DE346697C - - Google Patents

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Publication number
DE346697C
DE346697C DENDAT346697D DE346697DA DE346697C DE 346697 C DE346697 C DE 346697C DE NDAT346697 D DENDAT346697 D DE NDAT346697D DE 346697D A DE346697D A DE 346697DA DE 346697 C DE346697 C DE 346697C
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DE
Germany
Prior art keywords
oxygen
hydrocarbons
molecular weight
high molecular
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DENDAT346697D
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German (de)
Publication of DE346697C publication Critical patent/DE346697C/de
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00Recovery or refining of mineral waxes, e.g. montan wax

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Verfahren zur Herstellung von wollfett- oder wachsartigen Gemischen. Chlorierte höhere Kohlenwasserstoffe, wie solche aus den höheren Fraktionen des Erdöls und Braunkohlenteers leicht zugänglich sind, werden unter Erhitzen und Durchleiten von Luft oder Sauerstoff oder auch unter Vermischen mit Luft oder Sauerstoff unter Zugabe geringer Mengen von Sauerstoffüberträgern in' ein Gemisch von hochmolekularen Mono- und Dicarbonsäuren sowie von Alkoholen, Aldehyden und Ketonen übergeführt. Dieses Gemisch ist sowohl chemisch als physikalisch dem. Wollfett ähnlich und kann wie dieses ausgedehnte Verwendung finden.Process for the production of wool fat or waxy mixtures. Chlorinated higher hydrocarbons such as those from the higher fractions of the Petroleum and brown coal tar are readily available, are heated and passed through of air or oxygen or by mixing with air or oxygen Adding small amounts of oxygen carriers to a mixture of high molecular weight Mono- and dicarboxylic acids as well as alcohols, aldehydes and ketones. This mixture is both chemically and physically dem. Similar to wool grease and can how this find widespread use.

Z. B. werden 5 kg eines unter Kühlung bei 3o bis 40 ' chlorierten Paraffingatsches, der auf 3oo Teile 7o bis x2o Teile Chlor enthält, nach Zusatz von z Prozent Bleisuperoxyd unter Durchleiten von Sauerstoff bei einer Temperatur von 7o bis z3o ° oxydiert und das Gemisch mit Petroläther extrahiert.For example, 5 kg of one is chlorinated with cooling at 3o to 40 ' Slack wax containing 7o to x2o parts of chlorine to 300 parts, after addition of z percent lead peroxide with the passage of oxygen at one temperature oxidized from 7o to z3o ° and the mixture extracted with petroleum ether.

Der Extraktionsrückstand bildet eine gelbe viskose Masse, die noch einige Prozente Chlor enthalten kann und der die technisch wichtigen Eigenschaften des Wollfetts zukommen. Die Ausbeute beträgt go bis 98 Prozent des angewandten Kohlenwasserstoffs.The extraction residue forms a yellow, viscous mass which may still contain a few percent chlorine and which has the technically important properties of wool fat. The yield is up to 98 percent of the hydrocarbon used.

Benutzt man nur ganz hochmolekulare Kohlenwasserstoffe; so entstehen Massen von wachsartiger Beschaffenheit, und es können aus den Massen hochschmelzende Alkohole isoliert werden, welche auch in den Sinterrückständen gefunden werden. - -"" -"Only very high molecular weight hydrocarbons are used; so arise Masses of a waxy nature, and there can be high-melting points from the masses Alcohols are isolated, which are also found in the sinter residues. - - "" - "

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung von wollfett-oder wachsartigen Gemischen aus hochmolekularen aliphatischen Kohlenwasserstoffen, dadurch gekennzeichnet, daB man die Kohlenwasserstoffe der Chlorierung unterwirft und die chlorierten Produkte mit Luft oder Sauerstoff in Gegenwart. eines Sauerstoffübertx'ägers bei höherer Temperatur behandelt.PATENT CLAIM: Process for the production of wool-fat or waxy Mixtures of high molecular weight aliphatic hydrocarbons, characterized in that that the hydrocarbons are subjected to chlorination and the chlorinated products with air or oxygen in the presence. of an oxygen transmitter at higher Temperature treated.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE765126C (en) * 1940-06-30 1953-03-02 Ruhrchemie Ag Process for the production of high molecular weight fatty acids

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE765126C (en) * 1940-06-30 1953-03-02 Ruhrchemie Ag Process for the production of high molecular weight fatty acids

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