DE69918787D1 - Verfahren zur Herstellung eines Katalysators für die Polymerisation von Alpha-Olefinen - Google Patents

Verfahren zur Herstellung eines Katalysators für die Polymerisation von Alpha-Olefinen

Info

Publication number
DE69918787D1
DE69918787D1 DE69918787T DE69918787T DE69918787D1 DE 69918787 D1 DE69918787 D1 DE 69918787D1 DE 69918787 T DE69918787 T DE 69918787T DE 69918787 T DE69918787 T DE 69918787T DE 69918787 D1 DE69918787 D1 DE 69918787D1
Authority
DE
Germany
Prior art keywords
catalyst
olefins
alpha
support
agitator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69918787T
Other languages
English (en)
Other versions
DE69918787T2 (de
Inventor
Philippe Francois
Serge Bettonville
Dominique Marchand
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Manufacturing Belgium NV
Solvay SA
Original Assignee
Solvay Polyolefins Europe Belgium SA
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay Polyolefins Europe Belgium SA, Solvay SA filed Critical Solvay Polyolefins Europe Belgium SA
Publication of DE69918787D1 publication Critical patent/DE69918787D1/de
Application granted granted Critical
Publication of DE69918787T2 publication Critical patent/DE69918787T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00168—Controlling or regulating processes controlling the viscosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00184—Controlling or regulating processes controlling the weight of reactants in the reactor vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE1999618787 1998-12-22 1999-12-16 Verfahren zur Herstellung eines Katalysators für die Polymerisation von Alpha-Olefinen Expired - Fee Related DE69918787T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BE9800920 1998-12-22
BE9800920A BE1012363A3 (fr) 1998-12-22 1998-12-22 Procede pour la preparation d'un catalyseur pour la polymerisation des alpha-olefines, catalyseur obtenu et procede de polymerisation utilisant un tel catalyseur.

Publications (2)

Publication Number Publication Date
DE69918787D1 true DE69918787D1 (de) 2004-08-26
DE69918787T2 DE69918787T2 (de) 2005-01-13

Family

ID=3891586

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1999618787 Expired - Fee Related DE69918787T2 (de) 1998-12-22 1999-12-16 Verfahren zur Herstellung eines Katalysators für die Polymerisation von Alpha-Olefinen

Country Status (6)

Country Link
US (1) US6403519B1 (de)
EP (1) EP1013676B1 (de)
JP (1) JP2000191716A (de)
AT (1) ATE271567T1 (de)
BE (1) BE1012363A3 (de)
DE (1) DE69918787T2 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3709414B1 (ja) * 2004-09-21 2005-10-26 住重機器システム株式会社 撹拌機
DE102007057854A1 (de) * 2007-11-28 2009-06-04 Philipps-Universität Marburg Cyclopentadienylphosphazen-Komplexe (CpPN-Komplexe) von Metallen der 3. und 4. Gruppe und der Lanthanoide
AU2013343989B2 (en) * 2012-11-09 2017-04-20 Flsmidth A/S Stator for flotation machines

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2027756A (en) * 1934-12-20 1936-01-14 Lee Metal Products Company Inc Center line scraper agitator
US2449012A (en) * 1945-07-19 1948-09-07 Socony Vacuum Oil Co Inc Pipe exchanger scraper
US2589350A (en) * 1949-09-08 1952-03-18 Jr Raymond S Edmunds Rotary cylinder heat exchanger with scraper
US2883272A (en) * 1955-09-13 1959-04-21 Gen Electric Apparatus for the continuous polymerization of organopolysiloxanes
CH390222A (de) * 1960-11-14 1965-04-15 Luwa Ag Dünnschichtbehandlungsapparat
US3770252A (en) * 1970-06-19 1973-11-06 Snam Progetti Apparatus for treating viscous liquids
US4132484A (en) * 1974-06-11 1979-01-02 Hans Kimmel Mixer, particularly heating-cooling mixer for chemical processes
US4279295A (en) * 1976-12-16 1981-07-21 A. Johnson And Company (London) Limited Scraped-surface heat exchanger
DE3230763A1 (de) * 1982-08-16 1984-02-16 Schering AG, 1000 Berlin und 4709 Bergkamen Vorrichtung zum entfernen von substanzen an behaelterinnenwaenden
US4560671A (en) * 1983-07-01 1985-12-24 Union Carbide Corporation Olefin polymerization catalysts adapted for gas phase processes
WO1988008432A1 (en) * 1987-04-20 1988-11-03 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for polymerizing olefin
DE3700332A1 (de) * 1987-01-08 1988-07-21 Basf Ag Thermoplastische formmase und verfahren zu ihrer herstellung
US4893943A (en) * 1988-06-27 1990-01-16 The Ink Company Method and apparatus for low froth agitation of tanked fluids
US4958933A (en) * 1988-11-25 1990-09-25 Paul Zakich Cooler-extruder device
US5100560A (en) * 1991-05-31 1992-03-31 Abb Lummus Crest Inc. Apparatus and method for supercritical water oxidation
DE69307472T2 (de) * 1992-11-10 1997-05-15 Mitsubishi Chem Corp Verfahren zur Herstellung von Alpha-Olefinpolymeren
BE1007040A3 (fr) * 1993-05-25 1995-02-28 Solvay Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur.
US6063725A (en) 1995-11-07 2000-05-16 Mitsui Chemicals, Inc. Olefin polymerization catalyst system
DE19711022A1 (de) * 1997-03-17 1998-09-24 Basf Ag Verwendung eines Mehrstufenrührers zur Herstellung von Polymerisaten

Also Published As

Publication number Publication date
JP2000191716A (ja) 2000-07-11
ATE271567T1 (de) 2004-08-15
EP1013676A1 (de) 2000-06-28
BE1012363A3 (fr) 2000-10-03
EP1013676B1 (de) 2004-07-21
US6403519B1 (en) 2002-06-11
DE69918787T2 (de) 2005-01-13

Similar Documents

Publication Publication Date Title
EP0314797A4 (de) Olefin-polymerisationskatalysator und verfahren zum polymerisieren von olefin.
ATE245665T1 (de) Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
NO970629L (no) Olefin-polymerisasjonskatalysator på bærer
KR880013990A (ko) 올레핀 중합용 고체촉매
EP0231102A3 (en) Catalyst composition for polymerizing alpha-olefins
CA2027144A1 (en) Process and catalyst for producing syndiotactic polyolefins
DE59409990D1 (de) Verfahren zur Herstellung von Polyolefinen
EP0279863A4 (de) Katalysator zur polymerisierung von alpha-olefin und verfahren.
RU94046276A (ru) Способ получения этиленового полимера
ATE178617T1 (de) Katalysatorträger und katalysator für alpha- olefinpolymerisation; verfahren zu ihrer herstellung und polymerisation von alpha-olefinen in gegenwart des katalysators
ATE33497T1 (de) Verfahren zur herstellung eines auf vanadiumverbindungen basierten katalysators auf traeger fuer (misch)polymerisierung von aethylen und so erhaltener katalysator.
BR9809735A (pt) Catalisador e processo para a polimerização de olefinas
ZA911294B (en) Catalyst and prepolymer used for polymerising olefins,and (co-)polymer of ethylene obtainable therefrom
CA2155621A1 (en) Olefin Polymerization Catalyst and Process for Olefin Polymerization
DE69021991D1 (de) Verfahren zur Herstellung von Polyolefinpulver mit kontrollierter Morphologie unter Anwendung eines metallocenhaltigen Katalytorsystems.
DE69918787D1 (de) Verfahren zur Herstellung eines Katalysators für die Polymerisation von Alpha-Olefinen
MX9702453A (es) Proceso de polimerizacion de olefina proquiral sindiotactica.
ATE32731T1 (de) Verfahren zur polymerisation von ethylen und zur copolymerisation von ethylen mit alpha-olefinen und in diesem verfahren verwendete katalysatoren.
PL337396A1 (en) Method of obtaining catalytic compositions for use in polymerising alpha olefins, catalytic composition obtained thereby and polymerisation process employing such composition
DE69703883D1 (de) Yttrium enthaltend metallkomplexe und verfahren zur polymerisation von olefinen
DE60009467D1 (de) Alfa-olefin polymerisarionskatalysatorsytem und seine verwendung zur polymerisation von alfa-olefinen
ATE288930T1 (de) Verfahren zur herstellung eines katalysatorfeststoffs zur olefinpolymerisation
JPS57198708A (en) Catalyst for polyolefin production
JPS6436606A (en) Production of olefin polymer
JPS5540758A (en) Polymerization of alpha-olefin

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee