DE4324823A1 - Liq. fertiliser contg. molasses vinasse and ammonium salts - provides controlled amts. of NPK nutrients and improves soil structure, esp. when used as spray - Google Patents
Liq. fertiliser contg. molasses vinasse and ammonium salts - provides controlled amts. of NPK nutrients and improves soil structure, esp. when used as sprayInfo
- Publication number
- DE4324823A1 DE4324823A1 DE4324823A DE4324823A DE4324823A1 DE 4324823 A1 DE4324823 A1 DE 4324823A1 DE 4324823 A DE4324823 A DE 4324823A DE 4324823 A DE4324823 A DE 4324823A DE 4324823 A1 DE4324823 A1 DE 4324823A1
- Authority
- DE
- Germany
- Prior art keywords
- ammonium
- molasses
- ammonium salts
- fertiliser
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 24
- 235000013379 molasses Nutrition 0.000 title claims abstract description 22
- 150000003863 ammonium salts Chemical class 0.000 title claims abstract description 15
- 239000002689 soil Substances 0.000 title abstract description 13
- 235000015097 nutrients Nutrition 0.000 title abstract description 8
- 239000007921 spray Substances 0.000 title abstract description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 11
- 239000011707 mineral Substances 0.000 claims abstract description 11
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 5
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims abstract description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004254 Ammonium phosphate Substances 0.000 claims abstract description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims abstract description 3
- 235000019289 ammonium phosphates Nutrition 0.000 claims abstract description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical class OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 6
- 239000011574 phosphorus Substances 0.000 abstract description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 4
- 239000011591 potassium Substances 0.000 abstract description 4
- 229910052700 potassium Inorganic materials 0.000 abstract description 4
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- WTVRBGMDXKUPNQ-UHFFFAOYSA-O [NH4+].[NH4+].[O-][N+]([O-])=O.OP(O)([O-])=O Chemical compound [NH4+].[NH4+].[O-][N+]([O-])=O.OP(O)([O-])=O WTVRBGMDXKUPNQ-UHFFFAOYSA-O 0.000 abstract 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 abstract 1
- 239000001166 ammonium sulphate Substances 0.000 abstract 1
- 235000019837 monoammonium phosphate Nutrition 0.000 abstract 1
- 239000011368 organic material Substances 0.000 abstract 1
- 125000001477 organic nitrogen group Chemical group 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 235000015096 spirit Nutrition 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 230000004720 fertilization Effects 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- -1 phosphorus oxide Potassium Chemical compound 0.000 description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 2
- 229910001950 potassium oxide Inorganic materials 0.000 description 2
- 238000004856 soil analysis Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000282376 Panthera tigris Species 0.000 description 1
- 235000021536 Sugar beet Nutrition 0.000 description 1
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 1
- DHKHZGZAXCWQTA-UHFFFAOYSA-N [N].[K] Chemical compound [N].[K] DHKHZGZAXCWQTA-UHFFFAOYSA-N 0.000 description 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- WZLMXYBCAZZIRQ-UHFFFAOYSA-N [N].[P].[K] Chemical compound [N].[P].[K] WZLMXYBCAZZIRQ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229960002737 fructose Drugs 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 235000021049 nutrient content Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F5/00—Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
- C05F5/006—Waste from chemical processing of material, e.g. diestillation, roasting, cooking
- C05F5/008—Waste from biochemical processing of material, e.g. fermentation, breweries
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/27—Dispersions, e.g. suspensions or emulsions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Environmental & Geological Engineering (AREA)
- Dispersion Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
Description
Die Erfindung betrifft die Zusammensetzung eines organisch- mineralischen Düngemittels auf der Grundlage von Melasseschlem pen, aus denen nach Hinzufügung einer Phosphat- und einer Stickstoffkomponente ein kombiniertes Düngemittel mit vorgege benem Verhältnis der Hauptelemente Stickstoff - Phosphor - Ka lium entsteht. Außerdem wird das Verfahren zur Herstellung dieses Düngemittels gelöst.The invention relates to the composition of an organic mineral fertilizer based on molasses slurry pen, from which after the addition of a phosphate and a Nitrogen component a combined fertilizer with given ratio of the main elements nitrogen - phosphorus - Ka lium arises. It also uses the manufacturing process of this fertilizer.
Eingedickte Melasseschlempen als Industrieabfall in Brennereien bei der Herstellung von Spiritus aus Melasse werden entweder verbrannt, oder für die Herstellung von Eiweißkonzentraten verwendet. - Bekannt ist ebenfalls deren Verarbeitung und Ver wendung in der Futtermittelindustrie bei der Herstellung von granulierten Futtermitteln in Form der sog. Palleten.Thickened molasses wastes as industrial waste in distilleries in the manufacture of spirit from molasses either burned, or for the production of protein concentrates used. - Their processing and Ver is also known application in the feed industry in the production of granulated feed in the form of so-called pallets.
Gemäß US PAT 4,604.125 werden eingedickte Melasseschlempen zur Herstellung eines festen Mineraldüngemittels durch Aussalzen mit Phosphorsäure oder mit Zitronensäure unter Hinzugabe flüch tiger Substrate, wie z. B. Äthanol, verwendet. Die Melasse schlempen werden erst zusammen mit den Säuren im Verlaufe von 0,5 bis 2 Stunden erwärmt, danach wird Äthanol hinzuge fügt, und das Gemisch wird einer Vakuumkristallisierung unter zogen. Das Ergebnis ist ein kristallines Düngemittel, das an schließend noch Durchwasch- und Reinigungsvorgängen unterzo gen wird. Ein Nachteil dieses Verarbeitungsverfahrens ist, daß dabei vorwiegend Mineraldüngemittel gewonnen werden, wobei deren Herstellung einen großen Aufwand an Energie erfordert und technologisch anspruchsvoll, folglich auch ökonomisch unvorteilhaft ist. Außerdem verbleiben bei der Herstellung Residua organischen Charakters, die anschließend entsorgt werden müssen.According to US PAT 4,604,125, thickened molasses loops are used Production of a solid mineral fertilizer by salting out with phosphoric acid or with citric acid with the addition tiger substrates, such as. B. ethanol used. The molasses will only drank together with the acids in the course warmed from 0.5 to 2 hours, after which ethanol is added adds, and the mixture is subjected to vacuum crystallization pulled. The result is a crystalline fertilizer that adheres to finally, washing and cleaning processes will. A disadvantage of this processing method is that mainly mineral fertilizers are obtained, whereby the production of which requires a great deal of energy and technologically sophisticated, consequently also economically is disadvantageous. In addition, remain in the manufacture Residua of organic character, which subsequently disposed of Need to become.
Die Erfindung gemäß DE OS 32 11 330 löst die Nutzung einiger Arten von Melasseschlempen, der sog. Vinassen, als Substrate, die zum Abbau organischer Stoffe dienen. Mit Hilfe dieser Lösung wird eine Einschränkung des Verhältnisses der Elemente Kohlenstoff - Stickstoff im Boden erreicht und gleichzeitig eine Ergänzung des Nährstoffbestandes aufgrund empirischer Ver suche, namenhaft der Düngemittel auf der Grundlage der Elemen te Stickstoff - Kalium, vorgenommen. Ein Nachteil dieses Ver fahrens ist der verhältnismäßig große Gehalt an Kalium und der geringe Phosphorbestand im Düngemittel, was zu einer bedeu tenden Erhöhung des Kaliumstandes im Boden führen kann, was unerwünscht ist. Andererseits ist der Phosphorgehalt bei einer Reihe von Beispielen der Bodenzusammensetzung und der Pflan zendüngung unzulänglich.The invention according to DE OS 32 11 330 solves the use of some Types of molasses whiskers, so-called vinasses, as substrates, which serve to break down organic substances. With the help of this Solution becomes a restriction of the ratio of the elements Carbon - nitrogen reached in the soil and at the same time a supplement to the nutrient inventory based on empirical ver search by name of the fertilizer based on the elements te nitrogen - potassium. A disadvantage of this ver driving is the relatively large content of potassium and the low phosphorus level in the fertilizer, which means a increasing the level of potassium in the soil can lead to what is undesirable. On the other hand, the phosphorus content is one Set of examples of soil composition and the plant inadequate fertilization.
Die aufgezählten Nachteile beseitigt in einem beträchtlichen Maße die Erfindung, welche ein flüssiges organisch-minerali sches Düngemittel auf der Grundlage von Melasseschlempen dar stellt und dessen Wesen darin besteht, daß dieses aus einem flüssigen Gemisch von eingedickten Melasseschlempen und Ammo niumsalzen gebildet wird, welche 40 bis 80 Massenprozent Me lasseschlempen mit einer Dichte von 1,2 bis 1,45 g/ml und 20 bis 60 Massenprozent Ammoniumsalze der Phosphorsäure oder Ammoniumnitrat oder Ammoniumsulfat enthalten.The disadvantages listed are eliminated to a considerable extent Dimensions the invention, which is a liquid organic mineral is a fertilizer based on molasses and whose essence is that this consists of a liquid mixture of thickened molasses and ammo niumsalzen is formed, which 40 to 80 mass percent Me lassing with a density of 1.2 to 1.45 g / ml and 20 to 60 mass percent ammonium salts of phosphoric acid or Contain ammonium nitrate or ammonium sulfate.
Es ist von Vorteil, wenn als Ammoniumsalze entweder einzeln oder als Gemisch Ammonium-Monohydrophosphat und/oder Ammonium- Dihydrophosphat und/oder Ammoniumphosphat verwendet wird. It is advantageous if either individually as ammonium salts or as a mixture of ammonium monohydrophosphate and / or ammonium Dihydrophosphate and / or ammonium phosphate is used.
Ferner ist Gegenstand der Erfindung das Verfahren zur Herstellung des organisch-mineralischen Düngemittels, bei dem die eingedick ten Melasseschlempen mit einer Dichte von 1,2 bis 1,45 g/ml auf eine Temperatur von 40° bis 70°C vorgewärmt werden, bei gleichzeitiger Zubereitung einer konzentrierten Lösung eines Ammoniumsalzes oder eines Gemisches von Ammoniumsalzen der Phosphorsäure oder des Ammoniumnitrates oder des Ammoniumsul fates durch Erwärmung auf eine Temperatur von 40° bis 80°C. Danach wird anhand von im voraus vorgenommenen Bodenanalysen zu der Lösung der vorgewärmten Melasseschlempen unter ständi gem Rühren oder Kräuseln eine tabellenmäßig festgelegte Menge der konzentrierten Lösung der Ammoniumsalze bis zur vollstän digen Homogenisierung des Gemisches hinzugefügt.The invention also relates to the method for the production of the organic-mineral fertilizer, in which the thickened molasses with a density of 1.2 to 1.45 g / ml are preheated to a temperature of 40 ° to 70 ° C, at simultaneous preparation of a concentrated solution of a Ammonium salt or a mixture of ammonium salts Phosphoric acid or ammonium nitrate or ammonium sul fates by heating to a temperature of 40 ° to 80 ° C. Then, based on soil analyzes carried out in advance to the solution of the preheated molasses loaves under constant a quantity specified in the table according to stirring or curling the concentrated solution of the ammonium salts to the full added homogenization of the mixture.
Das organisch-mineralische Düngemittel gemäß der Erfindung enthält die Elemente Stickstoff - Phosphor - Kalium in einem ausgewogenen Verhältnis, das je nach Ergebnis der Bodenanalyse geändert wer den kann. Das Düngemittel enthält Stickstoff sowohl in anorga nischer als auch in organischer Form, was die Ernährung der Pflanze während deren gesamten Wachstumszeit ermöglicht. Phos phor ist in Form von im Wasser sehr gut löslichen Verbindungen enthalten, was ihn auch für Kulturpflanzen zugänglich macht. Insgesamt ist das Düngemittel sehr leicht anwendbar als Sprüh mittel in Form von Nebelsprühen, was eine Gleichmäßigkeit der Düngung der gesamten Bodenfläche garantiert. Das Düngemittel ist ökologisch völlig bedenklos und bereichert den Boden neben der direkten Einbringung von Nährmitteln um die organische Komponente, unterstützt die Abbauprozesse der organischen Masse und verbessert gleichzeitig die mechanische Struktur des Bodens dadurch, daß dieser durch die Freisetzung von Gasen während des Abbaues der organischen Masse aufgelockert wird.Contains the organic mineral fertilizer according to the invention the elements nitrogen - phosphorus - potassium in a balanced Ratio that changes depending on the result of the soil analysis that can. The fertilizer contains nitrogen in both anorga nischer as well as in organic form, what the nutrition of the Allows plant to grow throughout its growing season. Phos phor is in the form of water-soluble compounds contain, which also makes it accessible to crops. Overall, the fertilizer is very easy to use as a spray medium in the form of fog spray, which is a uniformity of Fertilization of the entire floor area guaranteed. The fertilizer is ecologically completely safe and enriches the soil alongside the direct introduction of nutrients around the organic Component, supports the degradation processes of the organic Mass while improving the mechanical structure of the Soil by the fact that it releases gases is loosened during the breakdown of the organic mass.
Für einen Boden mit mittelmäßigem Nährstoffbestand, Hauptfrucht
Wintergerste, wurde nach vorheriger Bodenanalyse ein Düngemit
tel aus 1,5 Tonnen eingedickten Melassenschlempen mit einer
Dichte von 1,32 g/ml, die auf 60°C erwärmt worden sind, zube
reitet. Gleichzeitig wurde ein Gemisch, bestehend aus 1 t kon
zentrierter Lösung von Ammoniumsalzen der Phosphorsäure, na
mentlich aus Ammonium-Monohydrophosphat und Ammonium-Dihydro
phosphat, des sog. Amophos, was umgerechnet auf Trockenmasse
0,1 t Salze beträgt, auf eine Temperatur von 70°C erwärmt.
Anschließend wurden die vorbereiteten Komponenten durch Ver
mischen innerhalb von 10 min. homogenisiert, wodurch eine
Dispersion entstand, die zum sofortigen Transport und Zer
sprühen zum Zwecke der Düngung bereitstand. Die gesamte Menge
wurde über eine Fläche von 1 ha unter einem Druck im Spritzge
rät von 0,7 bis 1,0 MPa versprüht. Innerhalb von 2 bis 3 Tagen
wurde die Stabilität dieser Dispersion empirisch ermittelt.
Durch die vorgenommene Laboranalyse wurde folgender Gehalt
an Grundnährstoffen festgestellt:
Stickstoff - 72,1 kg
Phosphor - 28,8 kg in Form von Phosphoroxid
Kalium - 120,6 kg in Form von KaliumoxidFor a soil with mediocre nutrient stock, main fruit winter barley, a fertilizer was prepared from 1.5 tonnes of thickened molasses with a density of 1.32 g / ml, which had been heated to 60 ° C, according to previous soil analysis. At the same time, a mixture consisting of 1 t concentrated solution of ammonium salts of phosphoric acid, namely ammonium monohydrophosphate and ammonium dihydrophosphate, the so-called Amophos, which is equivalent to dry matter 0.1 t salts, was brought to a temperature of 70 ° C warmed. The prepared components were then mixed by mixing within 10 min. homogenized, resulting in a dispersion that was ready for immediate transport and spraying for fertilization. The entire amount was sprayed over an area of 1 ha under a pressure in the sprayer from 0.7 to 1.0 MPa. The stability of this dispersion was determined empirically within 2 to 3 days. The following basic nutrient content was determined by the laboratory analysis:
Nitrogen - 72.1 kg
Phosphorus - 28.8 kg in the form of phosphorus oxide
Potassium - 120.6 kg in the form of potassium oxide
Für einen Boden mit reichhaltiger Versorgung mit Nährstoffen,
Hauptfrucht Zuckerrübe, wurde ein Düngemittel aus 2,5 t einge
dickten Melasseschlempen der gleichen Dichte, wie in Beispiel
1 , durch Vermischen mit 2 t konzentrierter Amophoslösung zu
bereitet. Unter Verwendung der gleichen Herstellungs- und Ver
sprühtechnologie wurde in 1 ha Boden infolge der Düngung fol
gende Menge an Grundnährstoffen eingebracht:
Stickstoff - 124,2 kg
Phosphor - 54,5 kg in Form von Phosphoroxid
Kalium - 198,3 kg in Form von Kaliumoxid
For a soil with a rich supply of nutrients, main fruit sugar beet, a fertilizer from 2.5 t of thickened molasses loaves of the same density as in Example 1 was prepared by mixing with 2 t of concentrated amophos solution. Using the same production and spraying technology, the following amount of basic nutrients was introduced into 1 ha of soil as a result of fertilization:
Nitrogen - 124.2 kg
Phosphorus - 54.5 kg in the form of phosphorus oxide
Potassium - 198.3 kg in the form of potassium oxide
Das organisch-mineralische Düngemittel gemäß der Erfindung ist für die flächenmäßige sowie für die lokale Anwendung der einge dickten Melasseschlempen als Abfall der Alkoholherstellung di rekt auf die Grundstücke aufgrund des im voraus bestimmten Be darfes an Bodennährstoffen geeignet. Eventuell ist es auch als Abbaumittel organischer Stoffe auf Ablageplätzen, wie z. B. Strohschober, Komposthaufen, Holz- und Zellstoffabfall, even tuell auch organischen Kommunalabfall geeignet.The organic mineral fertilizer according to the invention is for the area as well as for the local application of the thickened molasses as a waste of alcohol production di rectifies the land on the basis of the predetermined amount may be suitable for soil nutrients. It may also be as Degrading agents of organic substances on storage spaces, such as B. Straw stack, compost heap, wood and pulp waste, even Organic municipal waste is also suitable.
Claims (3)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS922571A CZ278603B6 (en) | 1992-08-21 | 1992-08-21 | Liquid organo-mineral fertilizer based on molasses residues and process for producing thereof |
| FR9314865A FR2713631B1 (en) | 1992-08-21 | 1993-12-10 | Liquid organic-mineral fertilizer based on molasses vinasses and process for preparing it. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE4324823A1 true DE4324823A1 (en) | 1994-02-24 |
| DE4324823C2 DE4324823C2 (en) | 1995-11-16 |
Family
ID=25745655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE4324823A Expired - Fee Related DE4324823C2 (en) | 1992-08-21 | 1993-07-23 | Liquid organic-mineral fertilizer based on molasses slurry, process for its production and its use |
Country Status (3)
| Country | Link |
|---|---|
| CZ (1) | CZ278603B6 (en) |
| DE (1) | DE4324823C2 (en) |
| FR (1) | FR2713631B1 (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2713631A1 (en) * | 1992-08-21 | 1995-06-16 | Hofschneider Miroslav | Liq. fertiliser contg. molasses vinasse and ammonium salts |
| WO1997026228A1 (en) * | 1996-01-18 | 1997-07-24 | Miroslav Hofschneider | Fertilizer |
| US6352569B1 (en) | 1999-01-22 | 2002-03-05 | Lear, A.S. | Liquid fertilizer based on bio-process organic residues |
| WO2002102740A1 (en) | 2001-06-18 | 2002-12-27 | Zdenek Beran | Liquid biotechnological fertiliser |
| WO2004020367A1 (en) * | 2002-08-27 | 2004-03-11 | Csr Distilleries Operations Pty Limited | Fertiliser and feed supplement composition |
| WO2008009083A1 (en) * | 2006-07-21 | 2008-01-24 | Antonio Carlos De Gissi Junior | Process to obtain polymeric-nature chemical compounds applied to fixation in fertilizers and related products |
| WO2008000214A3 (en) * | 2006-06-26 | 2008-09-12 | Tilco Biochemie Gmbh | Preparation for improving the constitution of plants |
| US9604887B2 (en) | 2015-04-20 | 2017-03-28 | True Organic Products, Inc. | Betaine based organic fertilizer |
| US9815744B2 (en) | 2015-09-24 | 2017-11-14 | True Organic Products, Inc. | pH adjusted betaine based organic fertilizer |
| US9850178B2 (en) | 2015-08-06 | 2017-12-26 | True Organic Products, Inc. | Betaine based organic fertilizer |
| US10301226B2 (en) | 2016-04-13 | 2019-05-28 | True Organic Products, Inc. | Ph adjusted organic fertilizer from anaerobic digestate and grain by-products |
| US11155504B1 (en) | 2019-01-10 | 2021-10-26 | True Organic Products, Inc. | Combination fertilizer |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2751958B1 (en) * | 1996-08-02 | 2000-02-04 | Bonsai B | FERTILIZER COMPOSITION FOR BONSAI |
| CZ300046B6 (en) * | 2005-08-24 | 2009-01-14 | PROKOP INVEST, a.s. | Method of comprehensive use of stillage from bioalcohol large-scale production |
| DE102005061117A1 (en) * | 2005-12-19 | 2007-06-21 | Tilco Biochemie Gmbh | Preparation for soil improvement and fertilization |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4604125A (en) * | 1983-06-15 | 1986-08-05 | Eni-Ente Nazionale Idrocarburi | Solid composition of organic fertilizer and of organo-mineral fertilizer |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1000846A (en) * | 1949-11-24 | 1952-02-18 | Fertilizer | |
| FR60788E (en) * | 1950-10-10 | 1955-01-26 | Fertilizer | |
| FR1101768A (en) * | 1954-03-24 | 1955-10-11 | Rech S Et D Applic Ind Et Agri | Process for the treatment of beet vinasses |
| JPH0742187B2 (en) * | 1985-04-15 | 1995-05-10 | 三井東圧化学株式会社 | Liquid fertilizer stabilization method |
| CZ278603B6 (en) * | 1992-08-21 | 1994-03-16 | Hofschneider Miroslav | Liquid organo-mineral fertilizer based on molasses residues and process for producing thereof |
-
1992
- 1992-08-21 CZ CS922571A patent/CZ278603B6/en not_active IP Right Cessation
-
1993
- 1993-07-23 DE DE4324823A patent/DE4324823C2/en not_active Expired - Fee Related
- 1993-12-10 FR FR9314865A patent/FR2713631B1/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4604125A (en) * | 1983-06-15 | 1986-08-05 | Eni-Ente Nazionale Idrocarburi | Solid composition of organic fertilizer and of organo-mineral fertilizer |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2713631A1 (en) * | 1992-08-21 | 1995-06-16 | Hofschneider Miroslav | Liq. fertiliser contg. molasses vinasse and ammonium salts |
| WO1997026228A1 (en) * | 1996-01-18 | 1997-07-24 | Miroslav Hofschneider | Fertilizer |
| US6352569B1 (en) | 1999-01-22 | 2002-03-05 | Lear, A.S. | Liquid fertilizer based on bio-process organic residues |
| WO2002102740A1 (en) | 2001-06-18 | 2002-12-27 | Zdenek Beran | Liquid biotechnological fertiliser |
| WO2004020367A1 (en) * | 2002-08-27 | 2004-03-11 | Csr Distilleries Operations Pty Limited | Fertiliser and feed supplement composition |
| WO2008000214A3 (en) * | 2006-06-26 | 2008-09-12 | Tilco Biochemie Gmbh | Preparation for improving the constitution of plants |
| WO2008009083A1 (en) * | 2006-07-21 | 2008-01-24 | Antonio Carlos De Gissi Junior | Process to obtain polymeric-nature chemical compounds applied to fixation in fertilizers and related products |
| US9604887B2 (en) | 2015-04-20 | 2017-03-28 | True Organic Products, Inc. | Betaine based organic fertilizer |
| US9850178B2 (en) | 2015-08-06 | 2017-12-26 | True Organic Products, Inc. | Betaine based organic fertilizer |
| US9815744B2 (en) | 2015-09-24 | 2017-11-14 | True Organic Products, Inc. | pH adjusted betaine based organic fertilizer |
| US10301226B2 (en) | 2016-04-13 | 2019-05-28 | True Organic Products, Inc. | Ph adjusted organic fertilizer from anaerobic digestate and grain by-products |
| US11155504B1 (en) | 2019-01-10 | 2021-10-26 | True Organic Products, Inc. | Combination fertilizer |
Also Published As
| Publication number | Publication date |
|---|---|
| DE4324823C2 (en) | 1995-11-16 |
| FR2713631A1 (en) | 1995-06-16 |
| CZ257192A3 (en) | 1994-03-16 |
| FR2713631B1 (en) | 1998-01-02 |
| CZ278603B6 (en) | 1994-03-16 |
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