DE681225C - Process for the production of mixtures from soaps and higher molecular weight dihydric alcohols - Google Patents

Process for the production of mixtures from soaps and higher molecular weight dihydric alcohols

Info

Publication number
DE681225C
DE681225C DED61684D DED0061684D DE681225C DE 681225 C DE681225 C DE 681225C DE D61684 D DED61684 D DE D61684D DE D0061684 D DED0061684 D DE D0061684D DE 681225 C DE681225 C DE 681225C
Authority
DE
Germany
Prior art keywords
molecular weight
higher molecular
soaps
mixtures
dihydric alcohols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DED61684D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Deutsche Hydrierwerke AG
Original Assignee
Deutsche Hydrierwerke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deutsche Hydrierwerke AG filed Critical Deutsche Hydrierwerke AG
Priority to DED61684D priority Critical patent/DE681225C/en
Application granted granted Critical
Publication of DE681225C publication Critical patent/DE681225C/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
    • A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
    • A61K47/08—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing oxygen, e.g. ethers, acetals, ketones, quinones, aldehydes, peroxides
    • A61K47/10—Alcohols; Phenols; Salts thereof, e.g. glycerol; Polyethylene glycols [PEG]; Poloxamers; PEG/POE alkyl ethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
    • A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
    • A61K47/08—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing oxygen, e.g. ethers, acetals, ketones, quinones, aldehydes, peroxides
    • A61K47/12—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00—Medicinal preparations characterised by special physical form
    • A61K9/0012—Galenical forms characterised by the site of application
    • A61K9/0014—Skin, i.e. galenical aspects of topical compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11

Description

Verfahren zur Herstellung von Gemischen aus Seifen und höhermolekularen zweiwertigen Alkoholen Nach delm Verfahren des Patents 579 896 werden natürlich vorkommende Ester aus höheren Fettsäuren und höhermolekularen ungesättigten Fettalkoholen dadurch in gesättigt Ester übergeführt, daß man diese Ester mit Schwefelsäure behandelt und die hierbei lerhaltenen Schwefelsäureester anschließend durch Hydrolyse in Oxyester umwandelt.Process for the production of mixtures of soaps and higher molecular weight Dihydric alcohols According to the method of patent 579 896, natural Occurring esters from higher fatty acids and higher molecular weight unsaturated fatty alcohols converted into saturated esters by treating these esters with sulfuric acid and the sulfuric acid esters obtained in this way then by hydrolysis in oxyesters converts.

Es wurde nun gefunden, daß sich diese Oxyester aus höhermolekularen Fettsäuren und höhermolekularen zweiwertigen Alkoholen im Gegensatz zu den bekannten natürlichen Wachsen außerordentlicbh leicht verseifen lassen und hierbei Produkte liefern, die auf Grund ihres Gehaltes an zweiwertigen Alkoholen und Oxyfettsäuren von großer technischer Bedeutung sind und sich vorzüglich als Schmiermittel und Dispersionen eignen. Bei der Verseifung mit wäßrigen Alkalien erhält man Emulsionen seifenartigen Charakters, die in der Kosmetik oder. zu technischen Zwecken, z. B. als Starrschmieren, verwendbar sind. It has now been found that these oxyesters are composed of higher molecular weight Fatty acids and higher molecular weight dihydric alcohols in contrast to the known saponify natural waxes extraordinarily easily and products deliver, due to their content of dihydric alcohols and oxyfatty acids are of great technical importance and are excellent as lubricants and Dispersions are suitable. On saponification with aqueous alkalis, emulsions are obtained soap-like character used in cosmetics or. for technical purposes, e.g. B. as rigid lubricants, can be used.

B e i s p i e l. Aus den flüssigen, in der Kälte abgepreßten Anteilen des Specköls des Physeter macrocephalus wird gemäß dem Verfahren des Patents 579 896 durch Sulfonierung und anschließende Hydrolyse ein Hartfett erhalten, das im wesentlichen aus den Fettsäureestern des Oxyoctadecyla]kohols besteht. Durch Verseifung mit wäßrigen Alkali erhält man in Fonn einer salbenartigen Masse ein Produkt, das neben fettsaurem Alkali hauptsächlich Dioxyoctadecan enthält. Example. From the liquid parts squeezed out in the cold of the Bacon Oil of Physeter macrocephalus is prepared according to the method of patent 579 896 obtained a hard fat by sulfonation and subsequent hydrolysis, which in consists essentially of the fatty acid esters of oxyoctadecyla] alcohol. By saponification with aqueous alkali, a product is obtained in the form of an ointment-like mass which besides fatty acid alkali mainly contains dioxyoctadecane.

Claims (1)

P A T E N T A N S P R U C H : Verfahren zur Herstellung von Gemischen aus Seifen und höhermolekularen zweiwertigen Alkoholen, dadurch gekennzeichnet, daß man die gemäß Patent 579 896 durch Einwirkung von Schwefelsäure auf natürlich vorkommende Ester aus höhermolekularen ungesättigten Fettalkoholen und höheren Fettsäuren und anschließende Hydrolyse der SchwSefelsäureester erhaltenen Oxyester in an sich bekannter Weise verseift. P A T E N T A N S P R U C H: Process for the preparation of mixtures from soaps and higher molecular weight dihydric alcohols, characterized in that that according to patent 579 896 by the action of sulfuric acid on natural Occurring esters from higher molecular weight unsaturated fatty alcohols and higher fatty acids and subsequent hydrolysis of the sulfuric acid ester obtained in itself saponified as is known.
DED61684D 1931-08-13 1931-08-13 Process for the production of mixtures from soaps and higher molecular weight dihydric alcohols Expired DE681225C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DED61684D DE681225C (en) 1931-08-13 1931-08-13 Process for the production of mixtures from soaps and higher molecular weight dihydric alcohols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DED61684D DE681225C (en) 1931-08-13 1931-08-13 Process for the production of mixtures from soaps and higher molecular weight dihydric alcohols

Publications (1)

Publication Number Publication Date
DE681225C true DE681225C (en) 1939-09-19

Family

ID=7058241

Family Applications (1)

Application Number Title Priority Date Filing Date
DED61684D Expired DE681225C (en) 1931-08-13 1931-08-13 Process for the production of mixtures from soaps and higher molecular weight dihydric alcohols

Country Status (1)

Country Link
DE (1) DE681225C (en)

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