DE59403392D1 - Process for cleaning flue gases - Google Patents

Process for cleaning flue gases

Info

Publication number
DE59403392D1
DE59403392D1 DE59403392T DE59403392T DE59403392D1 DE 59403392 D1 DE59403392 D1 DE 59403392D1 DE 59403392 T DE59403392 T DE 59403392T DE 59403392 T DE59403392 T DE 59403392T DE 59403392 D1 DE59403392 D1 DE 59403392D1
Authority
DE
Germany
Prior art keywords
flue gases
cleaning flue
cement
water
cleaning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE59403392T
Other languages
German (de)
Inventor
Michael Dr Rer Nat Schmidt
Detlev Dr Ing Kupper
Juergen Schneberger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Industrial Solutions AG
Original Assignee
Krupp Polysius AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Krupp Polysius AG filed Critical Krupp Polysius AG
Application granted granted Critical
Publication of DE59403392D1 publication Critical patent/DE59403392D1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02—Agglomerated materials, e.g. artificial aggregates
    • C04B18/027—Lightweight materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/508—Sulfur oxides by treating the gases with solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/604—Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/304—Linear dimensions, e.g. particle shape, diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/31—Pore size distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0233—Other waste gases from cement factories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48—Sorbents characterised by the starting material used for their preparation
    • B01J2220/4875—Sorbents characterised by the starting material used for their preparation the starting material being a waste, residue or of undefined composition
    • B01J2220/4887—Residues, wastes, e.g. garbage, municipal or industrial sludges, compost, animal manure; fly-ashes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/56—Use in the form of a bed
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034—Physico-chemical characteristics of the mixtures
    • C04B2111/00068—Mortar or concrete mixtures with an unusual water/cement ratio
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00—Gas separation: processes
    • Y10S95/90—Solid sorbent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00—Gas separation: processes
    • Y10S95/90—Solid sorbent
    • Y10S95/901—Activated carbon

Abstract

Off-gas from furnaces is treated by contacting with an absorbent material containing granular cement made by mixing a typical trade cement with water in a ratio of water to cement of 0.05-0.4.
DE59403392T 1994-01-17 1994-12-16 Process for cleaning flue gases Expired - Fee Related DE59403392D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4401166A DE4401166A1 (en) 1994-01-17 1994-01-17 Process for cleaning flue gases

Publications (1)

Publication Number Publication Date
DE59403392D1 true DE59403392D1 (en) 1997-08-21

Family

ID=6508070

Family Applications (2)

Application Number Title Priority Date Filing Date
DE4401166A Withdrawn DE4401166A1 (en) 1994-01-17 1994-01-17 Process for cleaning flue gases
DE59403392T Expired - Fee Related DE59403392D1 (en) 1994-01-17 1994-12-16 Process for cleaning flue gases

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE4401166A Withdrawn DE4401166A1 (en) 1994-01-17 1994-01-17 Process for cleaning flue gases

Country Status (5)

Country Link
US (1) US5538537A (en)
EP (1) EP0664145B1 (en)
AT (1) ATE155358T1 (en)
DE (2) DE4401166A1 (en)
NO (1) NO304640B1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19649663C1 (en) * 1996-11-29 1998-04-02 Schwenk Baustoffwerke Kg E Sulphur di:oxide removal from cement-making plant off-gases
DE69917305T2 (en) 1998-07-23 2005-06-23 Sumitomo Osaka Cement Co., Ltd. Exhaust gas treatment agent, method for producing the same and method for treating exhaust gas
DE19961691C5 (en) * 1999-12-20 2011-08-18 Bayerisches Institut für Angewandte Umweltforschung und -technik BIfA GmbH, 86167 Process for cleaning flue gas
US7794524B2 (en) * 2008-02-05 2010-09-14 F L Smidth A/S Method and apparatus for removing contaminants from industrial processing plants
US8187364B2 (en) * 2009-08-18 2012-05-29 Flsmidth A/S Method and apparatus for removing volatile contaminants from industrial plants
FR2951088B1 (en) * 2009-10-12 2012-09-28 Lafarge Sa USE OF A CONCRETE ELEMENT FOR THE TREATMENT OF GASES AND VOLATILE COMPOUNDS
RU2452561C2 (en) * 2010-07-12 2012-06-10 Елена Михайловна Евсина Sorbent for atmospheric air cleaning
RU2473383C2 (en) * 2011-01-11 2013-01-27 Елена Михайловна Евсина Sorbent to refine air of water vapors, acid gases and microorganisms in cabins of motor vehicles and premises

Family Cites Families (33)

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DE260229C (en) *
US1481221A (en) * 1923-03-21 1924-01-15 Hoechst Ag Process for separating gas and vapor mixtures
FR1495695A (en) * 1965-10-08 1967-12-20
DE1594673A1 (en) * 1965-11-13 1971-02-04 Bergwerksverband Gmbh Process for removing sulfur dioxide from gases containing sulfur dioxide
US3505008A (en) * 1967-10-30 1970-04-07 Dow Chemical Co Separation of fly ash and sulfur dioxide from flue gases
US3589863A (en) * 1968-03-08 1971-06-29 Dow Chemical Co Method of removing sulfur dioxide and particulate matter from gaseous streams
US3563704A (en) * 1968-08-13 1971-02-16 Westvaco Corp Removal and recovery of sulfur oxides from gases
JPS5023383B1 (en) * 1970-07-29 1975-08-07
GB1291933A (en) * 1970-10-16 1972-10-04 Bahco Ventilation Ab A method and apparatus for purifying gases
US3928005A (en) * 1974-02-19 1975-12-23 Fuller Co Method and apparatus for treating gaseous pollutants in a gas stream
AT363918B (en) * 1975-05-06 1981-09-10 Hoelter Heinz METHOD AND DEVICE FOR PURIFYING GAS
JPS5848600B2 (en) * 1975-09-08 1983-10-29 バブコツク日立株式会社 Cement clinker
JPS5250985A (en) * 1975-10-21 1977-04-23 Nippon Steel Corp Proces for simultaneously removing nox and sox in gas
US4049462A (en) * 1976-02-12 1977-09-20 Wehran Engineering Corporation Chemical fixation of desulfurization residues
DE3036504C2 (en) * 1980-09-27 1983-08-18 Rheinische Braunkohlenwerke Ag, 5000 Koeln Process for removing pollutants rich in fluorine and / or sulfur from gaseous and liquid media
DE3038457C2 (en) * 1980-10-11 1983-11-10 L. & C. Steinmüller GmbH, 5270 Gummersbach Use of a waste product from dry flue gas desulphurisation for the production of fly ash cement
JPS57207531A (en) * 1981-06-17 1982-12-20 Toshiba Corp Removing method for hydrogen sulfide in gas
DE3304344A1 (en) * 1983-02-09 1984-08-09 Keramikanlagen W. Strohmenger GmbH u. Co KG, 8524 Neunkirchen Granule dry filter
CA1221674A (en) * 1983-09-26 1987-05-12 Hiroshi Hagiwara Desulfurizing method for combustion exhaust gases
US4540553A (en) * 1983-09-26 1985-09-10 Onoda Cement Co., Inc. Desulfurizing agent
GB2146977B (en) * 1983-09-26 1987-02-18 Onoda Cement Co Ltd Desulfurizing agent
GB2152487A (en) * 1984-01-07 1985-08-07 Kloeckner Humboldt Deutz Ag Method of desulphurising flue gas
DE3400764A1 (en) * 1984-01-12 1985-07-25 Collo Gmbh, 5303 Bornheim Granular filter aid for removing noxious substances from the air
GB2172277B (en) * 1985-03-13 1989-06-21 Hokkaido Electric Power Preparation process of desulfurizing and denitrating agents
DE3543530A1 (en) * 1985-12-10 1987-10-15 Saxonlord Ltd Process for producing pellets which, inter alia, contain alkali metal oxides and/or alkaline earth metal oxides
DE3544764A1 (en) * 1985-12-18 1987-06-19 Metallgesellschaft Ag METHOD FOR REMOVING POLLUTANTS FROM EXHAUST GAS
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DE3735245A1 (en) * 1987-04-23 1989-05-03 Hoelter Heinz Dry gas purification to remove acidic pollutants such as SO3, SO2, HF, HCl and NOx by means of alkali-impregnated lime/aluminium cement silicates as sorbents
DE3717848A1 (en) * 1987-05-27 1988-12-08 Rwk Rhein Westfael Kalkwerke Inorganic material and process for the production thereof
DE3723381A1 (en) * 1987-07-15 1989-01-26 Krantz H Gmbh & Co Process for removing dust and fly ash as well as sulphur oxides and nitrogen oxides from flue gases
SU1699551A1 (en) * 1989-07-31 1991-12-23 Научно-производственное объединение "Союзстромэкология" Method of separating sulfur dioxide and alkaline cement dust from effluent gases
DE4107927C2 (en) * 1991-03-08 1994-11-24 Noell Abfall & Energietech Process for the immobilization of pollutant-containing residues from the flue gas cleaning

Also Published As

Publication number Publication date
EP0664145A1 (en) 1995-07-26
NO304640B1 (en) 1999-01-25
NO950164L (en) 1995-07-18
ATE155358T1 (en) 1997-08-15
DE4401166A1 (en) 1995-07-20
NO950164D0 (en) 1995-01-16
EP0664145B1 (en) 1997-07-16
US5538537A (en) 1996-07-23

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee