DE4235788A1 - Printing inks containing microcapsules for book or offset printing - Google Patents

Printing inks containing microcapsules for book or offset printing

Info

Publication number
DE4235788A1
DE4235788A1 DE4235788A DE4235788A DE4235788A1 DE 4235788 A1 DE4235788 A1 DE 4235788A1 DE 4235788 A DE4235788 A DE 4235788A DE 4235788 A DE4235788 A DE 4235788A DE 4235788 A1 DE4235788 A1 DE 4235788A1
Authority
DE
Germany
Prior art keywords
printing
printing inks
book
weight
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE4235788A
Other languages
German (de)
Inventor
Amparo Molina Salazar
I Carlos Molina
Egea Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE4235788A priority Critical patent/DE4235788A1/en
Priority to CZ95921A priority patent/CZ92195A3/en
Priority to PL93308488A priority patent/PL308488A1/en
Priority to BR9307286A priority patent/BR9307286A/en
Priority to EP93922951A priority patent/EP0665788A1/en
Priority to PCT/EP1993/002831 priority patent/WO1994009991A1/en
Priority to AU51776/93A priority patent/AU5177693A/en
Priority to JP6510621A priority patent/JPH08502699A/en
Priority to KR1019950701537A priority patent/KR950704123A/en
Priority to IL107281A priority patent/IL107281A0/en
Priority to CA002145070A priority patent/CA2145070A1/en
Priority to CO93415236A priority patent/CO4290371A1/en
Priority to CN93119531A priority patent/CN1086236A/en
Publication of DE4235788A1 publication Critical patent/DE4235788A1/en
Priority to FI951892A priority patent/FI951892A/en
Priority to NO951522A priority patent/NO951522D0/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
    • B41M5/165—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components characterised by the use of microcapsules; Special solvents for incorporating the ingredients
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
    • B41M5/1246—Application of the layer, e.g. by printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
    • B41M5/165—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components characterised by the use of microcapsules; Special solvents for incorporating the ingredients
    • B41M5/1655—Solvents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Color Printing (AREA)

Abstract

The invention concerns inks for letterpress or offset printing which contain microcapsules containing the colour formers, alkali-metal salts of colophonium as binders and glycols or glycol ethers as solvents.

Description

Die Erfindung betrifft Mikrokapseln enthaltende Druckfarben für den Buch- oder Offsetdruck, die Mikrokapseln, Alkalisalze von Ko­ lophonium als Bindemittel und Glykole oder Glykolether als Lö­ sungsmittel enthalten.The invention relates to printing inks containing microcapsules for Book or offset printing, microcapsules, alkali salts from Ko Iophonium as binder and glycols or glycol ether as Lö contain agents.

Als Mikrokapseln kommen alle gebräuchlichen Produkte in Betracht, bevorzugt werden Kunststoffkapseln in trockener Form verwendet. Im einzelnen seien beispielsweise Kapseln aus Polyamiden oder Polyurethanen und insbesondere solche aus Melamin-Formaldehyd- Harzen oder Acrylsäurederivaten genannt. Die Herstellung dieser Kapseltypen ist insbesondere aus der Patentliteratur bekannt. In der Regel enthalten die Kapseln Farbbildnerlösungen, die beim Zerstören der Kapseln mit den Nehmerseiten des Durchschreibesat­ zes Farbstoffe bilden. Nehmer und Durchschreibesätze sowie die Mikrokapseln sind Stand der Technik.All common products can be considered as microcapsules, plastic capsules in dry form are preferably used. In particular, capsules made of polyamides or Polyurethanes and especially those made from melamine-formaldehyde Resins or acrylic acid derivatives called. The making of this Capsule types are known in particular from the patent literature. In As a rule, the capsules contain color former solutions Destroy the capsules with the copy side of the carbonate satin zes form dyes. Takers and carbonless rates as well as the Microcapsules are state of the art.

Erfindungsgemäß enthaltene Bindemittel sind Kolophoniumderivate, im wesentlichen Alkalisalze der Abietinsäure, wobei als Alkali Kalium, Lithium und insbesondere Natrium zu nennen sind. Diese Bindemittel sind in den als Lösungsmittel verwendeten Glykolen und Glykolethern löslich. Einzelne Lösungsmittel sind beispiels­ weise Ethylenglykol, 1,2-Propylenglykol, Glycerin, Diethylengly­ kol, Dipropylenglykol, Polyglykole vom Molgewicht 200 bis 600, Ethylenglykolmono-methyl-, -ethyl- oder -butylether oder Mono­ ether von Polyglykolen. Gemische dieser Lösungsmittel sind eben­ falls geeignet. Bevorzugt sind niedrigviskose Lösungsmittel, wie z. B. Glycerin oder Propylenglykol.Binders contained according to the invention are rosin derivatives, essentially alkali salts of abietic acid, being the alkali Potassium, lithium and especially sodium are mentioned. This Binders are in the glycols used as solvents and glycol ethers soluble. Individual solvents are exemplary as ethylene glycol, 1,2-propylene glycol, glycerin, diethylene glycol kol, dipropylene glycol, polyglycols with a molecular weight of 200 to 600, Ethylene glycol monomethyl, ethyl or butyl ether or mono ether of polyglycols. Mixtures of these solvents are flat if appropriate. Low-viscosity solvents such as e.g. B. glycerol or propylene glycol.

Quantitativ sind die erfindungsgemäßen Druckfarben z. B. wie folgt zusammengesetzt:
10 bis 40 Gew.-% (vorzugsweise 15-30%) Bindemittel
20 bis 60 Gew.-% (vorzugsweise 25-50%) Lösungsmittel und
20 bis 50 Gew.-% (vorzugsweise 25-40%) Mikrokapseln.Quantitatively, the printing inks according to the invention are e.g. B. composed as follows:
10 to 40% by weight (preferably 15-30%) of binder
20 to 60 wt .-% (preferably 25-50%) solvent and
20 to 50% by weight (preferably 25-40%) microcapsules.

Die Mikrokapseln werden, wie bereits angegeben, vor zugsweise in trockener Form verwendet, da man so leichter die zur späteren Er­ zeugung des Schriftbildes nötige Konzentration erreicht. Die er­ findungsgemäßen Druckfarben erhält man durch Mischen der Kompo­ nenten, zweckmäßigerweise löst man zunächst das Bindemittel im Lösungsmittel und verrührt dann die Mikrokapseln in der Lösung.As already stated, the microcapsules are preferably in dry form because it is easier to use for later er generation of the typeface necessary concentration reached. Which he Inks according to the invention are obtained by mixing the compo  nenten, expediently first dissolve the binder in Solvent and then stir the microcapsules in the solution.

Zur Erzielung einer hohen Reibechtheit der Drucke ist es in der Regel zweckmäßig, der Druckfarbe noch einen Abstandshalter in Mengen bis zu 15 Gew.-%, vorzugsweise 5-10%, bezogen auf die Druckfarbe, zuzusetzen.It is in the to achieve a high rub fastness of the prints As a rule, the printing ink has a spacer Amounts up to 15 wt .-%, preferably 5-10%, based on the Printing ink to add.

Solche Abstandshalter sind ebenfalls aus der Patentliteratur be­ kannt, im einzelnen seien beispielsweise Titandioxid, Kunststoff­ kügelchen mit Durchmessern von 20-30 µ, Cellulosefasern oder kali­ brierte Stärke genannt.Such spacers are also from the patent literature knows, in particular, for example, titanium dioxide, plastic beads with diameters of 20-30 µ, cellulose fibers or kali called strength.

Überraschenderweise gelingt es, mit den erfindungsgemäßen Druck­ farben Papiere zu beschichten, mit denen man einwandfreie Durch­ schriften erhält. Insbesondere eignen sich die Druckfarben für den Spotdruck.Surprisingly, it succeeds with the pressure according to the invention to coat colored papers with which one can get through perfectly writings received. The printing inks are particularly suitable for the spot printing.

In den folgenden Beispielen beziehen sich Angaben über Teile und Prozente, sofern nicht anders vermerkt, auf das Gewicht.In the following examples, information about parts and Unless otherwise noted, percentages are by weight.

Beispiel 1example 1

35 Gew.-Teile Mikrokapselpulver (Mikrokapseln hergestellt gemäß den Angaben der EP-B-26 914, enthaltend eine Farbbilder-Schwarzmischung)
5 Gew.-Teile kalibrierte Stärke (z. B. Amyzet® KT, Firma Amylum, Belgien) als Abstandshalter
30 Gew.-Teile Natriumresinat (Kolophoniumsalz) und
30 Gew.-Teile Glycerin
werden in der Art vermischt, daß zunächst das Resinat im Glycerin gelöst wird und dann die Kapseln und der Abstandshalter ein­ gerührt werden. Man erhält eine farblose Druckfarbe, die im indi­ rekten Buchdruck auf die Geberseite eines Formularsatzes in einer Menge von ungefähr 6 g/m2 gedruckt wird. Beim Beschreiben des For­ mularsatzes, der als Nehmer eine Clay-Schicht aufweist, erhält man eine schwarze Durchschrift mit ausreichender Intensität. 35 parts by weight of microcapsule powder (microcapsules produced in accordance with the specifications of EP-B-26 914, containing a color image / black mixture)
5 parts by weight of calibrated starch (e.g. Amyzet® KT, Amylum, Belgium) as a spacer
30 parts by weight of sodium resinate (rosin salt) and
30 parts by weight of glycerin
are mixed in such a way that the resinate is first dissolved in the glycerol and then the capsules and the spacers are stirred in. A colorless printing ink is obtained which is printed in an indirect letterpress on the donor side of a set of forms in an amount of approximately 6 g / m 2 . When describing the form set, which has a clay layer as the receiver, a black copy with sufficient intensity is obtained.

Beispiel 2Example 2

Analog Beispiel 1 bereitet man eine Druckfarbe aus
40 Gew.-Teilen Mikrokapselpulver,
 5 Gew.-Teilen TiO₂ (Rutil) als Abstandshalter,
22 Gew.-Teilen Natriumresinat und
33 Gew.-Teilen 1,2-Propylenglykol.Analogously to example 1, a printing ink is prepared
40 parts by weight of microcapsule powder,
5 parts by weight of TiO₂ (rutile) as a spacer,
22 parts by weight of sodium resinate and
33 parts by weight of 1,2-propylene glycol.

Nach dem Verdrucken gemäß Beispiel 1 und dem Beschreiben erhält man Kopien mit guter Intensität.After printing according to Example 1 and writing one copies with good intensity.

Beispiel 3Example 3

Eine Druckfarbe aus
30 Gew.-Teilen Mikrokapselpulver, enthaltend eine blau schreibende Farbbildnermischung,
 5 Gew.-Teilen Cellulosemehl (Arbozell® B600/30 der Fa. Rettenmaier, Deutschland) als Abstandshalter,
25 Gew.-Teilen Natriumresinat und
40 Gew.-Teilen Glycerin
ergibt ebenfalls Kopien mit guter Intensität.A printing ink
30 parts by weight of microcapsule powder, containing a blue-writing color mixture,
5 parts by weight of cellulose flour (Arbozell® B600 / 30 from Rettenmaier, Germany) as a spacer,
25 parts by weight of sodium resinate and
40 parts by weight of glycerin
also gives copies of good intensity.

Claims (5)

1. Druckfarben für den Buch- oder Offset-Druck, die Mikrokap­ seln, Alkalisalze von Kolophonium als Bindemittel und Glykole oder Glykolether als Lösungsmittel enthalten.1. Printing inks for book or offset printing, the microcap seln, alkali salts of rosin as binders and glycols or glycol ether as a solvent. 2. Druckfarben gemäß Anspruch 1, die zusätzlich einen Abstands­ halter enthalten.2. Printing inks according to claim 1, which additionally a distance holder included. 3. Druckfarben gemäß Anspruch 1, die Mikrokapseln aus Melamin- Formaldehyd-Harzen enthalten.3. Printing inks according to claim 1, the microcapsules made of melamine Contain formaldehyde resins. 4. Druckfarben gemäß Anspruch 3, die mit Mikrokapselpulver her­ gestellt worden sind.4. Printing inks according to claim 3, the microcapsule powder forth have been asked. 5. Druckfarben gemäß Anspruch 1, die als Lösungsmittel Glycerin oder 1,2-Propylenglykol enthalten.5. Printing inks according to claim 1, the solvent as glycerol or contain 1,2-propylene glycol.
DE4235788A 1992-10-23 1992-10-23 Printing inks containing microcapsules for book or offset printing Withdrawn DE4235788A1 (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
DE4235788A DE4235788A1 (en) 1992-10-23 1992-10-23 Printing inks containing microcapsules for book or offset printing
JP6510621A JPH08502699A (en) 1992-10-23 1993-10-14 Printing ink containing microcapsules for letterpress or offset printing
KR1019950701537A KR950704123A (en) 1992-10-23 1993-10-14 MICROCAPSULE-CONTAINING INKS FOR LETTERPRESS OF OFFSET PRINTING
BR9307286A BR9307286A (en) 1992-10-23 1993-10-14 Printing inks for typographic or offset printing and process for the production of pressure sensitive transfer systems
EP93922951A EP0665788A1 (en) 1992-10-23 1993-10-14 Microcapsule-containing inks for letterpress or offset printing
PCT/EP1993/002831 WO1994009991A1 (en) 1992-10-23 1993-10-14 Microcapsule-containing inks for letterpress or offset printing
AU51776/93A AU5177693A (en) 1992-10-23 1993-10-14 Microcapsule-containing inks for letterpress or offset printing
CZ95921A CZ92195A3 (en) 1992-10-23 1993-10-14 Micro-capsule containing printing ink for letterpress printing or offset printing
PL93308488A PL308488A1 (en) 1992-10-23 1993-10-14 Printer's inks containing microcapsules for relief or offset printing and method of making transfer systems
IL107281A IL107281A0 (en) 1992-10-23 1993-10-14 Microcapsule-containing printing-ink and its production
CA002145070A CA2145070A1 (en) 1992-10-23 1993-10-14 Microcapsule-containing printing inks for letterpress or offset printing
CO93415236A CO4290371A1 (en) 1992-10-23 1993-10-22 PRINTING INKS CONTAINING MICROCAPSULES FOR TYPOGRAPHIC IMPRESSION
CN93119531A CN1086236A (en) 1992-10-23 1993-10-22 What be used for letterpress or offset printing contains microcapsule printing ink
FI951892A FI951892A (en) 1992-10-23 1995-04-20 Microcapsules containing ink for book and offset printing
NO951522A NO951522D0 (en) 1992-10-23 1995-04-21 Microcapsules that contain ink for book or offset printing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4235788A DE4235788A1 (en) 1992-10-23 1992-10-23 Printing inks containing microcapsules for book or offset printing

Publications (1)

Publication Number Publication Date
DE4235788A1 true DE4235788A1 (en) 1994-04-28

Family

ID=6471165

Family Applications (1)

Application Number Title Priority Date Filing Date
DE4235788A Withdrawn DE4235788A1 (en) 1992-10-23 1992-10-23 Printing inks containing microcapsules for book or offset printing

Country Status (15)

Country Link
EP (1) EP0665788A1 (en)
JP (1) JPH08502699A (en)
KR (1) KR950704123A (en)
CN (1) CN1086236A (en)
AU (1) AU5177693A (en)
BR (1) BR9307286A (en)
CA (1) CA2145070A1 (en)
CO (1) CO4290371A1 (en)
CZ (1) CZ92195A3 (en)
DE (1) DE4235788A1 (en)
FI (1) FI951892A (en)
IL (1) IL107281A0 (en)
NO (1) NO951522D0 (en)
PL (1) PL308488A1 (en)
WO (1) WO1994009991A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996036672A1 (en) * 1995-05-19 1996-11-21 Videojet Systems International, Inc. Duplicating inks for digital duplicators
US6042641A (en) * 1998-10-16 2000-03-28 The Mead Corporation CB printing ink
WO2019038596A1 (en) * 2017-08-19 2019-02-28 Hescoat GmbH Printing system

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2289069B (en) * 1994-03-31 1997-12-17 Toppan Moore Kk Microcapsule-containing oil-based coating liquid,ink,coated sheet,and method of prepring the same
CN104275923A (en) * 2014-05-06 2015-01-14 上海天美纸制品印务有限公司 Carbon-free paper printing and machining integrated machine

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3008390A1 (en) * 1980-03-05 1981-09-17 Basf Ag, 6700 Ludwigshafen LOW VISCOSIS, MICROCAPSULES AND BINDERS CONTAINING AQUEOUS COATING AND PRINTING INKS
US4601863A (en) * 1984-02-09 1986-07-22 Kanzaki Paper Manufacturing Co., Ltd. Process for producing powder of microcapsules
US4889877A (en) * 1988-01-07 1989-12-26 The Standard Register Company High solids CB printing ink
US4985484A (en) * 1989-02-27 1991-01-15 The Mead Corporation Process for the production of coating compositions containing microcapsules

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996036672A1 (en) * 1995-05-19 1996-11-21 Videojet Systems International, Inc. Duplicating inks for digital duplicators
AU699088B2 (en) * 1995-05-19 1998-11-19 Videojet Systems International, Inc. Duplicating inks for digital duplicators
US6042641A (en) * 1998-10-16 2000-03-28 The Mead Corporation CB printing ink
WO2019038596A1 (en) * 2017-08-19 2019-02-28 Hescoat GmbH Printing system

Also Published As

Publication number Publication date
CA2145070A1 (en) 1994-05-11
IL107281A0 (en) 1994-01-25
CN1086236A (en) 1994-05-04
BR9307286A (en) 1999-06-01
NO951522L (en) 1995-04-21
WO1994009991A1 (en) 1994-05-11
JPH08502699A (en) 1996-03-26
FI951892A0 (en) 1995-04-20
KR950704123A (en) 1995-11-17
PL308488A1 (en) 1995-08-07
AU5177693A (en) 1994-05-24
CZ92195A3 (en) 1995-10-18
CO4290371A1 (en) 1996-04-17
NO951522D0 (en) 1995-04-21
EP0665788A1 (en) 1995-08-09
FI951892A (en) 1995-04-20

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