DE395434C - Process for the preparation of copper chlorine solution - Google Patents

Process for the preparation of copper chlorine solution

Info

Publication number
DE395434C
DE395434C DEB109867D DEB0109867D DE395434C DE 395434 C DE395434 C DE 395434C DE B109867 D DEB109867 D DE B109867D DE B0109867 D DEB0109867 D DE B0109867D DE 395434 C DE395434 C DE 395434C
Authority
DE
Germany
Prior art keywords
copper
preparation
chloride
chlorine
chlorine solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB109867D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dipl-Ing Dr Adolf Barth
Original Assignee
Dipl-Ing Dr Adolf Barth
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dipl-Ing Dr Adolf Barth filed Critical Dipl-Ing Dr Adolf Barth
Priority to DEB109867D priority Critical patent/DE395434C/en
Application granted granted Critical
Publication of DE395434C publication Critical patent/DE395434C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G3/00Compounds of copper
    • C01G3/04Halides
    • C01G3/05Chlorides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Description

Verfahren zur Darstellung von Kupferchlorürlösung. Im Patente; K1. un, ist ein Verfahren zur Auflösung von Kupfer und Kupferlegierungen unter Zuhilfenahme von Kupferchlorid, Kupferchlorür bzw. basischen Kupferchloriden oder Kupferoxydulchloriden und unter Zusatz von geringen Säuremengen beschrieben. Es wurde nun gefunden, daß an Stelle von Salzsäure und Luft mit besonderem Vorteil Chlor verwendet werden kann. Der durch= die Verwendung von Chlor erreichte Vorteil besteht hauptsächlich darin, daß durch die größere Wärmeentwicklung eine erhebliche Beschleunigung des Lösungsvorganges eintritt.Process for the preparation of copper chloride solution. Im patents; K1. well, is a method for dissolving copper and copper alloys with the aid of copper chloride, copper chloride or basic copper chlorides or copper oxychloride and described with the addition of small amounts of acid. It has now been found that Instead of hydrochloric acid and air, chlorine can be used with particular advantage. The advantage achieved by = the use of chlorine is mainly: that a considerable acceleration of the dissolution process due to the greater heat development entry.

Der bisher unbekannte und nicht vorauszusehende Erfolg aber besteht darin, daß man beim Arbeiten in neutraler oder schwach alkalischer Lösung bei Anwesenheit von genügend Kochsalz und Kupfermetall bzw. Kupferlegierung oder reduktionsfähigem Kupfererz nicht etwa Kupferchlorid, sondern im wesentlichen in der Lösung Kupferchlorür erhält. Die Geschwindigkeit der Auflösung ist hierbei annähernd die gleiche wie bei Auflösung von geglühtem Kupferoxyd in Säure. Beispiel.The previously unknown and unforeseeable success, however, persists that when working in a neutral or weakly alkaline solution in the presence of sufficient table salt and copper metal or copper alloy or reducible Copper ore not, for example, copper chloride, but essentially in the solution copper chloride receives. The speed of dissolution here is approximately the same as when annealed copper oxide is dissolved in acid. Example.

Zoo 1 Kochsalzlösung vom spezifischen Gewicht 1,15 werden mit etwa Zoo g Kupferchlorid versetzt und mit dem zu lösenden Material (Kupfer, Kupferlegierungen, Kupfererze oder kupferhaltige Rückstände) je nach Form in einem Rührwerksbottich oder in einem mit Siebboden versehenen Behälter behandelt, in dem man Chlor einleitet. Durch Zusatz von etwas Kupferoxyd wird eine eventuelle saure Reaktion beseitigt. Der Chlorstrom wird geregelt, daß man nur eine Lösung von Kupferchlorür erhält.Zoo 1 saline solution with a specific gravity of 1.15 will be approx Zoo g copper chloride is added and the material to be dissolved (copper, copper alloys, Copper ores or residues containing copper) in an agitator vat, depending on the shape or treated in a container provided with a sieve bottom, into which chlorine is introduced. Any acidic reaction can be eliminated by adding a little copper oxide. The flow of chlorine is regulated so that only a solution of copper chloride is obtained.

Das Verfahren läßt sich gleichgut auf Kupfer, kupferhaltige Rückstände, Kupfererze und Kupferlegierungen anwenden. Statt Kochsalz können andere Alkali- oder Erdalkalichloride Verwendung finden.The process can be applied equally well to copper, copper-containing residues, Use copper ores and copper alloys. Instead of table salt, other alkali or alkaline earth chlorides are used.

Claims (1)

PATENTANSPRUCH: Verfahren zur Darstellung von Kupferchlorürlösung aus Kupfer, Kupferlegierungen, Kupfererzen oder kupferhaltigen Metallrückständen und -aschen, dadurch gekennzeichnet, daß man dieselben in starken Alkali- oder Erdalkalichloridlösungen bei Gegenwart von Kupferchlorid mit so viel Chlor in neutraler oder schwach alkalischer Lösung behandelt, daß das Kupfer nur als Chlorür gelöst wird.PATENT CLAIM: Process for the preparation of copper chloride solution from copper, copper alloys, copper ores or copper-containing metal residues and ash, characterized in that the same in strong alkali or alkaline earth chloride solutions in the presence of copper chloride with as much chlorine in neutral or weakly alkaline Solution treated so that the copper is only dissolved as chlorine.
DEB109867D 1923-06-03 1923-06-03 Process for the preparation of copper chlorine solution Expired DE395434C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB109867D DE395434C (en) 1923-06-03 1923-06-03 Process for the preparation of copper chlorine solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB109867D DE395434C (en) 1923-06-03 1923-06-03 Process for the preparation of copper chlorine solution

Publications (1)

Publication Number Publication Date
DE395434C true DE395434C (en) 1924-05-17

Family

ID=6992580

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB109867D Expired DE395434C (en) 1923-06-03 1923-06-03 Process for the preparation of copper chlorine solution

Country Status (1)

Country Link
DE (1) DE395434C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3030178A (en) * 1958-12-15 1962-04-17 Schering Ag Process for continuous production of cuprous chloride

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3030178A (en) * 1958-12-15 1962-04-17 Schering Ag Process for continuous production of cuprous chloride

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