DE511520C - Process for rendering sulfur compounds harmless in melt fluids from rock phosphates, especially in melt cements - Google Patents
Process for rendering sulfur compounds harmless in melt fluids from rock phosphates, especially in melt cementsInfo
- Publication number
- DE511520C DE511520C DEK108532D DEK0108532D DE511520C DE 511520 C DE511520 C DE 511520C DE K108532 D DEK108532 D DE K108532D DE K0108532 D DEK0108532 D DE K0108532D DE 511520 C DE511520 C DE 511520C
- Authority
- DE
- Germany
- Prior art keywords
- melt
- cements
- rendering
- sulfur compounds
- fluids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/60—Methods for eliminating alkali metals or compounds thereof, e.g. from the raw materials or during the burning process; methods for eliminating other harmful components
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/38—Preparing or treating the raw materials individually or as batches, e.g. mixing with fuel
- C04B7/42—Active ingredients added before, or during, the burning process
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Public Health (AREA)
- Toxicology (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Description
Verfahren zum Unschädlichmachen von Schwefelverbindungen in Schmelzflüssen aus Rohphosphaten, insbesondere in Schmelzzementen Bei Schlacken, die zur Weiterverarbeitung auf Zemente bestimmt sind, aber auch bei gewissen Sorten von Schmelzzementen ergibt sich. der Nachteil, :daß bei diesen Schlacken oder Schmelzzementen beim Anmachen mit Wasser eine sich unangenehm bemerkbar machende Schwefelwasserstoff entwicklung stattfindet. Die Schwefelwasserstoff entwickelnden Verbindungen haben außerdem noch den Nachteil, daß durch sie die Festigkeit der Zemente ungünstig beeinflußt wird.Process for rendering sulfur compounds harmless in melt rivers from rock phosphates, especially in molten cements are intended for cements, but also results in certain types of molten cement themselves. the disadvantage: that with these slags or molten cements when mixing with water an unpleasantly noticeable evolution of hydrogen sulfide takes place. The compounds that evolve hydrogen sulfide also have the disadvantage that they adversely affect the strength of the cements.
Es hat sich nun gezeigt, daß man :diese Schwefelwasserstoff entwickelnden Verbindungen so umlagern kann, ,daß die Schwefelwasserstoffentwicklung fast vollkommen vermieden wird.It has now been shown that: these evolve hydrogen sulphide Can rearrange compounds in such a way that the evolution of hydrogen sulfide is almost complete is avoided.
Zu dem Zweck mischt man entweder vor dem Schmelzfluß der Beschickung selbst oder aber, was noch wirksamer ist, dem fertigen Schmelzfluß Magnesiumoxyd zu, so daß sich dieses mit der Schmelze verbindet.To this end, either mixing is carried out prior to the melt flow of the charge itself or, what is still more effective, the finished melt flow magnesium oxide to, so that this connects to the melt.
Versuche ergaben, daß beispielsweise ein Zusatz von 3 Prozent Magnesiumoxyd, welcher der aus dem Prozeß einer gleichzeitigen Herstellung von. Phosphorsäure und Schmelzzement entstammenden flüssigen Schlacke hinzugefügt wurde, die Schwefelwasserstoffentwicklung beim Anmachen :der Schlacke mit Wasser um 17 Prozent herunterdrückte, während eine Reduktion um 30 Prozent nachzuweisen war, wenn diese 3 Prozent Magnesiumoxyd vor dem Schmelzfluß der Beschickung selbst hinzugefügt wurden.Tests have shown that, for example, an addition of 3 percent magnesium oxide, which is the result of the process of simultaneous production of. Liquid slag derived from phosphoric acid and molten cement was added, which produced hydrogen sulphide during mixing: the slag was lowered by 17 percent with water, while a reduction of 30 percent was demonstrated when this 3 percent magnesium oxide was added to the feed itself before the melt flow.
Die Schwefelwasserstoffentwicklung wird noch weiter unterdrückt :durch erhöhte Zugabe von Magnesiumoxyd.The evolution of hydrogen sulfide is suppressed even further: by increased addition of magnesium oxide.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEK108532D DE511520C (en) | 1928-03-20 | 1928-03-20 | Process for rendering sulfur compounds harmless in melt fluids from rock phosphates, especially in melt cements |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEK108532D DE511520C (en) | 1928-03-20 | 1928-03-20 | Process for rendering sulfur compounds harmless in melt fluids from rock phosphates, especially in melt cements |
Publications (1)
Publication Number | Publication Date |
---|---|
DE511520C true DE511520C (en) | 1930-10-30 |
Family
ID=7241440
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEK108532D Expired DE511520C (en) | 1928-03-20 | 1928-03-20 | Process for rendering sulfur compounds harmless in melt fluids from rock phosphates, especially in melt cements |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE511520C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1051713B (en) * | 1956-04-16 | 1959-02-26 | Herbert A R Zehrlaut | Process for the treatment of calcium aluminate cement |
-
1928
- 1928-03-20 DE DEK108532D patent/DE511520C/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1051713B (en) * | 1956-04-16 | 1959-02-26 | Herbert A R Zehrlaut | Process for the treatment of calcium aluminate cement |
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