DE832903C - Process for the production of low-oxygen steels - Google Patents
Process for the production of low-oxygen steelsInfo
- Publication number
- DE832903C DE832903C DED4567A DED0004567A DE832903C DE 832903 C DE832903 C DE 832903C DE D4567 A DED4567 A DE D4567A DE D0004567 A DED0004567 A DE D0004567A DE 832903 C DE832903 C DE 832903C
- Authority
- DE
- Germany
- Prior art keywords
- steels
- protective gas
- oxygen
- low
- calmed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Description
Verfahren zur Erzeugung sauerstoffarmer Stähle Durch geeignete Schmelzführung kann man im Siemens-Martin-Ofen sauerstoffarme Stähle erzeugen. Es hat sich aber gezeigt, daß diese Reinheit zum Teil dadurch wieder verlorengeht, daß der Stähl beim Abstich in die Pfanne und beim Abgießen in die Kokillen bis zum 20fachen des Ausgangsvolumens an Luft bzw. Sauerstoff aufnimmt. Dadurch bilden sich Oxyde in Mengen bis zu o,5 kg je Tonne Stahl, und Legierungselemente, wie Mangan, verbrennen und werden unwirksam. Man kann diese unerwünschte Oxydation dadurch vermeiden, daß man den Stähl unter Vakuum abgießt, was aber sehr komplizierte Vorrichtungen erfordert.Process for the production of low-oxygen steels By means of suitable melt management you can produce low-oxygen steels in the Siemens-Martin furnace. But it has showed that this purity is partly lost again because the steel when tapping into the pan and when pouring into the molds up to 20 times the Absorbs the initial volume of air or oxygen. This causes oxides to form in Quantities of up to 0.5 kg per ton of steel and alloying elements such as manganese burn and become ineffective. You can avoid this unwanted oxidation that the steel is poured under vacuum, but this requires very complicated devices.
Es hat sich nun gezeigt, daß diese Oxydation auch dann in einfacher Weise weitgehend vermieden werden kann, wenn man dafür Sorge trägt, daB der Stähl während des Abstichs und Abgießens ständig mit einem möglichst sauerstoffarmen Schutzgas in Berührung steht. Als Schutzgas kann Wasserstoff, Stickstoff, aber auch Koksofengas oder sonst irgendein Gas mit möglichst geringem Sauerstoffgehalt verwendet werden. Die Abschirmung des flüssigen. Stahls von der Luft geschieht z. B. in der Weise, daß die Abstichrinne'lose mit einem Blech abgedeckt und in den Raum zwischen Blech und Rinne das Schutzgas mit solchem Druck geleitet wird, daß die Luft verdrängt wird. Der flüssige Stähl nimmt dann teilweise das Schutzgas auf und bleibt auch während des möglichst niedrig zu haltenden freien Falls in die Pfanne noch unter einer gewissen Schutzhülle.It has now been shown that this oxidation is also easier This can largely be avoided if one takes care that the steel constantly with a protective gas that is as low in oxygen as possible during tapping and pouring is in contact. Hydrogen, nitrogen, but also coke oven gas can be used as protective gas or any other gas with the lowest possible oxygen content can be used. The shielding of the liquid. Steel from the air happens e.g. B. in the way, that the tapping channel is covered with a sheet metal and placed in the space between the sheet metal and channel the protective gas is passed at such a pressure that the air is displaced will. The liquid steel then partially absorbs the protective gas and stays there during the free fall into the pan, which is to be kept as low as possible, still under a certain protective cover.
Beim Abgießen aus der Pfanne kann man. z. B. das Ausgußloch außen mit einem ringförmig gebogenen Rohr mit kleinen Öffnungen umgeben, aus denen das Schutzgas in ausreichender Menge austritt und vom Stähl in den Trichter bzw. die Kokille gerissen wird. Weder beim Abstich noch beim Abgießen ist es notwendig, für eine völlige Dichtung zu sorgen, da das unter Überdruck stehende Schutzgas von sich aus das Eindringen von Luft verhindert und es für die Wirkung genügt, wenn der Sauerstoffdruck des mit dem Stahl in Berührung stehenden Gases stark vermindert ist.When pouring from the pan you can. z. B. the pouring hole outside surrounded by an annularly bent tube with small openings from which the Shielding gas escapes in sufficient quantity and from the steel into the funnel or the The mold is torn. Neither when racking nor when pouring it is necessary for a complete poetry to ensure that it is under overpressure Protective gas by itself prevents the ingress of air and allows it to take effect is sufficient if the oxygen pressure of the gas in contact with the steel is greatly reduced.
Die Wirkung dieser Maßnahmen ist so stark, daß sich auch dann, wenn man nur das Abgießen in entsprechender Weise unter Schutzgas vornimmt, höher Bekohlte Stähle ohne Zusatz von Ferrosilicium oder Aluminium in der Kokille praktisch wie beruhigte Stähle verhalten. Man kann also auf diese Weise ohne Zusatz der oft unerwünschten metallischen Beruhigungselemente höher gxeköhlte Stähle beruhigt oder halbberuhigt vergießen.The effect of these measures is so strong that even if one only makes the pouring in a corresponding manner under protective gas, higher coaled Steels without the addition of ferrosilicon or aluminum in the mold are practically like calm steels behave. So you can go this way without adding the often undesirable metallic calming elements higher cooled steels calmed or semi-calmed shed.
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DED4567A DE832903C (en) | 1950-06-25 | 1950-06-25 | Process for the production of low-oxygen steels |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DED4567A DE832903C (en) | 1950-06-25 | 1950-06-25 | Process for the production of low-oxygen steels |
Publications (1)
Publication Number | Publication Date |
---|---|
DE832903C true DE832903C (en) | 1952-03-03 |
Family
ID=7031067
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DED4567A Expired DE832903C (en) | 1950-06-25 | 1950-06-25 | Process for the production of low-oxygen steels |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE832903C (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1181252B (en) * | 1956-04-23 | 1964-11-12 | Hoerder Huettenunion Ag | Process for producing steel by refining pig iron |
DE1185205B (en) * | 1954-03-26 | 1965-01-14 | Max Planck Inst Eisenforschung | Process for cleaning molten steel |
EP0249656A1 (en) * | 1986-06-09 | 1987-12-23 | Inland Steel Company | Method for suppressing fuming in molten steel |
-
1950
- 1950-06-25 DE DED4567A patent/DE832903C/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1185205B (en) * | 1954-03-26 | 1965-01-14 | Max Planck Inst Eisenforschung | Process for cleaning molten steel |
DE1181252B (en) * | 1956-04-23 | 1964-11-12 | Hoerder Huettenunion Ag | Process for producing steel by refining pig iron |
EP0249656A1 (en) * | 1986-06-09 | 1987-12-23 | Inland Steel Company | Method for suppressing fuming in molten steel |
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