DE430398C - Process for impregnating vegetable, animal and mineral fibers, yarns and fabrics - Google Patents
Process for impregnating vegetable, animal and mineral fibers, yarns and fabricsInfo
- Publication number
- DE430398C DE430398C DESCH72909D DESC072909D DE430398C DE 430398 C DE430398 C DE 430398C DE SCH72909 D DESCH72909 D DE SCH72909D DE SC072909 D DESC072909 D DE SC072909D DE 430398 C DE430398 C DE 430398C
- Authority
- DE
- Germany
- Prior art keywords
- fabrics
- animal
- yarns
- mineral fibers
- leather
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004744 fabric Substances 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 3
- 235000013311 vegetables Nutrition 0.000 title claims description 3
- 239000002557 mineral fiber Substances 0.000 title description 2
- 239000010985 leather Substances 0.000 claims description 11
- 238000005470 impregnation Methods 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 7
- 239000012188 paraffin wax Substances 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 5
- 229940037003 alum Drugs 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 3
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims description 3
- 239000012670 alkaline solution Substances 0.000 claims description 2
- 239000012182 japan wax Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 4
- 239000004927 clay Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000008149 soap solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 2
- UJRBOEBOIXOEQK-UHFFFAOYSA-N oxo(oxochromiooxy)chromium hydrate Chemical compound O.O=[Cr]O[Cr]=O UJRBOEBOIXOEQK-UHFFFAOYSA-N 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
- D06M15/155—Treatment in the presence of salts derived from amphoteric metal hydroxides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Verfahren zum Imprägnieren von pflanzlichen, tierischen und mineralischen Faserstoffen, Garnen und Geweben. Es ist bekannt, Gewebe, wie z. B. Segeltuch, Windjacken, Pferdedecken, Rucksäcke usw., dadurch wasserdicht zu machen, daß tnan sie zunächst durch Bäder von essigsaurer oder schwefelsaurer Tonerde zieht und danach durch 6- bis 8prozentige Seifenlösungen, in denen Paraffin, Japanwachs, Stearin, Harzseife und ähnliche Stoffe einemulgiert sind, und daß man, wenn die Ware besonders griffig ausfallen soll, auch Tischlerleimlösungen der Seifenlösung beigibt. Es ist auch bekannt, daß man Gewebe mit alkalischen Auflösungen von lohgarem Leder wasserdicht imprägnieren kann, dadurch, daß man die mit solchen Lederlösungen imprägnierten Stoffe durch Füllbäder von z. B. Tonerdesalzen schickt, die das lohgare Leder auf der Faser als unlöslichen, stark wasserabstoßenden Niederschlag ausfüllen.Process for impregnating vegetable, animal and mineral Fibers, yarns and fabrics. It is known to use tissues such as. B. canvas, windbreakers, Horse rugs, rucksacks, etc., to be made waterproof by tnan them first through baths of acetic or sulfuric clay and then through 6- up to 8 percent soap solutions in which paraffin, Japan wax, stearin, resin soap and similar substances are emulsified, and that if the goods are particularly easy to grip should fail, joiner's glue solutions are also added to the soap solution. It is also known that fabrics can be waterproofed with alkaline solutions of brown leather can impregnate, by the fact that the impregnated with such leather solutions Substances by filling baths of z. B. Sends alumina salts, which the brown leather on fill the fiber as an insoluble, highly water-repellent precipitate.
Da diese Lederimprägnierungen die natürliche lichtbraune Farbe des Leders haben, sind sie jedoch nicht für alle Zwecke geeignet.Since these leather impregnations have the natural light brown color of the However, they are not for all purposes.
Löst man Chrom- oder Alaunleder in wässerigen Alkalien und filtriert die ausgeschiedenen Niederschläge von Chromoxydhydrat bzw. Tonerdehydrat ab, so erhält man hellfarbige Lösungen. Diese werden jedoch nicht ohne weiteres von den Tonerdesalzen gefüllt und geben daher keine haltbaren Imprägnierungen.Dissolve chrome or alum leather in aqueous alkalis and filter the precipitated precipitates of chromium oxide hydrate or alumina hydrate from, see above light-colored solutions are obtained. However, these are not readily accepted by the Alumina salts filled and therefore do not give a durable impregnation.
Es hat sich nun gezeigt, daß diese hellfarbigen Lösungen von Chrom- und Alaunleder sofort zu haltbaren, hellfarbigen Imprägnierungen führen, wenn man die Lösungen mit Harzleim verschneidet und dann in dem heißen Gemisch Paraffin, Stearin u. dgl. Stoffe emulgiert, die sich nach dem Erkalten nicht ausscheiden, sondern eine weißgelbe, salbenartige Masse bilden, die sich in der Hitze wieder glatt auflöst. Durch Vermittlung des Zuschnittes von etwas Harzseife zu den hellfarbigen Auflösungen von Chrom- und Alaunleder gelingt deren Emulsion mit Paraffin und die Ausscheidung und gleichzeitige Niederschlagung durch Füllsalze, z. B. essigsaure oder schwefelsaure Tonerde, so daß auf diese Weise weiße oder hellfarbige, haltbare Imprägnierungen erhalten werden können.It has now been shown that these light-colored solutions of chromium and alum leather immediately lead to durable, light-colored impregnations if you the solutions mixed with resin glue and then paraffin in the hot mixture, Stearin and similar substances emulsified that do not separate after cooling, but form a white-yellow, ointment-like mass that reappears in the heat dissolves smoothly. By arranging the cutting of some resin soap to the light colored ones Dissolving chrome and alum leather succeed in their emulsion with paraffin and the Excretion and simultaneous suppression by filling salts, e.g. B. acetic acid or sulfuric clay, so that in this way white or light-colored, durable Impregnations can be obtained.
Gegenüber den Seifenlösungen, welche normalerweise zur Imprägnierung verwendet «-erden, sind die hellfarbigen Auflösungen von Chromleder außerordentlich billig und bieten einen wirtschaftlichen Fortschritt. Beispiel. Man löst Chromlederabfälle unter Druck und Hitze in wässerigen Alkalien, filtriert von dem grüngrauen Niederschlage von Chromoxydhydrat ab, dampft die Lösung auf 5o Prozent Trockensubstanz ein, vermischt 8o Prozent Gewichtsteile - dieser heißen, 5oprozentigen Lösung mit 2o Prozent Gewichtsteilen 5oprozentigem Harzleim und emulgiert in dem heißen Gemisch io Gewichtsteile Paraffin.Compared to the soap solutions, which are normally used for impregnation used «-erden, the light-colored resolutions of chrome leather are extraordinary cheap and offer economic progress. Example. Chrome leather waste is removed under pressure and heat in aqueous alkalis, filtered from the green-gray precipitate of chromium oxide hydrate, the solution evaporates to 5o percent dry matter, mixed 8o percent parts by weight - this hot, 5 percent solution with 2o percent parts by weight 5 percent Resin glue and emulsified in the hot mixture 10 parts by weight of paraffin.
Diese Mischung verwendet man an Stelle der Seifenbäder zum Imprägnieren.This mixture is used instead of soap baths for impregnation.
Zur Ausführung der Imprägnierung zieht man die Gewebe und Textilien zuerst durch ein Bad von 6- bis ioprozentiger essigsaurer Tonerde und nach dem Auftrocknen dieser Beize durch die Chromleder-Harzleim-Paraffin-Emulsion, wodurch auf der Faser unlösliche, wasserabstoßende Niederschläge entstehen.To carry out the impregnation, the fabrics and textiles are pulled first by a bath of 6 to 10 percent acetic acid clay and after drying this stain through the chrome leather resin glue paraffin emulsion, which causes on the fiber insoluble, water-repellent precipitates arise.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESCH72909D DE430398C (en) | 1924-05-24 | 1924-05-24 | Process for impregnating vegetable, animal and mineral fibers, yarns and fabrics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESCH72909D DE430398C (en) | 1924-05-24 | 1924-05-24 | Process for impregnating vegetable, animal and mineral fibers, yarns and fabrics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE430398C true DE430398C (en) | 1926-06-15 |
Family
ID=7440561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DESCH72909D Expired DE430398C (en) | 1924-05-24 | 1924-05-24 | Process for impregnating vegetable, animal and mineral fibers, yarns and fabrics |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE430398C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE896789C (en) * | 1934-11-24 | 1953-11-16 | Boehme Fettchemie G M B H | Process for the finishing of textile goods made of cellulose hydrate fibers |
-
1924
- 1924-05-24 DE DESCH72909D patent/DE430398C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE896789C (en) * | 1934-11-24 | 1953-11-16 | Boehme Fettchemie G M B H | Process for the finishing of textile goods made of cellulose hydrate fibers |
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