DE59009767D1 - Granular, alkaline, phosphate-free cleaning additive. - Google Patents
Granular, alkaline, phosphate-free cleaning additive.Info
- Publication number
- DE59009767D1 DE59009767D1 DE59009767T DE59009767T DE59009767D1 DE 59009767 D1 DE59009767 D1 DE 59009767D1 DE 59009767 T DE59009767 T DE 59009767T DE 59009767 T DE59009767 T DE 59009767T DE 59009767 D1 DE59009767 D1 DE 59009767D1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- granular
- alkaline
- phosphate
- cleaning additive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000654 additive Substances 0.000 title abstract 2
- 230000000996 additive effect Effects 0.000 title abstract 2
- 238000004140 cleaning Methods 0.000 title 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The additive can be obtained by spray drying and contains (a) 35 to 60 % by weight of sodium salts of at least one homopolymeric or copolymeric (meth)acrylic acid, (b) 25 to 50 % by weight of sodium carbonate (calculated anhydrous), (c) 4 to 20 % by weight of sodium sulphate (calculated anhydrous) and (d) 1 to 7 % by weight of water and is distinguished by favourable particle properties and good storage stability.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3937469A DE3937469A1 (en) | 1989-11-10 | 1989-11-10 | GRANULAR, ALKALINE, PHOSPHATE-FREE CLEANING ADDITIVE |
Publications (1)
Publication Number | Publication Date |
---|---|
DE59009767D1 true DE59009767D1 (en) | 1995-11-16 |
Family
ID=6393283
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE3937469A Withdrawn DE3937469A1 (en) | 1989-11-10 | 1989-11-10 | GRANULAR, ALKALINE, PHOSPHATE-FREE CLEANING ADDITIVE |
DE59009767T Expired - Fee Related DE59009767D1 (en) | 1989-11-10 | 1990-11-02 | Granular, alkaline, phosphate-free cleaning additive. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE3937469A Withdrawn DE3937469A1 (en) | 1989-11-10 | 1989-11-10 | GRANULAR, ALKALINE, PHOSPHATE-FREE CLEANING ADDITIVE |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0432437B1 (en) |
AT (1) | ATE129008T1 (en) |
DE (2) | DE3937469A1 (en) |
ES (1) | ES2077619T3 (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4110510A1 (en) * | 1991-03-30 | 1992-10-01 | Henkel Kgaa | LOW-ALKALINE, CHLORINE AND PHOSPHATE-FREE MACHINE DISTRIBUTORS IN THE FORM OF HEAVY-DENTAL POWDERS AND GRANULES |
DE4112075A1 (en) * | 1991-04-12 | 1992-10-15 | Henkel Kgaa | METHOD FOR PRODUCING STABLE, BIFUNCTIONAL, PHOSPATE AND METASILICATE-FREE LOW-ALKALINE DETERGENT TABLETS FOR THE MACHINE DISHWASHER |
DE4121307A1 (en) * | 1991-06-27 | 1993-01-07 | Henkel Kgaa | METHOD FOR THE PRODUCTION OF STABLE, BIFUNCTIONAL, PHOSPHATE AND METASILICATE-FREE LOW-ALKALINE DETERGENT TABLETS FOR THE MACHINE DISHWASHER |
DE4137470A1 (en) * | 1991-11-14 | 1993-05-19 | Henkel Kgaa | METHOD FOR PRODUCING LOW-ALKALINE, ACTIVE-CHLORINE AND PHOSPHATE-FREE MACHINE DISPERSIVE AGENTS IN THE FORM OF HEAVY GRANULES |
EP0626996A1 (en) * | 1992-02-20 | 1994-12-07 | Henkel Kommanditgesellschaft auf Aktien | Process for producing low-alkaline dishwasher rinsing agents without active chlorine, silicates and phosphates, in the form of heavy granulates |
DE4213036A1 (en) * | 1992-04-21 | 1993-10-28 | Henkel Kgaa | Stable, free-flowing granulate of alkaline cleaning additive - contg. (meth)acrylic] acid (co)polymer, sodium silicate, sodium carbonate or sodium sulphate, sequestering agent and water |
US5898025A (en) * | 1992-09-25 | 1999-04-27 | Henkel Kommanditgesellschaft Auf Aktien | Mildly alkaline dishwashing detergents |
DE4315048A1 (en) * | 1993-04-01 | 1994-10-06 | Henkel Kgaa | Process for the production of stable, bifunctional, phosphate, metasilicate and polymer-free, low-alkaline detergent tablets for automatic dishwashing |
AU7932094A (en) * | 1993-11-03 | 1995-05-23 | Procter & Gamble Company, The | Control of calcium carbonate precipitation in automatic dishwashing |
DE4408718A1 (en) * | 1994-03-15 | 1995-09-21 | Henkel Kgaa | Breakage and storage stable, polyfunctional cleaning tablets, process for their preparation and their use |
US6150324A (en) | 1997-01-13 | 2000-11-21 | Ecolab, Inc. | Alkaline detergent containing mixed organic and inorganic sequestrants resulting in improved soil removal |
EP1776443A1 (en) | 2004-08-11 | 2007-04-25 | The Procter and Gamble Company | Process for making a granular detergent composition having improved solubility |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1337972A (en) * | 1970-01-08 | 1973-11-21 | Unilever Ltd | Detergent compositions |
US4399048A (en) * | 1977-10-06 | 1983-08-16 | Colgate-Palmolive Company | High bulk density particulate heavy duty laundry detergent |
CA1297376C (en) * | 1985-11-01 | 1992-03-17 | David Philip Jones | Detergent compositions, components therefor, and processes for theirpreparation |
DE3614779A1 (en) * | 1986-05-02 | 1987-11-05 | Henkel Kgaa | GRANULAR, PHOSPHATE-FREE WATER SOFTENER |
-
1989
- 1989-11-10 DE DE3937469A patent/DE3937469A1/en not_active Withdrawn
-
1990
- 1990-11-02 AT AT90121008T patent/ATE129008T1/en not_active IP Right Cessation
- 1990-11-02 EP EP90121008A patent/EP0432437B1/en not_active Expired - Lifetime
- 1990-11-02 DE DE59009767T patent/DE59009767D1/en not_active Expired - Fee Related
- 1990-11-02 ES ES90121008T patent/ES2077619T3/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ATE129008T1 (en) | 1995-10-15 |
EP0432437A1 (en) | 1991-06-19 |
DE3937469A1 (en) | 1991-05-16 |
EP0432437B1 (en) | 1995-10-11 |
ES2077619T3 (en) | 1995-12-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |