DE645939C - Brake or pressure fluids - Google Patents

Brake or pressure fluids

Info

Publication number
DE645939C
DE645939C DED68317D DED0068317D DE645939C DE 645939 C DE645939 C DE 645939C DE D68317 D DED68317 D DE D68317D DE D0068317 D DED0068317 D DE D0068317D DE 645939 C DE645939 C DE 645939C
Authority
DE
Germany
Prior art keywords
brake
glycerine
pressure
pressure fluids
cyclic ethers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DED68317D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Deutsche Hydrierwerke AG
Original Assignee
Deutsche Hydrierwerke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deutsche Hydrierwerke AG filed Critical Deutsche Hydrierwerke AG
Priority to DED68317D priority Critical patent/DE645939C/en
Application granted granted Critical
Publication of DE645939C publication Critical patent/DE645939C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M3/00Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/044Cyclic ethers having four or more ring atoms, e.g. furans, dioxolanes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046Hydroxy ethers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/284Esters of aromatic monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/285Esters of aromatic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/34Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/402Castor oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

Brems- bzw. Druckflüssigkeiten Zur Erzeugung eines hydraulischen Druckes, wie er beispielsweise zur Betätigung von Bremsen oder Druckstempeln erforderlich ist, sind bereits verschiedene Flüssigkeiten vorgeschlagen worden, von denen fette Öle, insbesondere Rizinusöl, mineralische Öle, Glycerin für sich oder in Mischung mit anderen Stoffen, wie Äthyl-, Butyl- oder Amylalkohol, die gebräuchlichsten sind. Alle diese Handelsprodukte weisen jedoch insofern Nachteile auf, als sie entweder bei erhöhten Temperaturen, wie sie im Automobilmotor und besonders beim Gebrauch in den Tropen häufig auftreten, zu leicht flüchtig oder bei tiefen Temperaturen infolge zu hoher Zähigkeit nur schwer beweglich sind oder aber der nötigen Gleitfähigkeit überhaupt entbehren, so daß es nicht möglich ist, bei einem verzweigten System, wie dies beispielsweise bei Automobilbremsen der Fall ist, an allen Stellen einen gleichmäßigen Druck zu erzeugen. Wieder andere Flüssigkeiten lassen die nötige Beständigkeit zumal bei erhöhten Temperaturen vermissen und neigen dann dazu, chemisch aggressiv zu wirken, indem sie beispielsweise Gummi, Leder, Kunststoffe oder Metalle, insbesondere Kupfer, angreifen und Zerstörungen hervorrufen.Brake or pressure fluids To generate hydraulic pressure, as required, for example, to operate brakes or pressure rams various liquids have been proposed, one of which is fat Oils, in particular castor oil, mineral oils, glycerine alone or as a mixture with other substances, such as ethyl, butyl or amyl alcohol, which are the most common. However, all of these commercial products have disadvantages in that they either at elevated temperatures, such as those in the automobile engine and especially during use occur frequently in the tropics, are too volatile or at low temperatures are difficult to move due to too high toughness or the necessary sliding ability dispense at all, so that it is not possible in a branched system, As is the case with automobile brakes, for example, one at all points to generate even pressure. Still other liquids leave the necessary resistance especially since miss at elevated temperatures and then tend to be chemically aggressive to work by, for example, rubber, leather, plastics or metals, in particular Copper, attack and cause destruction.

Es wurde nun gefunden,, :daß sich die cyclischen Äther, welche wenigstens 2 Sauerstoffatome im Ring enthalten und außerdem noch durch Hydroxylgruppen substituiert sind, ausgezeichnet als Brems- und Druckflüssigkeiten eignen. Die Produkte der beanspruchten Art lassen sich leicht durch Kondensation von Carbonylverbindungen, wie Formaldehyd, Acetaldehyd, Aceton, Benzaldehyd, Furfurol, Campher, Cyclohexanon, Methylcyclohexanon, Dekahydro-ß-naphtylketon usw., mit mehrwertigen, aliphatischen Alkoholen, wie Glycerin, Erythrit, Arabit, Dulcit, Mannit u. dgl., gewinnen. Durch Veresterung oder Verätherung der noch freie Hydroxylgruppen enthaltenden cyclischen Äther sind je nach Wunsch Brems- bzw. Druckflüssigkeiten mit niederer oder höherer Viscosität herstellbar. Als besonders geeignet für den Gebrauch als Brems- und Druckflüssigkeit bzw. für die Bereitung solcher Flüssigkeiten haben sich beispielsweise 2, 2-Dimethyl-q.-oxymethyldihydrodioxol (Acetonglycerin), Acetonglycerinbutyläther, Acetonarabit, Mannittriformal, Diacetonerythrit, Benzylidenglycerin so-,vie das aus Cyclohexanon und Glycerin erhältliche 2, 2-Pentamethylen-q.-oxymethyldihydrodioxol (Cyclohexanonglycerin) und das Cyclohexanonglycerinphtalat erwiesen.It has now been found,: that the cyclic ethers, which at least Contains 2 oxygen atoms in the ring and also substituted by hydroxyl groups are excellent as brake and pressure fluids. The products of the claimed Type can be easily removed by condensation of carbonyl compounds such as formaldehyde, Acetaldehyde, acetone, benzaldehyde, furfural, camphor, cyclohexanone, methylcyclohexanone, Decahydro-ß-naphthyl ketone, etc., with polyhydric, aliphatic alcohols such as glycerine, Erythritol, arabitol, dulcitol, mannitol and the like win. By esterification or etherification the cyclic ethers still containing free hydroxyl groups are as desired Brake or pressure fluids with lower or higher viscosity can be produced. As particularly suitable for use as a brake and pressure fluid or for the preparation of such liquids have, for example, 2,2-dimethyl-q.-oxymethyldihydrodioxole (Acetone glycerine), acetone glycerine butyl ether, acetone arabitol, mannitol triformal, diacetonerythritol, Benzylidene glycerine and the 2,2-pentamethylene-q.-oxymethyldihydrodioxole obtainable from cyclohexanone and glycerine (Cyclohexanone glycerine) and the cyclohexanone glycerine phthalate.

Die beanspruchten Produkte zeichnen sich durch neutrale Reaktion, große Temperaturbeständigkeit, gute Verschnittfähigkeit mit anderen bekannten Mitteln und eine bei allen in Betracht kommenden Temperaturen gute Gleitfähigkeit aus. Sie können sowohl für sich als in Mischung miteinander sowie zusammen mit anderen bekannten, für die gleichen Verwerdüngszwecke-bereits vorgeschlagenen Mitteln gebraucht werden.The claimed products are characterized by a neutral reaction, high temperature resistance, good blending ability with other known means and good sliding properties at all possible temperatures. she can be used both individually and in combination with one another as well as together with other known, for the same Verdüngszwecken-already proposed means to be needed.

Als geeignete Bremsflüssigkeiten seien beispielsweise Mischungen von 8o Gewichtstelen Rizinusöl und 5o Gewichtsteilen Cyclohexanonglycerin oder 5o Gewichtsteilen Glycerin und 5o Gewichtsteilen Diacetonerythrit genannt.Suitable brake fluids are, for example, mixtures of 8o weight steles of castor oil and 50 weight parts of cyclohexanone glycerine or 50 weight parts Glycerin and 50 parts by weight of diacetonerythritol called.

Für Druckstempel geeignete Flüssigkeiten können beispielsweise aus folgenden Mischungen bestehen: frs Teilen Glycerin und 35 Teilen Acetonmannit oder 45 Teilen Acetonglycerincetyläther und 55 Teilen Rizinusöl oder 3o Teilen Äthylenglykolmonoäthyläther und ;o Teilen Cyclopentanonglycerinphtalat.Liquids suitable for pressure stamps can, for example, consist of The following mixtures exist: for one part glycerine and 35 parts acetone mannitol or 45 parts of acetone glycerol cetyl ether and 55 parts of castor oil or 3o parts of ethylene glycol monoethyl ether and; o parts of cyclopentanone glycerol phthalate.

Claims (3)

PATENTANSPRÜCHE: i. Brems- bzw. Druckflüssigkeiten, bestehend aus cyclischen Äthern, welche wenigstens PATENT CLAIMS: i. Brake or pressure fluids, consisting of cyclic ethers, which at least 2 Sauerstoffatome im Ring enthalten und außerdem noch hydroxylsubstituiert sind. z. Brems- bzw. Druckflüssigkeit, bestehend aus Äthern oder Estern der im Anspruch i geschützten hydroxylsubstitnierten cyclischen Äther. Contains 2 oxygen atoms in the ring and also are still hydroxyl-substituted. z. Brake or pressure fluid, consisting of ethers or esters of the hydroxyl-substituted cyclic ethers protected in claim i. 3. Brems- bzw. Druckflüssigkeit, bestehend aus den im Anspruch i und 2 geschützten cyclischen Äthern im Gemisch miteinander oder mit anderen bekannten, in gleicher Weise wirkenden Mitteln.3. Brake or pressure fluid, consisting of those protected in claims i and 2 cyclic ethers mixed with one another or with other known ones in the same way Wise acting means.
DED68317D 1934-06-26 1934-06-26 Brake or pressure fluids Expired DE645939C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DED68317D DE645939C (en) 1934-06-26 1934-06-26 Brake or pressure fluids

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DED68317D DE645939C (en) 1934-06-26 1934-06-26 Brake or pressure fluids

Publications (1)

Publication Number Publication Date
DE645939C true DE645939C (en) 1937-06-05

Family

ID=7059954

Family Applications (1)

Application Number Title Priority Date Filing Date
DED68317D Expired DE645939C (en) 1934-06-26 1934-06-26 Brake or pressure fluids

Country Status (1)

Country Link
DE (1) DE645939C (en)

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