DE69830003T2 - Verfahren zum entfernen von überschüssigen farbstoffen von bedruckten oder gefärbten textilien - Google Patents
Verfahren zum entfernen von überschüssigen farbstoffen von bedruckten oder gefärbten textilien Download PDFInfo
- Publication number
- DE69830003T2 DE69830003T2 DE69830003T DE69830003T DE69830003T2 DE 69830003 T2 DE69830003 T2 DE 69830003T2 DE 69830003 T DE69830003 T DE 69830003T DE 69830003 T DE69830003 T DE 69830003T DE 69830003 T2 DE69830003 T2 DE 69830003T2
- Authority
- DE
- Germany
- Prior art keywords
- mediator
- enzyme
- esters
- salts
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 64
- 239000004753 textile Substances 0.000 title description 16
- 239000000982 direct dye Substances 0.000 title 1
- 102000004190 Enzymes Human genes 0.000 claims abstract description 56
- 108090000790 Enzymes Proteins 0.000 claims abstract description 56
- 239000004744 fabric Substances 0.000 claims abstract description 46
- 102000003992 Peroxidases Human genes 0.000 claims abstract description 32
- 108010029541 Laccase Proteins 0.000 claims abstract description 29
- 108040007629 peroxidase activity proteins Proteins 0.000 claims abstract description 28
- 230000008569 process Effects 0.000 claims abstract description 23
- 230000000694 effects Effects 0.000 claims abstract description 17
- ASOKPJOREAFHNY-UHFFFAOYSA-N 1-Hydroxybenzotriazole Chemical compound C1=CC=C2N(O)N=NC2=C1 ASOKPJOREAFHNY-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000001747 exhibiting effect Effects 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 239000000975 dye Substances 0.000 claims description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 35
- -1 hydroxy, formyl Chemical group 0.000 claims description 31
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 26
- 150000003839 salts Chemical class 0.000 claims description 26
- 150000002148 esters Chemical class 0.000 claims description 21
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 239000007800 oxidant agent Substances 0.000 claims description 13
- 230000002255 enzymatic effect Effects 0.000 claims description 12
- 238000007792 addition Methods 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 150000002431 hydrogen Chemical class 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 10
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 10
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 10
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- 150000002367 halogens Chemical class 0.000 claims description 10
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 10
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 10
- 241000222511 Coprinus Species 0.000 claims description 9
- 239000008187 granular material Substances 0.000 claims description 9
- 241000222354 Trametes Species 0.000 claims description 7
- 108010015428 Bilirubin oxidase Proteins 0.000 claims description 6
- 108010031396 Catechol oxidase Proteins 0.000 claims description 6
- 102000030523 Catechol oxidase Human genes 0.000 claims description 6
- 108010035722 Chloride peroxidase Proteins 0.000 claims description 6
- 241000222640 Polyporus Species 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 5
- 241000123326 Fomes Species 0.000 claims description 4
- 244000068988 Glycine max Species 0.000 claims description 4
- 235000010469 Glycine max Nutrition 0.000 claims description 4
- 241000226677 Myceliophthora Species 0.000 claims description 4
- 241001361634 Rhizoctonia Species 0.000 claims description 4
- 239000012634 fragment Substances 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 claims description 3
- 108700020962 Peroxidase Proteins 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 3
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000000985 reactive dye Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 230000003750 conditioning effect Effects 0.000 claims 1
- 238000004080 punching Methods 0.000 claims 1
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000001491 aromatic compounds Chemical class 0.000 abstract 1
- 150000002391 heterocyclic compounds Chemical class 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 20
- 238000004061 bleaching Methods 0.000 description 15
- 238000004043 dyeing Methods 0.000 description 14
- 239000000243 solution Substances 0.000 description 11
- 229920000742 Cotton Polymers 0.000 description 9
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 8
- 244000251987 Coprinus macrorhizus Species 0.000 description 7
- 241000233866 Fungi Species 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 108091028043 Nucleic acid sequence Proteins 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- YEDUAINPPJYDJZ-UHFFFAOYSA-N 2-hydroxybenzothiazole Chemical compound C1=CC=C2SC(O)=NC2=C1 YEDUAINPPJYDJZ-UHFFFAOYSA-N 0.000 description 4
- 235000001673 Coprinus macrorhizus Nutrition 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 4
- 102000004316 Oxidoreductases Human genes 0.000 description 4
- 108090000854 Oxidoreductases Proteins 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 229910001882 dioxygen Inorganic materials 0.000 description 4
- NPZTUJOABDZTLV-UHFFFAOYSA-N hydroxybenzotriazole Substances O=C1C=CC=C2NNN=C12 NPZTUJOABDZTLV-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 3
- ZMXJAEGJWHJMGX-UHFFFAOYSA-N methyl syringate Chemical compound COC(=O)C1=CC(OC)=C(O)C(OC)=C1 ZMXJAEGJWHJMGX-UHFFFAOYSA-N 0.000 description 3
- YFBSBLHMAWUCJB-UHFFFAOYSA-N methyl syringate Natural products COc1cc(cc(OC)c1O)C(=O)OO YFBSBLHMAWUCJB-UHFFFAOYSA-N 0.000 description 3
- 230000000813 microbial effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- WXQMFIJLJLLQIS-UHFFFAOYSA-N reactive blue 21 Chemical compound [Cu+2].C1=CC(S(=O)(=O)CCO)=CC=C1NS(=O)(=O)C1=CC=C2C([N-]3)=NC(C=4C5=CC=C(C=4)S(O)(=O)=O)=NC5=NC(C=4C5=CC=C(C=4)S(O)(=O)=O)=NC5=NC([N-]4)=C(C=C(C=C5)S(O)(=O)=O)C5=C4N=C3C2=C1 WXQMFIJLJLLQIS-UHFFFAOYSA-N 0.000 description 3
- HFIYIRIMGZMCPC-YOLJWEMLSA-J remazole black-GR Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC(=CC=3)S(=O)(=O)CCOS([O-])(=O)=O)C(O)=C2C(N)=C1\N=N\C1=CC=C(S(=O)(=O)CCOS([O-])(=O)=O)C=C1 HFIYIRIMGZMCPC-YOLJWEMLSA-J 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- INOIOAWTVPHTCJ-UHFFFAOYSA-N 6-acetamido-4-hydroxy-3-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]naphthalene-2-sulfonic acid Chemical compound CC(=O)NC1=CC=C2C=C(C(N=NC3=CC=C(C=C3)S(=O)(=O)CCOS(O)(=O)=O)=C(O)C2=C1)S(O)(=O)=O INOIOAWTVPHTCJ-UHFFFAOYSA-N 0.000 description 2
- 241001136792 Alle Species 0.000 description 2
- 241000222211 Arthromyces Species 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 241000222356 Coriolus Species 0.000 description 2
- 241000580475 Embellisia Species 0.000 description 2
- 241000223251 Myrothecium Species 0.000 description 2
- 150000001204 N-oxides Chemical class 0.000 description 2
- 108020004511 Recombinant DNA Proteins 0.000 description 2
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 2
- 241000222355 Trametes versicolor Species 0.000 description 2
- 241000082085 Verticillium <Phyllachorales> Species 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- 238000009981 jet dyeing Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000008057 potassium phosphate buffer Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- PDXQNMIMVOYWBA-UHFFFAOYSA-N 1-hydroxybenzotriazole;lithium Chemical compound [Li].C1=CC=C2N(O)N=NC2=C1 PDXQNMIMVOYWBA-UHFFFAOYSA-N 0.000 description 1
- IUUDLQWZXIIRNK-UHFFFAOYSA-N 1-hydroxybenzotriazole;magnesium Chemical compound [Mg].C1=CC=C2N(O)N=NC2=C1 IUUDLQWZXIIRNK-UHFFFAOYSA-N 0.000 description 1
- KKDMGRGLQBYFPA-UHFFFAOYSA-N 1-hydroxybenzotriazole;potassium Chemical compound [K].C1=CC=C2N(O)N=NC2=C1 KKDMGRGLQBYFPA-UHFFFAOYSA-N 0.000 description 1
- XXRXCJAZZQPWIM-UHFFFAOYSA-N 1-hydroxybenzotriazole;sodium Chemical compound [Na].C1=CC=C2N(O)N=NC2=C1 XXRXCJAZZQPWIM-UHFFFAOYSA-N 0.000 description 1
- ZJSQZQMVXKZAGW-UHFFFAOYSA-N 2H-benzotriazol-4-ol hydrate Chemical compound O.OC1=CC=CC2=C1N=NN2 ZJSQZQMVXKZAGW-UHFFFAOYSA-N 0.000 description 1
- VCJOUWZOYVYQME-UHFFFAOYSA-N 3-hydroxybenzotriazole-5-sulfonic acid Chemical compound C1=C(S(O)(=O)=O)C=C2N(O)N=NC2=C1 VCJOUWZOYVYQME-UHFFFAOYSA-N 0.000 description 1
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 241000203809 Actinomycetales Species 0.000 description 1
- 241000266330 Alternaria chartarum Species 0.000 description 1
- 240000003291 Armoracia rusticana Species 0.000 description 1
- 235000011330 Armoracia rusticana Nutrition 0.000 description 1
- 241000228212 Aspergillus Species 0.000 description 1
- 241000194103 Bacillus pumilus Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 241001465180 Botrytis Species 0.000 description 1
- 102100035882 Catalase Human genes 0.000 description 1
- 108010053835 Catalase Proteins 0.000 description 1
- 241000462056 Cestraeus plicatilis Species 0.000 description 1
- 241000222290 Cladosporium Species 0.000 description 1
- 241000222680 Collybia Species 0.000 description 1
- 102000018832 Cytochromes Human genes 0.000 description 1
- 108010052832 Cytochromes Proteins 0.000 description 1
- 244000115658 Dahlia pinnata Species 0.000 description 1
- 235000012040 Dahlia pinnata Nutrition 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 241000223221 Fusarium oxysporum Species 0.000 description 1
- 241000193385 Geobacillus stearothermophilus Species 0.000 description 1
- 102000001554 Hemoglobins Human genes 0.000 description 1
- 241000223198 Humicola Species 0.000 description 1
- 241000222418 Lentinus Species 0.000 description 1
- 241000222118 Leptoxyphium fumago Species 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000205003 Methanothrix thermoacetophila Species 0.000 description 1
- 241000235395 Mucor Species 0.000 description 1
- 241000907556 Mucor hiemalis Species 0.000 description 1
- 241000863420 Myxococcus Species 0.000 description 1
- 241001647006 Myxococcus virescens Species 0.000 description 1
- 241000221960 Neurospora Species 0.000 description 1
- 241000221961 Neurospora crassa Species 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 241000222385 Phanerochaete Species 0.000 description 1
- 241000222393 Phanerochaete chrysosporium Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241000222395 Phlebia Species 0.000 description 1
- 241000222397 Phlebia radiata Species 0.000 description 1
- 241000222350 Pleurotus Species 0.000 description 1
- 241000221945 Podospora Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 241000789035 Polyporus pinsitus Species 0.000 description 1
- 102100038280 Prostaglandin G/H synthase 2 Human genes 0.000 description 1
- 108090000459 Prostaglandin-endoperoxide synthases Proteins 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- 241000589540 Pseudomonas fluorescens Species 0.000 description 1
- 241000813090 Rhizoctonia solani Species 0.000 description 1
- 241000235527 Rhizopus Species 0.000 description 1
- 241000191043 Rhodobacter sphaeroides Species 0.000 description 1
- 241000190950 Rhodopseudomonas palustris Species 0.000 description 1
- 241000732549 Sphaerius Species 0.000 description 1
- 244000057717 Streptococcus lactis Species 0.000 description 1
- 235000014897 Streptococcus lactis Nutrition 0.000 description 1
- 241001454746 Streptomyces niveus Species 0.000 description 1
- 241000187094 Streptomyces thermoviolaceus Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 241000222357 Trametes hirsuta Species 0.000 description 1
- 241000223259 Trichoderma Species 0.000 description 1
- 240000001274 Trichosanthes villosa Species 0.000 description 1
- 102000003425 Tyrosinase Human genes 0.000 description 1
- 108060008724 Tyrosinase Proteins 0.000 description 1
- 241000266300 Ulocladium Species 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- URQAMACHHWVNRD-UHFFFAOYSA-N azane;1-hydroxybenzotriazole Chemical compound N.C1=CC=C2N(O)N=NC2=C1 URQAMACHHWVNRD-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- DZPYZQDOGIPDDF-UHFFFAOYSA-N calcium;1-hydroxybenzotriazole Chemical compound [Ca].C1=CC=C2N(O)N=NC2=C1 DZPYZQDOGIPDDF-UHFFFAOYSA-N 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 108010029942 microperoxidase Proteins 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012476 oxidizable substance Substances 0.000 description 1
- 108010001073 oxyhemoglobin oxidase Proteins 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 208000019585 progressive encephalomyelitis with rigidity and myoclonus Diseases 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000004045 reactive dyeing Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- KUIXZSYWBHSYCN-UHFFFAOYSA-L remazol brilliant blue r Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=C2C(=O)C3=CC=CC=C3C(=O)C2=C1NC1=CC=CC(S(=O)(=O)CCOS([O-])(=O)=O)=C1 KUIXZSYWBHSYCN-UHFFFAOYSA-L 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000012064 sodium phosphate buffer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/13—Fugitive dyeing or stripping dyes
- D06P5/135—Fugitive dyeing or stripping dyes with combined acids or bases + oxidants + reductants means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38654—Preparations containing enzymes, e.g. protease or amylase containing oxidase or reductase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P1/00—Preparation of compounds or compositions, not provided for in groups C12P3/00 - C12P39/00, by using microorganisms or enzymes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Zoology (AREA)
- Microbiology (AREA)
- General Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Mycology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Genetics & Genomics (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Detergent Compositions (AREA)
- Enzymes And Modification Thereof (AREA)
- Coloring (AREA)
- Woven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment Of Fiber Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK152697 | 1997-12-23 | ||
| DK152697 | 1997-12-23 | ||
| PCT/DK1998/000560 WO1999034054A1 (en) | 1997-12-23 | 1998-12-17 | Process for removal of excess dye from printed or dyed fabric or yarn |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69830003D1 DE69830003D1 (de) | 2005-06-02 |
| DE69830003T2 true DE69830003T2 (de) | 2006-03-02 |
Family
ID=8105750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69830003T Expired - Lifetime DE69830003T2 (de) | 1997-12-23 | 1998-12-17 | Verfahren zum entfernen von überschüssigen farbstoffen von bedruckten oder gefärbten textilien |
Country Status (17)
| Country | Link |
|---|---|
| EP (1) | EP1045934B1 (enExample) |
| JP (1) | JP2002500284A (enExample) |
| KR (1) | KR100549708B1 (enExample) |
| CN (1) | CN1333133C (enExample) |
| AT (1) | ATE294274T1 (enExample) |
| AU (1) | AU1663499A (enExample) |
| BR (1) | BR9814332A (enExample) |
| CA (1) | CA2314978C (enExample) |
| CZ (1) | CZ20002144A3 (enExample) |
| DE (1) | DE69830003T2 (enExample) |
| ES (1) | ES2242306T3 (enExample) |
| ID (1) | ID26252A (enExample) |
| PL (1) | PL341603A1 (enExample) |
| PT (1) | PT1045934E (enExample) |
| RU (1) | RU2220243C2 (enExample) |
| TR (1) | TR200001832T2 (enExample) |
| WO (1) | WO1999034054A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19948989A1 (de) * | 1999-10-12 | 2001-05-23 | Bayer Ag | Mediatoren, Peroxidverbindungen und pH-Stabilisatoren enthaltende lagerstabile Formulierungen und deren Verwendung in enzymatischen Bleichsystemen sowie enzymatische 2-Komponenten-Bleichsysteme und deren Verwendung |
| WO2001048304A1 (en) * | 1999-12-23 | 2001-07-05 | Novozymes A/S | Process for removal of excess disperse dye from printed or dyed textile material |
| ES2298877T3 (es) * | 2000-09-12 | 2008-05-16 | Filligent Limited | Filtro para humo de tabaco. |
| ATE338544T1 (de) | 2000-12-21 | 2006-09-15 | Nitromed Inc | Substituierte arylverbindungen als neue, cyclooxygenase-2-selektive inhibitoren, zusammensetzungen und verwendungsverfahren |
| DE10311765A1 (de) * | 2003-03-18 | 2004-09-30 | Bayer Chemicals Ag | Verwendung eines Oxidationssystems enthaltend einen makrocyclischen Metallkomplex und ein Oxidationsmittel zur Entfernung überschüssigen, nichtgebundenen Farbstoffs von gefärbten, textilen Materialien |
| DE10311766A1 (de) * | 2003-03-18 | 2004-09-30 | Bayer Chemicals Ag | Oxidationssystem enthaltend einen makrocyclischen Metallkomplex, dessen Herstellung und Verwendung |
| CN103958769A (zh) * | 2011-09-23 | 2014-07-30 | 诺维信公司 | 纺织品的颜色修饰 |
| MX363042B (es) | 2011-09-23 | 2019-03-06 | Novozymes As | Modificacion del color de textiles. |
| TR201909592T4 (tr) | 2012-08-16 | 2019-07-22 | Novozymes As | Tekstili endoglukanazla işlemden geçirmek için usul. |
| CN103865665A (zh) * | 2012-12-17 | 2014-06-18 | 江苏华艺服饰有限公司 | 一种去染料洗衣剂 |
| CN103498352B (zh) * | 2013-08-28 | 2015-07-15 | 辽宁腾达集团股份有限公司 | 一种利用染色固色液余热去除活性染料浮色的方法 |
| EP3060666B1 (en) | 2013-10-25 | 2020-09-30 | Novozymes A/S | Polypeptides having endoglucanase activity and polynucleotides encoding same |
| MX2016014432A (es) | 2014-05-15 | 2017-01-23 | Novozymes As | Modificacion del color de tejidos. |
| WO2016206621A1 (en) | 2015-06-26 | 2016-12-29 | Novozymes A/S | Biofinishing system |
| CN105733953B (zh) * | 2015-07-07 | 2018-08-24 | 大连交通大学 | 一种产漆酶真菌菌株的分离优化方法及应用 |
| CN110255694A (zh) * | 2019-07-05 | 2019-09-20 | 重庆大学 | 一种人工合成氧化还原介体活化高锰酸钾降解水中有机污染物的方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3618743B2 (ja) * | 1991-04-12 | 2005-02-09 | ノボザイムス アクティーゼルスカブ | 新たに捺染又は染色した繊維から過剰の染料を除去する方法 |
| WO1994012621A1 (en) * | 1992-12-01 | 1994-06-09 | Novo Nordisk | Enhancement of enzyme reactions |
| FI961157L (fi) * | 1993-06-16 | 1996-03-13 | Lignozym Gmbh | Menetelmä ligniinin, ligniinipitoisen aineen tai vastaavien aineiden muuttamiseksi, hajottamiseksi tai valkaisemiseksi |
-
1998
- 1998-12-17 JP JP2000526698A patent/JP2002500284A/ja not_active Ceased
- 1998-12-17 CZ CZ20002144A patent/CZ20002144A3/cs unknown
- 1998-12-17 AT AT98961084T patent/ATE294274T1/de not_active IP Right Cessation
- 1998-12-17 RU RU2000119782/04A patent/RU2220243C2/ru not_active IP Right Cessation
- 1998-12-17 BR BR9814332-8A patent/BR9814332A/pt not_active IP Right Cessation
- 1998-12-17 KR KR1020007006989A patent/KR100549708B1/ko not_active Expired - Fee Related
- 1998-12-17 WO PCT/DK1998/000560 patent/WO1999034054A1/en not_active Ceased
- 1998-12-17 AU AU16634/99A patent/AU1663499A/en not_active Abandoned
- 1998-12-17 TR TR2000/01832T patent/TR200001832T2/xx unknown
- 1998-12-17 ES ES98961084T patent/ES2242306T3/es not_active Expired - Lifetime
- 1998-12-17 ID IDW20001229A patent/ID26252A/id unknown
- 1998-12-17 CN CNB988126540A patent/CN1333133C/zh not_active Expired - Fee Related
- 1998-12-17 PT PT98961084T patent/PT1045934E/pt unknown
- 1998-12-17 PL PL98341603A patent/PL341603A1/xx unknown
- 1998-12-17 DE DE69830003T patent/DE69830003T2/de not_active Expired - Lifetime
- 1998-12-17 CA CA002314978A patent/CA2314978C/en not_active Expired - Fee Related
- 1998-12-17 EP EP98961084A patent/EP1045934B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1045934A1 (en) | 2000-10-25 |
| CZ20002144A3 (cs) | 2001-09-12 |
| PL341603A1 (en) | 2001-04-23 |
| CN1333133C (zh) | 2007-08-22 |
| ID26252A (id) | 2000-12-07 |
| PT1045934E (pt) | 2005-09-30 |
| ATE294274T1 (de) | 2005-05-15 |
| WO1999034054A1 (en) | 1999-07-08 |
| KR20010033488A (ko) | 2001-04-25 |
| RU2220243C2 (ru) | 2003-12-27 |
| CN1283241A (zh) | 2001-02-07 |
| TR200001832T2 (tr) | 2001-08-21 |
| CA2314978C (en) | 2008-05-06 |
| ES2242306T3 (es) | 2005-11-01 |
| JP2002500284A (ja) | 2002-01-08 |
| EP1045934B1 (en) | 2005-04-27 |
| KR100549708B1 (ko) | 2006-02-07 |
| AU1663499A (en) | 1999-07-19 |
| BR9814332A (pt) | 2001-11-06 |
| CA2314978A1 (en) | 1999-07-08 |
| DE69830003D1 (de) | 2005-06-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69525959T2 (de) | Bleichverfahren unter verwendung eines phenoloxidierenden enzyms, einer wasserstoffperoxidquelle und eines verstärkungsmittels | |
| DE69526104T2 (de) | Bleichverfahren unter verwendung eines phenol-oxidierenden enzymsystems und einem verstärkenden mittel | |
| DE69830003T2 (de) | Verfahren zum entfernen von überschüssigen farbstoffen von bedruckten oder gefärbten textilien | |
| DE69706434T2 (de) | Enzymatisches oxidationsverfahren | |
| US5951714A (en) | Enzymatic discharge printing of dyed textiles | |
| DE69717486T2 (de) | Gewebe behandelt mit cellulase und oxidoreductase | |
| US6048367A (en) | Process for removal of excess dye from printed or dyed fabric or yarn | |
| US5908472A (en) | Fabric treated with cellulase and oxidoreductase | |
| US6248134B1 (en) | Process for removal of excess dye from printed or dyed fabric or yarn | |
| US20030040455A1 (en) | Process for removal of excess disperse dye from printed or dyed textile material | |
| WO1997040229A1 (en) | Fabric treated with a cellulase and a hybrid enzyme comprising a phenol oxidizing enzyme | |
| EP1092762B1 (de) | Mediatoren, Peroxidverbindungen und pH-Stabilisatoren enthaltende lagerstabile Formulierungen und deren Verwendung in enzymatischen Bleichsystemen | |
| WO1997040127A1 (en) | Bleaching of fabric with a hybrid enzyme containing a phenol oxidizing enzyme fused to a cellulose binding domain | |
| EP1274898A1 (en) | Process for removal of excess disperse dye from printed or dyed textile material | |
| MXPA00006066A (en) | Process for removal of excess dye from printed or dyed fabric or yarn |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |