DE576939C - Process for the production of completely homogeneous dry matter extracts - Google Patents
Process for the production of completely homogeneous dry matter extractsInfo
- Publication number
- DE576939C DE576939C DEI37175D DEI0037175D DE576939C DE 576939 C DE576939 C DE 576939C DE I37175 D DEI37175 D DE I37175D DE I0037175 D DEI0037175 D DE I0037175D DE 576939 C DE576939 C DE 576939C
- Authority
- DE
- Germany
- Prior art keywords
- production
- drying
- completely homogeneous
- extracts
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000284 extract Substances 0.000 title claims description 10
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000000034 method Methods 0.000 title claims description 5
- 238000001035 drying Methods 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 8
- 235000019198 oils Nutrition 0.000 claims description 8
- 239000000944 linseed oil Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 235000021388 linseed oil Nutrition 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims description 3
- 239000002274 desiccant Substances 0.000 claims description 2
- 229910001385 heavy metal Inorganic materials 0.000 claims description 2
- 125000005608 naphthenic acid group Chemical class 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000010491 poppyseed oil Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000007787 solid Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 7
- 239000002966 varnish Substances 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000976 ink Substances 0.000 description 3
- 235000020778 linoleic acid Nutrition 0.000 description 3
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 3
- 125000005609 naphthenate group Chemical group 0.000 description 3
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 2
- 235000013495 cobalt Nutrition 0.000 description 2
- MZZUATUOLXMCEY-UHFFFAOYSA-N cobalt manganese Chemical compound [Mn].[Co] MZZUATUOLXMCEY-UHFFFAOYSA-N 0.000 description 2
- 229940044175 cobalt sulfate Drugs 0.000 description 2
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 2
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000008149 soap solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical class [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- -1 i: i Chemical compound 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical class [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Description
Verfahren zur Herstellung völlig homogener Trockenstoff-Extrakte Die gemäß den Patenten 352 356 und 395 646 zur Herstellung von Sikkativen, Leinölfirnisersatz und Ersatz für oxydierende Leinöle dienenden naphthensauren Salze des Kobalts, Mangans, Bleis, Zinks und Calciums, die sich wegen ihrer hervorragenden. trocknungsbeschleunigenden- Eigenschaften in der Firnis- und Lackindustrie bewährt und eingeführt haben, konnten bisher nur in festem Zustande oder gelöst in- flüchtigen organischen Lösungsmitteln, wie Lackbenzin, Terpentinöl, Benzol usw. auf den Markt gebracht werden, wo sie unter dem Namen Sollgene bekannt sind.Process for the production of completely homogeneous dry extracts The according to patents 352 356 and 395 646 for the production of siccatives, linseed oil varnish substitute and substitute for oxidizing linseed oils serving naphthenic acid salts of cobalt, manganese, Lead, zinc and calcium, which stand out because of their excellent. drying accelerating Properties that have been tried and tested in the varnish and lacquer industry and have been able to introduce them so far only in the solid state or dissolved in volatile organic solvents, such as mineral spirits, turpentine oil, benzene etc. are put on the market where they are under are known by the name Sollgene.
Zum Auflösen der festen Trockner in den flüchtigen Lösungsmitteln werden die ersteren in einem Kessel bei ioo bis 16o° C zunächst geschmolzen, worauf das flüchtige Lösungsmittel zugegeben wird. Die Durchführung dieses Löseverfahrens ist vielen Verbrauchern aus feuerpolizeilichen Gründen nicht gestattet. Wird das Lösen vom Erzeuger der Trockenstoffe vorgenommen, so entsteht durch die Verpackung und den Versand, gegebenenfalls im Feuerzug, eine nicht unerhebliche Verteuerung des. Produktes. Außerdem lassen sich die Trockner in Form dieser Lösungen nicht allgemein verwenden, da flüchtige Lösungsmittel für viele Zwecke wie für die Herstellung beispielsweise von Firnissen, Druckfarben, Linoxyn usw. nicht erwünscht sind, zum Teil sogar nachteilig wirken. Für die Herstellung von Lösungen dieser Stoffe in Leinöl muß dieses auf obengenannte Temperaturen erhitzt werden, um die festen Trockner in Lösung zu bringen, was vielen Abnehmern erhebliche Schwierigkeiten bereitet.To dissolve the solid dryer in the volatile solvents the former are first melted in a kettle at 100 to 160 ° C, whereupon the volatile solvent is added. The implementation of this solving process is not permitted for many consumers for reasons of fire protection. It will Loosening made by the producer of the dry matter, so arises through the packaging and shipping, possibly in a fire train, a not inconsiderable price increase of the. product. In addition, the dryer cannot be used in the form of these solutions commonly use as volatile solvents for many purposes such as for manufacturing for example of varnishes, printing inks, Linoxyn, etc. are not desirable for Part even have a detrimental effect. For the production of solutions of these substances in Linseed oil must be heated to the above-mentioned temperatures in order to dry the solid to bring into a solution, which causes considerable difficulties for many customers.
Der Versuch, die festen, als Soligene bekannten Trockenstoffe zur leichten und bequemen Handhabung in mehr. oder weniger konzentrierter Form in trocknenden oder halbtrocknenden ölen, wie Leinöl, Holzöl, Sojaöl usw., zu lösen, scheitert daran, daß das Lösevermögen dieser öle sehr beschränkt ist, so daß der größte Teil der in der Wärme gelösten Trockenstoffe allmählich beim Abkühlen und Stehenlassen wieder ausfällt und sich am Boden des Lösegefäßes festsetzt und erhärtet.Trying to use the solid drying agents known as Soligene easy and convenient handling in more. or less concentrated form in drying or semi-drying oils, such as linseed oil, wood oil, soybean oil, etc., fails because the solvent power of these oils is very limited, so that most of them of the dry matter dissolved in the heat gradually as it cools down and left to stand fails again and settles and hardens at the bottom of the dissolving vessel.
Es wurde nun gefunden, daß diese Nachteile verhindert werden können, wenn an Stelle der genannten öle deren freie Fettsäuren verwendet werden. Diese besitzen ein so hervorragendes Lösevermögen für Kaphthenate, besonders für die des Kobalts, Mangans und Kobalt-Mangans, daß sich damit beliebig hohe Konzentrationen von Lösungen dieser Trockner herstellen lassen. Dieses überraschende Lösevermögen war in keiner Weise vorauszusehen.It has now been found that these disadvantages can be prevented if their free fatty acids are used instead of the oils mentioned. These have such an excellent dissolving power for caphthenates, especially for those of des Cobalts, manganese and cobalt-manganese, that can be any high concentration of solutions have this dryer manufactured. This surprising Solvency was in no way foreseeable.
Die Herstellung der Extrakte erfolgt auf einfachste@rt"eqgemste Weise. dadurch, daß beim,- tviäss&ii deY"festen Trockner, unter Eiljsehinelwn. der 144hthenate, die erforderliche,-'Menge Leinölsäure je nach der gewünschten Xän@entratxZn zugesetzt wird, wobei durch kurzes Schmelzen unter gutem Rühierr mühelos ein""yöllig homogener Extrakt et4'Iten;,w'eoen kann. Das Schmelzen erfolgt daMf schön bei bedeutend niedrigerer Temperatur als beim festen Trockner.The extracts are produced in the simplest possible way. by the fact that at the - tviäss & ii deY "solid dryer, under Eiljsehinelwn. der 144hthenate, the required - 'amount of linoleic acid depending on the desired Xan @ entratxZn is added, whereby a "" yöllig is effortlessly created by briefly melting it with good stirring homogeneous extract et4'Iten; what can. Melting takes place nicely at significant lower temperature than the fixed dryer.
Die so hergestellten Extrakte der Schwermetallnaphthenate stellen klare, leicht flüssige bis hochviskose, aber völlig homogene Produkte dar, die gegenüber den festen Naphthenaten eine Reihe sehr beachtlicher Vorzüge aufweisen. Sie sind sowohl in trocknenden Ölen als auch in den gebräuchlichsten organischen Lösungsmitteln sehr leicht, restlos und klar löslich und gewähren deshalb den Vorteil einer äußerst leichten und bequemen Handhabung bei Herstellung von Firnissen, Druckfarben, Lacken usw. Diesen können sie kalt bzw. unter gelindem Erwärmen zugesetzt werden, wodurch Zeit und Arbeitslöhne ge= spart werden. Auch zeigen diese Firnisse, Druckfarben und Lacke eine bedeutend hellere Farbe als die mit festen Trncknern hergestellten und weisen unmittelbar nach ihrer Herstellung eine vorzügliche Trockenwirkung auf, was vermutlich darauf zurückzuführen ist, daß in den Extrakten der Dispersitätsgrad der Sikkativmetalle ein weit höherer ist als in den festen Trocknern. Die Naphthenatextrakte sind in der Wärme, ebenso auch bei Temperaturen unter o° unbegrenzt haltbar. Zersetzungen und Veränderungen durch Oxydation oder Gelatinieren treten bei ihnen nicht ein.The extracts of heavy metal naphthenates produced in this way provide clear, slightly liquid to highly viscous, but completely homogeneous products have a number of very notable advantages over the solid naphthenates. they are both in drying oils and in the most common organic solvents very easily, completely and clearly soluble and therefore grant the advantage of an extremely easy and convenient handling in the production of varnishes, printing inks, lacquers etc. They can be added cold or with gentle warming, whereby Time and wages are saved. These also show varnishes and printing inks and varnishes are significantly lighter in color than those made with solid driers and have an excellent drying effect immediately after their production, which is probably due to the fact that in the extracts the degree of dispersity the siccative metals is far higher than in the solid dryers. The naphthenate extracts can be kept indefinitely in the heat, even at temperatures below 0 °. Decompositions and changes by oxidation or gelatinization do not occur in them.
Beispiele i. iooo Gewichtsteile technisch reine Naphthensäure werden bei Kochtemperatur je nach der Säurezahl mit Zoo bis 2io Gewichtsteilen Ätznatron unter Rühren verseift, die klare Seifenlösung wird mit einer Lösung von etwa 63o bis 65o Gewichtsteilen Kobaltsulfat ausgefällt, der entstandene Niederschlag heiß etwa dreimal gewaschen, nach Ablassen des letzten Waschwassers durch einen kurzen Schmelzprozeß bei etwa 13o° C entwässert, wobei gleichzeitig die zum Lösen erforderliche Menge Leinölsäure zugesetzt wird. Die gangbarsten Konzentrationen sind: fester Trockner zu Leinölsäure wie i : i, 2 : 1, q. : l USW. Examples i. 100 parts by weight of technically pure naphthenic acid are saponified with zoo to 2io parts by weight of caustic soda while stirring at the boiling temperature, depending on the acid number, the clear soap solution is precipitated with a solution of about 63o to 65o parts by weight of cobalt sulfate, the precipitate formed is washed hot about three times, after draining the last one Wash water is dewatered by a short melting process at about 130 ° C., the amount of linoleic acid required for dissolving being added at the same time. The most common concentrations are: solid dryer to linoleic acid such as i: i, 2: 1, q. : l etc.
2. iooo Gewichtsteile Naphthensäure werden nach Beispiel i verseift, die klare Seifenlösung zuerst mit einer Lösung von q. Teilen Mangansulfat versetzt und die restliche Naphthenseife mit einer Lösung von ioo bis ilo Teilen Kobaltsulfat quantitativ ausgefällt und wie oben ausgewaschen. Während des Entwässerns durch Schmelzen gibt man je nach der gewünschten Konzentration iooo Gewichtsteile bzw. 5oo Gewichtsteile bzw. 25o Gewichtsteile usw. Leinölsäure, Holzölsäure usw. zu, wodurch ein völlighomogener Kobalt-Mangan-Extrakt erhalten wird.2. 100 parts by weight of naphthenic acid are saponified according to Example i, the clear soap solution first with a solution of q. Parts of manganese sulfate are added and the remaining naphthenic soap with a solution of 100 to 100 parts cobalt sulfate Quantitatively precipitated and washed out as above. During draining through Depending on the desired concentration, melts are added 100 parts by weight or 500 parts by weight or 25o parts by weight, etc., linoleic acid, wood oleic acid, etc. whereby a completely homogeneous cobalt-manganese extract is obtained.
Claims (2)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB339922D GB339922A (en) | 1929-02-23 | ||
| DEI37175D DE576939C (en) | 1929-02-23 | 1929-02-23 | Process for the production of completely homogeneous dry matter extracts |
| DEI38380D DE578416C (en) | 1929-02-23 | 1929-06-15 | Process for the production of completely homogeneous dry matter extracts |
| DEI41435D DE579683C (en) | 1929-02-23 | 1931-05-03 | Process for the production of completely homogeneous dry matter extracts |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI37175D DE576939C (en) | 1929-02-23 | 1929-02-23 | Process for the production of completely homogeneous dry matter extracts |
| DE383172X | 1931-05-02 | ||
| DEI41435D DE579683C (en) | 1929-02-23 | 1931-05-03 | Process for the production of completely homogeneous dry matter extracts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE576939C true DE576939C (en) | 1933-05-19 |
Family
ID=33032805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEI37175D Expired DE576939C (en) | 1929-02-23 | 1929-02-23 | Process for the production of completely homogeneous dry matter extracts |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE576939C (en) |
-
1929
- 1929-02-23 DE DEI37175D patent/DE576939C/en not_active Expired
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