DE60010538T2 - Cleansing cosmetic compositions and their use - Google Patents

Description

The The present invention relates to novel cosmetic compositions with improved properties for cleaning and at the same time for conditioning and for the hairdressing design of keratin substances and in particular the Hair is provided and in a cosmetically acceptable carrier a cleansing Base formulation consisting of surfactants with cleaning power and in the further cationic polymers in combination with a water-soluble, anionic polyurethane or polyurea. The invention also concerns the use of these compositions for the above-mentioned cosmetic Application.

to Cleaning and / or laundry the hair becomes common essentially cleaning compositions (or shampoos) on the basis of conventional surfactant Substances, in particular anionic, nonionic and / or amphoteric Type, but especially of the anionic type used. The Compositions are applied to damp hair, and by the foam produced by massaging or rubbing with the hands after do the washing up with water the dirt is removed from the hair.

These Although basic compositions have good detergency, however, the cosmetic properties associated with them are inadequate, especially since this relatively aggressive cleaning treatment more or less pronounced damage along the entire hair fiber can cause, in particular associated with it, that the lipids or proteins present in the hair fiber or at the surface the hair fiber are present, are gradually removed.

to Improvement of the cosmetic properties of the above cleansing Compositions and in particular compositions based on sensitized hair (i.e., hair that is particularly affected by chemical Exposure to in the atmosphere existing means and / or hair treatments, such as Permanent wave treatments, dyeings or discolorations, was strained or brittle It is customary today to apply in these compositions additional to incorporate cosmetic agents called conditioning agents be and mainly to serve the harmful ones or unwanted To offset or limit effects caused by the different Treatments or actions that cause the hair fibers more or less frequently exposed are. These conditioning agents can Of course also improve the cosmetic texture of natural hair.

at the conditioners currently used in shampoos mostly are used, they are cationic polymers; by these conditioning agents are compared with the corresponding ones cleansing compositions that do not contain these, the washed, Dry or damp hair easier to comb, softer and smoother.

you has been trying for some time to make conditioning shampoos, the washed hair not only the above-described cosmetic To give properties, but in a more or less strong extent too Hair styling properties, volume, light shaping and hold with it to bring. These cleansing shampoos, the general Better cosmetic properties often become easy as a 'shampoo with hairdressing properties'; this expression will be below Text used.

In spite of the lately in the field of hair detergents based on cationic However, these are not completely satisfactory for polymers putting, so that also at present a strong need for new products exists with regard to one or more of the above cosmetic properties are more efficient.

The The present invention is intended to meet this need.

To extensive research on this issue has the Applicant completely unexpected and surprising found that it was through the use of an anionic polycondensate with polyurethane sequence and / or polyurea sequence, hereinafter is defined, in cleaning compositions, the cationic Containing polymers, in particular compositions for hair treatment, possible All that is related to these cosmetic properties significantly and significantly improve, but get their good cleaning power remains.

In In the description and in the claims, the term polyurethane as synonymous with polycondensate containing at least one polyurethane sequence and / or polyurea sequence.

Without to set the present invention to a certain theory want, could during the flushing process between the cationic Po lymeren, the inventive anionic Polyurethanes and hair special interactions and / or affinities consist of a regular, essential and permanent deposition of the polyurethanes and / or cationic Polymers on the surface favor the hair, this qualitative and quantitative deposition is likely one of the reasons for the Improvements are, in the end, in terms of properties too especially with regard to easy combing, the hold, the elasticity and the volume of the treated hair. In any case, the cosmetic properties associated with the Basic formulations according to the invention related, the combination according to the invention [cationic polymer / polyurethane], significantly better than the cosmetic properties using compositions which are only one component in equivalent total concentration contain.

The The present invention is based on these findings.

According to the present The invention therefore provides novel cleansing compositions, in particular for the Hair treatment, indicated in a cosmetically acceptable medium a cleansing base formulation, at least one cationic polymer and at least one water-soluble anionic polycondensate with polyurethane sequence and / or polyurea sequence contain.

The The invention further relates to the use of the above-mentioned compositions for the Cleaning, conditioning and hair styling of keratin substances and in particular of hair in cosmetics.

Further Features, aspects and advantages of the invention will be apparent from the description and concrete examples, for explanation serve and by no means restrictive to be understood.

As stated above are the essential components the products of the invention to (i) one or more detergent surfactants which should form the cleansing base formulation, (ii) one or more cationic polymers and (iii) one or more water-soluble polyurethanes.

A - Purifying base formulation

The Compositions of the invention necessarily contain a cleansing base formulation, in general aqueous is.

Of the or the surfactant Substances that form the cleansing base formulation can be found among the anionic, amphoteric, nonionic, zwitterionic and cationic surfactant Substances or mixtures thereof. The cleansing Basic formulation contains however, preferably according to the invention anionic surfactant Substances or mixtures of anionic surfactants and amphoterics surfactant Substances or nonionic surfactants.

Of the Proportion of the cleaning base formulation is minimally chosen so that he just enough to make the finished composition a satisfied imparting foaming and / or cleaning power, wherein high proportions of the detergent base formulation no additional Bring benefits.

The According to the invention, the cleansing base formulation may therefore comprise 4 to 50% by weight, preferably 6 to 25% by weight, and more preferably 8 to 20 wt .-% of the total weight of the finished composition.

Especially the following surfactant Fabrics are for use in accordance with the present invention suitable:

(i) anionic surfactant (r) Substance (s)

As examples of anionic surfactants which can be used singly or in admixture in the context of the present invention, the salts (and in particular the alkali metal salts, especially the sodium salts, ammonium salts, amine salts, aminoalcohol salts or magnesium salts) of the following compounds can be mentioned in particular Non-limiting): alkyl sulfates, alkyl ether sulfates, alkyl amidoether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates; Alkyl sulfonates, alkyl phosphates, alkyl amide sulfonates, alkylaryl sulfonates, alpha-olefin sulfonates, paraffin sulfonates; Alkyl (C _6-24) sulfosuccinates, alkyl (C _6-24) ethersulfosuccinate, alkyl (C _6-24) amidsulfosuccinate; Alkyl (C _6-24 ) sulfoacetates; Acyl (C _6-24 ) sarcosinates and acyl (C _6-24 ) glutamates. Also, carboxylic acid alkyl (C _6-24 ) polyglycosides such as alkyl glucoside citrates, alkyl polyglucoside tartrates and alkyl polyglucoside sulfosuccinates, alkyl sulfosuccinamates; Acyl isethionates and N-Acyltaurate be given, wherein the alkyl or acyl groups of the various compounds preferably contain 12 to 20 carbon atoms and the aryl group is preferably phenyl or benzyl. Of the other useful anionic surfactants, the salts of fatty acids, for example, the salts of oleic acid, ricinoleic acid, palmitic acid, stearic acid and acids of coconut oil or hydrogenated coconut oil; and the acyl lactylates whose acyl group has 8 to 20 carbon atoms. They are also the alkyl-D-galactoside uronic acids and their salts and the polyalkoxylated carboxylic acid alkyl (C _6-24 ) ethers, the polyalkoxylated carboxylic acid alkyl (C _6-24 ) aryl ethers, the polyalkoxylated carboxylic acid alkyl (C _6-24 ) amido ethers and their Salts, in particular the compounds having from 2 to 50 alkylene oxide groups, especially ethylene oxide groups, as well as to mention their mixtures.

The anionic surfactant Substances with carboxy group are particularly preferred.

(ii) nonionic (r) surfactant (s) Substance (s)

The nonionic surfactants are also known compounds (see in particular 'Handbook of Surfactants' by MR PORTER, Edition Blackie & Son (Glasgow and London), 1991, pp. 116-178) and their nature is within the scope of the present invention not critical. They can therefore be selected in particular from the following compounds, the list not being intended to be limiting: alcohols, α-diols, alkylphenols or fatty acids which are polyethoxylated, polypropoxylated or etherified several times with glycerol, having a fatty chain which is, for example, 8 contains up to 18 carbon atoms, and wherein the number of ethylene oxide groups or propylene oxide groups in particular in the range of 2 to 50 and the number of glycerol groups may be in particular in the range of 2 to 30. The copolymers of ethylene oxide and propylene oxide, the condensates of ethylene oxide and propylene oxide with fatty alcohols; the polyethoxylated fatty amides which preferably have 2 to 30 moles of ethylene oxide, the polyglycerol-etherified fatty amides having on average 1 to 5 glycerol groups and in particular 1 to 5 to 4 glycerol groups; the polyethoxylated fatty amines which preferably have from 2 to 30 moles of ethylene oxide; the ethoxylated sorbitan fatty acid esters with 2 to 30 moles of ethylene oxide; the sucrose fatty acid esters, the polyethylene glycol fatty acid esters, the alkyl polyglycosides, N-alkylglucamine derivatives, amine oxides such as C _10-14 alkylamine oxides or N-acylaminopropyl morpholine oxides. It should be noted that the alkylpolyglycosides which are nonionic surfactants are particularly well suited in the context of the present invention.

(iii) amphoteric (r) or zwitterionic surfactant (s) Substance (s)

The amphoteric or zwitterionic surfactants, the nature of which is not critical to the present invention, may be particularly (but not limited to) aliphatic, secondary or tertiary amine derivatives wherein the aliphatic group is a straight or branched chain of 8 to 18 carbon atoms at least one water-soluble anionic group (for example, carboxylate, sulfonate, sulfate, phosphate or phosphonate); it is also possible to cite the C _8-20 -alkyl betaines, sulfobetaines, C _8-20 -alkyl-C _1-6 -amidoalkylbetaines or the C _8-20 -alkyl C _1-6 -amidoalkylsulfobetaines.

Among the amine derivatives are the products commercially available under the name MIRANOL and described, for example, in US Pat. Nos. 2,228,378 and 2,781,354; according to CTFA nomenclature (3rd edition, 1982) they are referred to as amphocarboxyglycinates and amphocarboxypropionates and have the following structures: Ra-CONHCH ₂ CH ₂ -N (R ₃ ) (R ₄ ) (CH ₂ COO ^- ) (2) wherein R _{2 is} an alkyl group derived from an acid R ₂ -COOH, which is dissolved in hydrolyzed cop raöl present, heptyl, nonyl or undecyl; R _{3 is} a β-hydroxyethyl group and R _{4 is} a carboxymethyl group; and R ₂ '-CONHCH ₂ CH ₂ -N (B) (C) (3) in which mean:
B is a group -CH ₂ CH ₂ OX ';
C is a group - (CH ₂ ) _z -Y 'with z = 1 or 2;
X 'is the group -CH ₂ CH ₂ -COOH or a hydrogen atom;
Y 'is the group -COOH or the group -CH ₂ -CHOH-SO ₃ H; and
R ₂ 'is an alkyl group of an acid R ₉ -COOH present in hydrolyzed coconut oil or linseed oil, an alkyl group, in particular having 7, 9, 11 or 13 carbon atoms, a C ₁₇ alkyl group and its isoform or a C ₁₇ unsaturated group.

These Compounds are described according to CTFA nomenclature (5th edition, 1993) as Disodium cocoamphodiacetate, disodium lauroamphodiacetate, disodium Capryloamphodiacetate, Disodium Caproamphodiacetate, Disodium Cocoamphodipropionate, Disodium Lauroamphodipropionate, Disodium Caprylamphodipropionate, Disodium capryloamphodipropionate, lauroamphodipropionic acid and Cocoamphodipropionic acid.

It is, for example, cocoamphodiacetate, which is available under the trade name MIRANOL ^® C2M concentrate from RHODIA CHIMIE.

In the compositions of the invention are preferably mixtures of surfactants and in particular Mixtures of anionic surfactants Substances and mixtures of anionic surfactants and amphoterics or nonionic surfactant Substances used. A particularly preferred mixture is a mixture, that of at least one carboxy-group anionic surfactant and at least one amphoteric or nonionic surfactant Fabric exists.

• – entweder einem amphoteren grenzflächenaktiven Stoff, wie beispielsweise Aminderivaten, die als Disodium Cocoamphodipropionate oder Sodium Cocoamphopropionate bezeichnet werden und insbesondere von der Firma RHODIA CHIMIE unter der Handelsbezeichnung 'MIRANOL^® C2M CONC' in wässriger Lösung mit 38 % Wirkstoff oder unter der Bezeichnung MIRANOL^® C32 im Handel sind;
• – oder einem amphoteren grenzflächenaktiven Stoff vom zwitterionischen Typ, wie beispielsweise Alkylbetainen und insbesondere dem Cocobetain, das unter der Bezeichnung 'DEHYTON^® AB 30' in wässriger Lösung mit 32 % WS von der Firma HENKEL im Handel ist, oder Alkylamidoalkylbetainen und insbesondere TEGOBETAINE^® F 50 von der Firma GOLDSCHMIDT;
• – oder einem nichtionischen grenzflächenaktiven Stoff vom Typ Alkylpolyglucosid.

Preferably, an anionic surfactant selected from the polyalkoxylated carboxylic acid alkyl (C _6-24 ) ethers, polyalkoxylated carboxylic acid alkyl (C _6-24 ) aryl ethers, polyalkoxylated carboxylic acid alkyl (C _6-24 ), amidoethers and mixtures thereof with a sulfonated or sulfated one surfactant, such as sodium, triethanolamine or ammonium C _12-14 alkyl sulfates, sodium C _12-14 alkyl ether sulfates ethoxylated with 2.2 moles of ethylene oxide, sodium cocoyl isethionate and mixtures thereof with the following compounds:

• - either an amphoteric surfactant such as amine derivatives, which are called Disodium Cocoamphodipropionate or Sodium Cocoamphopropionate and in particular from the company Rhodia Chimie under the trade name 'Miranol ^® C2M CONC' in aqueous solution with 38% active substance or under the name Miranol ^® C32 are in commerce;
• Or amphoteric zwitterionic surfactant, such as alkyl betaines, and especially cocobetaine sold under the name 'DEHYTON ^® AB 30' in aqueous solution with 32% w / w from HENKEL or alkylamidoalkyl betaines and in particular TEGOBETAINE ^® F 50 from GOLDSCHMIDT;
• Or a nonionic surfactant of the alkyl polyglucoside type.

(iv) cationic surfactant (s) Substance (s)

From the cationic surfactant Substances can in particular (non-limiting list): salts of primary, secondary or tertiary Fatty amines, optionally polyalkoxylated; quaternary ammonium salts, such as the chlorides or bromides of tetraalkylammonium, alkylamidoalkyltrialkylammonium, Trialkylbenzylammonium, trialkylhydroxyalkylammonium or alkylpyridinium; imidazoline derivatives; or amine oxides with cationic properties.

It it is noted that the cationic surfactant Substances whose use is not excluded, according to the present invention Invention are not preferred.

B - Cationic polymer (s)

The Compositions of the invention moreover, necessarily contain a cationic polymer.

The usable according to the invention Conditioners of the cationic polymer type may be mentioned under the compounds selected be that in themselves for that are known to cleanse the cosmetic properties of Compositions to treat treated hair, and in particular the compounds described in the patent application EP-A-0 337 354 and the French Patent Applications FR-A-2 270 846, 2 383 660, 2 598 611, 2 470 596 and 2,519,863.

in the As used herein, the term "cationic polymer" generally refers to any Polymers understood to be the cationic groups or groups that belong to cationic groups are ionizable.

preferred cationic polymers are selected from polymers which either as part of the polymer backbone or directly on one the main chain bonded lateral substituents primary, secondary, tertiary and / or quaternary Contain amino groups / ammonium groups.

The cationic polymers used generally have a number average molecular weight of about 500 to 5 x 10 ⁶ and preferably about 10 ³ to 3 x 10 ⁶ .

From the cationic polymers can in particular the polymers of the polyamine, polyaminoamide and quaternary polyammonium type to be named. These products are known per se.

The Polymers of the polyamine type, polyaminoamide type or quaternary polyammonium type, according to the present Invention are used and are given in particular can, are in the French Patents 2 505 348 or 2 542 997. Of these polymers can to be named:

worin bedeuten:
die Gruppen R₃, die gleich oder verschieden sind, Wasserstoff oder die Gruppe CH₃;
die Gruppen A, die gleich oder verschieden sind, eine geradkettige oder verzweigte Alkylgruppe mit 1 bis 6 Kohlenstoffatomen, vorzugsweise 2 oder 3 Kohlenstoffatomen, oder eine Hydroxyalkylgruppe mit 1 bis 4 Kohlenstoffatomen;
die Gruppen R₄, R₅ und R₆, die identisch oder voneinander verschieden sind, eine Alkylgruppe mit 1 bis 18 Kohlenstoffatomen oder Benzyl und vorzugsweise eine Alkylgruppe mit 1 bis 6 Kohlenstoffatomen;
die Gruppen R₁ und R₂, die gleich oder verschieden sind, Wasserstoff oder eine Alkylgruppe mit 1 bis 6 Kohlenstoffatomen, und vorzugsweise Methyl und Ethyl; und
X ein Anion, das von einer anorganischen oder organischen Säure abgeleitet sind, wie einem Methosulfatanion oder ein Halogenid, beispielsweise Chlorid oder Bromid.(1) The homopolymers or copolymers derived from acrylic or methacrylic acid esters or acrylic or methacrylamides and containing at least one unit of the following formulas:

in which mean:
the groups R ₃ , which are the same or different, are hydrogen or the group CH ₃ ;
the groups A, which are the same or different, represent a straight-chain or branched alkyl group having 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms, or a hydroxyalkyl group having 1 to 4 carbon atoms;
the groups R ₄ , R ₅ and R ₆ , which are identical or different, an alkyl group having 1 to 18 carbon atoms or benzyl, and preferably an alkyl group having 1 to 6 carbon atoms;
the groups R ₁ and R ₂ , which are the same or different, are hydrogen or an alkyl group having 1 to 6 carbon atoms, and preferably methyl and ethyl; and
X is an anion derived from an inorganic or organic acid, such as a methosulfate anion or a halide, for example, chloride or bromide.

The copolymers of group (1) may also contain one or more of units derived from comonomers selected from acrylamides, methacrylamides, diacetone acrylamides, acrylamides and methacrylamides substituted on the nitrogen with lower (C _1-4 ) alkyl groups. Acrylic acid or methacrylic acid or its esters, vinyl lactams such as vinyl pyrrolidone or vinyl caprolactam, and vinyl esters.

• – die Copolymere von Acrylamid und Dimethylaminoethylmethacrylat, das mit Dimethylsulfat oder einem Dimethylhalogenid quaternisiert ist, beispielsweise das unter der Bezeichnung HERCOFLOC von der Firma HERCULES im Handel befindliche Produkt,
• – die Copolymere von Acrylamid und Methacryloyloxyethyltrimethylammoniumchlorid, die beispielsweise in der Patentanmeldung EP-A-080976 beschrieben sind und unter der Bezeichnung BINA QUAT P 100 von CIBA GEIGY verkauft werden,
• – die Copolymere von Acrylamid und Methacryloyloxyethyltrimethylammoniummethosulfat, die unter der Bezeichnung RETEN von HERCULES im Handel sind,
• – die Copolymere von Vinylpyrrolidon und Dialkylaminoalkylacrylat oder -methacrylat, die gegebenenfalls quaternisiert sind, beispielsweise die Produkte, die unter der Bezeichnung 'GAFQUAT' von ISP im Handel sind, wie 'GAFQUAT 734' oder 'GAFQUAT 755', oder auch die Produkte mit der Bezeichnung 'COPOLYMER 845, 958 und 937'. Diese Polymere sind detailliert in den französischen Patenten 2 077 143 und 2 393 573 beschrieben worden,
• – die Terpolymere von Dimethylaminoethylmethacrylat/Vinylcaprolactam/Vinylpyrrolidon, beispielsweise das unter der Bezeichnung GAFFIX VC 713 von ISP erhältliche Produkt,
• – die Copolymere von Vinylpyrrolidon und Methacrylamidopropyldimethylamin, die insbesondere unter der Bezeichnung STYLEZE CC 10 von ISP angeboten werden,
• – und die Copolymere von Vinylpyrrolidon und quaternisiertem Dimethylaminopropylmethacrylamid, wie das Produkt, das unter der Bezeichnung 'GAFQUAT HS 100' von ISP im Handel ist.

Of the copolymers of group (1), there may be mentioned:

• The copolymers of acrylamide and dimethylaminoethyl methacrylate quaternized with dimethyl sulfate or a dimethyl halide, for example the product sold under the name HERCOFLOC by the company HERCULES,
• The copolymers of acrylamide and methacryloyloxyethyltrimethylammonium chloride, which are described, for example, in US Pat patent application EP-A-080976 and sold under the name BINA QUAT P 100 by CIBA GEIGY,
• The copolymers of acrylamide and methacryloyloxyethyltrimethylammonium methosulfate marketed under the name RETEN by HERCULES,
• The copolymers of vinylpyrrolidone and dialkylaminoalkyl acrylate or methacrylate, optionally quaternized, for example the products sold under the name 'GAFQUAT' by ISP, such as 'GAFQUAT 734' or 'GAFQUAT 755', or else the products containing the Designation 'COPOLYMER 845, 958 and 937'. These polymers have been described in detail in French Patents 2 077 143 and 2 393 573,
• The terpolymers of dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone, for example the product available under the name GAFFIX VC 713 from ISP,
• The copolymers of vinylpyrrolidone and methacrylamidopropyldimethylamine, sold in particular under the name STYLEZE CC 10 by ISP,
• And the copolymers of vinylpyrrolidone and quaternized dimethylaminopropylmethacrylamide, such as the product sold under the name 'GAFQUAT HS 100' by ISP.

(2) Derivatives of cellulose ethers containing quaternary ammonium groups and those in the French Patent 1 492 597, and in particular the polymers, under the names 'JR' (JR 400, JR 125, JR 30M) or 'LR' (LR 400, LR 30M) from the company UNION CARBIDE CORPORATION. These polymers are also known by CTFA nomenclature as quaternary ammonium derivatives of hydroxyethylcellulose defined with an epoxide containing a trimethylammonium group substituted, have been reacted.

(3) Cationic cellulose derivatives, such as cellulose copolymers or cellulose derivatives, which are grafted with a water-soluble quaternary ammonium monomer and which are described in particular in the patent US 4,131,576 For example, hydroxyalkyl celluloses, such as hydroxymethyl, hydroxyethyl or hydroxypropyl cellulose, which are grafted in particular with a methacryloylethyltrimethylammonium salt, a methacrylamidopropyltrimethylammonium salt or a dimethyldiallylammonium salt.

Commercial products, which meet this definition are in particular the products, under the name 'CELQUAT L 200 'and' CELQUAT H 100 'from NATIONAL STARCH are in the trade.

(4) cationic polysaccharides, particularly in patents US 3,589,578 and 4 031 307 For example, guar gums with cationic trialkylammonium groups; For example, guar gums modified with a salt (eg the chloride) of 2,3-epoxypropyl trimethyl ammonium have been used. Such products are commercially available in particular under the trade names JAGUAR C 13 S, JAGUAR C 15, JAGUAR C 17 or JAGUAR C 162 from MEYHALL.

(5) Polymers consisting of piperazinyl units and divalent alkylene or hydroxyalkylene groups with straight or branched chains optionally substituted by oxygen atoms, sulfur atoms or Nitrogen atoms or aromatic or heterocyclic rings interrupted and the oxidation products and / or quaternization products these polymers. Such polymers are especially in the French Patents 2,162,025 and 2,280,361.

(6) water-soluble Polyaminoamides, in particular by polycondensation of an acid with a polyamine are made; these polyaminoamides can with an epihalohydrin, a diepoxide, a dianhydride, an unsaturated one Dianhydride, a diunsaturated Derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, be crosslinked an alkyl bis-halide or an oligomer, the in the implementation of a reactive bifunctional compound and a bis-halohydrin, bis-azetidinium, bis-haloacyldiamine, Alkyl bis-halide, epihalohydrin, diepoxide or diunsaturated Derivative arises; the crosslinking agent is used in proportions of 0.025 to 0.35 mole per amino group of the polyaminoamide used; the polyaminoamides can alkylated or, if they have one or more tertiary amino groups, be quaternized. Such polymers are especially in the French Patents 2,252,840 and 2,368,508.

(7) Derivatives of polyaminoamides resulting from the condensation of Polyalkylenepolyamines with polycarboxylic acids and subsequent alkylation with bifunctional agents. It can, for example, the polymers of adipic acid and dialkylaminohydroxyalkyldialkylenetriamine, wherein the alkyl group has 1 to 4 carbon atoms, and preferably Methyl, ethyl or propyl. Such polymers are in particular in the French Patent 1,583,363 has been described.

From these derivatives can in particular the adipic acid / dimethylaminohydroxypropyldiethylenetriamine polymers under the name 'CARTARETINE F, F4 or F8' from the company SANDOZ are in the trade.

(8th) Polymers obtained by reacting a polyalkylenepolyamine, the two primary Having amino groups and at least one secondary amino group, with a dicarboxylic acid with diglycolic acid and saturated aliphatic dicarboxylic acids with 3 to 8 carbon atoms selected is, the molar ratio of polyalkylenepolyamine and dicarboxylic acid in the range of 0.8: 1 to 1.4: 1 and the resulting polyaminoamide with epichlorohydrin in a molar ratio of epichlorohydrin to the secondary amino groups of the polyaminoamide in the range of 0.5: 1 to 1.8: 1 reacted becomes. Such polymers are especially in the American Patents 3,227,615 and 2,961,347.

polymers of this type are in particular under the name 'HERCOSETT 57' from the company HERCULES INC. or under the name 'PD 170' or 'DELSETTE 101' by the company HERCULES in the trade, where in this case it is the copolymer adipic acid / epoxypropyl / diethylenetriamine is.

wobei in den Formeln:
k und t Null oder 1 bedeuten, wobei die Summe k + t gleich 1 ist, R₁₂ ein Wasserstoffatom oder die Methylgruppe bedeutet, die Gruppen R₁₀ und R₁₁ unabhängig voneinander eine Alkylgruppe mit 1 bis 22 Kohlenstoffatomen, eine Hydroxyalkylgruppe, worin die Alkylgruppe vorzugsweise 1 bis 5 Kohlenstoffatome aufweist, oder eine niedere (C_1-4) Amidoalkylgruppe bedeuten oder R₁₀ und R₁₁ gemeinsam mit dem Stickstoffatom, an das sie gebunden sind, heterocyclische Gruppen, wie Piperidinyl oder Morpholinyl, bilden können, und Y- ein Anion, wie Bromid, Chlorid, Acetat, Borat, Citrat, Tartrat, Hydrogensulfat, Hydrogensulfit, Sulfat oder Phosphat bedeutet. Diese Polymere sind insbesondere in dem französischen Patent 2.080.759 und seinem Zusatzpatent 2.190.406 beschrieben worden.(9) Methyldiallylamine or diallyldimethylammonium cyclopolymers, such as homopolymers or copolymers having, as the main constituent of the chain, units corresponding to the formulas (VI) or (VI '):

where in the formulas:
k and t are zero or 1, wherein the sum k + t is 1, R _{12 is} a hydrogen atom or the methyl group, the groups R ₁₀ and R _{11 are} independently an alkyl group having 1 to 22 carbon atoms, a hydroxyalkyl group, wherein the alkyl group preferably having 1 to 5 carbon atoms, or a lower (C _1-4 ) amidoalkyl group, or R ₁₀ and R ₁₁ together with the nitrogen atom to which they are attached may form heterocyclic groups such as piperidinyl or morpholinyl, and Y- Anion, such as bromide, chloride, acetate, borate, citrate, tartrate, hydrogen sulfate, hydrogen sulfite, sulfate or phosphate means. These polymers have been described in particular in French Patent 2,080,759 and its additional patent 2,190,406.

The groups R ₁₀ and R ₁₁ independently of one another preferably represent an alkyl group having 1 to 4 carbon atoms.

It can for example, the diallyldimethylammonium chloride homopolymer, the under the name 'MERQUAT 100 'from the company CALGON is trading (and its homologues with lower weight mediators Molecular weight) and the copolymers of diallyldimethylammonium chloride and acrylamide, which are available under the name 'MERQUAT 550'.

wobei in der Formel (VII) die Gruppen R₁₃, R₁₄, R₁₅ und R₁₆, die identisch oder voneinander verschieden sind, aliphatische, alicyclische oder arylaliphatische Gruppen mit 1 bis 20 Kohlenstoffatomen oder niedere hydroxyalkylaliphatische Gruppen bedeuten oder wobei die Gruppen R₁₃, R₁₄, R₁₅ und R₁₆ gemeinsam oder unabhängig voneinander mit den Stickstoffatomen, an die sie gebunden sind, Heterocyclen bilden, die gegebenenfalls ein zweites Heteroatom enthalten, das von Stickstoff verschieden ist, oder wobei die Gruppen R₁₃, R₁₄, R₁₅ und R₁₆ eine geradkettige oder verzweigte C_1-6-Alkylgruppe bedeuten, die mit einer Nitril-, Ester-, Acyl- oder Amidgruppe oder -CO-O-R₁₇-D oder -CO-NH-R₁₇-D substituiert ist, worin R₁₇ eine Alkylengruppe und D eine quartäre Ammoniumgruppe bedeuten.(10) The recurring unit quaternary diammonium polymer represented by the following formula:

in the formula (VII), the groups R ₁₃ , R ₁₄ , R ₁₅ and R ₁₆ , which are identical or different, aliphatic, alicyclic or arylaliphatic groups having 1 to 20 carbon atoms or lower hydroxyalkylaliphatic groups or wherein the groups R ₁₃ , R ₁₄ , R ₁₅ and R ₁₆ together or independently with the nitrogen atoms to which they are attached form heterocycles, which may be contain a second heteroatom, which is different from nitrogen, or wherein the groups R ₁₃ , R ₁₄ , R ₁₅ and R _{16 represents} a straight-chain or branched C _1-6 alkyl group, with a nitrile, ester, acyl or Amide group or -CO-OR ₁₇ -D or -CO-NH-R ₁₇ -D substituted, wherein R _{17 is} an alkylene group and D is a quaternary ammonium group.

A ₁ and B ₁ denote polymethylene groups having 2 to 20 carbon atoms which may be straight-chained or branched, saturated or unsaturated and which are attached to the main chain or in the main chain one or more aromatic rings or one or more oxygen atoms or sulfur atoms or one or more of may contain the following groups: sulfoxide, sulfone, disulfide, amino, alkyl amino, hydroxy, quaternary ammonium groups, ureido, amide or esters.

X ^- means an anion derived from an inorganic or organic acid.

• a) eine Glykolgruppe der Formel: -O-Z-O- , worin Z eine geradkettige oder verzweigte Kohlenwasserstoffgruppe oder eine Gruppe bedeutet, die einer der folgenden Formeln entspricht: -(CH₂-CH₂-O)_x-CH₂-CH₂- -[CH₂-CH(CH₃)-O]_y-CH₂-CH(CH₃) worin x und y ganze Zahlen von 1 bis 4 bedeuten und einen wohl definierten und einzigen Polymerisationsgrad darstellen, oder beliebige Zahlen von 1 bis 4 bedeuten und einen mittleren Polymerisationsgrad darstellen;
• b) ein bis-sekundäres Diamin, beispielsweise ein Piperazinderivat,
• c) ein bis-primäres Diamin der Formel : -NH-Y-NH- , worin Y eine geradkettige oder verzweigte Kohlenwasserstoffgruppe oder auch die zweiwertige Gruppe -CH₂-CH₂-S-S-CH₂-CH₂- bedeutet, oder
• d) die Ureylengruppe der Formel : -NH-CO-NH-.

The groups A ₁ , R ₁₃ and R ₁₅ may form a piperazine ring with the two nitrogen atoms to which they are attached; when A _{1 represents} a straight-chain or branched, saturated or unsaturated alkylene group or hydroxyalkylene group, the group B _{1 may} also be a group (CH ₂ ) _n -CO-D-OC- (CH ₂ ) _n -, in which

• a) a glycol group of the formula: -OZO-, in which Z denotes a straight-chain or branched hydrocarbon group or a group which corresponds to one of the following formulas: - (CH ₂ -CH ₂ -O) _x -CH ₂ -CH ₂ - - [CH ₂ -CH (CH ₃ ) -O] _y -CH ₂ -CH (CH ₃ ) wherein x and y are integers from 1 to 4 and represent a well-defined and single degree of polymerization, or represent any number from 1 to 4 and represent an average degree of polymerization;
• b) a bis-secondary diamine, for example a piperazine derivative,
• c) a bis-primary diamine of the formula: -NH-Y-NH-, in which Y represents a straight-chain or branched hydrocarbon group or else the divalent group -CH ₂ -CH ₂ -SS-CH ₂ -CH ₂ -, or
• d) the ureylene group of the formula: -NH-CO-NH-.

X ^- is preferably an anion such as chloride or bromide.

These Polymers generally freeze a number average molecular weight of 1 000 to 100 000 on.

polymers of this type are disclosed in particular in French patents 2,320,330, 2,270,846, 2,316,271, 2,336,434 and 2,413. 907 and in the patents US 2,273,780, 2,375,853, 2,388,614, 2,454,547, 3,206,462, 2,261,002, 2,271,378, 3,874,870, 4,001,432, 3,929,990, 3,966,904, 4,005,193, 4,025,617, 4,025,627, 4,025,653, 4,026,945 and 4,027,020 Service.

worin die Gruppen R₁, R₂, R₃ und R₄, die gleich oder verschieden sind, eine Alkyl- oder Hydroxyalkylgruppe mit etwa 1 bis 4 Kohlenstoffatomen bedeuten, n und p ganze Zahlen im Bereich von etwa 2 bis 20 bedeuten und X- ein von einer anorganischen oder organischen Säure abgeleitetes Anion ist.In particular, it is possible to use polymers which consist of recurring units of the following formula:

wherein the groups R ₁ , R ₂ , R ₃ and R ₄ , which are identical or different, denote an alkyl or hydroxyalkyl group having about 1 to 4 carbon atoms, n and p are integers in the range of about 2 to 20 and X- is an anion derived from an inorganic or organic acid.

A particularly preferred compound of the formula (a) is the compound with R ₁ , R ₂ , R ₃ and R ₄ = methyl, n = 3, p = 6 and X = Cl, which according to INCI nomenclature (CTFA) as hexadimethrines chlorides referred to as.

wobei in der Formel bedeuten:
R₁₈, R₁₉, R₂₀ und R₂₁, die identisch oder voneinander verschieden sind, ein Wasserstoffatom oder Methyl, Ethyl, Propyl, β-Hydroxyethyl, β-Hydroxypropyl oder -CH₂CH₂(OCH₂CH₂)_pOH, wobei p Null oder eine ganze Zahl im Bereich von 1 bis 6 bedeutet, mit der Maßgabe, dass R₁₈, R₁₉, R₂₀ und R₂₁ nicht gleichzeitig Wasserstoff bedeuten,
r und s, die gleich oder verschieden sind, eine ganze Zahl im Bereich von 1 bis 6,
q Null oder eine ganze Zahl im Bereich von 1 bis 34,
X ein Halogen, und
A ein Dihalogenid oder vorzugsweise -CH₂-CH₂-O-CH₂-CH₂-.(11) Quaternary polyammonium polymers consisting of units of the following formula (VIII):

where in the formula:
R ₁₈ , R ₁₉ , R ₂₀ and R ₂₁ , which are identical or different, represent a hydrogen atom or methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl or -CH ₂ CH ₂ (OCH ₂ CH ₂ ) _p OH, where p is zero or an integer in the range from 1 to 6, with the proviso that R ₁₈ , R ₁₉ , R ₂₀ and R _{21 are} not simultaneously hydrogen,
r and s, which are the same or different, an integer in the range of 1 to 6,
q is zero or an integer in the range of 1 to 34,
X is a halogen, and
A is a dihalide or preferably -CH ₂ -CH ₂ -O-CH ₂ -CH ₂ -.

These Compounds are described in particular in patent application EP-A-122 324 Service.

From These compounds can For example, the products' MIRAPOL A 15 ',' MIRAPOL AD1 ',' MIRAPOL AZ1 'and' MIRAPOL 175 'are given, which are sold by the company MIRANOL.

(12) quaternary Polymers of vinylpyrrolidone and vinylimidazole, such as the products sold under the names LUVIQUAT FC 905, FC 550 and FC 370 are sold by BASF.

(13) Polyamines, such as POLYQUART H, which is commercially available from HENKEL and later CTFA nomenclature as' POLYETHYLENE GLYCOL (15) TALLOW POLYAMINE ' becomes.

(14) Crosslinked polymers of methacryloyloxyalkyl (C _1-4 ) trialkyl (C _1-4 ) ammonium salts such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride or by copolymerization of acrylamide with dimethylaminoethyl methacrylate treated with methyl chloride is quaternized, which is crosslinked after the homopolymerization or copolymerization with a compound having olefinic double bond, in particular with methylene-bis-acrylamide. In particular, a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (weight ratio 20/80) may be used in the form of a dispersion containing 50% by weight of the copolymer in mineral oil. This dispersion is sold under the name "Salcare ^® SC 92" by the company Allied Colloids. A crosslinked methacryloyloxyethyltrimethylammonium chloride homopolymer containing about 50% by weight of homopolymer in mineral oil or liquid esters may also be used. This dispersion is sold under the name "Salcare ^® SC 95" or "Salcare ^® SC 96" by the company Allied Colloids.

Further cationic polymers used in the invention can, are the polyalkyleneimines, in particular polyethyleneimines, polymers, containing vinylpyridine or vinylpyridinium units, condensates of polyamines and epichlorohydrin, quaternary polyureylenes and chitin derivatives.

From the cationic polymers used in the present invention can be used become the quaternary Cellulo seetherderivate, for example, the products 'JR 400' of UNION CARBIDE CORPORATION, the cyclopolymers, in particular the dimethyldiallylammonium chloride / acrylamide copolymers, under the name 'MERQUAT 100 ',' MERQUAT 550 'and' MERQUAT S 'are available from CALGON, the cationic polysaccharides and in particular the example under the name 'JAGUAR C 13S 'from MEYHALL available, with guar gums modified with 2,3-epoxypropyltrimethylammonium chloride or the copolymers of vinylpyrrolidone and methacrylamidopropyldimethylamine, especially offered under the name STYLEZE CC 10 by ISP are preferred, and their mixtures.

The cationic polymers or the cationic polymers may be in accordance with the invention 0.01 to 10% by weight, preferably 0.05 to 5% by weight, and more preferably 0.1 to 3 wt.% Of the total weight of the composition.

(C) polyurethanes and / or polyureas

To an essential property of the cleaning compositions according to the invention for the Hair treatment, these also contain at least one polycondensate, the at least one polyurethane sequence and / or polyurea sequence wherein the polycondensate is soluble in water.

The polycondensates containing at least one polyurethane sequence and / or polyurea sequence, which are particularly contemplated within the scope of the present invention, are the polycondensates disclosed in patents EP 0 751 162 . EP 0 637 600 , FR 2 743 297 and EP 0 648 485 the applicant and the patents EP 0 656 021 or WO 94/03510 from BASF or EP 0 619 111 described by the company National Starch.

The used according to the invention Polycondensates are either in the form of acid or partial or complete Neutralization with an organic or inorganic base water-soluble.

The water-soluble according to the invention Lead polymers, when dissolved in water to compositions that appear clear to the naked eye (at a concentration of at least 1% active ingredient and at room temperature (20-25 ° C)).

• (1) mindestens einer Verbindung, die zwei oder mehr als zwei aktive Wasserstoffatome pro Molekül enthält,
• (2) mindestens einem Diol oder einem Gemisch von Diolen, die saure Gruppen oder deren Salze enthalten, und
• (3) mindestens einem Di- oder Polyisocyanat.
• Die Verbindungen (1) sind vorteilhaft unter den Diolen, Diaminen, Polyesterolen, Polyetherolen oder deren Gemischen ausgewählt.

The polycondensate may, for example, consist of an assembly of blocks, this block-shaped arrangement being obtained in particular on the basis of the following compounds:

• (1) at least one compound containing two or more than two active hydrogen atoms per molecule,
• (2) at least one diol or a mixture of diols containing acidic groups or their salts, and
• (3) at least one di- or polyisocyanate.
• The compounds (1) are advantageously selected from diols, diamines, polyesterols, polyetherols or mixtures thereof.

preferred Compounds (1) are the straight-chain polyethylene glycols and polypropylene glycols, in particular the compounds obtained by reaction of ethylene oxide or propylene oxide with water or diethylene glycol or dipropylene glycol be obtained in the presence of sodium hydroxide as a catalyst. These polyglycols generally have a molecular weight of about 600 to 20,000.

Further preferred organic compounds are the compounds which are mercapto, Amino, carboxy or hydroxy groups. Of these are in particular the polyhydroxy compounds, such as polyether diols, Polyester diols, polyacetal diols, polyamide diols, polyesterpolyamide diols, Poly (alkylene ether) diols, polythioether diols and polycarbonate diols.

preferred Polyether diols are, for example, the condensation products of Ethylene oxide, propylene oxide or tetrahydrofuran, their copolymerization products or condensation products grafted or as block polymers are present, for example, the mixtures of condensates of ethylene oxide and propylene oxide, and the products used in the polymerization of Olefins with alkylene oxide condensates arise under high pressure. Suitable polyethers are, for example by condensation of alkylene oxides and polyhydric alcohols, such as ethylene glycol, 1,2-propylene glycol and 1,4-butanediol.

The Polyester diols, polyester amides, polyamide diols are preferred saturated and are, for example, by reaction of saturated or unsaturated polycarboxylic obtained with polyhydric alcohols, diamines or polyamines. to For example, adipic acid, succinic acid, phthalic acid, isophthalic acid, terephthalic acid, and maleic be used. For the preparation of polyesters are suitable polyhydric alcohols For example, ethylene glycol, diethylene glycol, 1,2-propylene glycol, 1,4-butanediol, Neopentyl glycol and hexanediol. It can also amino alcohols, for example Ethanolamine. For the preparation of polyesteramides suitable diamines are ethylenediamine and hexamethylenediamine.

suitable Polyacetals can for example, starting from 1,4-butanediol or hexanediol and formaldehyde. Suitable polythioethers can for example, by condensation of thioglycols alone or in combination with other glycols, such as ethylene glycol, 1,2-propylene glycol or other polyhydroxylated compounds. The polyhydroxylated compounds that are already urea groups or urethane groups, and natural polyols that continue can be modified for example, castor oil and carbohydrates, can also be used.

The compound of group (1) is preferably a polyesterol, in particular a polyester diol, which is formed by reacting at least one (di) polyol (1 _a ) and at least one acid (1 _b ). The (di) polyol (1 _a ) is selected in particular from neopentyl glycol, 1,4-butanediol, hexanediol, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, neopentyl glycol and (di) polyethylene glycol. The acid (1b) is particularly selected from phthalic acid, isophthalic acid, adipic acid and (poly) lactic acid.

When Compound (2) can especially hydroxycarboxylic acids, such as dimethylolpropionic acid (DMPA), or 2,2-hydroxymethylcarboxylic acids are used. In general the connection (2) serves as a coupling block.

Particularly according to the invention preferred compounds (2) are the compounds selected from 2,2-dihydro-methyl-acetic acid, 2,2-dihydroxymethyl-propionic acid, 2,2-dihydroxymethyl-butyric acid and 2,2-dihydroxymethyl-pentanoic acid selected are.

The Di- or polyisocyanate (3) can in particular be chosen from hexamethylene diisocyanate, Isophorone diisocyanate (IDPI), toluene diisocyanate, diphenylmethane-4,4'-diisocyanate (DPMD), Dicyclohexylmethane-4,4'-diisocyanate (DCMD), Methylene di-p-phenyl diisocyanate, methylenebis (4-cyclohexyl isocyanate), Toluene diisocyanate, 1,5-naphthalene diisocyanate, 4,4'-diphenylmethane diisocyanate, 2,2'-dimethyl-4,4'-diphenylmethane diisocyanate, 1,3-phenylene diisocyanate, 1,4-phenylene diisocyanate, mixtures of 2,4- and 2,6-toluene diisocyanate, 2,2'-dichloro-4,4'-diisocyanato-diphenylmethane, 2,4-dibromo-1,5-diisocyanato-naphthalene, 1,4-diisocyanatobutane, hexane-1,6-diisocyanate and cyclohexane-1,4-diisocyanate.

The Polycondensate can be formed using an additional compound (4) which generally serves the polycondensate chain to extend. The compounds (4) can especially among the saturated ones or unsaturated Glycols such as ethylene glycol, diethylene glycol, neopentyl glycol and Triethylene glycol, aminoalcohols such as ethanolamine, propanolamine and butanolamine, heterocyclic, aromatic, cycloaliphatic and aliphatic primary Amines, diamines, carboxylic acids, for example, aliphatic, aromatic, heterocyclic carboxylic acids, such as oxalic acid, Succinic acid, Glutaric, adipic, sebacic and terephthalic acid, and aminocarboxylic acids selected become. Preferred compounds (4) are aliphatic diols.

One Particularly preferred anionic polyurethane is the polyurethane-1 (INCI name), marketed by BASF under the name LUVISET PUR is offered.

The polycondensates according to the invention can also using additional Formed compounds (5) having a Sili congerüst, such as polysiloxanes, polyalkylsiloxanes or polyarylsiloxanes and in particular, polyethylsiloxanes, polymethylsiloxanes and polyphenylsiloxanes, which optionally hydrocarbon groups grafted onto the silicon atoms contain.

Advantageous polyurethane sequences and / or polyurea sequences contain a recurring repeat unit of the following general formula: -X'-B-X'-CO-NH-R-NH-CO- (I '), in which mean:
X 'O and / or NH,
B is a divalent hydrocarbon group, which group may be substituted or unsubstituted, and
R is a divalent group which may be selected from the aromatic type alkylene groups, aliphatic type of 1 to 20 carbon atoms and cycloaliphatic type of 1 to 20 carbon atoms, which groups may be substituted or unsubstituted.

The group B is preferably a C _1-30 group which carries a group which has one or more carboxylic acid groups and / or one or more sulfonic acid groups, wherein the carboxy functions and / or sulfonic acid functions are present in free form or wholly or partly with an inorganic or organic base are neutralized.

worin b 0 oder eine ganze Zahl im Bereich von 1 bis 3 und c eine ganze Zahl im Bereich von 1 bis 20 und vorzugsweise 2 bis 12 bedeutet.The group R is advantageously selected from the groups of the following formulas:

wherein b is 0 or an integer in the range of 1 to 3 and c is an integer in the range of 1 to 20 and preferably 2 to 12.

The Group R is in particular among the groups hexamethylene, 4,4'-biphenylenemethane, 2,4- and / or 2,6-tolylene, 1,5-naphthylene, p-phenylene, methylene-4,4-bis-cyclohexyl and the isophorone-derived divalent group.

The polycondensate used according to the invention, which contains at least one polyurethane sequence and / or polyurea sequence, can advantageously also contain at least one polysiloxane sequence, the recurring basic unit of which corresponds, for example, to the following general formula (II '): -X'-P-X'-CO-NH-R-NH-CO- (II '), in which mean:
P is a polysiloxane segment,
- X 'O and / or NH, and
R is a divalent group selected from the aromatic type alkylene groups, aliphatic type of 1 to 20 carbon atoms and cycloaliphatic type of 1 to 20 carbon atoms, which groups may be substituted or unsubstituted.

wobei in der Formel:
– die Gruppen A, die gleich oder verschieden sein können, einerseits unter den einwertigen Kohlenwasserstoffgruppen mit 1 bis 20 Kohlenstoffatomen, die keine oder im Wesentlichen keine ethylenischen Doppelbindungen aufweisen, und andererseits den aromatischen Gruppen ausgewählt sind,
– Y eine zweiwertige Kohlenwasserstoffgruppe bedeutet, und
– z eine ganze Zahl ist, die so ausgewählt ist, dass die mittlere Molmasse des Polysiloxansegments im Bereich von 300 bis 10 000 liegt.Advantageously, the polysiloxane segment P corresponds to the following general formula:

where in the formula:
The groups A, which may be the same or different, are chosen, on the one hand, from the monovalent hydrocarbon groups having from 1 to 20 carbon atoms, which have no or substantially no ethylenic double bonds, and, on the other hand, the aromatic groups,
Y is a divalent hydrocarbon group, and
Z is an integer selected such that the average molecular weight of the polysiloxane segment is in the range from 300 to 10,000.

The divalent group Y is generally selected from alkylene groups of the formula - (CH ₂ ) _a -, where a is an integer which may range from 1 to 10.

The Groups A can among the alkyl groups, in particular methyl, ethyl, propyl, isopropyl, Butyl, pentyl, hexyl, octyl, decyl, dodecyl and octadecyl, the cycloalkyl groups, in particular cyclohexyl, the aryl groups, in particular phenyl and Naphthyl, the aralkyl groups, especially benzyl and phenylethyl, and Tolyl and xylyl selected be.

The Compositions of the invention for the Hair treatment contain the above-defined polyurethanes (polycondensates) in weight proportions ranging from 0.05 to 10% and preferably 0.1 to 5%, based on the total weight of the composition, can lie.

The relationship cationic polymer / polyurethane is generally in the range from 0.001 to 200, preferably 0.02 to 50 and especially 0.1 until 20.

The cosmetically acceptable, aqueous medium can consist exclusively of water or a mixture of water and a cosmetically acceptable solvent, for example a lower C _1-4 -alkanol, such as ethanol, isopropanol, t-butanol, n-butanol; Alkylene glycols, such as propylene glycol, glycol ethers.

The cleansing according to the invention Compositions generally have a pH in the range from 3 to 10 on. The pH is preferably in the range of 4 to 9 and can be conventionally by addition a base (inorganic or organic), for example ammonia or a primary, secondary or tertiary (Poly) amine, such as monoethanolamine, diethanolamine, triethanolamine, Isopropanolamine or 1,3-propanediamine, or by adding an inorganic or organic acid in the composition, preferably a carboxylic acid, such as citric acid, to the desired Value to be set.

In addition to the combination defined above, the compositions according to the invention may contain viscosity-adjusting agents such as electrolytes or thickeners. In particular, sodium chloride, sodium xylenesulfonate, scleroglucans, xanthan gums, alkanolamides of fatty acids, alkanolamides of alkyl ether carboxylic acids which are optionally ethoxylated with up to 5 moles of ethylene oxide, for example the product marketed under the name 'AMINOL A15' by the company CHEM Y, crosslinked Polyacrylic acids and crosslinked copolymers of acrylic acid and C _10-30 alkyl acrylates may be mentioned. These viscosity-adjusting agents are used in the compositions according to the invention in proportions which may be up to 10% by weight, based on the total weight of the composition.

The Compositions of the invention can also contain up to 5% pearlescent pigments or opacifiers which are well known in the art, for example, fatty alcohols> C16, sodium or Magnesium palmitate, sodium or magnesium stearate and sodium or Magnesium hydroxystearate, acyl derivatives with fatty chain, such as mono- or Distearates of ethylene glycol or polyethylene glycol, fatty chain ethers, such as the distearyl ether or 1-hexadecyloxy-2-octadecanol.

The cleansing according to the invention Compositions can Naturally also contain any additives that are usually in the field of Shampoos, for example perfumes, preservatives, Masking agents, thickeners, soothing substances, foam modifiers, Colorants, pearlescent pigments, hydrating agents, antidegradants Dandruff or against seborrhoea, sunscreen and the like.

Optionally, the compositions according to the invention may also contain other additives whose action consists in improving the cosmetic properties of the hair or the skin without impairing the stability of the compositions. These include, for example, the cationic surfactants, anionic, nonionic or amphoteric polymers, proteins, protein hydrolysates, ceramides, pseudoceramides, fatty acids with linear or branched C _16-40 fatty chains, such as 18-methyl eicosanoic acid, hydroxy acids, vitamins, panthenol, volatile or not volatile silicones which are soluble or insoluble in the medium, vegetable oils, synthetic oils and mixtures thereof.

The compositions of the present invention may also contain compounds which act synergistically in foaming, such as 1,2-alkanediols of 10 to 18 carbon atoms or fatty acid alkanolamides derived from mono- or diethanolamine.

Of the Specialist becomes self-evident the additional present (s) compounds) and / or select their proportions so that with the combination of the invention (cleansing base formulation + cationic polymer + polyurethane according to the invention) associated advantageous properties by the intended Addition or intended additives not or not material changed become.

The Compositions can in the form of more or less viscous liquids, creams or gels and they are for washing, care and / or hair styling suitable for the hair.

If the compositions of the invention as conventional Shampoos are used, they are easy on the damp Hair applied and produced by massaging or rubbing with hands Foam is then optionally with an exposure time by rinsing with Removed water, the process also be repeated several times can.

As stated above, the compositions of the invention act according to the rinse in a remarkable way hair-styling on the hair, these being Hairdressing properties in particular by simple styling and hold as well as express more volume and resilience, which are significantly better.

The The invention further relates to the use of one defined above Polycondensate to a hairdressing properties of a cleansing Composition for to improve the hair treatment that is at least one cationic Contains polymer.

in the The following are specific examples for explaining the invention, not limiting to be understood.

In the examples used the following compounds:

LUVISET PUR (BASF)

• Polyurethane-1 (INCI name) in aqueous-alcoholic solution with 30 active ingredient water-soluble polyurethane

AVALURE UR 450 (GOODRICH)

• Copolymer propylene glycol / isophorone diisocyanate / dimethylolpropanoic acid, aqueous-alcoholic Suspension with 38% active ingredient water-insoluble polyurethane

AKYPOSOFT 45 NV (KAO)

• Sodium lauryl ether carboxylate with 4.5 moles of ethylene oxide in aqueous solution with 22% active ingredient

AG 10 LK (KAO)

• Alkyl (C ₉ / C ₁₁ ) polyglucoside (1.4) in aqueous solution with 40% active ingredient

282930 (NATIONAL STARCH)

• Terpolymer vinyl acetate / crotonic acid / vinyl neodecanoate

STYLEZE CC 10 (ISP)

• Copolymers vinylpyrrolidone / methacrylamidopropyldimethylamine (80/20, by weight) in aqueous solution with 10% active ingredient

MERQUAT 100 (CALGON)

• Diallyldimethylammonium chloride homopolymer in aqueous solution with 40% active ingredient

MERQUAT 550 (CALGON)

• Copolymer diallyldimethylammonium chloride / acrylamide 50/50 (by weight) in aqueous Solution with 8% active ingredient

JAGUAR C 13 S (RHODIA CHEMISTRY)

• Hydroxypropylguartrimethylammoniumchlorid

DEHYTONE AB 30 (HENKEL)

• Cocoylbetaine in aqueous solution with 30% active ingredient

EXAMPLE 1

Two shampoo compositions are prepared, one composition according to the invention (composition A) and the other composition being a comparative composition (composition B) which differ from each other in the nature of the anionic polymer used:

Natural strands of hair 2.5 g and one length of 27 cm are moistened and then with 1 g of the composition according to the invention A brought into contact for 5 min and then rinsed with water. The strands be 20 min at 65 ° C dried under a hood. With composition B will as well method.

determination the handle of the strands

The Strands treated as described above are given to a panel of 10 test persons submitted.

she should the strands that they judge to be softer and smoother.

All 10 test persons declared unanimous that those treated with the inventive composition A. Hair is softer and smoother.

detection the fixing properties

Under Fixing properties are the cohesion caused by the deposition a material is conveyed as the hair that the relative Limited movement of the hair, as well as the temporal stability understood the entire hairstyle.

One simple means of assessing these properties is to to investigate their relaxation.

For this purpose, natural hair tresses of 2.5 g and a length L ₀ of 27 cm are first moistened and then brought into contact with 1 g of composition A according to the invention for 5 minutes and then rinsed with water. The still moist curls are rolled up on curlers with a diameter of 2 cm and a length of 7 cm. Then the tresses are dried for 20 minutes under a drying hood. After drying, the tresses are carefully removed from the curlers and attached to a solid support so that the hairs hang freely below their own weight.

With Comparative Composition B is also proceeded.

Then becomes the length (L) The determined by their own weight in front of a yardstick hanging wavy hair.

The Hair can itself, still in hanging State, then Relax for 2 h at room temperature.

The Length of suspended strands takes a certain length (ΔL) too.

ever less the length increase (ΔL), the more better is the time keeping of the hairstyle.

For the composition B is the increase in length 3 cm (mean for 2 strands), for the Composition A, however, only 2.55 cm (mean for 2 strands); this corresponds to an improvement in the reduction of Linear expansion of 15%; out of that is the better hold of the hairstyle that through the shampoo according to the invention achieved, clearly.

EXAMPLE 2

Das AVALURE UR 450 ist ein in Wasser unlösliches, anionisches Polyurethan.Two shampoo compositions are prepared, one composition according to the invention (composition A) and the other composition being a comparative composition (composition C) which differ from each other in the solubility of the anionic polyurethane used:

The AVALURE UR 450 is a water-insoluble, anionic polyurethane.

Natural strands of hair 2, 5 g and one length of 27 cm are moistened and then with 1 g of the composition according to the invention A brought into contact for 5 min and then rinsed with water. The strands be 20 min at 65 ° C dried under a hood. With the comparative composition C will do the same.

determination the handle of the strands

The Strands treated as described above are given to a panel of 10 test persons submitted.

she should the strands that they judge to be softer and smoother.

All 10 test persons declared unanimous that those treated with the inventive composition A. Hair is softer and smoother.

detection the fixing properties

It The procedure is as described in Example 1.

The Length of suspended strands takes a certain length (ΔL) too.

ever less the length increase (ΔL), the more better is the time keeping of the hairstyle.

For the composition C is the increase in length 3.6 cm (mean for 2 strands), for the composition A, on the other hand, only 2.55 cm (average for 2 strands), i.e., this corresponds an improvement in reduction of linear expansion of more than 29%; this is the better hold of the hairstyle that goes through the shampoo according to the invention achieved, clearly.

EXAMPLE 3

The following shampoo according to the invention is prepared: AKYPOSOFT 45 NV (KAO) 12 g WS AG 10 LK (KAO) 2 g WS STYLEZE CC 10 (ISP) 1 g WS LUVISET PUR (BASF) 1.23 g WS sodium chloride 2 g Water ad. 100 g pH adjusted to 7

EXAMPLE 4

The following shampoo according to the invention is prepared: Sodium lauryl ether sulfate (2.2 EO) 15.5 g WS Cocoylbetaine (DEHYTONE AB 30 from Henkel) 2.4 g WS Jaguar C 13 S (RHODIA) 0.05 g WS LUVISET PUR (BASF) 1 g WS polydimethylsiloxane 2.7 g WS 1- (hexadecyloxy) -2-octadecanol / cetyl 2.5 g WS Monoisopropanolamide of copra acids 1 g WS Natriumcetostearylsulfat 0.75 g WS preservative qs Water ad. 100 g pH adjusted to 7

EXAMPLE 5

The following shampoo according to the invention is prepared: BEAULIGHT SHAA (SANYO KASEI) 3 g WS AG 10 LK (KAO) 12 g WS MERQUAT 100 from CALGON 1 g WS LUVISET PUR (BASF) 3 g WS sodium chloride 1.5 g ethoxylated methyl glucoside dioleate (120 EO) 1 g WS Water ad. 100 g pH adjusted to 7

EXAMPLE 6

The following shampoo according to the invention is prepared: BEAULIGHT SHAA (SANYO KASEI) 4.5 g WS AG 10 LK (KAO) 6 g WS STYLEZE CC 10 (ISP) 1 g WS LUVISET PUR (BASF) 4.05 g WS sodium chloride 1.5 g ethoxylated methyl glucoside dioleate (120 EO) 1.5 g Water ad. 100 g pH adjusted to 7

Claims (19)

Cleansing composition, characterized in that it contains in a cosmetically acceptable medium a cleansing base formulation, at least one cationic polymer and at least one anionic polycondensate having at least one polyurethane sequence and / or polyurea sequence, wherein the polycondensate is water-soluble. Composition according to Claim 1, characterized that the cleaning base formulation one or more surface-active Contains substances, those among the anionic, amphoteric, nonionic and zwitterionic surfactant Substances and mixtures thereof are selected. Composition according to Claim 1 or 2, characterized that the cleansing base formulation in a weight fraction of 4 to 50%, based on the total weight of the composition, and preferably 6 to 25% is included. A composition according to any one of claims 1 to 3, characterized in that the polycondensate from an arrangement of blocks which is obtained starting from: (1) at least one A compound containing two or more active hydrogens per molecule; (2) at least one diol or a mixture of diols, the acidic groups or their salts contain; and (3) at least one di- or Polyisocyanate. Composition according to Claim 4, characterized the compounds (1) are chosen from diols, diamines, polyesterols, Polyetherols or mixtures thereof are selected. Composition according to Claim 2, characterized the compound (2) is a 2,2-hydroxymethylcarboxylic acid. Composition according to Claim 4, characterized that the compound (3) is hexamethylene diisocyanate, tolylene diisocyanate, Diphenylmethane-4,4'-diisocyanate, Dicyclohexylmethane-4,4'-diisocyanate, Methylene di-p-phenyl diisocyanate, methylene bis (4-cyclohexyl isocyanate), Isophorone diisocyanate, toluene diisocyanate, 1,5-naphthalene diisocyanate, 4,4'-diphenylmethane diisocyanate, 2,2'-dimethyl-4,4'-diphenylmethane diisocyanate, 1,3-phenylene, 1,4-phenylene diisocyanate, mixtures of 2,4- and 2,6-toluene diisocyanate, 2,2'-dichloro-4,4'-diisocyanatodiphenylmethane, 2,4-dibromo-1,5-diisocyanato-naphthalene, 1,4-diisocyanatobutane, hexane-1,6-diisocyanate and cyclohexane-1,4-diisocyanate selected is. Composition according to Claim 4, characterized that the polycondensate starting from at least one additional Compound is formed, which has a silicone skeleton and among the polysiloxanes, Polyalkylsiloxanes or polyarylsiloxanes, in particular the polyethylsiloxanes, Polymethylsiloxanes and polyphenylsiloxanes, is selected which optionally contain hydrocarbon chains which are based on the Silicon atoms are grafted. Composition according to any one of Claims 1 to 3, characterized in that the polyurethane sequences and / or polyurea sequences of the polymer have a recurring repeat unit of the following general formula (I '): -X'-B-X'-CO-NH-R-NH-CO- (I '), wherein: X 'is O and / or NH, B is a divalent hydrocarbon group, which group is unsubstituted or substituted, and R is a divalent group selected from the aromatic type alkylene groups of the aliphatic type having 1 to 20 carbon atoms and is selected from the cycloaliphatic type having 1 to 20 carbon atoms, which groups may be substituted or unsubstituted. A composition according to claim 9, characterized in that the group B is a divalent C _1-30 hydrocarbon group. A composition according to claim 9 or 10, characterized characterized in that the group R is selected from the groups hexamethylene, 4,4'-biphenylenemethane, 2,4- and / or 2,6-toluene, 1,5-naphthylene, p-phenylene, methylene-4,4-biscyclohexyl and isophorone derived divalent group selected is. Composition according to any one of Claims 1 to 3, characterized in that the polycondensate contains a recurring repeat unit of formula (II) below: -X'-P-X'-CO-NH-R-NH-CO- (II '), wherein: P is a polysiloxane segment, X 'is O and / or NH, R is a divalent group selected from the aromatic type alkylene groups, the aliphatic type of 1 to 20 carbon atoms and the cycloaliphatic type of 1 to 20 carbon atoms, which groups may be substituted or unsubstituted. Composition according to any one of the preceding claims, characterized in that the cationic polymer is chosen from: (1) homopolymers or copolymers derived from esters of acrylic or methacrylic acid or of acrylic or methacrylic amides containing at least one unit of the following formulas:

wherein: groups R ₃ , which are the same or different, are hydrogen or the group CH ₃ ; the groups A, which are the same or different, are a straight-chain or branched alkyl group having 1 to 6 carbon atoms or a hydroxyalkyl group having 1 to 4 carbon atoms; the groups R ₄ , R ₅ and R ₆ , which are identical or different, an alkyl group having 1 to 18 carbon atoms or benzyl; the groups R ₁ and R ₂ , which are the same or different, are hydrogen or an alkyl group having 1 to 6 carbon atoms; and X is an anion derived from an inorganic or organic acid; (2) derivatives of cellulose ethers containing quaternary ammonium groups; (3) cationic cellulose derivatives such as cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer; (4) cationic polysaccharides; (5) Polymers consisting of piperazinyl units and divalent alkylene or hydroxyalkylene groups with straight or branched chains, which are optionally interrupted by oxygen atoms, sulfur atoms or nitrogen atoms or aromatic or heterocyclic rings, and the oxidation products and / or quaternization of these polymers ; (6) water-soluble polyaminoamides prepared in particular by polycondensation of an acid with a polyamine; these polyaminoamides can be crosslinked with an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a diunsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bishaloacyldiamine, an alkyl bis-halide, or even an oligomer useful in the art the reaction of a reactive bifunctional compound and a bis-halohydrin, bis-azetidinium, bis-haloacyldiamin, alkyl bis-halide, epihalohydrin, diepoxide or diunsaturated derivative is formed; the crosslinking agent is used in proportions of 0.025 to 0.35 moles per amino group of the polyaminoamide. The polyaminoamides may be alkylated or, if they have one or more tertiary amino groups, quaternized; (7) derivatives of polyaminoamides resulting in the condensation of polyalkylenepolyamines with polycarboxylic acids followed by alkylation with bifunctional agents; (8) polymers prepared by reacting a polyalkylenepolyamine having two primary amino groups and at least one secondary amino group with a dicarboxylic acid selected from diglycolic acid and saturated aliphatic dicarboxylic acids having 3 to 8 carbon atoms; (9) alkyldiallylamine or dialkyldiallylammonium cyclopolymers; (10) the recurring unit quaternary diammonium polymer of the following formula:

wherein in the formula (VII), the groups R ₁₃ , R ₁₄ , R ₁₅ and R ₁₆ , which are identical or different, are aliphatic, alicyclic or arylaliphatic groups having 1 to 20 carbon atoms or lower hydroxyalkylaliphatic groups, or wherein the groups R ₁₃ , R ₁₄ , R ₁₅ and R ₁₆ together or independently with the nitrogen atoms to which they are attached form heterocycles which optionally contain a second heteroatom other than nitrogen, or wherein the groups R ₁₃ , R ₁₄ , R ₁₅ and R _{16 represent} a straight or branched C _1-6 alkyl group substituted with a nitrile, ester, acyl or amide group or -CO-OR ₁₇ -D or -CO-NH-R ₁₇ -D wherein R _{17 is} an alkylene group and D is a quaternary ammonium group; A ₁ and B ₁ denote polymethylene groups having 2 to 20 carbon atoms which may be straight-chained or branched, saturated or unsaturated and which are attached to the main chain or in the main chain one or more aromatic rings or one or more oxygen atoms or sulfur atoms or one or more of may contain the following groups: sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxy, quaternary ammonium groups, ureido, amide or esters; X ^{- represents} an anion derived from an inorganic or organic acid; The groups A ₁ , R ₁₃ and R ₁₅ may form a piperazine ring with the two nitrogen atoms to which they are attached; When A _{1 represents} a straight-chain or branched, saturated or unsaturated alkylene group or hydroxyalkylene group, the group B _{1 may} also denote a group (CH ₂ ) _n -CO-D-OC- (CH ₂ ) _n -, in which D denotes: a) a glycol group of the formula: -OZO-, in which Z denotes a straight-chain or branched hydrocarbon group or a group which corresponds to one of the following formulas: - (CH ₂ -CH ₂ -O) _x -CH ₂ -CH ₂ - - [CH ₂ -CH (CH ₃ ) -O] _y -CH ₂ -CH (CH ₃ ) wherein x and y are an integer of 1 to 4 and represent a well-defined and single degree of polymerization, or represent any number from 1 to 4 and represent an average degree of polymerization; b) a bis-secondary diamine, for example a piperazine derivative, c) a bis-primary diamine of the formula: -NH-Y-NH-, where Y is a straight-chain or branched hydrocarbon group or else the divalent group -CH ₂ -CH ₂ -SS -CH ₂ -CH ₂ -, or d) the ureylene group of the formula: -NH-CO-NH-. X- is preferably an anion; (11) Quaternary polyammonium polymers consisting of units of the following formula (VIII):

wherein in the formula: R ₁₈ , R ₁₉ , R ₂₀ and R ₂₁ , which are identical or different, represent a hydrogen atom or methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl or -CH ₂ CH ₂ (OCH ₂ CH ₂ ) pOH, where p is zero or an integer in the range of 1 to 6, with the proviso that R ₁₈ , R ₁₉ , R ₂₀ and R _{21 are} not simultaneously hydrogen, r and s are the same or different are an integer in the range of 1 to 6, q is zero or an integer in the range of about 1 to 34, X is a halogen atom, and A is a dihalide or preferably -CH ₂ CH ₂ -O-CH ₂ CH ₂ -. (12) Quaternary polymers of vinylpyrrolidone and vinylimidazole; (13) polyamines, such as POLYQUART H, which is commercially available from HENKEL and is referred to as 'POLYETHYLENGLYCOL (15) TALLOW POLYAMINE' according to CTFA nomenclature; (14) Crosslinked polymers of methacryloyloxyalkyl (C _1-4 ) trialkyl (C _1-4 ) ammonium salts; (15) Polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and epichlorohydrin, quaternary polyureylenes and chitin derivatives. Composition according to the preceding claim, characterized in that the cationic polymer is among the quaternary cellulose derivatives, Cyclopolymers, cationic polysaccharides, vinylpyrrolidone / methacrylamidopropyl dimethylamine copolymers and their mixtures selected is. Composition according to one of the preceding claims, characterized characterized in that the cationic polymer in a weight fraction from 0.01 to 10%, based on the total weight of the composition, and preferably 0.05 to 5%. Composition according to one of the preceding claims, characterized characterized in that the polycondensate in a weight fraction of 0.05 to 10%, based on the total weight of the composition, and preferably 0.1 to 5% is contained. Composition according to one of the preceding claims, characterized characterized in that it has a pH in the range of 4 to 9. Use of a composition according to one of previous claims for cleaning and / or care and / or conditioning and / or for the Hairdressing of keratinous materials. Use of a polycondensate according to one of the preceding claims to improve the hairdressing properties of a cleansing Composition for the hair treatment containing at least one cationic polymer.