DE602004008856D1 - Acrylatfunktionelles blockiertes Polyisocyanatharz für dual cure Beschichtungen - Google Patents

Acrylatfunktionelles blockiertes Polyisocyanatharz für dual cure Beschichtungen

Info

Publication number
DE602004008856D1
DE602004008856D1 DE602004008856T DE602004008856T DE602004008856D1 DE 602004008856 D1 DE602004008856 D1 DE 602004008856D1 DE 602004008856 T DE602004008856 T DE 602004008856T DE 602004008856 T DE602004008856 T DE 602004008856T DE 602004008856 D1 DE602004008856 D1 DE 602004008856D1
Authority
DE
Germany
Prior art keywords
acrylate
blocked polyisocyanate
dual cure
polyisocyanate resin
cure coatings
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DE602004008856T
Other languages
English (en)
Other versions
DE602004008856T2 (de
Inventor
Scott A Grace
Michael J Dvorchak
Richard R Roesler
Dinesh Pethiyagoda
Michael K Jeffries
Jan Weikard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro LLC
Original Assignee
Bayer MaterialScience LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience LLC filed Critical Bayer MaterialScience LLC
Publication of DE602004008856D1 publication Critical patent/DE602004008856D1/de
Application granted granted Critical
Publication of DE602004008856T2 publication Critical patent/DE602004008856T2/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67Unsaturated compounds having active hydrogen
    • C08G18/671Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/80Masked polyisocyanates
    • C08G18/8061Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81Unsaturated isocyanates or isothiocyanates
    • C08G18/8141Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
DE602004008856T 2003-10-27 2004-10-16 Acrylatfunktionelles blockiertes Polyisocyanatharz für dual cure Beschichtungen Active DE602004008856T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US694107 2003-10-27
US10/694,107 US7144955B2 (en) 2003-10-27 2003-10-27 Acrylate-functional blocked polyisocyanate resin for UV/thermally curable coatings

Publications (2)

Publication Number Publication Date
DE602004008856D1 true DE602004008856D1 (de) 2007-10-25
DE602004008856T2 DE602004008856T2 (de) 2008-06-19

Family

ID=34435467

Family Applications (1)

Application Number Title Priority Date Filing Date
DE602004008856T Active DE602004008856T2 (de) 2003-10-27 2004-10-16 Acrylatfunktionelles blockiertes Polyisocyanatharz für dual cure Beschichtungen

Country Status (4)

Country Link
US (1) US7144955B2 (de)
EP (1) EP1529793B1 (de)
CA (1) CA2486034C (de)
DE (1) DE602004008856T2 (de)

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DE10357712A1 (de) * 2003-12-09 2005-07-14 Bayer Materialscience Ag Härter
DE102004043540A1 (de) * 2004-09-09 2006-03-30 Bayer Materialscience Ag Niedrigviskose Allophanate mit aktinisch härtbaren Gruppen
US20070049676A1 (en) * 2005-08-26 2007-03-01 Xerox Corporation Thick electrophotographic imaging member undercoat layers
US20070066698A1 (en) * 2005-09-20 2007-03-22 Yang Wenliang P Dual cure compositions, methods of curing thereof and articles therefrom
JP5337762B2 (ja) * 2010-06-25 2013-11-06 株式会社日立産機システム コイル固着用不飽和ポリエステル樹脂組成物
US20120138223A1 (en) 2011-09-29 2012-06-07 General Electric Company Uv-ir combination curing system and method of use for wind blade manufacture and repair
WO2014014437A2 (en) 2012-07-16 2014-01-23 Empire Technology Development Llc Self-renewing hydrophilic organic coatings
CN108475008B (zh) 2015-12-22 2020-11-06 卡本有限公司 一种形成三维物体的方法
US10647054B2 (en) 2015-12-22 2020-05-12 Carbon, Inc. Accelerants for additive manufacturing with dual cure resins
US10787583B2 (en) 2015-12-22 2020-09-29 Carbon, Inc. Method of forming a three-dimensional object comprised of a silicone polymer or co-polymer
WO2017112521A1 (en) 2015-12-22 2017-06-29 Carbon, Inc. Production of flexible products by additive manufacturing with dual cure resins
WO2017112653A1 (en) 2015-12-22 2017-06-29 Carbon, Inc. Dual precursor resin systems for additive manufacturing with dual cure resins
KR101770819B1 (ko) * 2016-03-16 2017-08-23 경희대학교 산학협력단 복합 경화성 조성물의 경화방법
WO2018094131A1 (en) 2016-11-21 2018-05-24 Carbon, Inc. Method of making three-dimensional object by delivering reactive component for subsequent cure
JP2020523217A (ja) * 2017-06-08 2020-08-06 カーボン,インコーポレイテッド 付加製造において有用な光重合性樹脂のブロッキング基
WO2019112707A1 (en) 2017-12-08 2019-06-13 Carbon, Inc. Shelf stable, low tin concentration, dual cure additive manufacturing resins
US20200406550A1 (en) 2018-03-02 2020-12-31 Carbon, Inc. Sustainable additive manufacturing resins and methods of recycling
MX2020012326A (es) 2018-05-17 2021-06-15 Avery Dennison Corp Laminado amortiguador multicapa de cobertura parcial.
WO2020131675A1 (en) 2018-12-21 2020-06-25 Carbon, Inc. Energy absorbing dual cure polyurethane elastomers for additive manufacturing
WO2021101801A1 (en) 2019-11-18 2021-05-27 Carbon, Inc. Partial dentures and methods of making the same
CN110951046A (zh) * 2019-12-03 2020-04-03 蚌埠阿迪亚新材料有限公司 一种可uv/热双固化封闭聚异氰酸酯乳液及其制备方法
WO2021146237A1 (en) 2020-01-17 2021-07-22 Carbon, Inc. Chemical recycling of additively manufactured objects
WO2021202655A1 (en) 2020-04-03 2021-10-07 Carbon, Inc. Resins and methods for additive manufacturing of energy absorbing three-dimensional objects
CN113388075B (zh) * 2021-06-11 2023-03-24 珠海赛纳三维科技有限公司 一种3d打印用组合物、3d打印方法、装置

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JPS4831742B1 (de) 1968-03-01 1973-10-01
US3664361A (en) * 1970-08-24 1972-05-23 Puritan Bennett Corp Respiration system
US4008247A (en) 1973-11-02 1977-02-15 The B. F. Goodrich Company Ethylenically unsaturated blocked aromatic diisocyanates
US4342793A (en) 1977-01-14 1982-08-03 Henkel Corporation Interpenetrating dual cure resin compositions
DE3318147A1 (de) 1983-05-18 1984-11-22 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von, isocyanuratgruppen und olefinische doppelbindungen aufweisenden verbindungen, die nach diesem verfahren erhaeltlichen verbindungen und ihre verwendung als bindemittel bzw. bindemittelkomponente in ueberzugsmitteln
US5234970A (en) 1991-07-16 1993-08-10 W. R. Grace & Co.-Conn. Dual curing composition based on isocyanate trimer and use thereof
DE4237030A1 (de) 1992-11-03 1994-05-05 Basf Ag Bei Raumtemperatur vernetzende Copolymerisate
FR2699182B1 (fr) 1992-12-15 1995-07-13 Rhone Poulenc Chimie Monomere presentant au moins une fonction isocyanate et une insuturation son procede de synthese et (co)polymeres en decoulant.
DE19860041A1 (de) * 1998-12-23 2000-06-29 Basf Ag Durch Addition an Isocyanatgruppen als auch durch strahlungsinduzierte Addition an aktivierte C-C-Doppelbindungen härtbare Beschichtungsmittel
EP1224234B8 (de) 1999-09-30 2008-04-02 Basf Se Mit uv-strahlung und thermisch härtbare wässrige polyurethandispersionen sowie deren verwendung
DE10033697A1 (de) * 2000-07-12 2002-01-24 Basf Ag Mit UV-Strahlung und thermisch härtbare wässrige Polyurethandispersionen sowie deren Verwendung
US6815501B2 (en) 2002-04-09 2004-11-09 E. I. Du Pont De Nemours And Company Dual cure coating compositions and process for the production of multilayer coatings

Also Published As

Publication number Publication date
EP1529793A3 (de) 2006-02-22
DE602004008856T2 (de) 2008-06-19
EP1529793A2 (de) 2005-05-11
CA2486034C (en) 2012-05-15
US7144955B2 (en) 2006-12-05
CA2486034A1 (en) 2005-04-27
US20050090620A1 (en) 2005-04-28
EP1529793B1 (de) 2007-09-12

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