DE4103292A1 - Aq. hair dye contg. oxidn. dye precursor - consists of mixt. of ethane diol- or propane diol- ester with higher fatty acid and propane 1,2-diol - Google Patents

Aq. hair dye contg. oxidn. dye precursor - consists of mixt. of ethane diol- or propane diol- ester with higher fatty acid and propane 1,2-diol

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Publication number
DE4103292A1
DE4103292A1 DE19914103292 DE4103292A DE4103292A1 DE 4103292 A1 DE4103292 A1 DE 4103292A1 DE 19914103292 DE19914103292 DE 19914103292 DE 4103292 A DE4103292 A DE 4103292A DE 4103292 A1 DE4103292 A1 DE 4103292A1
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Prior art keywords
diol
propane
dye
hair
ethane
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Granted
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DE19914103292
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German (de)
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DE4103292C2 (en
Inventor
Heribert Lorenz
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Kao Germany GmbH
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Goldwell AG
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Emergency Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

An aq. hair dye contg. an oxidn. dye precursor and opt. a coupler, contains a mixt. of an ethane or propane diol mono-/di-ester of a 12-18C fatty acid, and 1,2-propane diol and/or its mono-(m)ethyl ether. The compsn. contains 0.25-2.5 wt% of an ethane or propane diol mono/distearate, pref. 0.5-1.5% of propane, 1,2-diol mono-/di-stearate, and 0.5-5 wt% of propane 1,2-diol. The compsn. may also contain panthenol. ADVANTAGE - The dye compsn. can be diluted with water and the dye is completely absorbed onto the hair. If the compsn. contains an oxidn. dye, it is easily miscible with the phase contg. peroxide.

Description

Die vorliegende Erfindung betrifft ein Haarfärbemittel, ent­ haltend Oxidationsfarbstoffvorprodukte und gegebenenfalls Kuppler, insbesondere ein solches in Form einer wäßrigen Emulsion, mit verbesserten anwendungstechnischen Eigenschaften.The present invention relates to a hair dye, ent holding oxidation dye precursors and optionally Coupler, especially one in the form of an aqueous one Emulsion, with improved performance properties.

Haarfärbemittel, seien es nun permanente - auf Basis von Oxidationsfarbstoffen oder semi-permanente - auf der Basis direktziehender Farbstoffe, erfreuen sich einer weiten Verbreitung. Zur Erreichung einer optimalen Färbeleistung ist es erforderlich, daß die Farbstoffe möglichst vollständig auf das Haar aufziehen. Die Färbemittelzusammensetzungen sollen auch mit Wasser leicht anrührbar bzw. verdünnbar sein, und, im Falle von Oxidationsfärbemittel enthaltenen Zusammensetzungen, gut und einfach mit der Peroxid enthaltenen Phase vermischbar sein.Hair dyes, be it permanent - based on Oxidizing dyes or semi-permanent - based direct dyes, enjoy a wide Distribution. To achieve optimal dyeing performance It is necessary that the dyes as completely as possible raise the hair. The colorant compositions are intended also be easily touched or diluted with water, and, im Case of oxidation-dye-containing compositions, good and easy to mix with the peroxide-containing phase his.

Die vorliegende Erfindung geht von der Aufgabenstellung aus, ein solches Haarfärbemittel zu schaffen.The present invention is based on the task, to create such a hair dye.

Die Lösung dieser Aufgabe besteht darin, einer an sich üblichen und bekannten Haarfärbemittelzusammensetzung auf wäßriger Grundlage, enthaltend Oxidationsfarbstoffvorprodukte und ge­ gebenenfalls Kuppler, ein Gemisch aus einem Ethan- bzw. Propandiolmono/di-C12-C18-fettsäureester, vorzugsweise in einer Menge von 0,25 bis 5,0, besonders bevorzugt 0,25 bis 2,5, insbesondere 0,5 bis 1,0 Gew.-% der Gesamtzusammensetzung des Mittels (d. h., der den Farbstoff enthaltenden Phase), und 1,2-Propandiol und/oder dessen Monomethyl- bzw. Mono­ ethylether, d. h. 3-Methoxy-bzw. 3-Ethoxypropanol(-1), vor­ zugsweise in einer Menge von 0,25 bis 5,0, insbesondere 0,5 bis 2,5 Gew.%, bezogen auf die Gesamtzusammensetzung, wie oben definiert, zuzusetzen.The solution to this problem is a conventional per se and known hair dye composition on an aqueous basis, containing oxidation dye precursors and where appropriate coupler, a mixture of an ethane or propanediol mono / di-C 12 -C 18 fatty acid esters, preferably in an amount of From 0.25 to 5.0, more preferably from 0.25 to 2.5, especially from 0.5 to 1.0, weight percent of the total composition of the agent (ie, the dye-containing phase), and 1,2-propanediol and / or its monomethyl or mono ethyl ether, ie 3-methoxy or. 3-Ethoxypropanol (-1), preferably in an amount of 0.25 to 5.0, in particular 0.5 to 2.5 wt.%, Based on the total composition, as defined above to add.

Geeignete Ethandiol- und Propandiolmono/di-fettsäureester sind Ethan- und 1,2-Propandiolmono-dilaurat, -cocoat, -myristat, -oleat, -ricinoleat, -palmitat, -stearat und -isostearat. Die 1,2-Propandiolmischester sind bevorzugt, da sie im Rahmen der Erfindung besonders gute Resultate zeigen.Suitable ethanediol and propanediol mono / di-fatty acid esters are ethane and 1,2-propanediol monodilaurate, cocoate, myristate, oleate, ricinoleate, palmitate, stearate and -isostearat. The 1,2-propanediol mixed esters are preferred because they show particularly good results in the context of the invention.

Ein besonders bevorzugter Ester, mit dem optimale Ergebnisse erzielt wurden, ist das 1,2-Propylenglykolmono/distearat.A particularly preferred ester, with the best results achieved is the 1,2-propylene glycol mono / distearate.

Der Anteil des Monoesters im Mischester kann dabei zwischen etwa 35 und 60% liegen, beispielsweise bei etwa 50%. Der HLB-Wert eines typischen Estergemisches liegt bei etwa 12. The proportion of monoester in the mixed ester can thereby between about 35 and 60%, for example about 50%. The HLB value of a typical ester mixture is included about 12.  

Die sonstigen Bestandteile der erfindungsgemäßen Haarfärbe­ mittel sind an sich bekannt.The other ingredients of the hair dye of the invention Medium are known per se.

Diese enthalten üblicherweise weitere Emulgatoren und Tenside, Lösungsvermittler, Verdickungsmittel, haarkonditionierende Substanzen wie Eiweißhydrolysate und synthetische Polymere, Stabilisatoren, Verdünnungsmittel, etc.These usually contain further emulsifiers and surfactants, Solubilizer, thickener, hair conditioning Substances such as protein hydrolysates and synthetic polymers, Stabilizers, diluents, etc.

Permanente Haarfärbemittel auf Basis von Oxidationsfarb­ stoffvorprodukten liegen in der Regel in zwei getrennten Phasen vor, wovon die eine die Farbstoffvorprodukte sowie Kuppler, Nuanceure, etc. enthält, während die andere, bis zur Anwendung davon getrennt gehaltene Phase das Oxidationsmittel, beispielsweise Wasserstoffperoxid oder andere Peroxide, vorzugsweise in Gegenwart von Stabilisatoren, aufweist.Permanent hair dye based on oxidation color Substance precursors are usually divided into two Phases, one of which is the dye precursors and couplers, nuances, etc., while the other phase kept separate until use the oxidizing agent, for example hydrogen peroxide or other peroxides, preferably in the presence of stabilizers, having.

Ausführliche Angaben über die Zusammensetzung und Herstellung von Haarfärbemitteln finden sich beispielsweise in der Mono­ graphie von K. Schrader, Grundlagen und Rezepturen der Kosmetika (1989, 2. Auflage, Dr. A. Hüthig Verlag), S. 782-815 auf die hier ausdrücklich Bezug genommen wird.Detailed information on the composition and production of hair dyes are found for example in the mono graphie by K. Schrader, basics and recipes of the Cosmetics (1989, 2nd edition, Dr. A. Hüthig Verlag), pp. 782-815 to which express reference is made.

Ein weiterer bevorzugter Bestandteil in den erfindungsgemäßen Haarfärbemitteln ist Panthenol, insbesondere in einer Menge von 0,05 bis 3,0, vorzugsweise 0,1 bis 1,0 Gew.-%, bezogen auf die Gesamtzusammensetzung des Mittels (wie oben definiert). Durch die Mitverwendung dieses Stoffes wird der Glanz des gefärbten Haares erhöht; gleichzeitig wird eine verbesserte Naßkämmbarkeit erreicht.Another preferred ingredient in the invention Hair dyes is panthenol, especially in an amount of 0.05 to 3.0, preferably 0.1 to 1.0 wt .-%, based on the Total composition of the agent (as defined above). By the concomitant use of this substance, the gloss of the dyed hair increases; at the same time an improved Wet combability achieved.

Im folgenden werden einige Beispiele zur Illustration der Erfindung gegeben. The following are some examples illustrating the Invention given.  

Die Beispiele 1 bis 4 beschreiben Haarfärbecremes, die in Cremegrundlagen entsprechend der Erfindung vorliegen.Examples 1 to 4 describe hair dye creams, which in Cream bases are present according to the invention.

Beispiel 1example 1

Gew.-%Wt .-% C₁₆-C₁₈-FettalkoholC₁₆-C₁₈ fatty alcohol 8,008.00 C₁₆-C₁₈-Fettalkoholsulfat, NatriumsalzC₁₆-C₁₈ fatty alcohol sulfate, sodium salt 4,004.00 C₁₂-C₁₄-FettsäuremonoethanolamidC₁₂-C₁₄ fatty acid monoethanolamide 4,604.60 1,2-Propylenglykolmono/distearat1,2-propylene glycol mono / distearate 0,600.60 C₁₂-C₁₄-FettalkoholpolyglykoletherC₁₂-C₁₄ Fettalkoholpolyglykolether 5,005.00 Ölsäureoleic acid 2,502.50 1,2-Propandiol1,2-propanediol 1,001.00 Pyrogenes SiliciumdioxidPyrogenic silica 0,850.85 Natriumlaurylsulfatsodium lauryl sulfate 0,500.50 Komplexbildnercomplexing 0,500.50 Ammoniumchloridammonium chloride 0,500.50 Natriumsulfitsodium 1,001.00 Parfümölperfume oil 0,360.36 Ammoniak, 25%igAmmonia, 25% 2,702.70 Panthenolpanthenol 0,600.60 Eiweißhydrolysatprotein hydrolyzate 0,600.60 Ascorbinsäureascorbic acid 0,200.20 p-Toluylendiaminsulfatp-Toluylenediamine 0,900.90 Resorcinresorcinol 0,150.15 3-Aminophenol3-aminophenol 0,100.10 4-Aminophenol4-aminophenol 0,400.40 Wasser adWater ad 100,00100.00

Beim Vermischen dieser Zusammensetzung mit 6%-igem Wasserstoff­ peroxid wird eine goldbraune Färbung auf dem Haar erzielt. Glanz und Naßkämmbarkeit des Haares sind ausgezeichnet.When mixing this composition with 6% hydrogen peroxide, a golden brown color is achieved on the hair. The shine and wet combability of the hair are excellent.

Beispiel 2Example 2

Der Ersatz der Entwickler/Kuppler-Kombination nach Beispiel 1 durch ein Gemisch ausThe replacement of the developer / coupler combination according to Example 1 through a mixture of

1,0 Gew.-% p-Toluylendiaminsulfat,
0,3 Gew.-% 4-Aminophenol,
0,4 Gew.-% Resorcin,
0,04 Gew.-% Bis-2,4-Diaminophenoxypropan1.0% by weight of p-toluenediamine sulfate,
0.3% by weight of 4-aminophenol,
0.4% by weight of resorcinol,
0.04% by weight of bis-2,4-diaminophenoxypropane

in der gleichen Creme-Grundlage ergab bei der Ausfärbung eine ausdrucksvolle Dunkelblondfärbung. in the same cream-based on coloration one expressive dark blonde color.  

Beispiel 3Example 3

Anstelle der Entwickler/Kuppler-Kombination nach Beispiel 1 wurde in der gleichen Cremegrundlage ein Gemisch ausInstead of the developer / coupler combination according to Example 1 was in the same cream base, a mixture of

0,06 Gew.-% p-Toluylendiaminsulfat,
0,04 Gew.-% α-Naphthol,
0,005 Gew.-% Bis-2,4-Diaminophenoxypropan0.06% by weight of p-toluenediamine sulfate,
0.04% by weight of α-naphthol,
0.005% by weight of bis-2,4-diaminophenoxypropane

eingesetzt. Nach Applikation mit 6%-igem H2O2 wird eine silber­ blonde Färbung erzielt.used. After application with 6% H 2 O 2 a silver blonde color is achieved.

Beispiel 4Example 4

Gew.-%Wt .-% Stearylalkoholstearyl 8,008.00 Kokosfettsäuremonoethanolamidcoconut fatty acid monoethanolamide 4,504.50 1,2-Propandiolmono/distearat1,2-Propanediol mono / distearate 1,301.30 C₁₂-C₁₆-FettalkoholpolyglykoletherC₁₂-C₁₆ Fettalkoholpolyglykolether 4,004.00 Natriumlaurylsulfatsodium lauryl sulfate 1,101.10 Ölsäureoleic acid 2,002.00 1,2-Propandiol1,2-propanediol 1,501.50 Komplexbildnercomplexing 0,500.50 Natriumsulfitsodium 1,001.00 Proteinhydrolysatprotein hydrolyzate 1,301.30 Ascorbinsäureascorbic acid 0,200.20 Parfümölperfume oil 0,400.40 Ammoniak, 25%igAmmonia, 25% 8,508.50 Ammoniumchloridammonium chloride 0,500.50 Panthenolpanthenol 0,850.85 p-Toluylendiaminsulfatp-Toluylenediamine 0,600.60 Resorcinresorcinol 0,050.05 3-Aminophenol3-aminophenol 0,020.02 4-Chlorresorcin4-chlororesorcinol 0,160.16 Wasser adWater ad 100,00100.00

Diese Creme läßt sich ausgezeichnet mit einer wäßrigen 6%-igen H2O2-Zusammensetzung anmischen und ergibt einen glänzenden mittelblonden Haarton.This cream can be perfectly mixed with an aqueous 6% H 2 O 2 composition and gives a shiny mitt blond hair tone.

Claims (5)

1. Haarfärbemittel auf wäßriger Basis, enthaltend Oxidations­ farbstoffvorprodukte und gegebenenfalls Kuppler, dadurch gekennzeichnet, daß es ein Gemisch aus einem Ethan- oder Propandiolmono/di-C12-C18-fettsäureester und 1,2- Propandiol und/oder dessen Monomethyl- oder Monoethylether enthält.1. hair dye on an aqueous basis, containing oxidation dye precursors and optionally couplers, characterized in that it is a mixture of an ethane or propanediol mono-di-C 12 -C 18 fatty acid esters and 1,2-propanediol and / or its monomethyl or Contains monoethyl ether. 2. Haarfärbemittel nach Anspruch 1, gekennzeichnet durch einen Gehalt an 0,25 bis 2,5 Gew.-%, bezogen auf die Gesamtzu­ sammensetzung des Mittels, an einem Ethan- oder Propandiol­ mono/distearat.2. hair dye according to claim 1, characterized by a Content of 0.25 to 2.5 wt .-%, based on the total zuzu composition of the composition, on an ethane or propanediol mono / distearate. 3. Haarfärbemittel nach Anspruch 1 oder 2 gekennzeichnet durch einen Gehalt an 0,5 bis 1,5 Gew.-% bezogen auf die Gesamtzusammensetzung des Mittels, an 1,2-Propandiolmono/ distearat.3. hair colorant according to claim 1 or 2 characterized by a content of 0.5 to 1.5 wt .-% based on the Total composition of the agent, on 1,2-propanediol mono / distearate. 4. Haarfärbemittel nach einem der Ansprüche 1 bis 3, ge­ kennzeichnet durch einen Gehalt an 0,5-5,0 Gew.%, bezogen auf die Gesamtzusammensetzung des Mittels, an 1,2- Propandiol.4. hair dye according to any one of claims 1 to 3, ge characterized by a content of 0.5-5.0 wt.%, Based to the total composition of the agent, at 1,2- Propanediol. 5. Haarfärbemittel nach einem der Ansprüche 1 bis 4, gekennzeichnet durch einen zusätzlichen Gehalt an Panthenol.5. hair dye according to any one of claims 1 to 4, characterized by an additional content of panthenol.
DE19914103292 1991-02-04 1991-02-04 Hair Dye Expired - Lifetime DE4103292C2 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0998897A1 (en) * 1998-10-14 2000-05-10 Goldwell Aktiengesellschaft Method for manufacturing stable aqueous hair dye emulsions
EP1036557A1 (en) * 1999-02-11 2000-09-20 GOLDWELL GmbH Preemulsion and its use for making hair dyes as well as a method for making hair dye emulsions
US6682572B2 (en) * 1997-10-03 2004-01-27 L'oreal S.A. Oxidation dyeing composition for keratin fibres
EP1707184A1 (en) * 2005-03-31 2006-10-04 L'oreal Dye composition with a reduced content of starting materials, process for dyeing keratin fibres using the same and device therefor
EP1035825B2 (en) † 1997-12-08 2008-09-24 Henkel AG & Co. KGaA Hair colorant preparation

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19617626C3 (en) * 1996-05-02 2003-04-03 Kao Corp Means for coloring and tinting of human hair
US7651533B2 (en) 2005-03-31 2010-01-26 Oreal Dye composition with a reduced content of starting materials, process for dyeing keratin fibers using the same and device therefor

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2158670B2 (en) * 1970-12-04 1978-02-16 Unilever N.V, Rotterdam (Niederlande) HAIR DYE PRODUCTS
DE2737291B2 (en) * 1976-08-20 1979-03-29 L'oreal, S.A., Paris Dyes for human hair
US4381920A (en) * 1979-08-03 1983-05-03 Michael-David Laboratories Method and composition for dyeing human hair
US4425132A (en) * 1978-04-06 1984-01-10 L'oreal Two-stage process for dyeing keratin fibres
US4725282A (en) * 1984-06-27 1988-02-16 Wella Aktiengesellschaft Oxidative hair dyeing composition based upon a carrier of low viscosity
US4787911A (en) * 1980-07-21 1988-11-29 L'oreal Surface-active oligomers, a process for their preparation and compositions containing them

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2158670B2 (en) * 1970-12-04 1978-02-16 Unilever N.V, Rotterdam (Niederlande) HAIR DYE PRODUCTS
DE2737291B2 (en) * 1976-08-20 1979-03-29 L'oreal, S.A., Paris Dyes for human hair
US4425132A (en) * 1978-04-06 1984-01-10 L'oreal Two-stage process for dyeing keratin fibres
US4381920A (en) * 1979-08-03 1983-05-03 Michael-David Laboratories Method and composition for dyeing human hair
US4787911A (en) * 1980-07-21 1988-11-29 L'oreal Surface-active oligomers, a process for their preparation and compositions containing them
US4725282A (en) * 1984-06-27 1988-02-16 Wella Aktiengesellschaft Oxidative hair dyeing composition based upon a carrier of low viscosity

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6682572B2 (en) * 1997-10-03 2004-01-27 L'oreal S.A. Oxidation dyeing composition for keratin fibres
EP1035825B2 (en) † 1997-12-08 2008-09-24 Henkel AG & Co. KGaA Hair colorant preparation
EP0998897A1 (en) * 1998-10-14 2000-05-10 Goldwell Aktiengesellschaft Method for manufacturing stable aqueous hair dye emulsions
AU753078B2 (en) * 1998-10-14 2002-10-10 Kpss-Kao Professional Salon Services Gmbh Process for the preparation of stable aqueous hair dyeing emulsions
EP1036557A1 (en) * 1999-02-11 2000-09-20 GOLDWELL GmbH Preemulsion and its use for making hair dyes as well as a method for making hair dye emulsions
EP1707184A1 (en) * 2005-03-31 2006-10-04 L'oreal Dye composition with a reduced content of starting materials, process for dyeing keratin fibres using the same and device therefor
FR2883735A1 (en) * 2005-03-31 2006-10-06 Oreal COLORING COMPOSITION WITH REDUCED CONTENT IN RAW MATERIALS, METHOD FOR COLORING KERATINIC FIBERS USING THE SAME AND DEVICE

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