nach mehreren Stunden zersetzt man mit Eis und trennt das er- haltene Reaktionsprodukt von der wäßrigen Schicht. Es stellt in wasserfreiem Zustand ein hochviskoses Öl dar, - welches für ob:enerwähnte Zwecke ge- eignet ist. Beispiel z i oo Teile ölsäunechlorid werden in etwa 2oö Teilen Benzol mit 7oTeilen Aluminiumchlorid bei io bis 15° versetzt und, wie in Beispiel i angegeben, auf- gearbeitet. Dias zäh viskose Öl eignet sich vorzüg- lich zur Herstellung von Ansirichfarbien, Kitten, u. dgl. _ . Beispiel 3 i 41 Teile Ölsäure werden in das Chlorid -über- geführt und unter Zusatz von 26, 5 Teilen m-Xylol mit 8o Teilen Alunvaiümchlorid 'bei .etwa i ö°.' ver- setzt. Nach Aufarbeitung erhält man ein helles Öl, welches z. B. für Verwendung in der Textilindustrie geeignet ist. - - - - Beispiel 4 7o Teile Ölsäurie-h:o:id werden mit etwa i 5o Teil-,n Chlorbenzol verrührt und mit 6o Teilen Aluminium- chlorid versetzt, wobei allmählich die Temperatur auf 40', später bis ioo° gesteigert wird. Das er- haltene gummiartige Produkt ist als Emulsion oder in. Lösung für Imprägnierungszwecke geeignet. The present reaction products are mostly soluble in the usual organic solvents such as gasoline, ether, acetone, methylene chloride, butyl acetate, benzene and its substitution products, tetrahydronaphthalene and the like; they are not very soluble in alcohols and not soluble in alkalis. Depending on their properties, they are suitable for a wide range of uses, such as B. for the production of Quirks, valley. Also for putty and in the Textile industry, especially: for those. Purposes, for which was previously used with linseed oil. Example 1- _. . t41 parts of oleic acid are converted into the chloride "led -und he -5 to io 'with 80 parts of aluminum- chloride = added with stirring. After Several Hours are decomposed with ice and the keep reaction product from the aqueous layer. In an anhydrous state it represents a highly viscous Oil represents - which for that: overall enerwähnte purposes is suitable. Example 100 parts of oleic acid chloride are roughly 20 parts Benzene with 70 parts of aluminum chloride at 10 to Offset by 15 ° and, as indicated in example i, worked. The viscous oil is particularly suitable Lich for the production of paints, putties, and the like _. Example 3 i 41 parts of oleic acid are converted into the chloride out and with the addition of 26.5 parts of m-xylene with 80 parts of aluminum chloride 'at about 1 °.' ver puts. After working up, a light-colored oil is obtained, which z. B. for use in the textile industry suitable is. - - - - Example 4 7o parts of oleic acid-h: o: id are mixed with about 15o part-, n Chlorobenzene stirred and mixed with 60 parts of aluminum chloride added, gradually increasing the temperature to 40 ', later increased to 100 °. The holding gummy product is available as an emulsion or in. Solution suitable for impregnation purposes.

Claims (1)

PATENTANSPRUCH:
Verfahren zur Herstellung von Kondensationsprodukten, dadurch gekennzeichnet, daß man HaFogenide ühg@sättigter höherer Carbonsäuren, insbesondere der Ölsäure, der Einwirkung von "kondensierend wirkenden Metallhalogenid@en mit ,oder ohne Zusatz von Kohlenwasserstoffen unterwirft:
PATENT CLAIM:
Process for the preparation of condensation products, characterized in that HaFogenide ühg @ saturated higher carboxylic acids, in particular oleic acid, are subjected to the action of "condensing metal halides with or without the addition of hydrocarbons:
DEC2406D 1944-12-05 1944-12-05 Process for the production of condensation products Expired DE863549C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEC2406D DE863549C (en) 1944-12-05 1944-12-05 Process for the production of condensation products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEC2406D DE863549C (en) 1944-12-05 1944-12-05 Process for the production of condensation products

Publications (1)

Publication Number Publication Date
DE863549C true DE863549C (en) 1953-01-19

Family

ID=7012910

Family Applications (1)

Application Number Title Priority Date Filing Date
DEC2406D Expired DE863549C (en) 1944-12-05 1944-12-05 Process for the production of condensation products

Country Status (1)

Country Link
DE (1) DE863549C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1165866B (en) * 1958-12-15 1964-03-19 Collo Rheincollodium Koeln G M Process for the production of factual products
US3328438A (en) * 1962-02-23 1967-06-27 Gen Mills Inc Polymerization of halogenated fatty acids and esters thereof using clay catalysts

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1165866B (en) * 1958-12-15 1964-03-19 Collo Rheincollodium Koeln G M Process for the production of factual products
US3328438A (en) * 1962-02-23 1967-06-27 Gen Mills Inc Polymerization of halogenated fatty acids and esters thereof using clay catalysts

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