DE3882808T2 - Verfahren und Vorrichtung zum Entfernen von Schwefelverbindungen aus Gasen und zur Regenerierung von verbrauchten Adsorptionsmitteln. - Google Patents

Verfahren und Vorrichtung zum Entfernen von Schwefelverbindungen aus Gasen und zur Regenerierung von verbrauchten Adsorptionsmitteln.

Info

Publication number
DE3882808T2
DE3882808T2 DE88108108T DE3882808T DE3882808T2 DE 3882808 T2 DE3882808 T2 DE 3882808T2 DE 88108108 T DE88108108 T DE 88108108T DE 3882808 T DE3882808 T DE 3882808T DE 3882808 T2 DE3882808 T2 DE 3882808T2
Authority
DE
Germany
Prior art keywords
gases
sulfur compounds
removing sulfur
regenerating spent
spent adsorbents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE88108108T
Other languages
English (en)
Other versions
DE3882808D1 (de
Inventor
Eli Gal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Environmental Services Inc
Original Assignee
General Electric Environmental Services Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Environmental Services Inc filed Critical General Electric Environmental Services Inc
Publication of DE3882808D1 publication Critical patent/DE3882808D1/de
Application granted granted Critical
Publication of DE3882808T2 publication Critical patent/DE3882808T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/48—Sulfur dioxide; Sulfurous acid
    • C01B17/50—Preparation of sulfur dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B01D53/08—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds according to the "moving bed" method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/508—Sulfur oxides by treating the gases with solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/20—Methods for preparing sulfides or polysulfides, in general
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • B01D2253/1124—Metal oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/304—Linear dimensions, e.g. particle shape, diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40003—Methods relating to valve switching
    • B01D2259/40005—Methods relating to valve switching using rotary valves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40007—Controlling pressure or temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40077—Direction of flow
    • B01D2259/40079—Co-current
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40077—Direction of flow
    • B01D2259/40081—Counter-current
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0462—Temperature swing adsorption

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Gas Separation By Absorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
DE88108108T 1987-06-04 1988-05-20 Verfahren und Vorrichtung zum Entfernen von Schwefelverbindungen aus Gasen und zur Regenerierung von verbrauchten Adsorptionsmitteln. Expired - Fee Related DE3882808T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/058,060 US4857285A (en) 1987-06-04 1987-06-04 Method and system for removal of sulfur compounds from gases and for regenerating spent sorbents

Publications (2)

Publication Number Publication Date
DE3882808D1 DE3882808D1 (de) 1993-09-09
DE3882808T2 true DE3882808T2 (de) 1994-03-31

Family

ID=22014410

Family Applications (1)

Application Number Title Priority Date Filing Date
DE88108108T Expired - Fee Related DE3882808T2 (de) 1987-06-04 1988-05-20 Verfahren und Vorrichtung zum Entfernen von Schwefelverbindungen aus Gasen und zur Regenerierung von verbrauchten Adsorptionsmitteln.

Country Status (3)

Country Link
US (1) US4857285A (de)
EP (1) EP0293688B1 (de)
DE (1) DE3882808T2 (de)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5118480A (en) * 1990-06-25 1992-06-02 General Electric Environmental Services, Incorporated Method for removing hcl and hf from coal derived fuel gas
DE4026071C2 (de) * 1990-08-17 1994-04-14 Steag Ag Verfahren und Vorrichtung zum Regenerieren von kohlenstoffhaltigem Adsorptionsmittel
JP2865845B2 (ja) * 1990-10-08 1999-03-08 三菱重工業株式会社 高温還元性ガスの精製方法
US5401475A (en) * 1991-07-08 1995-03-28 G.E. Environmental Services, Inc. Process and apparatus for generating elemental sulfur and re-usable metal oxide from spent metal sulfide sorbents
JPH0524808A (ja) * 1991-07-08 1993-02-02 General Electric Environ Service Inc 使用済み金属硫化物吸収剤より元素硫黄及び再使用可能金属酸化物を生成するための方法及びその装置
JPH0787889B2 (ja) * 1992-02-08 1995-09-27 大同ほくさん株式会社 混合ガスの分離方法およびそれに用いる装置
US5514351A (en) * 1992-04-15 1996-05-07 Mobil Oil Corporation Desulfurizing tailgas from sulfur recovery unit
US5458861A (en) * 1992-04-15 1995-10-17 Mobil Oil Corporation Desulfurizing a gas stream
US5292492A (en) * 1992-05-04 1994-03-08 Mobil Oil Corporation Recovering sulfur from ammonia acid gas stream
US5591417A (en) * 1992-04-15 1997-01-07 Mobil Oil Corporation Removing SOx, CO and NOx from flue gases
US5244641A (en) * 1992-04-28 1993-09-14 Phillips Petroleum Company Absorption of hydrogen sulfide and absorbent composition therefor
US5348921A (en) * 1993-06-14 1994-09-20 The United States Of America As Represented By The United States Department Of Energy Method for reducing sulfate formation during regeneration of hot-gas desulfurization sorbents
US5403366A (en) * 1993-06-17 1995-04-04 Texaco Inc. Partial oxidation process for producing a stream of hot purified gas
US5447702A (en) * 1993-07-12 1995-09-05 The M. W. Kellogg Company Fluid bed desulfurization
USH1539H (en) * 1993-11-12 1996-06-04 Shell Oil Company Method of reducing hydrogen chloride in synthesis gas
US5891415A (en) * 1995-05-17 1999-04-06 Azerbaidzhanskaya Gosudarstvennaya Neftianaya Academiya Process for selective oxidation of hydrogen sulfide to elemental sulfur
US5603913A (en) * 1995-05-17 1997-02-18 Azerbaidzhanskaya Gosudarstvennaya Neftianaya Academiya Catalysts and process for selective oxidation of hydrogen sulfide to elemental sulfur
US5958816A (en) * 1997-02-28 1999-09-28 Tricat, Inc. Method of presulfiding and passivating a hydrocarbon conversion catalyst
ES2194665T3 (es) * 2000-11-07 2003-12-01 Friedrich Hellmich Procedimiento para depurar gases de humo.
NL1020133C2 (nl) * 2002-03-08 2003-09-10 Diba B V Werkwijze voor de verwijdering van zuurstof uit gasstromen.
CA2433277C (en) * 2003-06-25 2008-02-26 Clean-Flo Gas Filtration Systems (1987) Ltd. Gas purification medium for removing sulfides from gaseous streams
CA2434233C (en) * 2003-07-03 2010-02-16 Clean-Flo Gas Filtration Systems (1987) Ltd. Method of scrubbing lower mass sulfides with a sulfide scrubbing medium capable of regeneration
US7901646B2 (en) * 2009-08-05 2011-03-08 General Electric Company System and method for sulfur recovery
US10065176B2 (en) * 2016-05-20 2018-09-04 General Electric Technology Gmbh System and method for reducing carbon dioxide emissions from a flue gas generated via combusting a fossil fuel
CN108283874A (zh) * 2018-04-25 2018-07-17 武汉都市环保工程技术股份有限公司 一种错流式三级移动床活性焦脱硫脱硝净化塔
GB2598340A (en) * 2020-08-27 2022-03-02 Sintef Tto As Gas capture system with combined temperature and pressure swings
CN115125031B (zh) * 2021-03-25 2024-04-26 中国石油化工股份有限公司 一种S Zorb中闭锁料斗卸剂方法
CN114471081B (zh) * 2022-04-19 2022-06-28 烟台泓源生物肥料有限公司 一种降低农药生产车间尾气VOCs的尾气处理装置

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE504089A (de) *
US1626664A (en) * 1921-08-26 1927-05-03 U G I Contracting Company Process of purifying illuminating gas
US1816533A (en) * 1929-07-17 1931-07-28 Huff Process of purifying gases
US2259409A (en) * 1938-06-03 1941-10-14 Walter H Duisberg Process for reactivating desulphurizing masses
US2682444A (en) * 1949-07-26 1954-06-29 Humphreys & Glasgow Ltd Continuous process for the removal of hydrogen sulfide from gas
US2983573A (en) * 1956-06-25 1961-05-09 Robert Dempster And Sons Ltd Removal of hydrogen sulphide from gases
GB1427112A (en) * 1973-06-25 1976-03-10 Yoshitomi Pharmaceutical Antifouling compositions
FR2295782A1 (fr) * 1974-12-27 1976-07-23 Inst Francais Du Petrole Procede d'epuration d'un gaz contenant du sulfure d'hydrogene et masses de contact utilisables a cet effet
US4089809A (en) * 1976-03-01 1978-05-16 The United States Of America As Represented By The United States Department Of Energy Regenerable sorbent and method for removing hydrogen sulfide from hot gaseous mixtures
GB1550354A (en) * 1976-04-22 1979-08-15 Exxonr Research & Eng Co Converting calcium sulphide to culcium oxide
US4273749A (en) * 1977-06-03 1981-06-16 Hitachi, Ltd. Refining process of hot gas containing hydrogen sulfide and ammonia
FR2432887A1 (fr) * 1978-08-08 1980-03-07 Inst Francais Du Petrole Procede d'epuration d'un gaz contenant du sulfure d'hydrogene
FR2456543A1 (fr) * 1979-05-15 1980-12-12 Inst Francais Du Petrole Procede d'epuration d'un gaz contenant du sulfure d'hydrogene
US4366131A (en) * 1979-05-31 1982-12-28 Irwin Fox Highly reactive iron oxide agents and apparatus for hydrogen sulfide scavenging
DE3131257C2 (de) * 1981-08-07 1986-10-30 VEG-Gasinstituut N.V., Apeldoorn Verfahren zum Entfernen von Schwefelwasserstoff aus Gasen
NL8105728A (nl) * 1981-10-30 1983-05-16 Tno Werkwijze voor het verwijderen van diwaterstofsulfide uit procesgassen met behulp van vaste acceptoren, werkwijze voor het cyclisch-regenereren van de gebruikte acceptoren bij hoge temperatuur, alsmede werkwijze voor het bereiden van acceptoren, die voor deze werkwijze geschikt zijn.
US4435371A (en) * 1982-02-26 1984-03-06 The Goodyear Tire & Rubber Company Sulfur removal from a gas stream
US4442078A (en) * 1982-07-07 1984-04-10 The United States Of America As Represented By The United States Department Of Energy Method of removing hydrogen sulfide from gases utilizing a zinc oxide sorbent and regenerating the sorbent
AT380407B (de) * 1983-10-07 1986-05-26 Voest Alpine Ag Verfahren zum entfernen von schwefel oder schwefelverbindungen und/oder anderen schadstoffen aus heissen reduzierenden gasen sowie vorrichtung zur durchfuehrung dieses verfahrens

Also Published As

Publication number Publication date
EP0293688A3 (en) 1990-03-28
EP0293688B1 (de) 1993-08-04
US4857285A (en) 1989-08-15
EP0293688A2 (de) 1988-12-07
DE3882808D1 (de) 1993-09-09

Similar Documents

Publication Publication Date Title
DE3882808T2 (de) Verfahren und Vorrichtung zum Entfernen von Schwefelverbindungen aus Gasen und zur Regenerierung von verbrauchten Adsorptionsmitteln.
DE3762903D1 (de) Verfahren und vorrichtung zur regeneration von abgas-filtersystemen.
DE3761257D1 (de) Verfahren und vorrichtung zur regeneration von partikelfiltersystemen.
DE3482165D1 (de) Verfahren und apparat zum entfernen von kohlenwasserstoffen aus luft-kohlenwasserstoffdampfmischungen.
DE3888522T2 (de) Vorrichtung und verfahren zum filtrieren.
DE3861354D1 (de) Vorrichtung und verfahren zur trennung von gasen.
ATA216683A (de) Verfahren zum entfernen von stickoxyden aus abgasen
AT379087B (de) Verfahren zur entfernung von kohlendioxid aus gasen
DE58902814D1 (de) Verfahren zur entfernung von silanverbindungen aus silanhaltigen abgasen.
DE3880633D1 (de) Vorrichtung und verfahren zum abziehen von abfaellen.
AT389460B (de) Verfahren und vorrichtung zur entfernung von schwefel aus dem abgas eines reduktionsschachtofens
DE69333160D1 (de) Verfahren und Vorrichtung zum Entfernen von Kohlenmonoxid aus Gasen
DE235713T1 (de) Verfahren zum entfernen von so2 aus gasstroemen.
DE3670957D1 (de) Verfahren und vorrichtung zum abtrennen von schadstoffen aus einem traegergas.
DE69311576D1 (de) Verfahren zur entfernung von schwefeldioxyd aus schwefeldioxyd enthaltenden gasströmen
DE69012025T2 (de) Verfahren zum Entfernen schädlicher Gase aus Abgasen der Müllverbrennung.
DE68906126T2 (de) Verfahren und vorrichtung zur entfernung von h2s.
DE3480780D1 (de) Verfahren und vorrichtung zum abtrennen von stegen und anguessen.
DE3874085T2 (de) Verfahren und vorrichtung zum entnehmen von diaprojektortraegern.
ATE123967T1 (de) Verfahren zum entfernen von zinnverbindungen aus abgasen.
DE69401097T2 (de) Verfahren und Vorrichtung zum Reinigen von SO2-haltigen Gasen
DE69434393D1 (de) Elektrochemische vorrichtung und verfahren zur entfernung und regeneration von sauerstoff
ATA299588A (de) Verfahren und vorrichtung zur regeneration von aktivkohleanlagen
AT388881B (de) Verfahren und vorrichtung zur rueckgewinnung von loesungsmitteln aus gasen
ATE27550T1 (de) Verfahren und vorrichtung zum reinigen von gasen.

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee