DE857240C - As a carrier of an emission layer made of alkaline earth oxides serving for the indirectly heated cathode of an electrical discharge vessel - Google Patents

As a carrier of an emission layer made of alkaline earth oxides serving for the indirectly heated cathode of an electrical discharge vessel

Info

Publication number
DE857240C
DE857240C DET2319D DET0002319D DE857240C DE 857240 C DE857240 C DE 857240C DE T2319 D DET2319 D DE T2319D DE T0002319 D DET0002319 D DE T0002319D DE 857240 C DE857240 C DE 857240C
Authority
DE
Germany
Prior art keywords
layer
carrier
alkaline earth
electrical discharge
discharge vessel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DET2319D
Other languages
German (de)
Inventor
Alexander Dipl-Ing Schmidt
Ernst Dipl-Ing Woeckel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Telefunken AG
Original Assignee
Telefunken AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Telefunken AG filed Critical Telefunken AG
Priority to DET2319D priority Critical patent/DE857240C/en
Application granted granted Critical
Publication of DE857240C publication Critical patent/DE857240C/en
Expired legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J1/00Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
    • H01J1/02Main electrodes
    • H01J1/13Solid thermionic cathodes
    • H01J1/20Cathodes heated indirectly by an electric current; Cathodes heated by electron or ion bombardment
    • H01J1/26Supports for the emissive material

Landscapes

  • Solid Thermionic Cathode (AREA)

Description

Die Erfindung betrifft eine als Emission.sschichtträger dienende Hülse für die indirekt geheizte Kathode eines elektrrischen Entladungsgefäßes. Um eine Beeinflussung der Entladung durch das Magnetfeld des Heizstromes zu verhindern, hat man solche Hülsen bereits aus einer inneren Schicht einer bei der Betriebstemperatur ferromagnetischen Eisen-Kobalt-Legierung undeiner äußeren, den Emissionsstoff, z. B. ein Erdalkalioxyd, tragenden Nickelschicht hergestellt. Es hat sich aber gezeigt, daß solche Kathoden entweder die volle Emission entsprechender Kathoden mit Nickelhülse gar nicht erreichen oder nach kurzer Betriebsdauer verlieren. Wie Untersuchungen gezeigt haben, sind diese Mißerfolge auf eine Vergiftung der Emissionsschicht durch Eisen, welches aus der eisenhaltigen Unterlage in sie eindringt, zurückzuführen. Es ist auch bekannt, eine Eis-en-Kobalt-Hülse mit Kupfer zu überziehen und darauf dieEmissionsschicht aufzutragen. Die Erfahrung lehrt jedoch, daß eine Erda.lkalioxydschicht auf Kupfer schlechter haftet als auf Nickel und außerdem durch das schneller als Nickel verdampfende Kupfer vergiftet wird. Schließlich sei noch darauf hingewiesen, daß es bekannt ist, einem aus Nickel bestehenden Emissionsschichtträger reduzierende Stoffe, z. B. Titan, zuzusetzen. Die Erfindung bezweckt die Beseitigung der erwähnten Emissionsverschlechterung bei den mit einem Nickelüberzug versehe ten eisenhaltigen Kathodenhülsen.The invention relates to a sleeve serving as an emission layer carrier for the indirectly heated cathode of an electrical discharge vessel. To a To prevent the discharge from being influenced by the magnetic field of the heating current, one has such sleeves already from an inner layer one at the operating temperature ferromagnetic iron-cobalt alloy and an external, the emission substance, e.g. B. an alkaline earth oxide, bearing nickel layer made. But it has been shown that such cathodes either the full emission of corresponding cathodes with nickel sleeves not achieved at all or lose after a short period of operation. Like investigations have shown, these failures are due to a poisoning of the emission layer Iron, which penetrates from the ferrous substrate into them, to be traced back. It is also known to coat an iron-en-cobalt sleeve with copper and place it on it to apply the emission layer. Experience teaches, however, that a layer of alkaline earth oxide adheres worse to copper than to nickel and, moreover, because of that, it adheres faster than Nickel evaporating copper is poisoned. Finally, it should be noted that it is known to reduce an emission layer carrier made of nickel Substances, e.g. B. titanium to be added. The invention aims to eliminate those mentioned Deterioration in emissions in the nickel-plated ferrous ones Cathode sleeves.

Zu diesem Zweck wird bei einer als Träger einer Emissions.schic'hlt aus Erdalkalioxyden dienenden Hülse für die indirekt geheizte Kathode eines elektrischen Entladungsgefäßes, die aus einer inneren Schicht einer bei Betriebstemperatur ferromagnetischen Eisenlegierung, z. B. einer Eisen-Kobalt-Legierung, und einer äußeren, z. B. 5 li dicken Schicht aus Nickel; welches gegebenenfalls reduzierende Zusätze enthält, besteht, gemäß der Erfindung zwischen den beiden Schichten eine Zwischenschicht aus einem Metall oder einer Metallegierung, z. B. aus Kupfer oder Silber, angeordnet, die eine Diffusion des Eisens in die Emissionsstoffunterlage verhindert. Es ist auf diese Weise möglich, den :Nickelüberzug verhältnismäßig dünn zu halten und den Werkstoff Nickel sparsam zu verbrauchen.- Die Ursache dafür, daß eine Verschlechterung der Emissionsfähigkeit 'hier nicht mehr stattfindet, ist darin zu suchen, daß die sich bei den vorkommenden Temperaturen mit dem Eisen nicht legierende Zwischenschicht das Eindringen von Eisen in das Nickel und die Emissionsschicht verhindert.For this purpose, one is sent as a carrier of an issue made of alkaline earth oxyden serving sleeve for the indirectly heated cathode of an electrical Discharge vessel, which consists of an inner layer of a ferromagnetic at operating temperature Iron alloy, e.g. B. an iron-cobalt alloy, and an outer, z. B. 5 left thick layer of nickel; which may contain reducing additives, there is, according to the invention, an intermediate layer between the two layers made of a metal or a metal alloy, e.g. B. made of copper or silver, arranged, which prevents the iron from diffusing into the emission material substrate. It is In this way possible to keep the nickel coating relatively thin and the Use nickel as a material sparingly.- The cause of deterioration the emissivity 'no longer takes place here is to be sought in the fact that the An intermediate layer that does not alloy with the iron at the temperatures that occur prevents iron from penetrating the nickel and the emission layer.

In der Abbildung ist ein Schnitt durch ein Ausführungsbeispiel der Erfindung stark vergrößert dargestellt. Es ist i die ferromagnetische Schicht, 2 die- Zwischenschicht, 3 die Trägerschicht für den Emissionsstoff und 4 die emittierende Schicht.In the figure is a section through an embodiment of the Invention shown greatly enlarged. It is i the ferromagnetic layer, 2 the intermediate layer, 3 the carrier layer for the emission substance and 4 the emitting layer Layer.

Die Schicht i möge z. B. aus einer Eisen Kobalt-Legierung mit io oder mehr Prozent Kobalt, die Schicht 2 aus. Kupfer, die Schicht 3 aus Nickel mit geringen reduzierenden Zusätzen, wie z. B. Titan, die Schicht 4 aus den üblichen Barium- und Strontiumoxyden bestehen.The layer i may e.g. B. from an iron cobalt alloy with io or more percent cobalt, layer 2 off. Copper, the layer 3 made of nickel with low reducing additives, such as B. titanium, the layer 4 from the usual barium and strontium oxides.

Die Dicke der ferromagnetischen Schicht i muß entsprechend den jeweiligen Anforderungen entsprechend stark sein. Die Dicke der Schichten 2 und 3 kann sehr gering gewählt werden. Geeignete Schichtdicken sind z. 13. o, i mm für Schicht i, o,oo5 mm für Schicht 2, o,oo5 mm für Schicht 3.The thickness of the ferromagnetic layer i must correspond to the respective Be strong according to requirements. The thickness of layers 2 and 3 can be very be chosen low. Suitable layer thicknesses are e.g. 13. o, i mm for layer i, o, oo5 mm for layer 2, o, oo5 mm for layer 3.

Claims (1)

PATEN TA NS PR UC11: Als Träger einer Emissionsschicht aus Erdalkalioxyden dienende Hülse für die indirekt geheizte Kathode eines elektrischen Entladungsgefäßes, die aus einer inneren Schicht einer bei Betriebstemperatur ferromagnetischen Eisenlegierung, z. B. einer Eisen-Kobalt-Legierung, und einer äußeren, z. B. _5,u dicken Schicht aus Nickel, welches gegebenenfalls reduzierende Zusätze enthält, besteht, dadurch gekennzeichnet, daß zwischen den beiden Schichten eine Zwischenschicht aus einem Metall oder einer Metallegierung, z. B. aus Kupfer oder Silber, angeordnet ist, die eine Diffusion des Eisens in die Emissionsstoffunterlage verhindert. Angezogene Druckschriften: Osterreichische Patentschriften Nr. 148 305, 152 648; USA.-Patentschrift Nr. 2 1.10 534. PATEN TA NS P R UC11: Serving as a carrier of an emission layer made of alkaline earth oxides for the indirectly heated cathode of an electrical discharge vessel, which consists of an inner layer of an iron alloy ferromagnetic at operating temperature, e.g. B. an iron-cobalt alloy, and an outer, z. B. _5, u thick layer of nickel, which optionally contains reducing additives, characterized in that between the two layers an intermediate layer of a metal or a metal alloy, z. B. made of copper or silver, which prevents diffusion of the iron into the emission material substrate. Cited publications: Austrian Patent Specifications No. 148 305, 152 648; U.S. Patent No. 2,110,534.
DET2319D 1941-04-19 1941-04-19 As a carrier of an emission layer made of alkaline earth oxides serving for the indirectly heated cathode of an electrical discharge vessel Expired DE857240C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DET2319D DE857240C (en) 1941-04-19 1941-04-19 As a carrier of an emission layer made of alkaline earth oxides serving for the indirectly heated cathode of an electrical discharge vessel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DET2319D DE857240C (en) 1941-04-19 1941-04-19 As a carrier of an emission layer made of alkaline earth oxides serving for the indirectly heated cathode of an electrical discharge vessel

Publications (1)

Publication Number Publication Date
DE857240C true DE857240C (en) 1952-11-27

Family

ID=7543791

Family Applications (1)

Application Number Title Priority Date Filing Date
DET2319D Expired DE857240C (en) 1941-04-19 1941-04-19 As a carrier of an emission layer made of alkaline earth oxides serving for the indirectly heated cathode of an electrical discharge vessel

Country Status (1)

Country Link
DE (1) DE857240C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE942460C (en) * 1952-10-24 1956-05-03 Telefunken Gmbh Process for the production of oxide cathodes for electrical discharge tubes

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT148305B (en) * 1934-03-26 1937-01-11 Telefunken Gmbh Indirectly heatable hot cathode for discharge tubes.
AT152648B (en) * 1934-06-08 1938-02-25 Aeg Hot cathode for discharge vessels.
US2140534A (en) * 1937-01-11 1938-12-20 Ken Rad Tube And Lamp Corp Electrode for electron discharge devices

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT148305B (en) * 1934-03-26 1937-01-11 Telefunken Gmbh Indirectly heatable hot cathode for discharge tubes.
AT152648B (en) * 1934-06-08 1938-02-25 Aeg Hot cathode for discharge vessels.
US2140534A (en) * 1937-01-11 1938-12-20 Ken Rad Tube And Lamp Corp Electrode for electron discharge devices

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE942460C (en) * 1952-10-24 1956-05-03 Telefunken Gmbh Process for the production of oxide cathodes for electrical discharge tubes

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