DE59708452D1 - Katalysator und verfahren zur herstellung von aldehyden durch hydroformylierung von olefinisch ungesättigten verbindungen - Google Patents

Katalysator und verfahren zur herstellung von aldehyden durch hydroformylierung von olefinisch ungesättigten verbindungen

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Publication number
DE59708452D1
DE59708452D1 DE59708452T DE59708452T DE59708452D1 DE 59708452 D1 DE59708452 D1 DE 59708452D1 DE 59708452 T DE59708452 T DE 59708452T DE 59708452 T DE59708452 T DE 59708452T DE 59708452 D1 DE59708452 D1 DE 59708452D1
Authority
DE
Germany
Prior art keywords
catalyst
unsaturated compounds
olefinically unsaturated
producing aldehydes
hydroformylating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE59708452T
Other languages
English (en)
Inventor
Sandra Bogdanovic
Carl-Dieter Frohning
Helmut Bahrmann
Matthias Beller
Steffen Haber
Hans-Jerg Kleiner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Sales Germany GmbH
Original Assignee
Celanese Chemicals Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Chemicals Europe GmbH filed Critical Celanese Chemicals Europe GmbH
Priority to DE59708452T priority Critical patent/DE59708452D1/de
Application granted granted Critical
Publication of DE59708452D1 publication Critical patent/DE59708452D1/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • B01J31/1683Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins the linkage being to a soluble polymer, e.g. PEG or dendrimer, i.e. molecular weight enlarged complexes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B01J31/2423Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member comprising aliphatic or saturated rings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2461Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
    • B01J31/2466Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring comprising aliphatic or saturated rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • C07F15/008Rhodium compounds without a metal-carbon linkage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96Water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE59708452T 1996-07-29 1997-07-21 Katalysator und verfahren zur herstellung von aldehyden durch hydroformylierung von olefinisch ungesättigten verbindungen Expired - Fee Related DE59708452D1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE59708452T DE59708452D1 (de) 1996-07-29 1997-07-21 Katalysator und verfahren zur herstellung von aldehyden durch hydroformylierung von olefinisch ungesättigten verbindungen

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19630536A DE19630536C2 (de) 1996-07-29 1996-07-29 Katalysator und dessen Verwendung für die Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen
DE19718195A DE19718195A1 (de) 1996-07-29 1997-04-30 Verfahren zur Herstellung von Aldehyden durch Hydroformylierung von olefinisch ungesättigten Verbindungen
PCT/EP1997/003926 WO1998004346A1 (de) 1996-07-29 1997-07-21 Katalysator und verfahren zur herstellung von aldehyden durch hydroformylierung von olefinisch ungesättigten verbindungen
DE59708452T DE59708452D1 (de) 1996-07-29 1997-07-21 Katalysator und verfahren zur herstellung von aldehyden durch hydroformylierung von olefinisch ungesättigten verbindungen

Publications (1)

Publication Number Publication Date
DE59708452D1 true DE59708452D1 (de) 2002-11-14

Family

ID=26027912

Family Applications (3)

Application Number Title Priority Date Filing Date
DE19630536A Expired - Fee Related DE19630536C2 (de) 1996-07-29 1996-07-29 Katalysator und dessen Verwendung für die Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen
DE19718195A Withdrawn DE19718195A1 (de) 1996-07-29 1997-04-30 Verfahren zur Herstellung von Aldehyden durch Hydroformylierung von olefinisch ungesättigten Verbindungen
DE59708452T Expired - Fee Related DE59708452D1 (de) 1996-07-29 1997-07-21 Katalysator und verfahren zur herstellung von aldehyden durch hydroformylierung von olefinisch ungesättigten verbindungen

Family Applications Before (2)

Application Number Title Priority Date Filing Date
DE19630536A Expired - Fee Related DE19630536C2 (de) 1996-07-29 1996-07-29 Katalysator und dessen Verwendung für die Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen
DE19718195A Withdrawn DE19718195A1 (de) 1996-07-29 1997-04-30 Verfahren zur Herstellung von Aldehyden durch Hydroformylierung von olefinisch ungesättigten Verbindungen

Country Status (8)

Country Link
US (1) US6191063B1 (de)
EP (1) EP0938379B1 (de)
JP (1) JP2001503314A (de)
KR (1) KR20000029633A (de)
CN (1) CN1226189A (de)
CA (1) CA2261861A1 (de)
DE (3) DE19630536C2 (de)
WO (1) WO1998004346A1 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19700804C1 (de) 1997-01-13 1998-08-06 Hoechst Ag Verfahren zur Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen mit 6 bis 16 Kohlenstoffatomen in Anwesenheit einer Rhodium und sulfonierte Triarylphosphine als Katalysator enthaltenden wäßrigen Phase
ATE297807T1 (de) * 1999-06-17 2005-07-15 Firmenich & Cie Stereospezifische isomerierung von allylaminen unter verwendung von immobilisierten chiralen phospho-liganden
DE10164720B4 (de) * 2001-07-07 2013-12-19 Oxea Gmbh Verfahren zur Herstellung von Aldehyden
CN115010586B (zh) * 2021-03-05 2024-10-11 中国石油化工股份有限公司 一种氢甲酰化反应方法和系统

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2857055B2 (ja) * 1994-03-30 1999-02-10 株式会社クラレ 1,9−ノナンジアールの製造方法
DE4440552A1 (de) * 1994-11-12 1996-05-15 Hoechst Ag Verfahren zur Herstellung von Formylcarbonsäureestern

Also Published As

Publication number Publication date
JP2001503314A (ja) 2001-03-13
KR20000029633A (ko) 2000-05-25
DE19630536C2 (de) 1998-11-05
WO1998004346A1 (de) 1998-02-05
DE19630536A1 (de) 1998-02-05
DE19718195A1 (de) 1998-11-05
CN1226189A (zh) 1999-08-18
EP0938379A1 (de) 1999-09-01
CA2261861A1 (en) 1998-02-05
US6191063B1 (en) 2001-02-20
EP0938379B1 (de) 2002-10-09

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