DE488554C - Process for the production of coatings on light metals - Google Patents
Process for the production of coatings on light metalsInfo
- Publication number
- DE488554C DE488554C DEJ31815D DEJ0031815D DE488554C DE 488554 C DE488554 C DE 488554C DE J31815 D DEJ31815 D DE J31815D DE J0031815 D DEJ0031815 D DE J0031815D DE 488554 C DE488554 C DE 488554C
- Authority
- DE
- Germany
- Prior art keywords
- coatings
- production
- light metals
- baths
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000576 coating method Methods 0.000 title claims description 10
- 229910052751 metal Inorganic materials 0.000 title claims description 6
- 239000002184 metal Substances 0.000 title claims description 6
- 150000002739 metals Chemical class 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 5
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 229910001385 heavy metal Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 238000004870 electrical engineering Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/37—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also hexavalent chromium compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/24—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing hexavalent chromium compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/24—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing hexavalent chromium compounds
- C23C22/26—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing hexavalent chromium compounds containing also organic compounds
- C23C22/27—Acids
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
Description
Verfahren zur Herstellung von Überzügen auf Leichtmetallen Zusatz zum Patent 475 789 In dem Patent 475 789 ist ein Verfahren beschrieben, auf Leichtmetallen, insbesondere Aluminium, Magnesium und seinen Legierungen, einen oxydischen Uberzug dadurch herzustellen, daß die Metalle reit einem wasserlöslichen Chromat und Flußsäure enthaltenden Bad behandelt werden. Diesen Bädern können noch in kleinen Mengen Schwermetallsalze beigegeben sein.Process for the production of coatings on light metals additive to the patent 475 789 In the patent 475 789 a process is described, on light metals, in particular aluminum, magnesium and their alloys, an oxide coating by producing the metals with a water-soluble chromate and hydrofluoric acid containing bath. These baths can contain small amounts of heavy metal salts be added.
Es wurde nun gefunden, daß oxydische Überzüge von anderem Farbcharakter erhalten werden können, wenn den Bädern wasserlösliche Permanganate zugesetzt werden, wobei die Menge des Chromates verringert werden kann.It has now been found that oxide coatings of a different color character can be obtained if water-soluble permanganates are added to the baths, whereby the amount of chromate can be reduced.
Es ist bekannt, für elektrotechnische Zwecke bestimmte Metallgegenstände mit einem elektrisch isolierenden Uberzug aus Oxyden des Mangans zu versehen, indem solche Gegenstände, z. B. Aluminiumdraht, nach geeigneter Vorbehandlung in auf 8o bis ioo ° erhitzte saure Bäder, die Kaliumpermanganat enthalten, eingetaucht.werden. Der so erhaltene Überzug besitzt braune bis schwarze Farbe.It is known to use metal objects intended for electrical engineering purposes to be provided with an electrically insulating coating of oxides of manganese by such items, e.g. B. aluminum wire, after suitable pretreatment in to 8o Acidic baths heated to 100 ° and containing potassium permanganate can be immersed. The coating obtained in this way is brown to black in color.
Von diesem Verfahren unterscheidet sich das nach vorliegender Erfindung dadurch, daß in Gegenwart der Chromate bzw. Bichromate übrigens nicht elektrisch isolierende Überzüge erhalten werden, welche je nach, der Menge des verwandten Permanganates bzw. Chromates in ihrer Farbe von Gelb über Goldrot, Hellbraun und Dunkelbraun bis Blauschwarz variieren.This differs from this method according to the present invention by the fact that in the presence of the chromates or bichromates it is not electrical insulating coatings are obtained, depending on the amount of permanganate used or chromates in their color from yellow to golden red, light brown and dark brown to Blue-black vary.
In Gegenwart des Bichromates sind die Bäder viel länger haltbar, als wenn Permanganat allein verwandt wird. Auch bildet sich der Überzug bereits bei niedrigeren Temperaturen; als sie nach dem älteren Patent angewandt werden müssen.In the presence of the bichromate, the baths last much longer than when permanganate is used alone. The coating is also already forming lower temperatures; than they have to be applied according to the earlier patent.
Die Überzüge nach vorliegender Erfindung sollen und können nicht für Isolationszwecke benutzt werden, dienen viehmehr hauptsächlich, z. B. auf Autokarosserien, als Ersatz eines farbigen Anstriches.The coatings of the present invention should not and cannot be used for Isolation purposes are used, serve much more mainly, z. B. on car bodies, as a replacement for colored paint.
Claims (1)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEJ31815D DE488554C (en) | 1927-07-26 | 1927-07-26 | Process for the production of coatings on light metals |
| DEJ32358D DE489974C (en) | 1927-07-26 | 1927-10-08 | Process for the production of coatings on light metals |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEJ31815D DE488554C (en) | 1927-07-26 | 1927-07-26 | Process for the production of coatings on light metals |
| DEJ32358D DE489974C (en) | 1927-07-26 | 1927-10-08 | Process for the production of coatings on light metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE488554C true DE488554C (en) | 1930-01-06 |
Family
ID=61187021
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEJ31815D Expired DE488554C (en) | 1927-07-26 | 1927-07-26 | Process for the production of coatings on light metals |
| DEJ32358D Expired DE489974C (en) | 1927-07-26 | 1927-10-08 | Process for the production of coatings on light metals |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEJ32358D Expired DE489974C (en) | 1927-07-26 | 1927-10-08 | Process for the production of coatings on light metals |
Country Status (1)
| Country | Link |
|---|---|
| DE (2) | DE488554C (en) |
-
1927
- 1927-07-26 DE DEJ31815D patent/DE488554C/en not_active Expired
- 1927-10-08 DE DEJ32358D patent/DE489974C/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE489974C (en) | 1930-01-23 |
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