DE3470416D1 - An oxidation process for the manufacture of aryl esters - Google Patents

An oxidation process for the manufacture of aryl esters

Info

Publication number
DE3470416D1
DE3470416D1 DE8484105213T DE3470416T DE3470416D1 DE 3470416 D1 DE3470416 D1 DE 3470416D1 DE 8484105213 T DE8484105213 T DE 8484105213T DE 3470416 T DE3470416 T DE 3470416T DE 3470416 D1 DE3470416 D1 DE 3470416D1
Authority
DE
Germany
Prior art keywords
manufacture
cpd
oxidation process
mixt
aryl esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8484105213T
Other languages
German (de)
Inventor
Anil B Goel
Peter E Throckmorton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ashland LLC
Original Assignee
Ashland Oil Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ashland Oil Inc filed Critical Ashland Oil Inc
Priority claimed from EP84105213A external-priority patent/EP0160721B1/en
Application granted granted Critical
Publication of DE3470416D1 publication Critical patent/DE3470416D1/en
Expired legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Process comprises contacting a mixt. of an aromatic cpd. selected from benzene, naphthalene, anthracene, phenanthrene, biphenyl and/or terphenyls, a carboxylic acid (1) and molecular O2 in the liq. phase at 100-300 deg. C with a catalyst composed of Pd-, Sb- and Cr or Mn-acetates, and continuously removing water formed in the process from the reaction mixt. as the aryl ester is formed. (1) is pref. R(COOH)n where n=1 or more, R=5-nC hydrocarbon gp., and is esp. dodecane or ocenoic acid. Aromatic cpd. is continuously added to reaction mixt. as the aryl ester is formed. Ni cpd. in catalyst compsn. is pref. nickel acetate.
DE8484105213T 1984-05-08 1984-05-08 An oxidation process for the manufacture of aryl esters Expired DE3470416D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP84105213A EP0160721B1 (en) 1982-11-15 1984-05-08 An oxidation process for the manufacture of aryl esters

Publications (1)

Publication Number Publication Date
DE3470416D1 true DE3470416D1 (en) 1988-05-19

Family

ID=8191929

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8484105213T Expired DE3470416D1 (en) 1984-05-08 1984-05-08 An oxidation process for the manufacture of aryl esters

Country Status (2)

Country Link
AT (1) ATE33490T1 (en)
DE (1) DE3470416D1 (en)

Also Published As

Publication number Publication date
ATE33490T1 (en) 1988-04-15

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