DE563257C - Process for the production of emulsifying, cleaning, wetting agents u. like - Google Patents
Process for the production of emulsifying, cleaning, wetting agents u. likeInfo
- Publication number
- DE563257C DE563257C DEI28710D DEI0028710D DE563257C DE 563257 C DE563257 C DE 563257C DE I28710 D DEI28710 D DE I28710D DE I0028710 D DEI0028710 D DE I0028710D DE 563257 C DE563257 C DE 563257C
- Authority
- DE
- Germany
- Prior art keywords
- emulsifying
- cleaning
- production
- wetting agents
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 4
- 239000000080 wetting agent Substances 0.000 title claims description 4
- 238000004140 cleaning Methods 0.000 title claims description 3
- 230000001804 emulsifying effect Effects 0.000 title claims description 3
- 159000000003 magnesium salts Chemical class 0.000 claims description 5
- 239000000084 colloidal system Substances 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000003077 lignite Substances 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 150000003460 sulfonic acids Chemical class 0.000 claims description 2
- 239000002641 tar oil Substances 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Herstellung von Emulgierungs-, Reinigungs-, Netzmitteln u. dgl. Das Hauptpatent betrifft die Herstellung von Emulgierungs-, Reinigungs-, Netzmitteln u. dgl. durch Sulfonierung von Braunkohlenteerölkohlenwasserstoffen im Gemisch mit ;wenigstens 5o % aromatischer bzw. hydroaromatischer Kohlenwasserstoffe oder ihrer Abkömmlinge.Process for the production of emulsifying agents, cleaning agents and wetting agents and the like. The main patent relates to the production of emulsifying, cleaning, Wetting agents and the like by sulfonating brown coal tar oil hydrocarbons in a mixture with; at least 50% aromatic or hydroaromatic hydrocarbons or their descendants.
Bei der weiteren Bearbeitung wurde nun gefunden, daß die Magnesiumsalze dieser Körper im Gegensatz zu den Alkalisalzen bzw. den freien Säuren nicht hygroskopisch sind, was für ihre technische Verwendung von großem Vorteil ist. Magnesiumsalze von solchen Sulfonsäuren, die beim Verdünnen einer hydrolytischen Spaltung unterliegen, die zur Abscheidung von 1VIagnesiumhydroxyd führt, versetzt man vorteilhaft mit Mineralsalzen, wie z. B. Natrium- oder Ammoniumsulfat, oder mit Schutzkolloiden, wodurch Trübungen vermieden werden. Die Produkte haben dieselben Eigenschaften wie die des Hauptpatents. Beispiel Eine gemäß Beispiel, des Hauptpatents aus ioo Teilen Solaröl und 5o Teilen -Kylol erhältliche Sulfonsäure wird in das Kalksalz übergeführt und die Kalklösung mit Magnesiumsulfat umgesetzt. Ausbeute i 9o Teile Magnesiumsalz. 5o Teile des so erhaltenen Magnesiumsalzes werden mit 5o Teilen Natriumsulfat in der Kugelmühle gemischt, wodurch ein Produkt erhalten wird, das selbst in großer Verdünnung keinerlei Trübung zeigt.In further processing it has now been found that the magnesium salts In contrast to the alkali salts or the free acids, this body is not hygroscopic are, which is of great advantage for their technical use. Magnesium salts of those sulfonic acids which are subject to hydrolytic cleavage when diluted, which leads to the deposition of 1% magnesium hydroxide, is advantageously mixed with Mineral salts such as B. sodium or ammonium sulfate, or with protective colloids, whereby cloudiness is avoided. The products have the same properties as that of the main patent. Example One according to the example of the main patent from 100 parts Sulphonic acid, which is available from solar oil and 50 parts of kylene, is converted into the lime salt and the lime solution reacted with magnesium sulfate. Yield of i 90 parts of magnesium salt. 5o parts of the magnesium salt obtained in this way are mixed with 5o parts of sodium sulfate in mixed by the ball mill, thereby obtaining a product that is even large in size Dilution does not show any turbidity.
Das Natriumsulfat kann ganz oder zum Teil durch Schutzkolloide, wie solche z. B. gemäß österreichischem Patent I06; i3 erhalten werden, bzw. durch sulfoniertes Wollfett o. dgl. ersetzt werden.The sodium sulfate can wholly or partly by protective colloids, such as such z. B. according to Austrian patent I06; i3 can be obtained, or by sulfonated Wool grease or the like. Be replaced.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI28710D DE563257C (en) | 1926-08-06 | 1926-08-06 | Process for the production of emulsifying, cleaning, wetting agents u. like |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI28710D DE563257C (en) | 1926-08-06 | 1926-08-06 | Process for the production of emulsifying, cleaning, wetting agents u. like |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE563257C true DE563257C (en) | 1932-11-04 |
Family
ID=7187116
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEI28710D Expired DE563257C (en) | 1926-08-06 | 1926-08-06 | Process for the production of emulsifying, cleaning, wetting agents u. like |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE563257C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE749302C (en) * | 1933-01-30 | 1945-02-03 | Chem Ind Basel | Wetting, cleaning, dispersing and emulsifying agents |
-
1926
- 1926-08-06 DE DEI28710D patent/DE563257C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE749302C (en) * | 1933-01-30 | 1945-02-03 | Chem Ind Basel | Wetting, cleaning, dispersing and emulsifying agents |
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