DE740250C - Nitriding container - Google Patents

Nitriding container

Info

Publication number
DE740250C
DE740250C DEK157079D DEK0157079D DE740250C DE 740250 C DE740250 C DE 740250C DE K157079 D DEK157079 D DE K157079D DE K0157079 D DEK0157079 D DE K0157079D DE 740250 C DE740250 C DE 740250C
Authority
DE
Germany
Prior art keywords
nitriding
aluminum
heat
chromium
resistant steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEK157079D
Other languages
German (de)
Inventor
Dr-Ing Fritz Bruehl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Krupp Stahl AG
Original Assignee
Krupp Stahl AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Krupp Stahl AG filed Critical Krupp Stahl AG
Priority to DEK157079D priority Critical patent/DE740250C/en
Application granted granted Critical
Publication of DE740250C publication Critical patent/DE740250C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/04Treatment of selected surface areas, e.g. using masks

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Description

Nitrierbehälter Es sind bereits Rohre zum Erhitzen von geschmolzenen Metallen, Flüssigkeiten, Gasen und Dämpfen bekannt, die aus einem Warmfesten Saahl mit o,2 bis 2% Nlolybdan und 0,7 bis 1o% Chrom sowie Zusätzen än Silicium und Aluminium bestehen können und an der dem Angriff der geschmolzenen Metalle, Flüssigkeiten, Gasen oder Dämpfen ausgesetzten Seite mit einem Uberzwg aus Aluminium, Chrom oder Zirkon versehen sind. Bei diesen Rohren hat der Aluminiumüberzug aber nicht wie beine die Wirkung; die Zersetzung von Nitriergasen zu verhindern. Ferner ist es eine Stahllegierung mit 0,o5 bis o,20% Kohlen-Stoff; 0,2 bis 0,7% Silicium, 0,2 bis n,45 Mangan und 4 bis 10 % Chrom als warm-.festen Werkstoff für Überhitzer- und Kesselrohre zu verwenden.Nitriding tanks There are already pipes for heating molten Metals, liquids, gases and vapors known from a heat-resistant Saahl with 0.2 to 2% molybdenum and 0.7 to 10% chromium and additives such as silicon and aluminum can exist and at the attack of molten metals, liquids, Side exposed to gases or vapors with a cover made of aluminum, chrome or Zircon are provided. In these pipes, however, the aluminum coating does not look like legs the effect; to prevent the decomposition of nitriding gases. Furthermore it is a steel alloy with 0.05 to 0.20% carbon material; 0.2 to 0.7% silicon, 0.2 up to n.45 manganese and 4 to 10% chromium as a heat-resistant material for superheater and boiler tubes to be used.

Nitrierbehälter, in denen die der Nitrierhärtung zu unterwerfenden Werkstücke dem Einfluß von stickstoffabgebenden Mitteln bei erhöhter Temperatur ausgesetzt werden, sind bisher aus austentischen Chromnickelstahllegierungen hergestellt worden, die auf das Nitriergas nicht zersetzend einwirken. Die Erfindung bezweckt, Nitrierbehälter zu schaffen, die zu ihrer Herstellung nicht der hoch nickel- oder chromhaltigen, chemisch neutralen Stahllegierungen bedürfen.Nitriding tanks in which those to be subjected to nitriding hardening Workpieces are exposed to the influence of nitrogen-releasing agents at elevated temperatures have been made from austenitic chromium-nickel steel alloys which do not have a decomposing effect on the nitriding gas. The invention aims To create nitriding vessels that are not of high nickel or nickel content for their manufacture chemically neutral steel alloys containing chromium.

Dieser Zweck wird nach der Erfindung dadurch erreicht, daß die Nitrierbehälter aus einem warmfesten Stahl hergestellt und mit einer Auskleidung aus Aluminium oder einer Aluminiumlegierung versehen werden: Es hat sieh nämlich gezeigt, daß das Aluminium keinen schädlichen Einfluß auf die Nitriergase ausübt. Man kann daher den mit dem Nitriergas in Berührung kommenden Teil des Nitriierbehälters z. B. aus Aluminiumblech oder einer im wesentlichen aus Aluminium bestehenden Legierung herstellen. Zur Erzielung genügender Festigkeit des Nitrierbehälters bei der Nitriertemperatur wird erfindungsgemäß zur Herstellung des äußeren Teiles des Nitrierbehälters irgendein warmfester Werkstoff verwendet, der gegen die Nitriergase nicht neutral zu sein braucht.This purpose is achieved according to the invention in that the nitriding container Made of a heat-resistant steel and lined with aluminum or an aluminum alloy: it has shown that aluminum has no harmful influence on the nitriding gases. One can therefore use the Nitriding gas coming into contact part of the nitriding container z. B. made of aluminum sheet or produce an alloy consisting essentially of aluminum. To achieve sufficient strength of the nitriding vessel at the nitriding temperature is according to the invention for the production of the outer part of the nitriding vessel any Heat-resistant material used, which is not neutral to the nitriding gases needs.

Die verwendeten warmfesten Stahllegierungen können beispielsweise etwa 4 bis 10% Chrom und gegebenenfalls bis zu 5 % Silicium, bis 3% Aluminium, bis 3% Wolfram, bis 3 % Molybdän einzeln oder zu mehreren enthalten. Als geeignet hat sich z. B. ein Stahl erwiesen, der bis zu o,1 % Kohlenstoff, etwa Chrom und die üblichen Gehalbe an Silicium und Mangan aufweist.The heat-resistant steel alloys used can, for example about 4 to 10% chromium and optionally up to 5% silicon, up to 3% aluminum, up to Contains 3% tungsten, up to 3% molybdenum individually or in groups. Has as suitable z. B. proved a steel that contains up to 0.1% carbon, such as chromium and the the usual content of silicon and manganese.

In der Zeichnung ist, ein Nitrierbehälter nach der Erfindung im Schnitt dargestellt. Der Behälter sowohl wie sein Deckel bestehen aus einer Außenschicht 1 aus irgendeinem warmfesten Stahl und einer Auskleidung z aus Aluminiumblech bzw. aus einer Aluminiumlegierung. Ein Rohr 4 dient zur Aufnahme des Thermoelements, während die Rohre 5 und 6 für die Zuführung bzw. Ableitung der Nitriergase bestimmt sind.In the drawing is a nitriding container according to the invention in section shown. Both the container and its lid consist of an outer layer 1 made of any heat-resistant steel and a lining z made of aluminum sheet or made of an aluminum alloy. A tube 4 is used to accommodate the thermocouple, while the tubes 5 and 6 are intended for the supply and discharge of the nitriding gases are.

Claims (2)

PATENTANSPRÜCHE: i. Nitrierbehälter, dadurch gekennzeichnet, daß er aus warmfestem Stahl besteht und eine Auskleidung aus Aluminium oder einer Aluminiumlegierung aufweist. PATENT CLAIMS: i. Nitriding container, characterized in that it consists of heat-resistant steel and a lining made of aluminum or an aluminum alloy having. 2. Nitrierbehälter nach Anspruch i, dadurch gekennzeichnet, da# der warmfeste Stahl etwa 4 bis 1 o % Chrom und gegebenenfalls bis 5% Silicium, bis 3% Aluminium, bis 3% Wolfram, bis 3% Molybdän einzeln oder zu mehreren enthält. Zur Abgrenzung des Anmeldungsgegenstandes vom Stand der Technik sind im Erteilungsverfahren in Betracht gezogen worden: deutsche Patentschrift ...... Nr. 490017; britische ...... - 350048, 354 965; »The Iron Age«, 9. Oktober 1930, S. 1oog A; »Stahl und Eisen«, 1931, S. 1576; Fürth, »Die Werkstoffe für den Bau chemischer Apparate«, 1928, S, 178; Freytag, »Die Werkstoff der chemischen Industrie«, 1939, S.34-2. Nitriding container according to claim i, characterized in that # the heat-resistant steel contains about 4 to 10% chromium and optionally up to 5% silicon, up to 3% aluminum, up to 3% tungsten, up to 3% molybdenum individually or in groups. To distinguish the subject of the application from the state of the art, the following were considered in the granting procedure: German patent specification ...... No. 490017; British ...... - 350048, 354 965; "The Iron Age," October 9, 1930, p. 10 A; "Stahl und Eisen", 1931, p. 1576; Fürth, "Materials for the Construction of Chemical Apparatus", 1928, p, 178; Freytag, "The Material of the Chemical Industry", 1939, p.34-
DEK157079D 1940-03-17 1940-03-17 Nitriding container Expired DE740250C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEK157079D DE740250C (en) 1940-03-17 1940-03-17 Nitriding container

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEK157079D DE740250C (en) 1940-03-17 1940-03-17 Nitriding container

Publications (1)

Publication Number Publication Date
DE740250C true DE740250C (en) 1943-10-15

Family

ID=7253616

Family Applications (1)

Application Number Title Priority Date Filing Date
DEK157079D Expired DE740250C (en) 1940-03-17 1940-03-17 Nitriding container

Country Status (1)

Country Link
DE (1) DE740250C (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE490017C (en) * 1925-09-05 1930-01-23 Fried Krupp Akt Ges The use of chromium and chromium-nickel steel alloys known per se as a building material preventing the catalytic decomposition of the nitriding gas for parts of nitriding ovens
GB350048A (en) * 1930-03-12 1931-06-11 David Colville & Sons Ltd Improvements in the manufacture of steel
GB354965A (en) * 1929-07-20 1931-08-20 Krupp Ag Improvements relating to tubes for use in highly heating molten metals, liquids, vapours and gases

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE490017C (en) * 1925-09-05 1930-01-23 Fried Krupp Akt Ges The use of chromium and chromium-nickel steel alloys known per se as a building material preventing the catalytic decomposition of the nitriding gas for parts of nitriding ovens
GB354965A (en) * 1929-07-20 1931-08-20 Krupp Ag Improvements relating to tubes for use in highly heating molten metals, liquids, vapours and gases
GB350048A (en) * 1930-03-12 1931-06-11 David Colville & Sons Ltd Improvements in the manufacture of steel

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