DE69521984T2 - Verbrückte metallocene zur verwendung in katalysatorsystemen für die polymerisierung von olefinen - Google Patents
Verbrückte metallocene zur verwendung in katalysatorsystemen für die polymerisierung von olefinenInfo
- Publication number
- DE69521984T2 DE69521984T2 DE69521984T DE69521984T DE69521984T2 DE 69521984 T2 DE69521984 T2 DE 69521984T2 DE 69521984 T DE69521984 T DE 69521984T DE 69521984 T DE69521984 T DE 69521984T DE 69521984 T2 DE69521984 T2 DE 69521984T2
- Authority
- DE
- Germany
- Prior art keywords
- bridge
- olefins
- polymerization
- bridged metallocenes
- catalyst systems
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP94870182 | 1994-11-22 | ||
PCT/EP1995/004609 WO1996016069A1 (en) | 1994-11-22 | 1995-11-21 | Bridged metallocenes for use in catalyst systems for the polymerisation of olefins |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69521984D1 DE69521984D1 (de) | 2001-09-06 |
DE69521984T2 true DE69521984T2 (de) | 2002-04-04 |
Family
ID=8218682
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69521984T Expired - Fee Related DE69521984T2 (de) | 1994-11-22 | 1995-11-21 | Verbrückte metallocene zur verwendung in katalysatorsystemen für die polymerisierung von olefinen |
Country Status (10)
Country | Link |
---|---|
US (1) | US6177529B1 (de) |
EP (1) | EP0740671B1 (de) |
JP (1) | JPH09508147A (de) |
KR (1) | KR100417970B1 (de) |
AT (1) | ATE203752T1 (de) |
CA (1) | CA2163418A1 (de) |
DE (1) | DE69521984T2 (de) |
DK (1) | DK0740671T3 (de) |
ES (1) | ES2161919T3 (de) |
WO (1) | WO1996016069A1 (de) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL1003017C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom-bevattende groep gesubstitueerd fluoreen. |
EP1552726A2 (de) * | 2002-10-18 | 2005-07-13 | iFire Technology Corp. | Farb-elektrolumineszente vorrichtungen |
US20040102311A1 (en) * | 2002-11-21 | 2004-05-27 | Abbas Razavi | Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof |
EP2984111A4 (de) | 2013-04-11 | 2016-11-30 | Exxonmobil Chem Patents Inc | Verfahren zur herstellung von polyolefinen unter verwendung von metallocen-polymerisationskatalysatoren und copolymeren davon |
KR102343937B1 (ko) * | 2017-12-26 | 2021-12-27 | 주식회사 엘지화학 | 메탈로센 담지 촉매 및 이를 이용한 폴리프로필렌의 제조 방법 |
WO2019132450A1 (ko) * | 2017-12-26 | 2019-07-04 | 주식회사 엘지화학 | 메탈로센 담지 촉매 및 이를 이용한 폴리프로필렌의 제조 방법 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
US4892851A (en) * | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
US5243001A (en) | 1990-11-12 | 1993-09-07 | Hoechst Aktiengesellschaft | Process for the preparation of a high molecular weight olefin polymer |
DE59104869D1 (de) * | 1990-11-12 | 1995-04-13 | Hoechst Ag | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation. |
JP3289834B2 (ja) * | 1991-03-04 | 2002-06-10 | 三井化学株式会社 | 新規遷移金属化合物およびそれを用いたα−オレフィンの重合方法 |
NL9101502A (nl) | 1991-09-06 | 1993-04-01 | Dsm Nv | Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen. |
US5710222A (en) * | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
EP0582195B1 (de) * | 1992-08-03 | 2000-12-20 | TARGOR GmbH | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung spezieller Metallocene |
GB9300934D0 (en) * | 1993-01-19 | 1993-03-10 | Bp Chem Int Ltd | Metallocene complexes |
US5486585A (en) | 1993-08-26 | 1996-01-23 | Exxon Chemical Patents Inc. | Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts. |
-
1995
- 1995-11-21 KR KR1019960703282A patent/KR100417970B1/ko not_active IP Right Cessation
- 1995-11-21 ES ES95941622T patent/ES2161919T3/es not_active Expired - Lifetime
- 1995-11-21 DE DE69521984T patent/DE69521984T2/de not_active Expired - Fee Related
- 1995-11-21 WO PCT/EP1995/004609 patent/WO1996016069A1/en active IP Right Grant
- 1995-11-21 JP JP8516584A patent/JPH09508147A/ja not_active Ceased
- 1995-11-21 EP EP95941622A patent/EP0740671B1/de not_active Expired - Lifetime
- 1995-11-21 AT AT95941622T patent/ATE203752T1/de not_active IP Right Cessation
- 1995-11-21 DK DK95941622T patent/DK0740671T3/da active
- 1995-11-22 CA CA002163418A patent/CA2163418A1/en not_active Abandoned
-
1998
- 1998-06-12 US US09/096,941 patent/US6177529B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR100417970B1 (ko) | 2004-06-26 |
EP0740671A1 (de) | 1996-11-06 |
DK0740671T3 (da) | 2001-11-12 |
CA2163418A1 (en) | 1996-05-23 |
EP0740671B1 (de) | 2001-08-01 |
WO1996016069A1 (en) | 1996-05-30 |
KR960706509A (ko) | 1996-12-09 |
ES2161919T3 (es) | 2001-12-16 |
JPH09508147A (ja) | 1997-08-19 |
US6177529B1 (en) | 2001-01-23 |
ATE203752T1 (de) | 2001-08-15 |
DE69521984D1 (de) | 2001-09-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ATE173268T1 (de) | Verbrückte, chirale metallocene, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren | |
DE59409990D1 (de) | Verfahren zur Herstellung von Polyolefinen | |
ES2163404T3 (es) | Procedimiento para la produccion de poliolefinas y catalizador poliolefinico. | |
KR950000719A (ko) | 브릿지 샌드위치-결합 메탈로센 | |
ATE290536T1 (de) | Metallocenverbindung und ihre verwendung in olefin-polymerisation | |
DE69717614D1 (de) | Polymerisation verfahren zur herstellung von polyolefin-elastomeren kationenerzeugender co-katalysator für die activierung von metallocen-katalysatorvorläufer, polyolefin-elastomeren mit einer einziger kombination von eigenschaften und daraus hergestellte produkten | |
DE59712813D1 (de) | Metallocene | |
DE69820130D1 (de) | Verfahren zur Olefinpolymerisation unter stossweiser Zugabe von Wasserstoff | |
BR9506342A (pt) | Processo multi-estágios para a (co) polimerização de olefinas | |
MY132781A (en) | Olefin polymerization | |
DE3788096T2 (de) | Polymerisationskatalysator auf Träger. | |
CA2183102A1 (en) | Polymerization catalyst systems, their production and use | |
DE69815846D1 (de) | Verwendung von metallocenkatalysatoren zur herstellung von regiospezifischen, isotaktischen polyolefinen | |
EP0743317A3 (de) | Metallocene mit einem heterocyclischen Ring und Katalysatoren, die sie enthalten | |
DE69319837D1 (de) | Cyclopentadienylgruppe enthaltende Alpha-Olefin-Polymerisationskatalysatoren auf Basis von Chrom und Verfahren zur Polymerisation von Alpha-Olefinen | |
DE69521984T2 (de) | Verbrückte metallocene zur verwendung in katalysatorsystemen für die polymerisierung von olefinen | |
DE69608426D1 (de) | Cylcopentadienyl-metall-alkalimetall der gruppe 6 b alpha-olefin polymerisationsaustauschkatalysatoren und ihre verwendung im polymersisationsverfahren | |
DE69704683D1 (de) | Substituierte Metallocen-Katalysator für die Olefinpolymerisation | |
MY112158A (en) | Multistage process for the (co) polymerization of olefins |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8327 | Change in the person/name/address of the patent owner |
Owner name: ATOFINA RESEARCH, SENEFFE, FELUY, BE |
|
8339 | Ceased/non-payment of the annual fee |