DE554372C - Process for the production of shoe polishes, floor polishes and. like - Google Patents
Process for the production of shoe polishes, floor polishes and. likeInfo
- Publication number
- DE554372C DE554372C DE1930554372D DE554372DD DE554372C DE 554372 C DE554372 C DE 554372C DE 1930554372 D DE1930554372 D DE 1930554372D DE 554372D D DE554372D D DE 554372DD DE 554372 C DE554372 C DE 554372C
- Authority
- DE
- Germany
- Prior art keywords
- polishes
- production
- shoe
- floor
- carnauba wax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 4
- 239000004203 carnauba wax Substances 0.000 claims description 8
- 235000013869 carnauba wax Nutrition 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000006071 cream Substances 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- 150000002314 glycerols Chemical class 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000005498 polishing Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 238000002844 melting Methods 0.000 description 9
- 230000008018 melting Effects 0.000 description 6
- 239000004359 castor oil Substances 0.000 description 5
- 235000019438 castor oil Nutrition 0.000 description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 241000779819 Syncarpia glomulifera Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- DMCJFWXGXUEHFD-UHFFFAOYSA-N pentatriacontan-18-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)CCCCCCCCCCCCCCCCC DMCJFWXGXUEHFD-UHFFFAOYSA-N 0.000 description 2
- 239000001739 pinus spp. Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 2
- 229940036248 turpentine Drugs 0.000 description 2
- 235000010919 Copernicia prunifera Nutrition 0.000 description 1
- 244000180278 Copernicia prunifera Species 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- VETNMUXXCNEZFK-UHFFFAOYSA-N Montanone Natural products CC1CC(OC(=O)C)C2C(OC(=O)C2=C)C3C1C(=O)C=C3C VETNMUXXCNEZFK-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- VETNMUXXCNEZFK-OYBMWFINSA-N [(3aR,4S,6S,6aS,9aR,9bR)-6,9-dimethyl-3-methylidene-2,7-dioxo-4,5,6,6a,9a,9b-hexahydro-3aH-azuleno[4,5-b]furan-4-yl] acetate Chemical compound O=C(O[C@@H]1[C@H]2C(=C)C(=O)O[C@@H]2[C@H]2C(C)=CC(=O)[C@H]2[C@@H](C)C1)C VETNMUXXCNEZFK-OYBMWFINSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- -1 ketones Alcohols Chemical class 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- ODSVXDFDFCXJDV-UHFFFAOYSA-N tritetracontan-22-one Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)CCCCCCCCCCCCCCCCCCCCC ODSVXDFDFCXJDV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/14—Other polishing compositions based on non-waxy substances
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
Description
Verfahren zur Herstellung von Schuhcremes, Bohnermassen u. dgl. Es ist bekannt, daß das im wesentlichen aus dem i2-Oxystearinsäuretriglycerid bestehende hydrierte (gehärtete) Rizinusöl einen Schmelzpunkt besitzt, der dem des Karnaubawachses sehr nahe liegt. Trotzdem aber ist das Produkt an Stelle des Karnaubawachses nicht verwendbar, da es in seiner Struktur kristallinisch und daher bröckelnd den wachsartigen Charakter des Karnaubawachses vermissen läßt. Auch besitzt es nicht das Bindungsvermögen für Lösungsmittel, welches das Karnaubawachs gerade für die Zwecke der Fabrikation von Schuhcremes, Bohnermassen u. dgl. geeignet macht. Eine aus i Teil gehäftetem Rizinusöl und 3 Teilen Terpentinöl hergestellte Schuhcreme läßt jedenfalls das glatte Aussehen einer Karnaubawachscreme vermissen, zeigt kristallinische Ausscheidungen und läßt sich z. B. durch Fingerdruck leicht wieder in das kristallinische Glycerid und das verwandte Lösungsmittel trennen.Process for the production of shoe polishes, floor polishes and the like it is known that this consists essentially of the i2-oxystearic acid triglyceride Hydrogenated (hardened) castor oil has a melting point that is similar to that of carnauba wax is very close. Nevertheless, the product is not in place of the carnauba wax usable because it is crystalline in its structure and therefore crumbling the waxy Lacks the character of the carnauba wax. Nor does it have the ability to bind for solvents, which carnauba wax is used for manufacturing purposes of shoe polishes, floor polishes and the like. One from i part stuck Castor oil and 3 parts turpentine oil made shoe polish leaves the smooth anyway Missing the appearance of a carnauba wax cream shows crystalline precipitates and can be z. B. easily back into the crystalline glyceride by finger pressure and separate the solvent used.
Es wurde nun aber gefunden, daß man das gehärtete Rizinusöl dennoch vorzüglich zur Herstellung karnaubawachsähnlicher Präparationen verwenden kann, wenn man dasselbe gleichzeitig mit hochmolekularen und hochschmelzenden Oxo- oder Oxyverbindungen der Fettreihe bzw. deren Derivaten zusamnienschmilzt und in Anwendung bringt. Die so erhaltenen Produkte besitzen Aussehen, Bruch und Lösungsmittel- (Terpentin-) Bindungsvermögen des echten Karnaubawachses und sind auch äußerlich kaum von diesem zu unterscheiden. Die Schmelzpunkte liegen ebenfalls denen des Karnaubawachses sehr nahe.It has now been found, however, that the hydrogenated castor oil can still be used can be used excellently for the production of carnauba wax-like preparations, if you do the same thing at the same time with high molecular weight and high melting oxo or Oxy compounds of the fat series or their derivatives melt together and in use brings. The products thus obtained have appearance, breakage and solvent (turpentine) Binding capacity of the real carnauba wax and are also hardly of this externally to distinguish. The melting points are also very close to those of carnauba wax vicinity.
Ein für die Herstellung von Schuhcremes und Bohnermassen durchaus geeignetes Produkt erhält man beispielsweise durch Zusaminenschmelzen von 8o Teilen gehärtetem Rizinusöl mit 2o Teilen Behenon (F. 92° C). Löst man dasselbe in 3 Teilen Terpentinöl oder ähnlichen in der Schuhcreme- und Bohnermassenindustrie gebräuchlichen Lösungsmitteln oder Lösungsmittelgemischen, so erhält man eine steife, cremeartige Masse ohne kristallinische Ausscheidungen, die alle Eigenschaften der heute als Schuhputzmittel, Bohnermassen u. dgl. üblichen Fabrikate aufweist. An Stelle des hier benutzten Behenons können mit gleichem Erfolge auch die Ketone anderer Fettsäuren, wie beispielsweise das Stearon (F. 88° C) oder Montanon, Verwendung finden. Die gleichen Erfolge erzielt man aber auch, wenn an Stelle der Ketone hochschmelzende Alkohole- der aliphatischen Reihe, wie beispielsweise Pentatriakontanol-i8 (F. 92° C), Hentriakontanol-i6 (F. 85,6° C) u. a., oder hochschmelzende Derivate solcher Alkohole, wie beispielsweise der Oxalsäuredimyricylester (F. 9i° C) oder der Palmitinsäureoerylester (F. 79° C), verwendet werden. Auch ist es keineswegs nötig, lediglich chemisch reine Produkte zu verarbeiten, ein geringer Säuregehalt oder andere Verunreinigungen wirken in keiner Weise störend, wenn nur der Schmelzpunkt der Zusatzstoffe 70° C nicht wesentlich unterschreitet. Gegebenenfalls sind daher auch Zusatzstoffe verwendbar, die, wie oxydiertes Montanwachs, erhebliche Mengen hochschmelzender ketonartiger Verbindungen u. dgl. enthalten.Definitely one for the production of shoe polishes and floor polishes a suitable product is obtained, for example, by melting 80 parts together hydrogenated castor oil with 20 parts of behenon (m.p. 92 ° C). Do the same thing in 3 parts Oil of turpentine or similar ones commonly used in the shoe polish and floor polish industry Solvents or solvent mixtures, a stiff, creamy one is obtained Mass without crystalline precipitates, which have all the properties of today as Has shoe polishes, floor polishes and the like. Instead of The behenons used here can also use the ketones of other fatty acids, such as stearon (m.p. 88 ° C) or montanone, are used. the However, the same results can also be achieved if high-melting ketones are used instead of ketones Alcohols of the aliphatic series, such as, for example, Pentatriakontanol-18 (F. 92 ° C), hentriacontanol-16 (m.p. 85.6 ° C) and others, or high-melting derivatives of such Alcohols, such as dimyricyl oxalate (mp 91 ° C.) or aeryl palmitate (M.p. 79 ° C) can be used. It is also by no means necessary, only chemically pure Process products, low acidity or other impurities works In no way bothersome, if only the melting point of the additives is 70 ° C significantly below. If necessary, additives can therefore also be used, which, like oxidized montan wax, contain considerable amounts of high-melting ketone-like ones Compounds and the like included.
An Stelle des gehärteten Rizinusöles können schließlich in gleicher Weise auch die Glykolester oder die Mono- und Diglyceride der i2-Oxystearinsäure verwandt werden, die sich in ihrem Schmelzpunkt nur wenig von dem des Triglycerids unterscheiden.Instead of the hardened castor oil you can finally use the same Also the glycol esters or the mono- and diglycerides of i2-oxystearic acid which differ in their melting point only slightly from that of the triglyceride differentiate.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE554372T | 1930-02-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE554372C true DE554372C (en) | 1932-07-07 |
Family
ID=6564070
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1930554372D Expired DE554372C (en) | 1930-02-16 | 1930-02-16 | Process for the production of shoe polishes, floor polishes and. like |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE554372C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE967238C (en) * | 1953-02-06 | 1957-10-24 | Basf Ag | Easily emulsifiable or colloidally soluble wax products |
-
1930
- 1930-02-16 DE DE1930554372D patent/DE554372C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE967238C (en) * | 1953-02-06 | 1957-10-24 | Basf Ag | Easily emulsifiable or colloidally soluble wax products |
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