DE3426449A1 - Process for the preparation of surface coating materials and enamel paints based on secondary raw materials (waste materials) and polystyrene foam (Styropor) - Google Patents

Process for the preparation of surface coating materials and enamel paints based on secondary raw materials (waste materials) and polystyrene foam (Styropor)

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Publication number
DE3426449A1
DE3426449A1 DE19843426449 DE3426449A DE3426449A1 DE 3426449 A1 DE3426449 A1 DE 3426449A1 DE 19843426449 DE19843426449 DE 19843426449 DE 3426449 A DE3426449 A DE 3426449A DE 3426449 A1 DE3426449 A1 DE 3426449A1
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DE
Germany
Prior art keywords
materials
surface coating
preparation
enamel paints
styropor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19843426449
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German (de)
Inventor
Leo Dipl.-Ing. 5000 Köln Winetzky
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Individual
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Individual
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Publication date
Application filed by Individual filed Critical Individual
Priority to DE19843426449 priority Critical patent/DE3426449A1/en
Publication of DE3426449A1 publication Critical patent/DE3426449A1/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/06Polystyrene

Abstract

The invention relates to the use of polystyrene foam packaging material which has been thrown away after its use and is suitable for the preparation of surface coating materials and enamel paints. From 1 m<3> of such waste materials, 300-400 kg of surface coating materials or 600-700 kg of enamel paints can be prepared in any paint factory. In the production of polystyrene foam, Porofor is used, which evolves a large amount of nitrogen and forms the foam structure. There is evidence that Styropor is a somewhat plasticised polystyrene which has a thin-walled structure and is highly suitable as a raw material for the preparation of surface coating materials and enamel paints.

Description

EtTfURFEtTfURF

VERFAHREN ZUR HERSTELIUNG VON LACKEN UND EMAILLEFAREEN AUF DER BASIS VO@ SEKUNDÄRROH@STOFFEN (ABFALLSTOFFEN) AUS POROPCLYSTYROL (STYROPOR) Diese Erfirdung gehört zu einem Verfahren zur Verwendung von Verpackungsmaterial aus Poropolystyrol, das nach seiner Verwendung in größeren Mengen in den Müll gelangt und das bisher keine Weiteryerwendung gefunden hat.PROCESS FOR MANUFACTURING LACQUERS AND ENAMELS ON THE BASE VO @ SECONDARY RAW @ MATERIALS (WASTE MATERIALS) MADE FROM POROPCLYSTYROL (STYROPOR) This invention belongs to a method of using packaging material made of poropolystyrene, that ends up in the garbage after its use in larger quantities and that so far found no further use.

Das Verfahren besteht darin, daß unverbrauchte Poropolystyrolabfälle zerkleinert und in einem Lösungsmittel unter Zusatz von Plastifizierurgsmitteln, Teeren, Kautschuken, Pigmenten, Iösungs und Verdünnungsmitteln gelöst werden, wodurch man verschiedene Lackfarbstoffe erhält.The method consists in that unconsumed poropolystyrene waste crushed and in a solvent with the addition of plasticizers, Tars, rubbers, pigments, solvents and thinners are dissolved, whereby different varnish dyes are obtained.

Die auf Poropolystyrolbasis hergestellten Lacke und E@aillefarben gehören zu der Grunde von "flüchtigen Lacken", die erst nach der Verflüchtigung des Lösemittels eine Folie bilden.The varnishes and E @ aille paints made on the basis of poropolystyrene belong to the reason of "volatile paints", which only after the volatilization of the solvent form a film.

Die Poropolystyrollacke haben entsprechend ihr@r Verwendung eine lösung von Polystyrol, Plastifizierungs@itteln, Teeren, Kautschuken in einer Mischung von flichtigen losungs- und Verdünnungsmitteln. Ihrem Aussehen nach sind diese Lacke eine durchsichtige zähe Flüssigkeit mit dem charakteristischen Geruch der verwendeten Lösungs- und Verdünnungsmittel.The poropolystyrene lacquers have a solution according to their use of polystyrene, plasticizers, tars, rubbers in a mixture of volatile solvents and thinners. In terms of their appearance, these varnishes are a transparent viscous liquid with the characteristic smell of the one used Solvents and thinners.

Auf diese Weise gewinnt man aus Poropolystyrolabfällen Lacke und Emaillefarben für Holz, Metall, Leder, Gummi und Lacke für Isolierurgszwecke.In this way, varnishes and enamel paints are obtained from poropolystyrene waste for wood, metal, leather, rubber and paints for insulating purposes.

Der Herstellungsprozess fi?r Poropoivstvrollacke und Poropolystyrolemaillefarben ist unkompliziert und erfordert keine sperrigen und teure Anlagen. Er kann in jeder beliebigen Lackfabrik durchgeführt werden und besteht aus folgenden Vorgängen: 1. Lösung des Poropolystyrols und Erzielung einer 25- bis 30prozentigen Poropolystyrollösung.The manufacturing process for Poropoivstvrollacken and Poropolystyrene enamel paints is straightforward and does not require bulky and expensive equipment. He can be in everyone any paint factory and consists of the following operations: 1. Dissolving the poropolystyrene and obtaining a 25 to 30 percent poropolystyrene solution.

?. Mischung der Poropolystyrollösung mit Plastifizierungs mitteln, Teeren, Kautschuken, Pigmenten mit Verdünnungsmitteln entsprechend der Bestimmung des Lackes und der Emaille und gemäß den ausgearbeiteter und erprobten Rezepturen.?. Mixing the poropolystyrene solution with plasticizers, Tars, rubbers, pigments with diluents as specified of the lacquer and the enamel and according to the elaborated and tested recipes.

3. Reinigung der Lacke und Emaillefarber. und Typenbestimmung.3. Cleaning of varnishes and enamel paints. and type determination.

4. Verpackung nach bestimmtem Gewicht. 4. Packing according to a certain weight.

In der Technolog@scher Schema zur Herstellung von lacken und Emaillefarben wird verwendet Reaktor, fur erhalten verschiedene Regime (günstuge Bedingungen von Temperaturen) für dem Prozeß für auflösen von Poropolystyrol mit verschiedenartige Sösungsmitteln. Es ist in Betracht voraussehen ausnutzen dem Reaktor für @lastifizieren von Polystyrol mit hilfe Lösungen von Kautschuk. Es ist bekannt, daß Plastifizierung. von Pölystyrol mit Nitrilkautschuk wird durgeführt auf Walzmaschinen bei einem großen Wärmegrad.Bei Produktion Poropolyst@irol. Polystyrol wird gemischt mit Porofor wird bearbeittet bei 150°und Druck 250-300 kg/in mit eine große menge entwickelten Stickstoff. Gruppe@-C# N Besitzt eine proBe Reaktionskraft. @s gibt Beweise daß Styropor i@t etwas Plastifizierter Polystyrol,welcher eine dünnwandige Struktur has und ist seher gut- taugt als Rohstoff für Herstellung von Lacken und Emaillenfarben.In the Technolog @ scher scheme for the production of varnishes and enamel colors is used reactor, for obtaining various regimes (favorable conditions of Temperatures) for the process of dissolving poropolystyrene with various types Solvents. Consider using the reactor for plasticizing of polystyrene with the help of solutions of rubber. It is known that plasticizing. Polystyrene with nitrile rubber is carried out on rolling machines at a large During production Poropolyst @ irol. Polystyrene is mixed with Porofor processed at 150 ° and pressure 250-300 kg / in with a large amount of evolved nitrogen. Group @ -C # N Has a proBe reaction force. @ there is evidence that styrofoam i @ t some plasticized polystyrene, which has and is very thin-walled structure Well-suited as a raw material for the manufacture of lacquers and enamel paints.

ZUM BEISPIELSCHEMA FÜR DIE HERSTELLUNG VON LACKEN UND EMAILIE-FARBEN UNTER VERWENDUNG VON POROPOLYSTYROLABFÄLLEN Das Lösungsmittel gelangt aus Tank 1 durch inerten Gasdruck in den Meßbehälter 2, aus dem es selbstfließend in den Reaktor 3 fließt 7ur Auflösung der Poropolystyrolabfälle.FOR EXAMPLE SCHEME FOR THE PRODUCTION OF LACQUERS AND ENAMEL PAINTS USING POROPOLYSTYRENE WASTE The solvent leaks from tank 1 by inert gas pressure in the measuring container 2, from which it flows into the reactor 3 flows to dissolve the poropolystyrene waste.

Vorher wird der Reaktor mit einer bestimmter Menge von Poropolystyrolabfällen beladen, damit man als Grund rohstoff eine 25- bis 3Oprozentige Poropolystyrollösung erhält.Before that, the reactor is filled with a certain amount of poropolystyrene waste loaded so that the basic raw material is a 25 to 30 percent poropolystyrene solution receives.

Als Lösungsmittel verwenden wir Dichlormethan oder auch andere Lösungsmittel, weil das Poropolystyrol eie dinnwandige Struktur hat und leicht aufgelöst werden kann.We use dichloromethane or other solvents as solvents, because the poropolystyrene has a thin-walled structure and is easily dissolved can.

Als Apparat zum Auflösen des Poropolystyrols verwenden wir eiren Standardreaktor mit großem Fassungsvermögen, da 1 1 Poropolystyrol ca. 35 g wiegt, um die Intensivierung des Prozesses, die Auflösung, eine geringe Erwärmurg, eie intensivierte Vermischung und eine Hermetisierung des Prozesses duchfiihren zu können. Aus dem Reaktor 3 gelangt das Lösungsmittel in das Rührwerk 4, wo das Plastifizierungsittel und andere Stoffe gemäß der Reeptur zugefügt werden.We use a standard reactor as the apparatus for dissolving the poropolystyrene With a large capacity, since 1 1 poropolystyrene weighs approx. 35 g to intensify of the process, the dissolution, a little heating, an intensified mixing and to be able to hermetize the process. Comes out of reactor 3 the solvent in the agitator 4, where the plasticizer and other substances can be added according to the recipe.

Nach der Mischung aller Ingre@ientien wird der erhaltene Lack in der Superzentrifuge 5 zur Reinigung zentrifugiert und gelangt anschließend in den Tank6 für den fertigen Lack, von wo aus er mit der Pumpe 7 auf Lager 13 gebracht wird. Für die Herstellung von Emaillefarben gelangt er in den Meßbe@älter 8. Aus dem Meßbehälter flieht der Lack selbstfließend in das Rührwerk 9, wo die Vermischung mit Farbpaste erfolgt. Die Farbpaste wird in einer besonderen Abteilung, in Kugelmühlen vorbereitet, wo die Verreibung der Pig@ente mit dem Plastifizierungsmittel vorgerommen wird. Aus den Rührwerk 9 wird die erhaltene E@aillefarbe in der Superzentrifuge 10 zentrifugiert und gelargt dann in den Tank 11, von wo aus sie mit der Pumpe 12 in die Tanks 13 für einfarbige Emaille @epumpt wird. Nach der Lagerurg und der Qualitätskontrolle gelargen die Lacke und Emaillefarben zu der WaaFe 14 und der Abfüllung 15.After all the ingredients have been mixed, the varnish obtained is in the Supercentrifuge 5 is centrifuged for cleaning and then enters tank 6 for the finished paint, from where it is brought to storage 13 with the pump 7. For the production of enamel paints, it goes into the measuring container older than 8. From the measuring container the lacquer escapes self-flowing into the agitator 9, where it is mixed with color paste he follows. The color paste is prepared in a special department, in ball mills, where the trituration of the pig @ duck with the plasticizer is carried out. The E @ aille color obtained is centrifuged in the supercentrifuge 10 from the agitator 9 and then stored in the tank 11, from where they are transferred to the tank 13 with the pump 12 for monochrome enamel is @pumped. After the warehouse and quality control The lacquers and enamel colors are stored in WaaFe 14 and bottling 15.

Claims (1)

Patentanspruch.Claim. Verfahren zur Herstellung von Lacken und @maillefarben dadurch gekehnzeichen daß Poropolystyrol (Abfallstoffen) fur die Produktion von Lacken und Emaillefarben ve@wendet wird.Process for the production of lacquers and @maillefarben thereby kehnzeichen that poropolystyrene (waste materials) for the production of varnishes and enamel paints ve @ is applied.
DE19843426449 1984-07-18 1984-07-18 Process for the preparation of surface coating materials and enamel paints based on secondary raw materials (waste materials) and polystyrene foam (Styropor) Withdrawn DE3426449A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19843426449 DE3426449A1 (en) 1984-07-18 1984-07-18 Process for the preparation of surface coating materials and enamel paints based on secondary raw materials (waste materials) and polystyrene foam (Styropor)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19843426449 DE3426449A1 (en) 1984-07-18 1984-07-18 Process for the preparation of surface coating materials and enamel paints based on secondary raw materials (waste materials) and polystyrene foam (Styropor)

Publications (1)

Publication Number Publication Date
DE3426449A1 true DE3426449A1 (en) 1985-10-17

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DE19843426449 Withdrawn DE3426449A1 (en) 1984-07-18 1984-07-18 Process for the preparation of surface coating materials and enamel paints based on secondary raw materials (waste materials) and polystyrene foam (Styropor)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4119930A1 (en) * 1991-06-17 1992-12-24 Franz Xaver Appel Waste foamed polystyrene recovery by dissolving in a solvent - using appts. including means to convey polystyrene from upper container into lower, airtight-closable, solvent container
DE4307677A1 (en) * 1993-03-11 1994-09-15 Jung Reiner Process for the recycling of polystyrene foam scrap
DE10328312A1 (en) * 2003-06-23 2005-01-27 Kröner, Romeo Polystyrene scrap or packaging is recovered and processed to give lacquers or adhesives for bonding plastics by first dissolving the scrap in an organic solvent
WO2018127755A1 (en) 2017-01-04 2018-07-12 Acuna Rougier Cristina Lucia Process for fabrication of paints based on expanded polystyrene (eps) waste

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4119930A1 (en) * 1991-06-17 1992-12-24 Franz Xaver Appel Waste foamed polystyrene recovery by dissolving in a solvent - using appts. including means to convey polystyrene from upper container into lower, airtight-closable, solvent container
DE4307677A1 (en) * 1993-03-11 1994-09-15 Jung Reiner Process for the recycling of polystyrene foam scrap
DE10328312A1 (en) * 2003-06-23 2005-01-27 Kröner, Romeo Polystyrene scrap or packaging is recovered and processed to give lacquers or adhesives for bonding plastics by first dissolving the scrap in an organic solvent
WO2018127755A1 (en) 2017-01-04 2018-07-12 Acuna Rougier Cristina Lucia Process for fabrication of paints based on expanded polystyrene (eps) waste

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