DE69516594T2 - Verfahren und Wärmetauscher zum Verdampfen einer Flüssigkeit durch indirekten Wärmetausch mit einem Dampf hierfür - Google Patents
Verfahren und Wärmetauscher zum Verdampfen einer Flüssigkeit durch indirekten Wärmetausch mit einem Dampf hierfürInfo
- Publication number
- DE69516594T2 DE69516594T2 DE69516594T DE69516594T DE69516594T2 DE 69516594 T2 DE69516594 T2 DE 69516594T2 DE 69516594 T DE69516594 T DE 69516594T DE 69516594 T DE69516594 T DE 69516594T DE 69516594 T2 DE69516594 T2 DE 69516594T2
- Authority
- DE
- Germany
- Prior art keywords
- evaporating
- liquid
- heat exchanger
- heat exchange
- therefor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
- F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/32—Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
- B01D3/322—Reboiler specifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J5/00—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
- F25J5/002—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger
- F25J5/005—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger in a reboiler-condenser, e.g. within a column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28C—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
- F28C3/00—Other direct-contact heat-exchange apparatus
- F28C3/06—Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour
- F28C3/08—Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour with change of state, e.g. absorption, evaporation, condensation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D9/00—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D9/0062—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by spaced plates with inserted elements
- F28D9/0068—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by spaced plates with inserted elements with means for changing flow direction of one heat exchange medium, e.g. using deflecting zones
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2235/00—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
- F25J2235/50—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being oxygen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/50—Processes or apparatus involving steps for recycling of process streams the recycled stream being oxygen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2250/00—Details related to the use of reboiler-condensers
- F25J2250/04—Down-flowing type boiler-condenser, i.e. with evaporation of a falling liquid film
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
- F25J2290/32—Details on header or distribution passages of heat exchangers, e.g. of reboiler-condenser or plate heat exchangers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0033—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for cryogenic applications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S62/00—Refrigeration
- Y10S62/902—Apparatus
- Y10S62/903—Heat exchange structure
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/286,233 US5438836A (en) | 1994-08-05 | 1994-08-05 | Downflow plate and fin heat exchanger for cryogenic rectification |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69516594D1 DE69516594D1 (de) | 2000-06-08 |
DE69516594T2 true DE69516594T2 (de) | 2000-09-21 |
Family
ID=23097672
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69516594T Expired - Fee Related DE69516594T2 (de) | 1994-08-05 | 1995-07-14 | Verfahren und Wärmetauscher zum Verdampfen einer Flüssigkeit durch indirekten Wärmetausch mit einem Dampf hierfür |
Country Status (9)
Country | Link |
---|---|
US (3) | US5438836A (de) |
EP (1) | EP0695921B1 (de) |
JP (1) | JP3051662B2 (de) |
KR (1) | KR100227238B1 (de) |
CN (1) | CN1128343A (de) |
BR (1) | BR9503333A (de) |
CA (1) | CA2153920A1 (de) |
DE (1) | DE69516594T2 (de) |
ES (1) | ES2145184T3 (de) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5592832A (en) * | 1995-10-03 | 1997-01-14 | Air Products And Chemicals, Inc. | Process and apparatus for the production of moderate purity oxygen |
US5699671A (en) * | 1996-01-17 | 1997-12-23 | Praxair Technology, Inc. | Downflow shell and tube reboiler-condenser heat exchanger for cryogenic rectification |
DE19605500C1 (de) * | 1996-02-14 | 1997-04-17 | Linde Ag | Vorrichtung und Verfahren zum Verdampfen einer Flüssigkeit |
US5755279A (en) * | 1996-03-29 | 1998-05-26 | The Boc Group, Inc. | Heat exchanger |
US5775129A (en) * | 1997-03-13 | 1998-07-07 | The Boc Group, Inc. | Heat exchanger |
GB9705889D0 (en) * | 1997-03-21 | 1997-05-07 | Boc Group Plc | Heat exchange method and apparatus |
US6044902A (en) * | 1997-08-20 | 2000-04-04 | Praxair Technology, Inc. | Heat exchange unit for a cryogenic air separation system |
JP4592125B2 (ja) | 1998-10-05 | 2010-12-01 | 大陽日酸株式会社 | 流下液膜式凝縮蒸発器 |
FR2798599B1 (fr) * | 1999-09-21 | 2001-11-09 | Air Liquide | Vaporiseur-condenseur a thermosiphon et installation de distillation d'air correspondante |
US6295836B1 (en) | 2000-04-14 | 2001-10-02 | Praxair Technology, Inc. | Cryogenic air separation system with integrated mass and heat transfer |
US6237366B1 (en) | 2000-04-14 | 2001-05-29 | Praxair Technology, Inc. | Cryogenic air separation system using an integrated core |
US6581402B2 (en) * | 2000-09-27 | 2003-06-24 | Idalex Technologies, Inc. | Method and plate apparatus for dew point evaporative cooler |
FR2822079B1 (fr) * | 2001-03-16 | 2003-05-16 | Air Liquide | Procede et installation de production d'oxygene ultra-pur par distillation d'air |
US6393866B1 (en) | 2001-05-22 | 2002-05-28 | Praxair Technology, Inc. | Cryogenic condensation and vaporization system |
US6560989B1 (en) * | 2002-06-07 | 2003-05-13 | Air Products And Chemicals, Inc. | Separation of hydrogen-hydrocarbon gas mixtures using closed-loop gas expander refrigeration |
US6666046B1 (en) | 2002-09-30 | 2003-12-23 | Praxair Technology, Inc. | Dual section refrigeration system |
FR2845152B1 (fr) * | 2002-10-01 | 2005-06-17 | Air Liquide | Echangeur de chaleur a plaques comportant une ailette epaisse, et utilisation d'un tel echangeur de chaleur. |
DE10258067A1 (de) * | 2002-12-11 | 2004-07-01 | Thyssenkrupp Encoke Gmbh | Verfahren und Vorrichtung zur Kühlung von Brüdendämpfen in einer Desorptionskolonne |
US7163051B2 (en) * | 2003-08-28 | 2007-01-16 | Praxair Technology, Inc. | Heat exchanger distributor for multicomponent heat exchange fluid |
PE20060221A1 (es) * | 2004-07-12 | 2006-05-03 | Shell Int Research | Tratamiento de gas natural licuado |
US7263859B2 (en) * | 2004-12-27 | 2007-09-04 | L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process and apparatus for cooling a stream of compressed air |
US7421856B2 (en) | 2005-06-17 | 2008-09-09 | Praxair Technology, Inc. | Cryogenic air separation with once-through main condenser |
US20070028649A1 (en) * | 2005-08-04 | 2007-02-08 | Chakravarthy Vijayaraghavan S | Cryogenic air separation main condenser system with enhanced boiling and condensing surfaces |
US9476641B2 (en) * | 2007-09-28 | 2016-10-25 | Praxair Technology, Inc. | Down-flow condenser reboiler system for use in an air separation plant |
US8298412B2 (en) * | 2008-09-17 | 2012-10-30 | Koch-Glitsch, Lp | Structured packing module for mass transfer column and process involving same |
FR2938904B1 (fr) * | 2008-11-24 | 2012-05-04 | Air Liquide | Echangeur de chaleur |
KR101011740B1 (ko) * | 2009-03-31 | 2011-02-07 | 한국해양대학교 산학협력단 | 모터의 중력 보상기 |
US8460517B2 (en) * | 2009-09-02 | 2013-06-11 | Gtc Technology Us Llc | Methods and apparatuses for steam addition to a reboiler coupled to an extractive distillation column for improved extractive distillation |
KR101190228B1 (ko) | 2010-05-06 | 2012-10-12 | 한국과학기술연구원 | 베벨 기어를 이용한 중력 보상 기구 및 방법 및 이를 이용하는 로봇암 |
CN103119388B (zh) * | 2010-09-29 | 2016-08-03 | 气体产品与化学公司 | 板翅式换热器及其制造方法、换热工艺及空气分离工艺 |
US20130008186A1 (en) * | 2011-07-07 | 2013-01-10 | Newman Michael D | Cryogen heat plate heat exchanger |
CN102650491B (zh) * | 2012-05-10 | 2013-10-16 | 西安交通大学 | 空分板翅型膜式主冷液体分布器 |
CN102650492A (zh) * | 2012-05-10 | 2012-08-29 | 西安交通大学 | 空分板翅型降膜式冷凝蒸发器 |
CN102840885B (zh) * | 2012-09-17 | 2015-09-16 | 南京工业大学 | 风洞实验冷凝水流量测量装置 |
FR3032521B1 (fr) * | 2015-02-06 | 2017-02-17 | Air Liquide | Echangeur de chaleur comprenant un dispositif de distribution de liquide frigorigene |
CN105546935A (zh) * | 2016-02-05 | 2016-05-04 | 江苏建筑职业技术学院 | 空分膜式主冷液体分布器 |
BR102016018208B1 (pt) | 2016-08-08 | 2022-04-12 | Mahle Metal Leve S.A. | Sistema de pré-filtragem de combustível diesel |
DE102017216819B4 (de) * | 2017-09-22 | 2021-03-11 | Hanon Systems | Abgaskühler und Abgasrückführsystem mit einem Abgaskühler |
RU2686942C1 (ru) * | 2018-08-29 | 2019-05-06 | Публичное акционерное общество криогенного машиностроения (ПАО "Криогенмаш") | Узел ректификации установки разделения воздуха |
US11774189B2 (en) * | 2020-09-29 | 2023-10-03 | Air Products And Chemicals, Inc. | Heat exchanger, hardway fin arrangement for a heat exchanger, and methods relating to same |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1152432B (de) * | 1962-04-21 | 1963-08-08 | Linde Eismasch Ag | Platten-Kondensator-Verdampfer, insbesondere fuer Gas- und Luftzerleger |
US3568462A (en) * | 1967-11-22 | 1971-03-09 | Mc Donnell Douglas Corp | Fractionating device |
FR2547898B1 (fr) * | 1983-06-24 | 1985-11-29 | Air Liquide | Procede et dispositif pour vaporiser un liquide par echange de chaleur avec un deuxieme fluide, et leur application a une installation de distillation d'air |
USRE33026E (en) * | 1983-06-24 | 1989-08-22 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process and device for vaporizing a liquid by heat exchange with a second fluid and their application in an air distillation installation |
JPS60253782A (ja) * | 1984-05-30 | 1985-12-14 | 日本酸素株式会社 | 大型空気分離装置用凝縮器 |
GB8719349D0 (en) * | 1987-08-14 | 1987-09-23 | Boc Group Ltd | Liquefied gas boilers |
JP2641497B2 (ja) * | 1988-05-27 | 1997-08-13 | 株式会社日立製作所 | パターン形成方法 |
US5222549A (en) * | 1988-07-04 | 1993-06-29 | Japan Oxygen Co., Ltd. | Condenser/evaporator |
FR2650379B1 (fr) * | 1989-07-28 | 1991-10-18 | Air Liquide | Appareil de vaporisation-condensation pour double colonne de distillation d'air, et installation de distillation d'air comportant un tel appareil |
GB9016766D0 (en) * | 1990-07-31 | 1990-09-12 | Boc Group Plc | Boiling liquefied gas |
FR2665755B1 (fr) * | 1990-08-07 | 1993-06-18 | Air Liquide | Appareil de production d'azote. |
ES2087268T3 (es) * | 1990-12-17 | 1996-07-16 | Air Liquide | Columna de destilacion de aire con relleno ondulado-cruzado. |
US5122174A (en) * | 1991-03-01 | 1992-06-16 | Air Products And Chemicals, Inc. | Boiling process and a heat exchanger for use in the process |
FR2685071B1 (fr) * | 1991-12-11 | 1996-12-13 | Air Liquide | Echangeur de chaleur indirect du type a plaques. |
FR2690231B1 (fr) * | 1992-04-17 | 1994-06-03 | Air Liquide | Echangeur de chaleur a ruissellement et installation de distillation d'air comportant un tel echangeur. |
-
1994
- 1994-08-05 US US08/286,233 patent/US5438836A/en not_active Expired - Fee Related
-
1995
- 1995-05-24 US US08/449,044 patent/US5724834A/en not_active Expired - Lifetime
- 1995-05-31 US US08/454,885 patent/US5537840A/en not_active Expired - Lifetime
- 1995-07-14 JP JP7200337A patent/JP3051662B2/ja not_active Expired - Lifetime
- 1995-07-14 KR KR1019950020703A patent/KR100227238B1/ko not_active IP Right Cessation
- 1995-07-14 EP EP95111088A patent/EP0695921B1/de not_active Expired - Lifetime
- 1995-07-14 CN CN95108418A patent/CN1128343A/zh active Pending
- 1995-07-14 DE DE69516594T patent/DE69516594T2/de not_active Expired - Fee Related
- 1995-07-14 ES ES95111088T patent/ES2145184T3/es not_active Expired - Lifetime
- 1995-07-14 CA CA002153920A patent/CA2153920A1/en not_active Abandoned
- 1995-07-14 BR BR9503333A patent/BR9503333A/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA2153920A1 (en) | 1996-02-06 |
EP0695921B1 (de) | 2000-05-03 |
DE69516594D1 (de) | 2000-06-08 |
EP0695921A1 (de) | 1996-02-07 |
CN1128343A (zh) | 1996-08-07 |
BR9503333A (pt) | 1996-05-21 |
US5724834A (en) | 1998-03-10 |
JPH0861868A (ja) | 1996-03-08 |
US5537840A (en) | 1996-07-23 |
KR100227238B1 (ko) | 1999-11-01 |
ES2145184T3 (es) | 2000-07-01 |
KR960008259A (ko) | 1996-03-22 |
US5438836A (en) | 1995-08-08 |
JP3051662B2 (ja) | 2000-06-12 |
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