DE43900C - Separation of the tarry sub. stamping out of the waste - sulfuric acid of the petroleum, paraffin and tar industry - Google Patents
Separation of the tarry sub. stamping out of the waste - sulfuric acid of the petroleum, paraffin and tar industryInfo
- Publication number
- DE43900C DE43900C DENDAT43900D DE43900DA DE43900C DE 43900 C DE43900 C DE 43900C DE NDAT43900 D DENDAT43900 D DE NDAT43900D DE 43900D A DE43900D A DE 43900DA DE 43900 C DE43900 C DE 43900C
- Authority
- DE
- Germany
- Prior art keywords
- waste
- paraffin
- petroleum
- sulfuric acid
- separation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002699 waste material Substances 0.000 title claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title claims description 7
- 239000012188 paraffin wax Substances 0.000 title claims description 4
- 239000003208 petroleum Substances 0.000 title claims description 3
- 238000000926 separation method Methods 0.000 title claims description 3
- 239000011269 tar Substances 0.000 title description 6
- QAOWNCQODCNURD-UHFFFAOYSA-M bisulphate group Chemical group S([O-])(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- OTYBMLCTZGSZBG-UHFFFAOYSA-L Potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 239000001120 potassium sulphate Substances 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000005755 formation reaction Methods 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 description 7
- 239000012535 impurity Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L mgso4 Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- UBBSASFKEJHWOE-UHFFFAOYSA-M [K+].OS(O)(=O)=O.OS([O-])(=O)=O Chemical compound [K+].OS(O)(=O)=O.OS([O-])(=O)=O UBBSASFKEJHWOE-UHFFFAOYSA-M 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/90—Separation; Purification
- C01B17/92—Recovery from acid tar or the like, e.g. alkylation acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
KLASSE 23: Fettindostrie.CLASS 23: Fettindostrie.
Paraffin- und Theer-Industrie.Paraffin and tar industry.
Die Abfallschwefelsäure der Paraffin-, Petroleum- und Theerindustrie bildet, obgleich sie noch 50 bis 60 pCt. an wasserfreier Schwefelsäure enthält, ein werthloses und lästiges Abfallproduct, da sie wegen der aufgenommenen übelriechenden Verunreinigungen nur schwierig Verwendung findet.The waste sulfuric acid of the paraffin, petroleum and tar industries does, although it does 50 to 60 pct. of anhydrous sulfuric acid, a worthless and troublesome waste product, because it is difficult to use because of the ingested malodorous impurities.
Das nachstehende Verfahren gestattet es, unter Abscheidung dieser Verunreinigungen diese Säure technisch zu verwerthen.The following procedure allows these impurities to be separated out to utilize this acid technically.
Man füllt die Abfallsäure in eine verbleite Eisenpfanne, vermischt sie mit so viel Natriumoder Kaliumsulfat, dafs sich Bisulfat bilden kann, erhitzt und dampft ab.You fill the waste acid into a leaded iron pan, mix it with as much sodium or Potassium sulphate, which can form bisulphate, is heated and evaporated.
Es bildet sich Bisulfat und bald tritt ein Zeitpunkt ein, wo sich die Unreinigkeiten der Abfallsäure oben als dicker Theer abscheiden, welcher leicht vom Salz getrennt werden kann.Bisulphate is formed and soon there will be a point in time when the impurities of the Separate the waste acid at the top as thick tar, which can easily be separated from the salt.
Man läfst nun entweder das flüssige Bisulfat unten ab oder schöpft den Theer oben ab.Either drain the liquid bisulfate from below or skim off the tar from above.
Das Bisulfat wird alsdann in einem Flammenofen unter leichter Erhitzung bei Ueberschufs von Luft entwässert, wobei zugleich etwaige noch zurückgebliebene Unreinigkeiten zerstört werden, und kann dann beliebig verwendet werden.The bisulfate is then placed in a flame furnace with slight heating if there is an excess dehydrated by air, at the same time destroying any remaining impurities and can then be used as desired.
Fügt man der Abfallsäure aufser dem Natriumoder Kaliumsulfat noch ein anderes lösliches Sulfat, welches specifisch schwerer ist, z. B. Magnesiumsulfat, hinzu, so findet die Abscheidung des Theeres noch leichter statt.If you add another soluble acid to the waste acid in addition to sodium or potassium sulfate Sulfate, which is specifically heavier, e.g. B. magnesium sulfate is added, so the separation takes place the tar even more easily.
Statt der Abfallsäure bereits fertige Sulfate zuzusetzen, kann man auch Chlornatrium oder Chlorkalium anwenden und sich das Bisulfat aus der Abfallsäure selbst bilden lassen, wobei die entstehende Salzsäure in bekannter Weise durch geeignete Vorrichtungen zu gewinnen ist.Instead of adding ready-made sulfates to the waste acid, you can also use sodium chloride or Apply potassium chloride and let the bisulfate form from the waste acid itself, whereby the hydrochloric acid formed can be obtained in a known manner using suitable devices.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE43900C true DE43900C (en) |
Family
ID=319183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT43900D Active DE43900C (en) | Separation of the tarry sub. stamping out of the waste - sulfuric acid of the petroleum, paraffin and tar industry |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE43900C (en) |
-
0
- DE DENDAT43900D patent/DE43900C/en active Active
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