DE60120005D1 - Katalysator für asymmetrische Epoxidierungen von Enonen und Verfahren zur Herstellung optisch-aktiver Epoxide - Google Patents

Katalysator für asymmetrische Epoxidierungen von Enonen und Verfahren zur Herstellung optisch-aktiver Epoxide

Info

Publication number
DE60120005D1
DE60120005D1 DE60120005T DE60120005T DE60120005D1 DE 60120005 D1 DE60120005 D1 DE 60120005D1 DE 60120005 T DE60120005 T DE 60120005T DE 60120005 T DE60120005 T DE 60120005T DE 60120005 D1 DE60120005 D1 DE 60120005D1
Authority
DE
Germany
Prior art keywords
enones
catalyst
preparation
optically active
asymmetric epoxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60120005T
Other languages
English (en)
Other versions
DE60120005T2 (de
Inventor
Junji Inanaga
Takumi Kagawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Tosoh Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2000052148A external-priority patent/JP4378826B2/ja
Priority claimed from JP2000073996A external-priority patent/JP4525993B2/ja
Application filed by Tosoh Corp filed Critical Tosoh Corp
Application granted granted Critical
Publication of DE60120005D1 publication Critical patent/DE60120005D1/de
Publication of DE60120005T2 publication Critical patent/DE60120005T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/37—Lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/20—Non-coordinating groups comprising halogens
    • B01J2540/22—Non-coordinating groups comprising halogens comprising fluorine, e.g. trifluoroacetate
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
DE60120005T 2000-02-23 2001-02-22 Katalysator für asymmetrische Epoxidierungen von Enonen und Verfahren zur Herstellung optisch-aktiver Epoxide Expired - Lifetime DE60120005T2 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2000052148 2000-02-23
JP2000052148A JP4378826B2 (ja) 2000-02-23 2000-02-23 エノン類の不斉エポキシ化反応用錯体触媒、及びそれを用いた光学活性エポキシドの製造方法
JP2000073996A JP4525993B2 (ja) 2000-03-13 2000-03-13 不斉エポキシ化触媒及び光学活性エポキシドの製造方法
JP2000073996 2000-03-13

Publications (2)

Publication Number Publication Date
DE60120005D1 true DE60120005D1 (de) 2006-07-06
DE60120005T2 DE60120005T2 (de) 2007-04-12

Family

ID=26586272

Family Applications (3)

Application Number Title Priority Date Filing Date
DE60120005T Expired - Lifetime DE60120005T2 (de) 2000-02-23 2001-02-22 Katalysator für asymmetrische Epoxidierungen von Enonen und Verfahren zur Herstellung optisch-aktiver Epoxide
DE60116383T Expired - Lifetime DE60116383T2 (de) 2000-02-23 2001-02-22 Katalysator für asymmetrische Epoxidierungen von Enonen und Verfahren zur Herstellung optisch-aktiver Epoxide
DE60129608T Expired - Lifetime DE60129608T2 (de) 2000-02-23 2001-02-22 Verfahren zur Herstellung optisch aktiver Epoxide

Family Applications After (2)

Application Number Title Priority Date Filing Date
DE60116383T Expired - Lifetime DE60116383T2 (de) 2000-02-23 2001-02-22 Katalysator für asymmetrische Epoxidierungen von Enonen und Verfahren zur Herstellung optisch-aktiver Epoxide
DE60129608T Expired - Lifetime DE60129608T2 (de) 2000-02-23 2001-02-22 Verfahren zur Herstellung optisch aktiver Epoxide

Country Status (3)

Country Link
US (2) US6680275B2 (de)
EP (3) EP1439001B1 (de)
DE (3) DE60120005T2 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6680275B2 (en) 2000-02-23 2004-01-20 Tosoh Corporation Catalyst for asymmetric epoxidation of enones and process for producing optically active epoxide employing it
US7169944B2 (en) * 2002-09-25 2007-01-30 Tosoh Corporation Optically active epoxy compounds and processes for their production
CN115504873B (zh) * 2021-06-23 2024-05-28 中国石油化工股份有限公司 一种催化转化环己烯制备环己烯酮的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5336653A (en) * 1992-11-03 1994-08-09 Chisso Corporation Catalyst for asymmetric synthesis
JP3755210B2 (ja) 1996-10-22 2006-03-15 日産化学工業株式会社 希土類金属錯体触媒を用いる不斉エポキシ化反応
US6201123B1 (en) 1998-07-08 2001-03-13 Techno Polymer Co., Ltd. Catalyst composition, catalyst solution and process for preparing optically active epoxide
JP4283377B2 (ja) 1998-07-08 2009-06-24 東ソー株式会社 エノン類の不斉エポキシ化触媒及びそれを用いた光学活性エポキシドの製造方法
US6680275B2 (en) 2000-02-23 2004-01-20 Tosoh Corporation Catalyst for asymmetric epoxidation of enones and process for producing optically active epoxide employing it
US6809059B2 (en) 2000-08-21 2004-10-26 Johnson Matthey Plc Catalyst

Also Published As

Publication number Publication date
EP1366815B1 (de) 2005-12-28
DE60116383T2 (de) 2006-07-13
DE60116383D1 (de) 2006-02-02
DE60129608T2 (de) 2008-05-21
EP1366815A1 (de) 2003-12-03
EP1439001B1 (de) 2007-07-25
DE60129608D1 (de) 2007-09-06
US20040116721A1 (en) 2004-06-17
US20010051737A1 (en) 2001-12-13
US6878835B2 (en) 2005-04-12
EP1439001A1 (de) 2004-07-21
EP1127616B1 (de) 2006-05-31
US6680275B2 (en) 2004-01-20
DE60120005T2 (de) 2007-04-12
EP1127616A1 (de) 2001-08-29

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