DE69207551D1 - Katalytisches Verfahren für Kettenverlängerung - Google Patents

Katalytisches Verfahren für Kettenverlängerung

Info

Publication number
DE69207551D1
DE69207551D1 DE69207551T DE69207551T DE69207551D1 DE 69207551 D1 DE69207551 D1 DE 69207551D1 DE 69207551 T DE69207551 T DE 69207551T DE 69207551 T DE69207551 T DE 69207551T DE 69207551 D1 DE69207551 D1 DE 69207551D1
Authority
DE
Germany
Prior art keywords
chain extension
catalytic process
catalytic
extension
chain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69207551T
Other languages
English (en)
Other versions
DE69207551T2 (de
Inventor
Edward Gerrard Samsel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Corp North America Inc
Original Assignee
Albemarle Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Corp filed Critical Albemarle Corp
Publication of DE69207551D1 publication Critical patent/DE69207551D1/de
Application granted granted Critical
Publication of DE69207551T2 publication Critical patent/DE69207551T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/88—Growth and elimination reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/062—Al linked exclusively to C
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69207551T 1991-10-25 1992-10-23 Katalytisches Verfahren für Kettenverlängerung Expired - Fee Related DE69207551T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US78211691A 1991-10-25 1991-10-25
US07/881,928 US5210338A (en) 1991-10-25 1992-05-12 Catalyzed chain growth process

Publications (2)

Publication Number Publication Date
DE69207551D1 true DE69207551D1 (de) 1996-02-22
DE69207551T2 DE69207551T2 (de) 1996-05-15

Family

ID=27119949

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69207551T Expired - Fee Related DE69207551T2 (de) 1991-10-25 1992-10-23 Katalytisches Verfahren für Kettenverlängerung

Country Status (5)

Country Link
US (1) US5210338A (de)
EP (1) EP0539876B1 (de)
JP (1) JPH05239070A (de)
CA (1) CA2080102C (de)
DE (1) DE69207551T2 (de)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5276220A (en) * 1992-06-18 1994-01-04 Ethyl Corporation Actinide catalyzed chain growth process
US5498735A (en) * 1993-08-05 1996-03-12 Idemitsu Petrochemical Co., Ltd. Process of producing α-olefin
US5670589A (en) * 1995-02-08 1997-09-23 Phillips Petroleum Company Organoaluminoxy product, catalyst systems, preparation, and use
US5536859A (en) * 1995-02-27 1996-07-16 Amoco Corporation Alpha-olefin catalyst and process
US5597937A (en) * 1995-05-11 1997-01-28 Albemarle Corporation Conversion of deep internal olefins into primary alkylaluminum compounds by isomerization-displacement
US6489424B2 (en) 1997-04-17 2002-12-03 Denki Kagaku Kogyo Kabushiki Kaisha Transition metal catalyst component for polymerization, aromatic vinyl compound polymer having stereoregularity and method for its preparation by means of the catalyst component
EP0872492B1 (de) * 1997-04-17 2003-12-03 Denki Kagaku Kogyo Kabushiki Kaisha Übergangsmetallverbindung als Katalysatorbestandteil für die Polymerisation, Copolymer mit Stereoregularität aus einer aromatischen Vinyl-Verbindung und einem Olefin und Verfahren zu seiner Herstellung mit Hilfe der Übergangsmetallverbindung als Katalysatorbestandteil
US6329479B1 (en) * 1997-04-17 2001-12-11 Denki Kagaku Kogyo Kabushiki Kaisha Transition metal compound as catalyst component for polymerization, aromatic vinyl compound-olefin copolymer having stereoregularity and method for its preparation by means of the transition metal compound as catalyst component
ZA989699B (en) * 1997-10-29 1999-04-25 Montell Technology Company Bv Catalysts for the polymerization of olefins and process for the preparation thereof
US7160949B2 (en) * 2000-01-21 2007-01-09 Mitsui Chemicals, Inc. Olefin block copolymers, processes for producing the same and uses thereof
AU2002219867A1 (en) * 2000-11-27 2002-06-03 The Dow Chemical Company Process for the preparation of an aluminium alkyl growth product and its use in the oligomerisation of olefins
US6444867B1 (en) * 2001-05-17 2002-09-03 Bp Corporation North America Inc. Process for linear alpha olefins
US7087686B2 (en) 2001-08-06 2006-08-08 Bp Chemicals Limited Chain growth reaction process
US6822108B2 (en) * 2001-12-12 2004-11-23 E. I. Du Pont De Nemours And Company Manufacture of trialkylaluminum compounds and α-alcohols
EP1461343A4 (de) * 2001-12-12 2006-11-02 Du Pont Herstellung von trialkylaluminiumverbindungen und alpha-alkoholen
BRPI0507523A (pt) * 2004-03-16 2007-07-03 Union Carbide Chem Plastic composição de catalisador e processo para a preparação de derivados oligoméricos de monÈmeros olefìnicos e processos para a oligomerização catalìtica de etileno e para preparar copolìmeros e etileno e uma ou mais a-olefinas c4-8
RU2375381C2 (ru) 2004-03-17 2009-12-10 Дау Глобал Текнолоджиз Инк. Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера высшего олефина
JP5133050B2 (ja) * 2004-03-17 2013-01-30 ダウ グローバル テクノロジーズ エルエルシー エチレンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物
NZ549262A (en) 2004-03-17 2010-08-27 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
US7696280B2 (en) * 2004-04-30 2010-04-13 Chevron Phillips Chemical Company, Lp HDPE resins for use in pressure pipe and related applications
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
JP5623699B2 (ja) 2005-03-17 2014-11-12 ダウ グローバル テクノロジーズ エルエルシー レジオイレギュラーなマルチブロックコポリマーを形成するための可逆的移動剤を含む触媒組成物
AU2006227977A1 (en) 2005-03-17 2006-09-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
WO2007035492A1 (en) * 2005-09-15 2007-03-29 Dow Global Technologies Inc. Catalytic olefin block copolymers via polymerizable shuttling agent
TWI417304B (zh) * 2005-09-15 2013-12-01 Dow Global Technologies Llc 藉由多中心穿梭劑來控制聚合物之架構及分子量分佈
EP2220128B2 (de) † 2007-11-09 2021-03-10 University of Maryland, College Park Verfahren zur herstellung von polyolefinen durch lebende koordinative kettentransferpolymerisation
EP2459598B1 (de) 2009-07-29 2017-10-18 Dow Global Technologies LLC Zwei- oder mehrendige kettenübertragungsreagenzien und ihre verwendung zur herstellung von blockcopolymeren
CN103182156B (zh) * 2011-12-28 2016-04-06 中国石油天然气股份有限公司 烷基铝生产过程中危险废弃物的回收处理方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3017438A (en) * 1962-01-16 Storage
US2977381A (en) * 1956-01-16 1961-03-28 Goodrich Gulf Chem Inc Organo-metal compounds and production thereof
US3391219A (en) * 1962-04-25 1968-07-02 Ethyl Corp Production of olefins
US3376331A (en) * 1963-10-30 1968-04-02 Exxon Research Engineering Co Preparation of aluminum cyclopentadienyl compounds
US3415861A (en) * 1964-03-31 1968-12-10 Ethyl Corp Organoaluminum compound production
US3476789A (en) * 1966-09-19 1969-11-04 Mobil Oil Corp Method for preparing tri-hydrodicyclopentadienyl aluminum and substituted derivatives thereof
US3476788A (en) * 1966-09-19 1969-11-04 Mobil Oil Corp Derivatives of the growth reaction of ethylene with trihydrodicyclopentadienyl aluminum
US3551467A (en) * 1967-05-31 1970-12-29 Mitsui Petrochemical Ind Process for preparing diolefin nickel halide complexes
US4268697A (en) * 1979-06-21 1981-05-19 The Procter & Gamble Company Synthesis of long-chain alkanes having terminal functionality
US4658078A (en) * 1986-08-15 1987-04-14 Shell Oil Company Vinylidene olefin process
US4851378A (en) * 1987-07-23 1989-07-25 Texas Alkyls, Inc. Olefin polymerization of copolymerization catalyst components

Also Published As

Publication number Publication date
JPH05239070A (ja) 1993-09-17
DE69207551T2 (de) 1996-05-15
US5210338A (en) 1993-05-11
EP0539876B1 (de) 1996-01-10
EP0539876A3 (en) 1993-05-26
EP0539876A2 (de) 1993-05-05
CA2080102A1 (en) 1993-04-26
CA2080102C (en) 2002-09-17

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: AMOCO CORP., CHICAGO, ILL., US

8339 Ceased/non-payment of the annual fee