DE3345881A1 - Kontinuierliches verfahren zum extrahieren von wasser und kohlenwasserstoffen mit hoeherem molekulargewicht als methan mittels eines physikalischen loesungsmittels aus einem naturgas - Google Patents
Kontinuierliches verfahren zum extrahieren von wasser und kohlenwasserstoffen mit hoeherem molekulargewicht als methan mittels eines physikalischen loesungsmittels aus einem naturgasInfo
- Publication number
- DE3345881A1 DE3345881A1 DE19833345881 DE3345881A DE3345881A1 DE 3345881 A1 DE3345881 A1 DE 3345881A1 DE 19833345881 DE19833345881 DE 19833345881 DE 3345881 A DE3345881 A DE 3345881A DE 3345881 A1 DE3345881 A1 DE 3345881A1
- Authority
- DE
- Germany
- Prior art keywords
- stream
- natural gas
- solvent
- hydrocarbons
- stage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims description 351
- 229930195733 hydrocarbon Natural products 0.000 title claims description 187
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 175
- 239000003345 natural gas Substances 0.000 title claims description 119
- 239000002904 solvent Substances 0.000 title claims description 116
- 238000000605 extraction Methods 0.000 title claims description 109
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 41
- 238000011437 continuous method Methods 0.000 title 1
- 239000000047 product Substances 0.000 claims description 112
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 110
- 238000000034 method Methods 0.000 claims description 87
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 82
- 239000007788 liquid Substances 0.000 claims description 72
- 239000007789 gas Substances 0.000 claims description 65
- 239000004215 Carbon black (E152) Substances 0.000 claims description 63
- 239000001294 propane Substances 0.000 claims description 55
- 239000000203 mixture Substances 0.000 claims description 51
- 230000008569 process Effects 0.000 claims description 37
- 238000000926 separation method Methods 0.000 claims description 28
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 26
- 230000002378 acidificating effect Effects 0.000 claims description 19
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 18
- 239000012263 liquid product Substances 0.000 claims description 18
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 17
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 230000008929 regeneration Effects 0.000 claims description 14
- 238000011069 regeneration method Methods 0.000 claims description 14
- 239000000284 extract Substances 0.000 claims description 7
- 230000001105 regulatory effect Effects 0.000 claims description 7
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- 239000001273 butane Substances 0.000 claims description 6
- 235000009508 confectionery Nutrition 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 6
- 230000003247 decreasing effect Effects 0.000 claims description 5
- 238000011068 loading method Methods 0.000 claims description 5
- -1 tetramethyl sulfone Chemical class 0.000 claims description 5
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 239000006227 byproduct Substances 0.000 claims description 3
- 235000013773 glyceryl triacetate Nutrition 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 3
- 229960002622 triacetin Drugs 0.000 claims description 3
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 150000001983 dialkylethers Chemical class 0.000 claims description 2
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 2
- 239000002912 waste gas Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 229930014626 natural product Natural products 0.000 claims 1
- 235000013844 butane Nutrition 0.000 description 19
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 18
- 239000000446 fuel Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 10
- 238000001816 cooling Methods 0.000 description 9
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 9
- 238000010521 absorption reaction Methods 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 5
- 235000013847 iso-butane Nutrition 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 238000011144 upstream manufacturing Methods 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 4
- 239000001282 iso-butane Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000013022 venting Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 238000000384 X-ray magnetic circular dichroism spectroscopy Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- SFROHDSJNZWBTF-UHFFFAOYSA-N butane;ethane;propane Chemical compound CC.CCC.CCCC SFROHDSJNZWBTF-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- BPHQZTVXXXJVHI-UHFFFAOYSA-N dimyristoyl phosphatidylglycerol Chemical compound CCCCCCCCCCCCCC(=O)OCC(COP(O)(=O)OCC(O)CO)OC(=O)CCCCCCCCCCCCC BPHQZTVXXXJVHI-UHFFFAOYSA-N 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G5/00—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
- C10G5/04—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas with liquid absorbents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/11—Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1025—Natural gas
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Separation By Low-Temperature Treatments (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/507,564 US4511381A (en) | 1982-05-03 | 1983-06-24 | Process for extracting natural gas liquids from natural gas streams with physical solvents |
| US06/532,005 US4526594A (en) | 1982-05-03 | 1983-09-14 | Process for flexibly rejecting selected components obtained from natural gas streams |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3345881A1 true DE3345881A1 (de) | 1985-01-03 |
| DE3345881C2 DE3345881C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1988-02-25 |
Family
ID=27055892
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19833345881 Granted DE3345881A1 (de) | 1983-06-24 | 1983-12-19 | Kontinuierliches verfahren zum extrahieren von wasser und kohlenwasserstoffen mit hoeherem molekulargewicht als methan mittels eines physikalischen loesungsmittels aus einem naturgas |
Country Status (5)
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4743282A (en) * | 1982-05-03 | 1988-05-10 | Advanced Extraction Technologies, Inc. | Selective processing of gases containing olefins by the mehra process |
| WO1987000518A1 (en) * | 1985-07-26 | 1987-01-29 | El Paso Hydrocarbons Company | Processing inert-rich natural gas streams |
| AU6187886A (en) * | 1985-10-04 | 1987-04-16 | Advanced Extraction Technologies Inc. | Conditioning natural gas with preferential physical solvents |
| AU6284086A (en) * | 1985-10-04 | 1987-04-24 | Advanced Extraction Technologies Inc. | Selective processing of gases containing olefins by the mehra process |
| JPS63502584A (ja) * | 1985-10-04 | 1988-09-29 | アドヴアンストウ イクストラクシヨン テクノロジ−ズ インコ−ポレ−テド | メ−ラ法によるオレフィン類含有ガスの選択的処理 |
| FR2618876B1 (fr) * | 1987-07-30 | 1989-10-27 | Inst Francais Du Petrole | Procede de traitement et de transport d'un gaz contenant du methane et de l'eau |
| FR2641542B1 (fr) * | 1988-11-15 | 1994-06-24 | Elf Aquitaine | Procede de decarbonatation et de degazolinage simultanes d'un melange gazeux constitue principalement d'hydrocarbures consistant en methane et hydrocarbures en c2 et plus et renfermant egalement co2 |
| FR2740468B1 (fr) * | 1995-10-27 | 1997-12-12 | Inst Francais Du Petrole | Procede de sechage de gaz au glycol incluant la purification des rejets gazeux |
| DE60336752D1 (de) * | 2002-12-12 | 2011-05-26 | Fluor Corp | Verfahren zur enfernung von saurem gas |
| DE60310073T2 (de) * | 2003-09-09 | 2007-04-05 | A.S. Trust & Holdings Inc. | Kohlenwasserstoffzusammensetzung sowie Kühl- und Waschmittel, die diese enthalten |
| CA2756142C (en) | 2009-03-25 | 2014-05-13 | Fluor Technologies Corporation | Improved configurations and methods for high pressure acid gas removal |
| CN114717031A (zh) * | 2021-01-05 | 2022-07-08 | 中国石油化工股份有限公司 | 一种低温混合溶剂脱出天然气中氮气的方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3770622A (en) * | 1970-12-28 | 1973-11-06 | Fluor Corp | Treatment of wet natural gas mixtures to recover liquid hydrocarbons |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3664091A (en) * | 1969-06-27 | 1972-05-23 | Fish Engineering & Constructio | Process and system for removing acid gas from natural gas |
| DE2828498A1 (de) * | 1978-06-29 | 1980-01-17 | Linde Ag | Verfahren und vorrichtung zur zerlegung eines gasgemisches |
| US4252548A (en) * | 1979-01-02 | 1981-02-24 | Kryos Energy Inc. | Carbon dioxide removal from methane-containing gases |
| US4421535A (en) * | 1982-05-03 | 1983-12-20 | El Paso Hydrocarbons Company | Process for recovery of natural gas liquids from a sweetened natural gas stream |
-
1983
- 1983-12-12 CA CA000443043A patent/CA1215217A/en not_active Expired
- 1983-12-16 GB GB08333501A patent/GB2142041B/en not_active Expired
- 1983-12-19 IT IT49541/83A patent/IT1172382B/it active
- 1983-12-19 FR FR8320335A patent/FR2547810B1/fr not_active Expired
- 1983-12-19 DE DE19833345881 patent/DE3345881A1/de active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3770622A (en) * | 1970-12-28 | 1973-11-06 | Fluor Corp | Treatment of wet natural gas mixtures to recover liquid hydrocarbons |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2142041A (en) | 1985-01-09 |
| GB2142041B (en) | 1987-10-07 |
| FR2547810B1 (fr) | 1987-05-22 |
| IT1172382B (it) | 1987-06-18 |
| FR2547810A1 (fr) | 1984-12-28 |
| CA1215217A (en) | 1986-12-16 |
| IT8349541A0 (it) | 1983-12-19 |
| GB8333501D0 (en) | 1984-01-25 |
| DE3345881C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1988-02-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8127 | New person/name/address of the applicant |
Owner name: ADVANCED EXTRACTION TECHNOLOGIES, INC., HOUSTON, T |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |