DE69313022D1 - Verflüssigungsverfahren - Google Patents

Verflüssigungsverfahren

Info

Publication number
DE69313022D1
DE69313022D1 DE69313022T DE69313022T DE69313022D1 DE 69313022 D1 DE69313022 D1 DE 69313022D1 DE 69313022 T DE69313022 T DE 69313022T DE 69313022 T DE69313022 T DE 69313022T DE 69313022 D1 DE69313022 D1 DE 69313022D1
Authority
DE
Germany
Prior art keywords
liquefaction process
liquefaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69313022T
Other languages
English (en)
Other versions
DE69313022T2 (de
Inventor
Robert Arthur Beddome
Joseph Alfred Weber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Praxair Technology Inc
Original Assignee
Praxair Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Praxair Technology Inc filed Critical Praxair Technology Inc
Publication of DE69313022D1 publication Critical patent/DE69313022D1/de
Application granted granted Critical
Publication of DE69313022T2 publication Critical patent/DE69313022T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0045—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0012—Primary atmospheric gases, e.g. air
    • F25J1/0015—Nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0012—Primary atmospheric gases, e.g. air
    • F25J1/0017—Oxygen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
    • F25J1/0037—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0042—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by liquid expansion with extraction of work
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0201—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
    • F25J1/0202—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration in a quasi-closed internal refrigeration loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0234—Integration with a cryogenic air separation unit
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0285—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings
    • F25J1/0288—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/04—Internal refrigeration with work-producing gas expansion loop
    • F25J2270/06—Internal refrigeration with work-producing gas expansion loop with multiple gas expansion loops
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/34—Details about subcooling of liquids

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Separation By Low-Temperature Treatments (AREA)
DE69313022T 1992-06-05 1993-06-04 Verflüssigungsverfahren Expired - Fee Related DE69313022T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/894,587 US5231835A (en) 1992-06-05 1992-06-05 Liquefier process

Publications (2)

Publication Number Publication Date
DE69313022D1 true DE69313022D1 (de) 1997-09-18
DE69313022T2 DE69313022T2 (de) 1998-02-05

Family

ID=25403279

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69313022T Expired - Fee Related DE69313022T2 (de) 1992-06-05 1993-06-04 Verflüssigungsverfahren

Country Status (8)

Country Link
US (1) US5231835A (de)
EP (1) EP0573074B1 (de)
JP (1) JPH0650657A (de)
KR (1) KR0164870B1 (de)
CN (1) CN1076817C (de)
CA (1) CA2097751C (de)
DE (1) DE69313022T2 (de)
ES (1) ES2105009T3 (de)

Families Citing this family (39)

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FR2710370B1 (fr) * 1993-09-21 1995-12-08 Air Liquide Procédé et ensemble de compression d'un gaz.
US5655388A (en) * 1995-07-27 1997-08-12 Praxair Technology, Inc. Cryogenic rectification system for producing high pressure gaseous oxygen and liquid product
US5584194A (en) * 1995-10-31 1996-12-17 Gardner; Thomas W. Method and apparatus for producing liquid nitrogen
US5660241A (en) * 1995-12-20 1997-08-26 Dowell, A Division Of Schlumberger Technology Corporation Pressure compensated weight on bit shock sub for a wellbore drilling tool
US5836173A (en) * 1997-05-01 1998-11-17 Praxair Technology, Inc. System for producing cryogenic liquid
US5979440A (en) * 1997-06-16 1999-11-09 Sequal Technologies, Inc. Methods and apparatus to generate liquid ambulatory oxygen from an oxygen concentrator
US5799505A (en) * 1997-07-28 1998-09-01 Praxair Technology, Inc. System for producing cryogenic liquefied industrial gas
US6006545A (en) * 1998-08-14 1999-12-28 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Liquefier process
US6085547A (en) * 1998-09-18 2000-07-11 Johnston; Richard P. Simple method and apparatus for the partial conversion of natural gas to liquid natural gas
US6085545A (en) * 1998-09-18 2000-07-11 Johnston; Richard P. Liquid natural gas system with an integrated engine, compressor and expander assembly
US6269656B1 (en) 1998-09-18 2001-08-07 Richard P. Johnston Method and apparatus for producing liquified natural gas
US6085546A (en) * 1998-09-18 2000-07-11 Johnston; Richard P. Method and apparatus for the partial conversion of natural gas to liquid natural gas
US6298688B1 (en) 1999-10-12 2001-10-09 Air Products And Chemicals, Inc. Process for nitrogen liquefaction
US6220053B1 (en) 2000-01-10 2001-04-24 Praxair Technology, Inc. Cryogenic industrial gas liquefaction system
US6484533B1 (en) * 2000-11-02 2002-11-26 Air Products And Chemicals, Inc. Method and apparatus for the production of a liquid cryogen
US6978638B2 (en) * 2003-05-22 2005-12-27 Air Products And Chemicals, Inc. Nitrogen rejection from condensed natural gas
US6779361B1 (en) 2003-09-25 2004-08-24 Praxair Technology, Inc. Cryogenic air separation system with enhanced liquid capacity
US7134296B2 (en) * 2004-10-13 2006-11-14 Praxair Technology, Inc. Method for providing cooling for gas liquefaction
CA2601445C (en) 2005-03-16 2012-10-02 Fuelcor Llc Systems, methods, and compositions for production of synthetic hydrocarbon compounds
US8376035B2 (en) * 2006-06-22 2013-02-19 Praxair Technology, Inc. Plate-fin heat exchanger
US20090320520A1 (en) * 2008-06-30 2009-12-31 David Ross Parsnick Nitrogen liquefier retrofit for an air separation plant
KR101932035B1 (ko) * 2012-02-08 2018-12-26 삼성전자주식회사 기판 처리용 유체 공급 시스템 및 방법
US9631863B2 (en) * 2013-03-12 2017-04-25 Mcalister Technologies, Llc Liquefaction systems and associated processes and methods
US20150168058A1 (en) * 2013-12-17 2015-06-18 L'air Liquide, Societe Anonyme Pour I'etude Et I'exploitation Des Procedes Georges Claude Apparatus for producing liquid nitrogen
BR112017003616A2 (pt) * 2014-08-22 2017-12-05 Peregrine Turbine Tech Llc método para gerar energia em um sistema, sistema configurado para gerar energia e motor
FR3044747B1 (fr) * 2015-12-07 2019-12-20 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procede de liquefaction de gaz naturel et d'azote
US10281203B2 (en) 2016-08-05 2019-05-07 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for liquefaction of industrial gas by integration of methanol plant and air separation unit
US10634425B2 (en) 2016-08-05 2020-04-28 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Integration of industrial gas site with liquid hydrogen production
US10288346B2 (en) 2016-08-05 2019-05-14 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for liquefaction of industrial gas by integration of methanol plant and air separation unit
US20180038639A1 (en) * 2016-08-05 2018-02-08 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Robust recovery of natural gas letdown energy for small scale liquefied natural gas production
US10393431B2 (en) 2016-08-05 2019-08-27 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for the integration of liquefied natural gas and syngas production
US10655913B2 (en) 2016-09-12 2020-05-19 Stanislav Sinatov Method for energy storage with co-production of peaking power and liquefied natural gas
WO2021126513A1 (en) 2019-12-19 2021-06-24 Praxair Technology, Inc. System and method for supplying cryogenic refrigeration
US11740014B2 (en) * 2020-02-27 2023-08-29 Praxair Technology, Inc. System and method for natural gas and nitrogen liquefaction with independent nitrogen recycle loops
CN111672236A (zh) * 2020-05-19 2020-09-18 茂名华粤华源气体有限公司 一种液体二氧化碳分离提纯的制备方法
CN113503691B (zh) * 2021-07-12 2022-11-22 北京中科富海低温科技有限公司 一种两级压缩循环氮气液化装置及其液化方法
CN114087845B (zh) * 2021-11-19 2022-07-15 北京大臻科技有限公司 一种基于仲氢循环的液氢生产装置、系统及方法
WO2023244883A1 (en) 2022-06-16 2023-12-21 Praxair Technology, Inc. Liquid nitrogen energy storage system and method
FR3141998A1 (fr) 2022-11-10 2024-05-17 Engie Dispositif et procédé de sous-refroidissement d’un gaz liquefié

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DE2206620B2 (de) * 1972-02-11 1981-04-02 Linde Ag, 6200 Wiesbaden Anlage zum Verflüssigen von Naturgas
DE2457262A1 (de) * 1974-12-04 1976-06-10 Linde Ag Verfahren zur rueckverfluessigung von verdampften kohlenwasserstoffen
GB8418840D0 (en) * 1984-07-24 1984-08-30 Boc Group Plc Gas refrigeration
US4778497A (en) * 1987-06-02 1988-10-18 Union Carbide Corporation Process to produce liquid cryogen
US4894076A (en) * 1989-01-17 1990-01-16 Air Products And Chemicals, Inc. Recycle liquefier process

Also Published As

Publication number Publication date
US5231835A (en) 1993-08-03
EP0573074A2 (de) 1993-12-08
JPH0650657A (ja) 1994-02-25
ES2105009T3 (es) 1997-10-16
KR0164870B1 (ko) 1999-01-15
EP0573074A3 (de) 1994-12-07
DE69313022T2 (de) 1998-02-05
EP0573074B1 (de) 1997-08-13
CA2097751A1 (en) 1993-12-06
CA2097751C (en) 1996-06-18
CN1082183A (zh) 1994-02-16
CN1076817C (zh) 2001-12-26
KR940000841A (ko) 1994-01-10

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Legal Events

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8339 Ceased/non-payment of the annual fee