DE355174C - Process for the preparation of resinous products from nuclear methylated phenols - Google Patents

Process for the preparation of resinous products from nuclear methylated phenols

Info

Publication number
DE355174C
DE355174C DEC29582D DEC0029582D DE355174C DE 355174 C DE355174 C DE 355174C DE C29582 D DEC29582 D DE C29582D DE C0029582 D DEC0029582 D DE C0029582D DE 355174 C DE355174 C DE 355174C
Authority
DE
Germany
Prior art keywords
preparation
methylated phenols
nuclear
products
resinous products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEC29582D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHEM FAB VORM WEILER TER MEER
Original Assignee
CHEM FAB VORM WEILER TER MEER
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHEM FAB VORM WEILER TER MEER filed Critical CHEM FAB VORM WEILER TER MEER
Priority to DEC29582D priority Critical patent/DE355174C/en
Application granted granted Critical
Publication of DE355174C publication Critical patent/DE355174C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/28—Chemically modified polycondensates

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Verfahren zur, Darstellung von harzartigen Produkten aus kernmethylierten Phenolen. Durch Patent 355173 ist ein Verfahren zur Darstellung von harzartigen Produkten aus kernmethylierten Phenolen geschützt, welches darin besteht, daß man Kresole, deren Chlorsubstitutionsprodukte oder andere kernmethylierte Phenole bei Temperaturen über ioo° so lange mit Chlor behandelt, bis nur noch wenig mit Wasserdampf flüchtige Bestandteile vorhanden sind und der Rückstand beim Erkalten zu einer amorphen, festen Masse erstarrt. Es wurde nun weiter gefunden, daß man zu ganz ähnlichen Harzen auch gelangt, wenn nvan zunächst das Chlor auf die erwähnten Phenolhomologen bei gewöhnlicher oder wenig erhöhter Temperatur einwirken läßt und die entstandenen kristallisierbaren bzw. öligen kernchlorierten Verbindungen einer nachträglichen Erwärmung auf Temperaturen über Ioo°, gegebenenfalls unter vermindertem Druck, unterwirft.Process for the preparation of resin-like products from nuclear methylated Phenols. By patent 355173 is a method for the preparation of resinous Protected products from nuclear methylated phenols, which consists in that one Cresols, their chlorine substitution products or other nuclear methylated phenols Treated temperatures above 100 ° with chlorine until only a little with water vapor volatile constituents are present and the residue turns into an amorphous, solid mass solidified. It has now been found that very similar resins can be obtained even if the chlorine first contributes to the phenol homologues mentioned normal or slightly elevated temperature can act and the resulting crystallizable or oily nuclear chlorinated compounds of a subsequent Heating to temperatures above 100 °, if appropriate under reduced pressure, is subjected.

Beispiel. 2oo Teile technisch reines Kr esol werden ohne äußere Erwärmaulg so lange chloriert, bis eine Gewichtszunahme von 28o bis 300 Teilen eingetreten ist. Das Reaktionsprodukt wird, zweckmäßig unter verinindertem Druck, auf 16o° erhitzt, wobei Sälzsäure abgespalten wird. Man erhält etwa d.oo Teile eines braunen, harten Hanzes., das in Benzolkohlenwasserstoffen löslich, in Allkohol und verdünnten Alkalien unlöslich ist.Example. 200 parts of technically pure cresol are made without external heating mouth chlorinated until a weight increase of 28o to 300 parts has occurred is. The reaction product is heated to 160 °, expediently under reduced pressure, where salt acid is split off. About d.oo parts of a brown, hard one are obtained Hanzes. Which is soluble in benzene hydrocarbons, in alcohol and dilute alkalis is insoluble.

Claims (1)

PATENT-ANspRUcH:. Abänderung des durch Patent 355173 geschützten Verfahrens zur Darstellung von harzartigen Produkten aus kernmethylierten Phenolen, darin bestehend, daß man hier K.resole oder ihre höheren Homologen zunächst bei gewöhnlicher oder wenig erhöhter Temperatur mit Chlor sättig und die Einwirkungsprodukte einer Nacherhitzung auf Temperaturen über ioo°, gegebenenfalls unter vermindertem Druck, unterwirft.PATENT CLAIM :. Modification of the process protected by patent 355173 for the preparation of resin-like products from nuclear methylated phenols, consisting of that here K.resoles or their higher homologues are initially used with ordinary or slightly elevated temperature saturated with chlorine and the action products of post-heating subjected to temperatures above 100 °, optionally under reduced pressure.
DEC29582D 1920-08-24 1920-08-24 Process for the preparation of resinous products from nuclear methylated phenols Expired DE355174C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEC29582D DE355174C (en) 1920-08-24 1920-08-24 Process for the preparation of resinous products from nuclear methylated phenols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEC29582D DE355174C (en) 1920-08-24 1920-08-24 Process for the preparation of resinous products from nuclear methylated phenols

Publications (1)

Publication Number Publication Date
DE355174C true DE355174C (en) 1922-06-21

Family

ID=7019024

Family Applications (1)

Application Number Title Priority Date Filing Date
DEC29582D Expired DE355174C (en) 1920-08-24 1920-08-24 Process for the preparation of resinous products from nuclear methylated phenols

Country Status (1)

Country Link
DE (1) DE355174C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3025264A (en) * 1959-05-20 1962-03-13 Kenneth R Lind Resin production

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3025264A (en) * 1959-05-20 1962-03-13 Kenneth R Lind Resin production

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