DE3728174A1 - Refrigerant and oil disposal station for cooling devices, air-conditioning systems and other devices - Google Patents

Refrigerant and oil disposal station for cooling devices, air-conditioning systems and other devices

Info

Publication number
DE3728174A1
DE3728174A1 DE19873728174 DE3728174A DE3728174A1 DE 3728174 A1 DE3728174 A1 DE 3728174A1 DE 19873728174 DE19873728174 DE 19873728174 DE 3728174 A DE3728174 A DE 3728174A DE 3728174 A1 DE3728174 A1 DE 3728174A1
Authority
DE
Germany
Prior art keywords
refrigerant
oil
est
disposal station
disposed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19873728174
Other languages
German (de)
Inventor
Reinhold Holstein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DE19873728174 priority Critical patent/DE3728174A1/en
Publication of DE3728174A1 publication Critical patent/DE3728174A1/en
Withdrawn legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B45/00Arrangements for charging or discharging refrigerant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02Separation of non-miscible liquids
    • B01D17/0208Separation of non-miscible liquids by sedimentation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02Separation of non-miscible liquids
    • B01D17/04Breaking emulsions
    • B01D17/048Breaking emulsions by changing the state of aggregation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2345/00Details for charging or discharging refrigerants; Service stations therefor
    • F25B2345/002Collecting refrigerant from a cycle

Landscapes

  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Compressor (AREA)

Abstract

The subject of the invention is a disposal station for refrigerant and compressor oil. This disposal station has the function of removing refrigerant and oil from the devices which are to be disposed of, of collecting (temporarily storing) the refrigerant and oil and of separating the oil and refrigerant accumulated in this manner to as large an extent as possible and of making them available for further usage. The disposal station is based on the process of separating the accumulated materials by means of phase change of the refrigerant, brought about by pressure reduction in the collecting container. The disposal station is to be operated decentrally (for example in communal recycling centres, at landfill sites, on refuse collection vehicles) in order to supply the materials accumulated there for further usage in large quantities.

Description

Ausgehend von der derzeitigen SituationBased on the current situation

  • - Umweltbelastung durch Kältemittel (R 11, R 12, . . .)- Environmental pollution caused by refrigerants (R 11 , R 12 ,...)
  • - Umweltbelastung durch Öl (Kompressorenöl)- Environmental pollution caused by oil (compressor oil)
  • - allein in der BRD fallen im Jahr 3,5 Mio. Kühl- und Gefrier­ geräte (ohne Klimaanlagen) als Abfall an, d. h. ca. 500 t Kältemittel und 1 Mio. l Kompressorenöl gelangen in die Umwelt- In the FRG alone 3.5 million refrigerators and freezers fall each year appliances (without air conditioning) as waste, d. H. approx. 500 t Refrigerant and 1 million l of compressor oil are released into the environment
  • - es existieren Recycling-Verfahren für Kältemittel (Fa. Gramkow in Sonderborg, Fa. Hoechst)- There are recycling processes for refrigerants (Gramkow in Sonderborg, Hoechst)
  • - es existieren Recycling- bzw. Beseitigungs-Verfahren für Öle- There are recycling and disposal processes for oils

stellt sich das Problem, die Verbindung zwischen dem Ort der Abfall- Entstehung und dem des Abfall-Recycling, der Abfall-Weiterverwertung bzw. -Beseitigung herzustellen.the problem arises, the connection between the location of the waste Origin and that of waste recycling, waste recycling manufacture or elimination.

Diese Verbindung zwischen "Abfall-"Quelle" und "Abfall-Senke" beinhaltet Kältemittel und ÖlThis connection between "waste" source "and" waste sink "implies Refrigerant and oil

  • - aus dem zu entsorgenden Gerät zu entnehmen- to be removed from the device to be disposed of
  • - zwischenzulagern (sammeln)- intermediate storage (collecting)
  • - weitestgehend voneinander zu trennen, zu reinigen und sortenrein einer Weiterverwendung bereitzustellen.- to be separated as far as possible from each other, cleaned and sorted to provide for further use.

Kältemittel und Öl zu trennen ist auch Gegenstand des US-Patents 43 64 236 (Lower et al; "Kältemittel-Rückgewinnung und Wieder- Abfüll-System"); das dort beschriebene Verfahren entspricht dem eines normalen Ölabscheiders (wie aus der Druckluft-Technik bekannt) und hat den Nachteil, daß das so rückgewonnene Öl unter Normal-Druck (1 bar) durch das im Öl gelöste Kältemittel aufschäumt, und das Kältemittel wiederum nur unvollständig vom Öl "gereinigt" ist.Separating refrigerant and oil is also the subject of the US patent 43 64 236 (Lower et al; "Refrigerant Recovery and Recovery Filling system "); the procedure described there corresponds to that of one normal oil separator (as known from compressed air technology) and has the disadvantage that the oil thus recovered under normal pressure (1 bar) due to the refrigerant dissolved in the oil, and the refrigerant is incompletely "cleaned" of the oil.

Das der Erfindung zugrunde liegende Verfahren wird an Hand der Bilder 1 und 2 erläutert. The method on which the invention is based is explained with reference to Figures 1 and 2.

Der Aufbau der Entsorgungs-Station (EST) ist in Bild 1 dar­ gestellt.The structure of the disposal station (EST) is shown in Figure 1.

Die EST wird dezentral betrieben, z. B. in kommunalen Recycling-Zentren, bei Mülldeponien oder auf Müllfahrzeugen. Dabei werden Kältemittel und Öl im Sammelbehälter (1) der EST gesammelt und zwischengespeichert. Um die Stoffe einer Weiter­ verarbeitung zuzuführen, wird der Sammelbehälter periodisch oder nach Bedarf in die Behälter (2) und (3) entleert.The EST is operated decentrally, e.g. B. in municipal recycling centers, at landfills or on garbage trucks. Refrigerant and oil are collected and temporarily stored in the EST storage tank ( 1 ). In order to feed the substances for further processing, the collection container is emptied periodically or as required into containers ( 2 ) and ( 3 ).

In der Praxis kann dies bedeuten, daß ein Tankfahrzeug die dezentralen EST's anfährt, um Öl und Kältemittel aufzunehmen. Durch die Größe des Sammelbehälters (1) kann so eine optimale Sammelfrequenz vorbestimmt werden.In practice, this can mean that a tanker drives to the decentralized ESTs to take up oil and refrigerant. The size of the collecting container ( 1 ) allows an optimal collecting frequency to be predetermined.

Die Arbeitsweise der EST soll im folgenden an Hand von Bild 2 dargelegt werden. Die EST arbeitet in 3 Phasen:The mode of operation of the EST will be explained in the following with the help of Figure 2. The EST works in 3 phases:

  • I. Kältemittel und Öl aus den zu entsorgenden Geräten aufnehmen,I. Refrigerant and oil from the devices to be disposed of record, tape,
  • II. Kältemittel an Behälter (2) abgeben,II. Deliver refrigerant to tank ( 2 ),
  • III. Öl an Behälter (3) abgeben.III. Dispense oil to container ( 3 ).

Diesen Phasen entsprechen die Ventil-Stellungen I, II, III der Mehrweg-Ventile (6).The valve positions I, II, III of the reusable valves ( 6 ) correspond to these phases.

Phase IPhase I

  • Kältemittel und Öl der zu entsorgenden Geräte werden mittels Kompressor (4) in den Sammelbehälter (5) ge­ pumpt.Refrigerant and oil of the devices to be disposed of are pumped into the collection container ( 5 ) by means of a compressor ( 4 ).

Die EST verbleibt so lange in Phase I, bis der Sammelbehälter (5) ge­ leert wird; der Sammelbehälter (5) befindet sich dann in dem Zustand, daß Kältemittel und Öl, wie in Bild 2 dargestellt, geschichtet sind.The EST remains in phase I until the collection container ( 5 ) is emptied; The collecting container ( 5 ) is then in the state that the refrigerant and oil are layered as shown in Figure 2.

Phase IIPhase II

  • Das Kältemittel des Sammelbehälters (5) wird in den Behälter (2) übernommen. Dabei wird das Kältemittel durch Unterdruck gasförmig aus Sammelbehälter (5) mittels Kompressor (4) entnommen, der es dann in den Behälter (2) pumpt. Durch den dabei im Sammelbehälter (5) entstehenden Unterdruck wird die darin enthaltene Feuchtigkeit (aus Öl und Kältemittel) gemeinsam mit dem Kältemittel ent­ nommen und an einen Trockner abgegeben.The refrigerant in the collection container ( 5 ) is transferred to the container ( 2 ). The refrigerant is removed in gaseous form from the collecting container ( 5 ) by means of a compressor ( 4 ), which then pumps it into the container ( 2 ). Due to the resulting negative pressure in the collecting container ( 5 ), the moisture contained therein (from oil and refrigerant) is removed together with the refrigerant and released to a dryer.

Die EST verbleibt solange in Phase II, bis ein vorgegebener Unter­ druck im Sammelbehälter (5) erreicht ist. The EST remains in phase II until a predetermined vacuum in the collection container ( 5 ) is reached.

Phase IIIPhase III

  • Das Öl des Sammelbehälters (5) wird in den Be­ hälter (3) übernommen.The oil in the reservoir ( 5 ) is transferred to the reservoir ( 3 ).

Am Ende der Phase III herrscht im Sammelbehälter (5) Unterdruck; der Sammelbehälter ist leer.At the end of phase III, there is negative pressure in the collecting container ( 5 ); the collection container is empty.

Claims (5)

1. Entsorgungs-Station (EST) für Kältemittel und Öl (Kompressoren­ öl), dadurch gekennzeichnet, daß
  • - Kältemittel und Öl aus dem zu entsorgenden Gerät (Kreis­ lauf) gemeinsam entnommen werden kann,
  • - das Kältemittel gemeinsam mit dem entnommenen Öl in einem Behältnis gesammelt und ggfls. zwischengelagert wird,
  • - Kältemittel und Öl beim Leeren des Behältnisses durch einen Phasenwechsel des Kältemittels (flüssig/gasförmig/ flüssig) getrennt werden; dieser Phasenwechsel wird durch Druckverminderung im Behältnis verursacht,
  • - die EST in 3 Phasen arbeitet: einer Aufnahme-Phase, in der Kältemittel und Öl aus dem zu entsorgenden Kreislauf aufgenommen werden, und zwei Abgabe-Phasen, einer für das Kältemittel und einer für das Öl.
1. disposal station (EST) for refrigerant and oil (compressor oil), characterized in that
  • - Refrigerant and oil can be removed from the device to be disposed of (circuit) together,
  • - The refrigerant is collected together with the extracted oil in a container and if necessary. is stored temporarily
  • - When emptying the container, the refrigerant and oil are separated by changing the phase of the refrigerant (liquid / gaseous / liquid); this phase change is caused by a decrease in pressure in the container,
  • - The EST works in 3 phases: an absorption phase, in which refrigerant and oil are taken up from the circuit to be disposed of, and two delivery phases, one for the refrigerant and one for the oil.
2. EST nach Anspruch 1, dadurch gekennzeichnet, daß beim angewendeten Verfahren "Phasenwechsel durch Druckverminderung" das im Öl ge­ löste Kältemittel frei wird; dasselbe gilt für die im Öl vor­ handene Restfeuchtigkeit.2. EST according to claim 1, characterized in that when applied Process "phase change by pressure reduction" the ge in the oil released refrigerant is released; the same applies to those in oil existing residual moisture. 3. EST nach Anspruch 1 und 2, dadurch gekennzeichnet, daß die für den Phasenwechsel notwendige Verdampfungsenergie durch die wieder freiwerdende Kondensationsenergie aufgewendet werden kann.3. EST according to claim 1 and 2, characterized in that for the Phase change necessary evaporation energy through the again released condensation energy can be used. 4. EST nach Anspruch 1 bis 3, dadurch gekennzeichnet, daß die Sorten­ reinheit der zu entsorgenden Stoffe aufnahme- als auch abgabeseitig nach dem Schlüssel-Schloß-Prinzip gesichert werden kann, indem die EST aufnahme- und abgabeseitig, der zu entsorgende Kreislauf und die Behältnisse (abgabeseitig der EST) für Kältemittel und Öl mit sorten-spezifischen Adaptern versehen sind.4. EST according to claim 1 to 3, characterized in that the varieties Purity of the materials to be disposed of on the receiving and delivery sides can be secured by the key-lock principle by the EST reception and delivery side, the circuit to be disposed of and the containers (on the EST side) for refrigerant and oil variety-specific adapters are provided. 5. EST nach Anspruch 1 bis 4, dadurch gekennzeichnet, daß die in den einzelnen Phasen zu verrichtende Arbeit von nur einem Kompressor geleistet werden kann.5. EST according to claim 1 to 4, characterized in that the in the work to be done in the individual phases by only one compressor can be achieved.
DE19873728174 1987-08-24 1987-08-24 Refrigerant and oil disposal station for cooling devices, air-conditioning systems and other devices Withdrawn DE3728174A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19873728174 DE3728174A1 (en) 1987-08-24 1987-08-24 Refrigerant and oil disposal station for cooling devices, air-conditioning systems and other devices

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19873728174 DE3728174A1 (en) 1987-08-24 1987-08-24 Refrigerant and oil disposal station for cooling devices, air-conditioning systems and other devices

Publications (1)

Publication Number Publication Date
DE3728174A1 true DE3728174A1 (en) 1989-03-09

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DE19873728174 Withdrawn DE3728174A1 (en) 1987-08-24 1987-08-24 Refrigerant and oil disposal station for cooling devices, air-conditioning systems and other devices

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0360113A2 (en) * 1988-09-17 1990-03-28 York International GmbH Method for the non-pollutant discharge of a refrigeration system
DE3915400A1 (en) * 1989-05-11 1990-11-15 Bbc York Kaelte Klima Removal of chloro:fluoro:carbon gas from insulation foam - a pulveriser and compressor in separate airtight chambers extract gas which is removed, collected and condensed to form pure liquid CFC
DE10139236A1 (en) * 2001-08-09 2003-04-10 Zaug Recycling Gmbh Separation of mixture of waste refrigerator coolant and oil comprises double evaporation sequence with energy recovery

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0360113A2 (en) * 1988-09-17 1990-03-28 York International GmbH Method for the non-pollutant discharge of a refrigeration system
EP0360113A3 (en) * 1988-09-17 1990-07-25 Brown Boveri-York Kalte- Und Klimatechnik Gmbh Method for the non-pollutant discharge of a refrigeration system, and device for carrying out the method
DE3915400A1 (en) * 1989-05-11 1990-11-15 Bbc York Kaelte Klima Removal of chloro:fluoro:carbon gas from insulation foam - a pulveriser and compressor in separate airtight chambers extract gas which is removed, collected and condensed to form pure liquid CFC
DE10139236A1 (en) * 2001-08-09 2003-04-10 Zaug Recycling Gmbh Separation of mixture of waste refrigerator coolant and oil comprises double evaporation sequence with energy recovery

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8139 Disposal/non-payment of the annual fee