DE589126C - Process for the manufacture of electric valve plates by applying a layer of selenium to an electrode - Google Patents
Process for the manufacture of electric valve plates by applying a layer of selenium to an electrodeInfo
- Publication number
- DE589126C DE589126C DES88221D DES0088221D DE589126C DE 589126 C DE589126 C DE 589126C DE S88221 D DES88221 D DE S88221D DE S0088221 D DES0088221 D DE S0088221D DE 589126 C DE589126 C DE 589126C
- Authority
- DE
- Germany
- Prior art keywords
- selenium
- electrode
- heating
- applying
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/06—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising selenium or tellurium in uncombined form other than as impurities in semiconductor bodies of other materials
- H01L21/10—Preliminary treatment of the selenium or tellurium, its application to the foundation plate, or the subsequent treatment of the combination
- H01L21/103—Conversion of the selenium or tellurium to the conductive state
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02656—Special treatments
- H01L21/02664—Aftertreatments
- H01L21/02667—Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth
Description
In der Patentschrift 501228 ist.ein Verfahren zur Herstellung elektrischer Ventile beschrieben, bei welchem Selen in amorphem Zustand auf eine Elektrode aufgetragen, dann mit dieser zusammen erhitzt und dann die zweite Elektrode auf die Selenschicht aufgelegt wird.In patent specification 501228 ist.ein method for the production of electric valves described in which selenium in amorphous Condition applied to an electrode, then heated together with this and then the second electrode is placed on the selenium layer.
Gegenstand der Erfindung ist eine weitere Ausbildung dieses. Verfahrens. Es hat sich gezeigt, daß es von großem Vorteil ist, zunächst auf eine niedrige Temperatur, insbesondere nur auf eine verhältnismäßig niedrige Temperatur wie 120 ° C zu erwärmen, bis die Überführung des amorphen Selens inThe subject of the invention is a further development of this. Procedure. It has shown that it is of great advantage to start at a low temperature, in particular only to be heated to a relatively low temperature such as 120 ° C, until the amorphous selenium is converted into
15' den kristallinischen Zustand erfolgt ist, und dann erst auf eine höhere Temperatur, z. B. 2oo° C, 'zu erhitzen.15 'the crystalline state has occurred, and only then to a higher temperature, e.g. B. 200 ° C, 'to be heated.
Bei verhältnismäßig niedriger Temperatur erfolgt die Umwandlung des amorphen Selens in das kristallinische viel langsamer als. bei höherer Temperatur. Während die Umwandlung bei einer hohen Temperatur von beispielsweise 2100 in wenigen Minuten erfolgt, kann die Umwandlung bei einer niedrigen Temperatur von beispielsweise ioo° Stunden beanspruchen.At a relatively low temperature, the conversion of amorphous selenium into crystalline selenium takes place much more slowly than. at higher temperature. While the conversion takes place at a high temperature of for example 210 0 in a few minutes, the conversion at a low temperature, for example ioo ° hours can claim.
Das langsam bei niedriger Temperatur entstandene kristallinische Selen hat eine günstigere Struktur und Oberflächenbeschaffenheit als das schnell kristallisierte. Diese vorteilhaftere Beschaffenheit macht sich auch bei nachfolgender hoher Erhitzung bemerkbar. Diese hohe Erhitzung auf eine Temperatur von mehr als 1750 ist notwendig, um eine große Leitfähigkeit in der Durchgangsrichtung des Ventils zu erzielen. Geht jedoch dieser Erhitzung eine Erwärmung auf niedrigere Temperatur voraus, so wird die Differenz im elektrischen Widerstände der Durchgangsrichtung und der Absperrichtung bedeutend vergrößert.The crystalline selenium slowly formed at low temperature has a more favorable structure and surface quality than the rapidly crystallized selenium. This more advantageous quality is also noticeable with subsequent high heating. This high heating to a temperature of more than 175 0 is necessary in order to achieve high conductivity in the direction of passage of the valve. However, if this heating is preceded by heating to a lower temperature, the difference in the electrical resistance of the direction of passage and the direction of shut-off is significantly increased.
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DES88221D DE589126C (en) | 1928-10-30 | 1928-10-31 | Process for the manufacture of electric valve plates by applying a layer of selenium to an electrode |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DES0088221 | 1928-10-30 | ||
DES88221D DE589126C (en) | 1928-10-30 | 1928-10-31 | Process for the manufacture of electric valve plates by applying a layer of selenium to an electrode |
Publications (1)
Publication Number | Publication Date |
---|---|
DE589126C true DE589126C (en) | 1933-12-02 |
Family
ID=25997473
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DES88221D Expired DE589126C (en) | 1928-10-30 | 1928-10-31 | Process for the manufacture of electric valve plates by applying a layer of selenium to an electrode |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE589126C (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE742762C (en) * | 1939-03-15 | 1943-12-10 | Philips Patentverwaltung | Method for manufacturing a barrier electrode system with a selenium electrode |
DE754795C (en) * | 1936-10-19 | 1952-10-13 | Siemens Schuckertwerke A G | Process for the manufacture of selenium rectifiers |
DE919360C (en) * | 1949-08-17 | 1954-10-21 | Western Electric Co | Selenium rectifier with tellurium and process for its manufacture |
DE925847C (en) * | 1949-10-31 | 1955-03-31 | Licentia Gmbh | Method of manufacturing selenium rectifiers |
DE970124C (en) * | 1944-01-17 | 1958-09-04 | Siemens Ag | Process for the manufacture of selenium rectifiers |
DE971615C (en) * | 1948-10-01 | 1959-02-26 | Siemens Ag | Process for the manufacture of dry selenium rectifiers |
-
1928
- 1928-10-31 DE DES88221D patent/DE589126C/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE754795C (en) * | 1936-10-19 | 1952-10-13 | Siemens Schuckertwerke A G | Process for the manufacture of selenium rectifiers |
DE742762C (en) * | 1939-03-15 | 1943-12-10 | Philips Patentverwaltung | Method for manufacturing a barrier electrode system with a selenium electrode |
DE970124C (en) * | 1944-01-17 | 1958-09-04 | Siemens Ag | Process for the manufacture of selenium rectifiers |
DE971615C (en) * | 1948-10-01 | 1959-02-26 | Siemens Ag | Process for the manufacture of dry selenium rectifiers |
DE919360C (en) * | 1949-08-17 | 1954-10-21 | Western Electric Co | Selenium rectifier with tellurium and process for its manufacture |
DE925847C (en) * | 1949-10-31 | 1955-03-31 | Licentia Gmbh | Method of manufacturing selenium rectifiers |
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