DE602005006822D1 - METHOD FOR PRODUCING A COPPER GERMANIUM BOR PRE-ALLOY AND USE THEREOF FOR THE PRODUCTION OF SILVER COPPER ALLOYS - Google Patents
METHOD FOR PRODUCING A COPPER GERMANIUM BOR PRE-ALLOY AND USE THEREOF FOR THE PRODUCTION OF SILVER COPPER ALLOYSInfo
- Publication number
- DE602005006822D1 DE602005006822D1 DE602005006822T DE602005006822T DE602005006822D1 DE 602005006822 D1 DE602005006822 D1 DE 602005006822D1 DE 602005006822 T DE602005006822 T DE 602005006822T DE 602005006822 T DE602005006822 T DE 602005006822T DE 602005006822 D1 DE602005006822 D1 DE 602005006822D1
- Authority
- DE
- Germany
- Prior art keywords
- alloy
- silver
- copper
- boron
- master
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/06—Alloys based on silver
- C22C5/08—Alloys based on silver with copper as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Adornments (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
A master metal composition adapted for alloying with silver to give an alloy containing at least 77 wt % Ag and at least 0.5 wt % Ge comprises Cu, Ge and boron together with any further ingredients for said alloy and any impurities. It further provides a process for making silver alloy containing silver in an amount of at least 77 wt % Ag, 1-7.2 wt % Cu copper, at least 0.5 wt % Ge and B together with any further ingredients for said alloy and any impurities, comprising the step of melting together fine silver and a master metal composition which is at least a ternary alloy of copper, germanium and boron, e.g. 92.5-92.8 wt % Ag, 6.0-6.3 wt % Cu, about 1.2 wt % Ge and 1-15 ppm boron as grain refiner. The resulting silver alloy exhibits good tarnish and firestain resistance and can exhibit significant precipitation hardening on gradual air cooling. In a further aspect the invention relates to method for manufacturing a copper-based master alloy for use in the manufacture of silver alloy products, wherein the molten master alloy prior to solidification is treated with a decomposable boron compound e.g. a boron hydride or metal borohydride.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0421179A GB2418432A (en) | 2004-09-23 | 2004-09-23 | Silver alloy and its production using a master metal |
GB0508501A GB0508501D0 (en) | 2004-09-23 | 2005-04-27 | Metal alloy and its use |
PCT/GB2005/050163 WO2006032933A1 (en) | 2004-09-23 | 2005-09-23 | Copper-boron master alloy and its use in making silver-copper alloys |
Publications (1)
Publication Number | Publication Date |
---|---|
DE602005006822D1 true DE602005006822D1 (en) | 2008-06-26 |
Family
ID=35432080
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE602005006822T Active DE602005006822D1 (en) | 2004-09-23 | 2005-09-23 | METHOD FOR PRODUCING A COPPER GERMANIUM BOR PRE-ALLOY AND USE THEREOF FOR THE PRODUCTION OF SILVER COPPER ALLOYS |
Country Status (8)
Country | Link |
---|---|
US (1) | US20080078484A1 (en) |
EP (1) | EP1794335B1 (en) |
JP (1) | JP2008513607A (en) |
AT (1) | ATE395442T1 (en) |
AU (1) | AU2005286209A1 (en) |
CA (1) | CA2580960A1 (en) |
DE (1) | DE602005006822D1 (en) |
WO (1) | WO2006032933A1 (en) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9222150B2 (en) | 2004-06-02 | 2015-12-29 | Peter Gamon Johns | Process for making finished or semi-finished articles of silver alloy |
GB2485374B (en) * | 2010-11-11 | 2013-07-24 | Argentium Internat Ltd | Alloy for investment casting |
GB2426250A (en) * | 2005-05-20 | 2006-11-22 | Middlesex Silver Co Ltd | Silver alloys |
WO2006123190A1 (en) * | 2005-05-20 | 2006-11-23 | Middlesex Silver Co. Limited | Silver-copper-germanium alloy manufacturing |
GB2428045A (en) * | 2005-07-07 | 2007-01-17 | Middlesex Silver Co Ltd | Silver-copper-germanium alloy |
US20060231171A1 (en) * | 2005-04-19 | 2006-10-19 | Davis Samuel A | Method for adding boron to metal alloys |
GB2434376A (en) * | 2006-01-23 | 2007-07-25 | Middlesex Silver Co Ltd | Making boron containing gold alloys using a master alloy |
EP1930478B1 (en) * | 2006-12-06 | 2013-06-19 | Enthone, Inc. | Electrolyte composition and method for the deposition of quaternary copper alloys |
US8501088B2 (en) * | 2007-07-25 | 2013-08-06 | Nippon Steel & Sumikin Materials Co., Ltd. | Solder alloy, solder ball and electronic member having solder bump |
WO2009034834A1 (en) * | 2007-09-10 | 2009-03-19 | Murata Manufacturing Co., Ltd. | Ceramic multilayer substrate and method for producing the same |
KR101283580B1 (en) * | 2011-12-14 | 2013-07-05 | 엠케이전자 주식회사 | Tin-based solder ball and semiconductor package including the same |
JP2014047127A (en) * | 2012-09-04 | 2014-03-17 | Toyo Tanso Kk | Metal-carbon composite material, manufacturing method of metal-carbon composite material, and sliding member |
RU2513502C1 (en) * | 2013-04-16 | 2014-04-20 | Федеральное Государственное Автономное Образовательное Учреждение Высшего Профессионального Образования "Сибирский Федеральный Университет" | White alloy based on 925-assay silver modified by silicon |
CN103643072B (en) * | 2013-11-20 | 2015-12-09 | 北海鑫利坤金属材料科技开发有限公司 | A kind of silver alloy with excellent mechanical performances |
CN107208186A (en) * | 2014-11-28 | 2017-09-26 | 迭戈·佩雷蒂 | Foundry alloy for manufacturing White gold alloy |
GB2561376A (en) * | 2017-04-12 | 2018-10-17 | Argentium International Ltd | Silver alloys, investment casting using the alloys and casting grain |
WO2023196341A1 (en) | 2022-04-05 | 2023-10-12 | Doggone Investment Co. LLC | Apparatus and method for production of high purity copper-based alloys |
CN114990378B (en) * | 2022-06-14 | 2023-03-10 | 西安理工大学 | Preparation method of high-conductivity and high-wear-resistance copper-boron alloy |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4406370A (en) * | 1980-03-29 | 1983-09-27 | Foseco International Limited | Additive containers for metal casting |
US5039479A (en) * | 1990-09-05 | 1991-08-13 | United Precious Metal Refining Co., Inc. | Silver alloy compositions, and master alloy compositions therefor |
US6726877B1 (en) * | 1993-11-15 | 2004-04-27 | Anthony Phillip Eccles | Silver alloy compositions |
US6168071B1 (en) * | 1994-11-17 | 2001-01-02 | Peter Gamon Johns | Method for joining materials together by a diffusion process using silver/germanium alloys and a silver/germanium alloy for use in the method |
US6217632B1 (en) * | 1998-06-03 | 2001-04-17 | Joseph A. Megy | Molten aluminum treatment |
GB9926313D0 (en) * | 1999-11-05 | 2000-01-12 | Johns Peter G | A silver/copper/germanium alloy composition |
GB0112623D0 (en) * | 2001-05-23 | 2001-07-18 | Johns Peter G | Method of producing silver-copper alloys |
-
2004
- 2004-09-23 US US11/663,600 patent/US20080078484A1/en not_active Abandoned
-
2005
- 2005-09-23 DE DE602005006822T patent/DE602005006822D1/en active Active
- 2005-09-23 CA CA002580960A patent/CA2580960A1/en not_active Abandoned
- 2005-09-23 JP JP2007532976A patent/JP2008513607A/en not_active Withdrawn
- 2005-09-23 WO PCT/GB2005/050163 patent/WO2006032933A1/en active IP Right Grant
- 2005-09-23 AU AU2005286209A patent/AU2005286209A1/en not_active Abandoned
- 2005-09-23 EP EP05805095A patent/EP1794335B1/en active Active
- 2005-09-23 AT AT05805095T patent/ATE395442T1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ATE395442T1 (en) | 2008-05-15 |
US20080078484A1 (en) | 2008-04-03 |
EP1794335B1 (en) | 2008-05-14 |
JP2008513607A (en) | 2008-05-01 |
WO2006032933A1 (en) | 2006-03-30 |
CA2580960A1 (en) | 2006-03-30 |
EP1794335A1 (en) | 2007-06-13 |
AU2005286209A1 (en) | 2006-03-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: ARGENTIUM INTERNATIONAL LIMITED, SURREY, GB |
|
8328 | Change in the person/name/address of the agent |
Representative=s name: BOEHMERT & BOEHMERT, 28209 BREMEN |