DE509118C - Process for the manufacture of explosives - Google Patents

Process for the manufacture of explosives

Info

Publication number
DE509118C
DE509118C DEF69400D DEF0069400D DE509118C DE 509118 C DE509118 C DE 509118C DE F69400 D DEF69400 D DE F69400D DE F0069400 D DEF0069400 D DE F0069400D DE 509118 C DE509118 C DE 509118C
Authority
DE
Germany
Prior art keywords
explosives
nitrates
alcohols
cyclic
manufacture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEF69400D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KARL FLICK DR ING
WALTER FRIEDERICH DR ING
Original Assignee
KARL FLICK DR ING
WALTER FRIEDERICH DR ING
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KARL FLICK DR ING, WALTER FRIEDERICH DR ING filed Critical KARL FLICK DR ING
Priority to DEF69400D priority Critical patent/DE509118C/en
Application granted granted Critical
Publication of DE509118C publication Critical patent/DE509118C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B25/00—Compositions containing a nitrated organic compound
    • C06B25/04—Compositions containing a nitrated organic compound the nitrated compound being an aromatic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Verfahren zur Herstellung von Sprengstoffen Zu den verschiedensten Zwecken, wie zur Herstellung von Sprengkapseln, Zündladungskörpern, Artilleriesprenggeschossen und Sprengladungen aller Art, sind die Nitrate des Pentaerythrits und des Anhydroenneaheptits vorgeschlagen worden. Das Pentaerythrittetranitrat hat man auch bereits bei Herstellung von rauchlosen Pulvern verwandt. Für die verschiedensten Zwecke, wie zur Ladung von Sprengkapseln, Füllung von detonierenden Zündschnüren und verschiedenen Sprengladungen, wird das Pentaerythrittetranitrat schon verwandt.Process for the manufacture of explosives Among the most diverse Purposes, such as for the production of detonators, detonators, artillery explosive projectiles and explosive charges of all kinds are the nitrates of pentaerythritol and anhydroenneaheptite has been proposed. The pentaerythritol granitrate is also available during manufacture related to smokeless powders. For a wide variety of purposes, such as cargo of detonators, filling of detonating fuses and various explosive charges, pentaerythritol granitrate is already being used.

Es wurde gefunden, daß die zyklischen KetonalkoholeTetramethylolcyclopentanon,Tetramethylolcyclohexanon, Oktomethylolcyclohexandion sowie ihre Reduktionsprodukte die zyklischen Alkohole Tetramethylolcyclopentanol, Tetramethylolcyclohexanol und Oktomethylolcyclohexandiol beim Nitrieren mit konzentrierter Salpetersäure oder mit Mischsäure Nitrate bilden. Diese Nitrate sind seither nicht bekannt geworden. Die Ketonalkohole und zyklischen Alkohole sind zum Teil in der Literatur beschrieben. Sie entstehen bei der Kondensation von zyklischen Ketonen mit Formaldehyd bei Gegenwart von Alkalien oder alkalischen Erden sowie anderen alkalisch reagierenden Stoffen. Die zyklischen Alkohole entstehen auch aus den zugehörigen Ketonalkoholen durch Reduktion. Sie sind alle synthetisch zugänglich.It has been found that the cyclic ketone alcohols tetramethylolcyclopentanone, tetramethylolcyclohexanone, Octomethylolcyclohexanedione and their reduction products, the cyclic alcohols Tetramethylolcyclopentanol, tetramethylolcyclohexanol and octomethylolcyclohexanediol form nitrates when nitrating with concentrated nitric acid or mixed acids. These nitrates have not become known since then. The ketone alcohols and cyclic Some alcohols are described in the literature. They arise from condensation of cyclic ketones with formaldehyde in the presence of alkalis or alkaline Earth and other alkaline substances. The cyclic alcohols arise also from the associated ketone alcohols by reduction. They are all synthetic accessible.

Die Nitrate dieser Körper sind recht beständig. Sie halten Lagerungen bei 5o° Wärme lange aus, ohne daß man Zersetzungserscheinungen feststellen kann. Naturgemäß sind die Nitrate der reinen zyklischen Alkohole energiestärker als die Ketonalkohole. Die Schmelzpunkte der Nitrate liegen derart, daß man sie zum Teil für sich allein, zum Teil in Mischung miteinander zur Herstellung von gegossenen Sprengladungen benutzen kann. Die Detonationsgeschwindigkeiten der Nitrate liegen sehr hoch und überschreiten zum Teil 8ooo m in der Sekunde. Die Sprengstoffe sind weniger empfindlich gegen mechanische Beanspruchung als das Pentaerythrittetranitrat. Seither sind keine Sprengstoffe von ähnlichem Energiegehalt bekannt geworden, die man bei Temperaturen unterhalb i oo' gießen kann. Die Sprengstoffe bedeuten also auch auf dem Gebiet der gießbaren Sprengstoffe einen wesentlichen Fortschritt, zumal einige Ausgangsmaterialien bereits Handelsprodukte sind und die anderen auf synthetischem Wege zugänglich sind.The nitrates in these bodies are quite consistent. They hold bearings at 50 ° for a long time without any signs of decomposition being observed. Naturally, the nitrates of the pure cyclic alcohols are more energetic than that Ketone alcohols. The melting points of the nitrates are such that some of them can be used on its own, sometimes mixed with one another for the production of cast Can use explosive charges. The detonation velocities of the nitrates lie very high and sometimes exceed 8,000 m per second. The explosives are less sensitive to mechanical stress than pentaerythritol tetranitrate. Since then, no explosives with a similar energy content have become known to the one can pour at temperatures below i oo '. So the explosives mean also made significant progress in the field of castable explosives, especially some raw materials are already commercial products and the others are synthetic Paths are accessible.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung von Sprengstoffen, dadurch gekennzeichnet, daß zyklische Ketonalkohole und zyklische Alkohole, wie Tetramethylolcyclohexanon, Tetramethylolcyclopentanon, Oktomethylolcyclohexandion, Tetramethylolcyclohexanol, Tetramethylolcyclopentanol, Oktomethylolcyclohexandiol, nitriert werden und die erhaltenen Nitrate für sich allein, im Gemenge miteinander oder mit anderen Sprengstoffen für alle bekannt gewordenen Zwecke verwandt werden.PATENT CLAIM: Process for the production of explosives, thereby characterized that cyclic ketone alcohols and cyclic alcohols such as tetramethylolcyclohexanone, Tetramethylolcyclopentanone, octomethylolcyclohexanedione, tetramethylolcyclohexanol, Tetramethylolcyclopentanol, octomethylolcyclohexanediol, are nitrated and the obtained nitrates on their own, in a mixture with one another or with other explosives be used for all known purposes.
DEF69400D 1929-10-11 1929-10-11 Process for the manufacture of explosives Expired DE509118C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEF69400D DE509118C (en) 1929-10-11 1929-10-11 Process for the manufacture of explosives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF69400D DE509118C (en) 1929-10-11 1929-10-11 Process for the manufacture of explosives

Publications (1)

Publication Number Publication Date
DE509118C true DE509118C (en) 1930-10-08

Family

ID=7111110

Family Applications (1)

Application Number Title Priority Date Filing Date
DEF69400D Expired DE509118C (en) 1929-10-11 1929-10-11 Process for the manufacture of explosives

Country Status (1)

Country Link
DE (1) DE509118C (en)

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