DE3226498A1 - Novel pesticidal compositions, processes for their preparation, and their use - Google Patents

Abstract

The present invention relates to novel pesticidal compositions and to processes for their preparation, these compositions consisting of one or more insecticidal active substances and one or more alkyl phosphates of the general formula I <IMAGE> besides conventional carriers, diluents, solvents and/or other inert auxiliaries.

Description

Title: New Pesticide Compositions,

Method of making and using it Description The invention relates to the subject matter set out in Addresses 1-48.

To reduce crop losses in crop cultivation due to weeds, Weeds, eating and sucking insects, fungi, mites, spider mites, nematodes and other pests can be seen today on the use of chemical pesticides (Pesticides) no longer do without.

A large number of chemical has been used to combat pests Substances enforced.

There are a few pesticides in use Problems still unsolved. The pesticides often need to be in high concentrations are used and can thus become toxic to the environment.

The most important requirements for a pesticide are one possible high selectivity and activity against the pests, as low as possible Activity towards the useful plants as well as the least possible interference with them biological environment.

There are therefore high demands on the selectivity of a pesticide posed. In order to reduce the burden on the environment, the amount of pesticide should be used the per hectare to control the pests is needed, if possible can be kept low, which, however, often leads to a loss of activity.

Another requirement is the ease of use with both the production as well as the application.

It has now surprisingly been found that the amount of pesticide required to control pests (weeds, grass weeds, insects, fungi, etc.) per hectare of cultivated area can be reduced by up to 40-60%, in some cases by up to 80% , if one of the pesticide active ingredients or the mixture of several pesticide active ingredients is an alkyl phosphate of the general formula 1 where R1 = -CH2NH3 + or -CH2N + (CH3) 3 and either R2 = -CH2OR4 and R3 = -CH2OR5 or R2 = -CH (OR4) CH20R5 and R3 = H and for both possibilities R4 and R5> the same or different can be, a straight-chain or branched, saturated or unsaturated alkyl or acyl group with 3-22 carbon atoms, preferably 12-18 carbon atoms, or a mixture of several such alkyl phosphates of the general formula I in a weight ratio of 1: 0.2 to 1:20 admits and this without damaging or impairing the useful plants.

The alkyl phosphates of the general formula 1 are known compounds which, for example, according to conventional methods (H.Eibl, in Research Monographs in Cell and Tissue Physiology, Vol. 7, Pages 19-50) can be obtained. The connections of the general formula I themselves show no effectiveness and no toxicity in warm-blooded animals.

The new pesticide compositions have great economy in addition to the advantage of the treatment that the degradation, especially in the useful plants, is accelerated and there are no more pesticide residues in the crops during harvest available. Quick dismantling can also shorten waiting times.

In addition, the new pesticidal compositions show an essential feature better adhesion to the plants or stored goods to be protected.

The addition of the alkyl phosphates will continue to absorb the Pesticide accelerated by the pests, so that also protect the plants the amount of pesticide required can be significantly reduced.

To produce the new pesticide compositions, the pesticides with one or more of the alkyl phosphates of the general formula 1 in a weight ratio 1: 0.2 to 1:20, preferably 1: 0.5 to 1:10, but especially in a weight ratio 1: 1 to 1: 5, mixed.

The following compounds are particularly suitable as alkyl phosphates of the general formula I: 1. Alkyl phosphates of the general formula I where R1 R1 '= CH2-N (CH3) 3 R2 = -CH (OR4) -CH2-0R5 R3 = H R4, R5 = identical or different, denotes a straight-chain or branched, saturated or unsaturated acyl group with 3-22 carbon atoms, such as, for example: 4-hydroxy-N, N, N-trimethyl-10 * oxo-7-tl-oxobutoxy) -3,5,9-trioxa-4-phosphadecane-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxoheptyl) -oxy] -3,5,9-trioxa-4-phosphahexadecane-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-10-oxo-7- [1-oxononyl) -oxy] -3,5,9-trioxa-4-phosphaoctadecane-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-10-oxo-7-n (1-oxododecyl) -oxsyS-3,5,9-trioxa-4-phosphaheneicosane-1-ammonium hydroxide-4-oxide; 4-Hydroxy-N, N, N-trimethyl-10-oxo-7-r (1-oxotetradecyl) -oxyS-3,5,9-trioxa-4-phosphatricosane-1-ammonium hydroxide 4-oxide; 4-Hydroxy-N, N * N-trimethyl -IO-oxo-7-W (1-oxohexadecyl) -oxy7-3,5,9-trioxa-4-phosphapentacosan-1-ammonium hydroxide-4-oxide; 4-Hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxooctadecy) -oxyJ-3,5,9-trioxa-4 »phosphapentacosan-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxodocosyl) -oxy] -3,5,9-trioxa-4-phosphahene triacontane-1-ammonium hydroxide-4-oxide; 4-Hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxo-9-octadecenyl) -oxy] -3,5,9-trioxa-4-phosphaheptacos-18-en-1- ammonium hydroxide-4-oxide; 4-Hydroxy-N, N, N-trimethyl-10-oxo-7- [1-oxo-9-hexadecenyl) -oxy] -3,5,9-trioxa-4-phosphapentacos-18-en-1-ammonium hydroxide -4-oxide; 4-Hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxo-11-octadecenyl) -oxyI-3,5,9-trioxa-4-phosphaheptacos-20-en-1-ammonium hydroxide -4-oxide; 4-Hydroxy-NsN, N-trimethyl-10-oxo-7-r (1-oxo-9,12-heptadecadienyl) -oxy] -3,5,9-trioxa-4-phosphahexacosa-18,21-diene- 1-ammonium hydroxide-4-oxide; 4-Hydroxy-N, NsN-trimethyte-10-oxo-7 "o-xo-16-octadecenyl) -oxy) -3,5 * 9-trioxa-4-phosphaheptacos-25-en-1-ammonium hydroxide-4- oxide; 4-hydroxy-N, N, N-trimethyl-10-oxo-7 oxo-9,12-octadecadienyl) -oxy] -3,5,9-trioxa-4-phosphaheptacos-18-en-1 ammonium hydroxide 4-oxide; 4-hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxo-9-octadecenyl) -oxyJ-3,5,9-trioxa-4-phosphaheptacos-18-en -1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-10-oxo-7-f (1-oxo-9-tetradecenyl) -oxy7-3,5,9-trioxa-4- phosphatricos-18-en-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-10-oxo-7-l «(l-oxo-11-eicosenyl) -oxyS-3,5s9- trioxa-4-phosphanoacos-20-en-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, NtN-trimethyl-10-oxo-7-f (1-oxo-5, a, 11,14-octadecatetraenyl) -oxy] -3,5,9-trioxa-4-phosphaheptacosa-14, 17, 20, 23-tetraene-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-10-oxo -7 - [(1-oxo-9,12-octadecadienyl) -oxy-3,5t9-trioxa-4-phosphaheptacosa-18, 21-diene-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-10-oxo-7-r. (1-oxo-9-hexadecenyl) -oxyl-3, 5,9-trioxa-4-phosphapentacos en-1-ammonium hydroxide-4-oxide; 4-Hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxohexadecyl) -oxyI-3,5,9-trioxa-4-phosphaheptacosa-18,21-diene-1-ammonium hydroxide-4 -oxide; 4-Hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxo-9-hexadecenyl) -oxyl-3,5,9-trioxa-4-phosphapentacos-18-en-1-ammonium hydroxide -4-oxide; 4-Hydroxy-N, N, N-trimethyl-10-oxo-7-r (1-oxooctadecyl) -oxyl-3,5,9-trioxa-4-phosphaheptacos-18-en-1-ammonium hydroxide-4-oxide ; 4-hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxohexadecyl) -oxyl-3,5s9-trioxa-4-phosphaheptacosane-1-ammonium hydroxide 4-ox4d; 4-Hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxo-6-octadecenyl) oxy'7-3,5,9-tri oxa-4-phosphaheptacosan-1-ammonium hydroxide-4 -oxide; 4-Hydroxy-N, N, N, 25-tetramethyl-7-tt16-methyl-1-oxoheptadecyl) -oxy / -10-oxo-3,5,9-trioxa-4-phosphahexacosanv 1-ammonium hydroxide-4-oxide ; 4-Hydroxy- N, N, N, 1,2,16,20,24, -heptamethyl-1-oxo-7 - [(3,7,11,15-tetramethyl-1-oxohexadecyl) -oxy] -3 , 5,9 trioxa-4-phosphapentacosan-1-ammonium hydroxide-4-oxide; 2. Alkyl phosphates of the general formula I where R1 = -CH2N + (CH3) 3 R2 = -CH (OR4) -CH2-OR5 R3 = H R4 = saturated or unsaturated alkyl group with 3-22, especially 10-18 carbon atoms R5 = saturated or unsaturated acyl group with 3.22, in particular denotes 12-18 carbon atoms, such as, for example: 4-hydroxy-N, N, N-trimethyl-7 - [(1-oxadecyl) -oxy] -3,5,9-trioxa-4-phosphapentacosan-1- ammonium hydroxide-4-oxide; 4-Hydroxy-N, N, N-trTmethyl-7-D (1-oxododecYl) -oxvvl-3,5,9-trioxa-4-phosphaheptacos-18-en-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-7 - [(1-oxooctadecyl) oxy] -3,5,9-trioxa-4-phosphaheptacosane-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-7 - [(1-oxooctadecyl) -oxy] -3,5,9-trioxa-4-phosphaheptacos-18-en-1-ammonium hydroxide-4-oxide; 3. Alkyl phosphates of the general formula I. where R1 = CH2N + (CH3) 3 R2 = -CH (O4) -CH2-OR5 R3 = H R4, R5 = saturated or unsaturated alkyl group with 3-22, especially 12-18, carbon atoms such as: 4-hydroxy-N, N, N-trimethyl-7- (9-octadecenyloxy) -3,5,9-trioxa-4-phosphaheptacos 18-en-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-7- (hexadecyloxy) -3,5,9-trioxa-4-phosphapentacosane-1-ammonium hydroxide-4-oxide; 4-hydroxy-N * N, N-trimethyl-7- (octadecyloxy) -3,5,9-trioxa-4-phosphaheptacosane-1-ammonium hydroxide-4-oxide; 4-hydroxy-N, N, N-trimethyl-7- (9,12-octadecadienyloxy) -3,5,9-trioxa-4-phosphaheptacosa-18,21-diene-1-ammonium hydroxide-4-oxide; 4. Alkyl phosphates of the general formula 1 where R1 = CH2N (CH3) 3 R2 = -CH (OR4) -CH2OR5 R3 = H R4 = saturated or unsaturated alkyl group with 3-22, especially 12-18, carbon atoms R5 = saturated or unsaturated acyl group with 3-22, especially 12 -18, carbon atoms such as: 4-Hydroxy-N, N, N-trimethyl-7- (hexylxy) -10-oxo-3,5,9-trioxa-4-phosphapentadecane-1-ammonium hydroxide-4- oxide; 4-hydroxy-N, N, N-trimethyl-7- (hexadecyloxy) -10-oxo-3,5,9-trioxa-4-phosphaheptacos-18-en-1-ammonium hydroxide-4-oxide; 5. Alkyl phosphates of the general formula I. where R1 = -CHzNH36 R2 = -CH (OR4) -CH20R5 R3 = H R4, R5 = identical or different, saturated or unsaturated alkyl or acyl group with 3-22 carbon atoms, in particular acyl group with 16-18 carbon atoms such as

1- '(C (2-Aminoethoxy) hydroxyphosphinyi) oxy) methyl-1,2-ethanediyl ester with hexadecanecarboxylic acid or octadecanecarboxylic acid, linoleic acid, linolenic acid, palmitic acid, Ulic acid and the like.

6. Alkyl phosphates of the general formula I. where R1 = -CH2NH3 + or -CH2N + (CH3) 3 R2 - CH2OR4 R3 = CH20R5 R4, R5 = identical or different, saturated or unsaturated alkyl or acyl group with 3-22 carbon atoms, especially acyl groups with 16-18 carbon atoms such as

4-hydroxy-N, N, N-trimethyl-9-oxo-6 - [(1-oxoheptyl) -oxy] -3,5,9-trioxa-4-phosphahexadecane-1-ammonium hydroxide-4-oxide; 4-Hydroxy-N, N, N-trimethyl-9-oxo-6 - [((1-oxohexadecyl) -oxy) methyl] -3,5,8-trioxa-4-phosphatetracosane-1-ammonium hydroxide-4-oxide ; 4-hydroxy-9-oxo-7 - [((1-oxohexadecyl) oxy) methyl) ff-3,5,8-trioxa-4-phosphatetracosane-1-ammonium hydroxide-4-oxide; 4-HydroxytN, N, N-trmethyl-9-oxo-6-r ((lo) -oxy) -methyl) g-3,5,8-trioxa-4 * phosphatetr-acos-17-en-1-ammonium hydroxide -4-oxide; 4-Hydroxy-9-oxo-6 - [((1-oxo-9-hexadecenyl) oxy) methyl)] - 3,5,8-trioxa-4-phosphatetracos-17-en-1-ammonium hydroxide-4 -oxide.

Alkyl phosphates of the general formula I are particularly preferred where R1 = -CH2NH3 or -CH2N + (CH3) 3 R2 = -CH (OR4) -CH2OR5 R3 = H or R1 = -CH2NH3 + or -CH2-N + (CH3) 3 R2 = -CH2OR4 R3 = -CH20R5 where R4 = R5 = are the same, a saturated or unsaturated acyl group of C14-C22, in particular C16-C18 carbon atoms, such as the following acyl radicals: CH3 (CH2) nCO-, where n = an integer from 12-20 indicates, or 0 /1 CH, (CII, I. - (CH = CHCH,) (CH 2) m'C-, where m = an integer from 1-9 and o = an integer from 1-4, such as acyl residues of the following fatty acids: myristic, palmitic, stearic, arachine, behen, palmit, oil, linoleum , Linolenic or arachidonic acid, in particular palmitic, oil or linolenic acid and mixtures of these alkyl phosphates.

In particular, herbicides, insecticides, fungicides, Acaricides or nematicides into consideration.

As a herbicide; virtually any herbicide can be used. Compounds from the group of photosynthesis inhibitors, respiratory inhibitors, the growth substances, the Milose inhibitor and the germ inhibitor in question.

Particularly suitable examples are: 1. Phenoxycarboxylic acid derivatives of the general formula I in which a) R1, R2 and R3, which can be the same or different from one another, = H, CH3 or halogen, in particular chlorine, but with a maximum of two radicals being H, R4 - H or CH3 n = 0-2, Y = 0 or SX = O, NH or S R5, when X = 0, = H, straight-chain or branched C1-12-alkyl, hydroxyalkyl, such as hydroxyethyl, or alkali or alkaline earth cations and, in particular, ammonium cations, ie salts of the acids with Ammcniak or organic amines, such as, for example, hydroxyethylamine or trihydroxyethylamine, or R5, when X = NH, = H, NH2, optionally phenyl inhibited by 1-3 halogen atoms, heterocyclic groups, such as, for example, 2-thiazolyl, or b) R1 and R3 = R4 and R5 have the same meaning as in a), R6 = CH3> halogen or trifluoromethyl and m = 1-3; The substances are known compounds as described in the following patents: US Pat. No. 3,352,897, US Pat. No. 2,390,942, DE-PS 915 876, DE-AS 1 115 515, FR-PS 1 222 916, GB -PS 8 22 199, GB-PS 57 34 77, DE-AS 11 24 296, GB-PS 10 41 982, CA-PS 570 065, US-PS 30 76 025.

Examples of compounds of general formula I are: 4-chloro-phenoxyacetic acid-N, O-methylamide, 2,4-dichlorophenoxyacetic acid, 2,4-dichlorophenoxyacetic acid hydrazide, 2-methyl-4-chlorophenoxyacetic acid hydrazide, 2-chloro-4-fluorophenoxyacetic acid, 2-chloro-4-fluorophenoxyacetic acid butyl ester, 4-chloro-2-methyl-phenoxyacetic acid, 4-chloro-2-methyl-phenoxythioacetic acid, N- (2-chlorophenyl) -4-chloro-2-methyl-phenoxyacetic acid amide, N- (3-trifluoromethylphenyl) -2,4-dimethyl-phenoxyacetic acid amide, 2,4-dimethylphenoxyessi gic acid, 2,4,5-trichlorophenoxyacetic acid, 2- (4-chlorophenoxy) propionic acid, 2- (2-methylphenoxy) propionic acid, 2- (2-methyl-4-chlorophenoxy) propionic acid (mecoprop) 2- (2-methyl-4-chlorophenoxy) propionic acid N- (trifluoromethylphenyl ) amide, 2- (2,4,5-trichlorophenoxy) propionic acid (fenoprop).

2- [4- (2,4-dichlorophenoxy) phenox] propionic acid, 2- [4- (4-chlorophenoxy) phenoxy] propionic acid, 4- (4-chlorophenoxy) butyric acid, 4- (4- chloro-2-methylphenoxy) butyric acid (MCPB), 4- (2,4,5-trichlorophenoxy) -butyric acid, but in particular 2,4-dichlorophenoxyessi Acid (2,4-D) and their salts and esters, such as the sodium or ammonium salt or Salts with ethanolamine or triethanolamine, 2,4,5-trichlorophenoxyacetic acid (2,4,5-triphenac) as well as their salts and esters, which after combination with one Alkyl phosphate especially as a selective foliar herbicide for combating dicotyledons Weeds such as knotweed, chamomile and thistle in cereals, maize, rice, Let sugar cane or grassland put in.

2. Urea derivatives of the general formula II in which R1, R2 = H, straight-chain or branched C1 4-alkyl, cycloalkyl, halogen, in particular chlorine, trifluoromethyl, nitro, alkoxy, optionally phenoxy substituted by halogen, where at most one of the groups Ri and R2 are H, R3 H, CH3 C2H5, R4 = H, cycloalkyl, C1 4 -alkyl, methoxy.

The compounds of general formula II are known compounds as described in the following patents: U.S. Patent 2 655 447, DE-PS 935 165, DE-PS 951 181, DE-OS 20 39 041, DE-OS 21 07 774, DE-OS 21 37 992, DE-OS 20 so 776, DE-PS 968 273, DE-OS 19 05 598.

Compounds of the formula II are, for example: 3-phenyl-1,1-dimethylurea (Fenuron), 1- (2-methyl-cyclohexyl) -3-phenylurea (Siduron), 3- (4-isopropyl-phenyl) -1,1-dimethylurea (Isoproturon) 3- (4-t-butyl-phenyl) -1,1-dimethylurea, 3- (4-chlorophenyl) -1,1-dimethylurea (Monuron), 3- (314-dichlorophenyl) -1,1-dimethylurea (Diuron), N- (3,4-dichloropheny) -N-diethylurea, 1-n-butyl-1-methyl-3- (3,4-dichlorophenyl) urea! (Neburon), N- (3-trifluoromethylphenyl) -1,1-dimethylurea (Fluometuron), 3- (3-chloro-4-methylphenyl) -1,1-dimethylurea (chlorotoluron), 3- (4-Chlorophenyl) -1-methyl-1- (1-methyl-prop-2-ynyl) -urea (Butoron), 1- (n, 4 -Dimethylbenzyl) -3- (4-methylphenyi) -urea, 3- (3-chloro-4-methoxyphenyl) -1,1-dimethylurea (Metoxuron), 3-f (4-chlorophenoxy) phenyl7-1,1-dimethylurea (chloroxuron), 3- (4-chlorophenyl) -1-methoxy-1-methylurea (Monolinuron), 3- (4-bromophenyl) -1-methoxy-1-methylurea (metobromuron), 3- (3,4-dichlorophenyl) -1-methoxy-1-methylurea (Linuron), 3- (3-chloro-4-bromophenyl) -1-methoxy-1-methylurea (Chlorbromuron), 3- [3-chloro-4- (chlorodifluoromethylthio) phenyl] -1,1-dimethyl urea (thiochloromethyl), but in particular: 3- (4-isopropyl-phenyl) -1,1-dimethylurea (isoproturon; or 3- (3,4-dichlorophenyl) -1-methocy-1-methylurea (Linuron), which can be used in combination with alkyl phosphates especially as selective pre- and post-herbicides for control against grass weeds, such as Alopercurus myosuroides, Apera spicaventi, Poa spp., Avena fatura and annual weeds in winter wheat, winter barley and rye or Weeds in vegetable, fruit and wine growing are suitable.

3. Organic phosphorus and arsenic compounds such as 0,0-di-isopropyl-S [2- (phenylsulfonylamino) -ethyl] -dithiophosphate (Bensulide), n- (Phosphonomethyl) -glycine (Glyphosate), Ethylcarbamoylphosphoric acid salts, Methyl arsenic acid disodium salt, dimethyl arsenic acid.

4. Alcohols and aldehydes, such as ethyl xanthogen disulfide, alcyl alcohol, Acrolein.

5. Substituted alkanecarboxylic acid, e.g.

Monochloroacetic acid, N, N-diallylchloroacetamine (allidochlor), 2,3,6-trichlorophenylacetic acid (Chlorfenac) benzamidooxyacetic acid (Benzadox), 4-chloro-2-oxobenzothiazolin-3-yl-acetic acid (Benazolin), N, N-dimethyl-2,2-diphenylacetamide (diphenamide), trichloroacetic acid, Ethylene glycol bis (trichtoroacetate), methyl 2-chloro-3- (4-chlorophenyl) propionate (Chlorophenprop), 2,2-dichloropropionic acid, ß-naphtyloxyessugic acid methyl ester, 2- (1-naphthyloxy) -propionic acid-N, N-dimethylamide (Naproamid).

6. Aromatic carboxylic acid derivatives of the general formula In which R1-R5, which can be the same or different, = halogen, NH2, methoxy, -COOH3, -COONH-naphthyl, NO2, with a maximum of 4 groups being H, A = -COOR6 * -CONP7R8, -CSNR7R8, -COSR6 , R6 = H, alkali, alkaline earth, alkyl, hydroxyalkyl, R7 = H, alkyl, R8 =; .H ', alkyl, hydroxyalkyl, benzyl.

The substances of the general formula III are known compounds described, for example, in the following patents: U.S. Patent 3 027 248, GB-PS 987 253, US-PS 3,534,098, US-PS 3,013,054, US-PS 3,081,162, US-PS 2 923 634, GB-PS 671 153.

Compounds of the formula III are, for example: 2,6-dichlorobenzonitrile (dichlorbenil), 2,6-dichlorobenzoic acid thioamide (chlorothiamide), N- (1,1-dimethylpropynyl) -3,5-dichlorobenzamide (propyzamide), 3-amino-2, 5-dichlorobenzoic acid (chloramben), 3,6-dichloro-2-methoxy-benzoic acid (dicamba), 2,3,6-trichlorobenzoic acid, dimethyl-2,3,5,6-tetrachloroterephthalate (Chlorthal), N- (1- Naphthyl) phthalamic acid (naptalam); 7. Phenol derivatives of the general formula IV in which R1-5, which can be identical or different = H, NO2, straight-chain or branched C14-alkyl, halogen, nitrile, trifluoromethyl, where a maximum of 4 groups are H, and R4 = H, -COCH-3, -CSOalkyl, -COCH2-Cl, -COO-alkyl, -N = CH-aryl, phenyl, optionally substituted by trifluoromethyl, nitro, alkyl, NH2, alkoxy, halogen.

Both. Substances are known compounds such as they are described in the following patents: GB-PS 1,067,031, US-PS 2,192,197, GB-PS 1 096 037, DE-PS 10 88 757, US-PS 3 080 225, US-PS 3 652 645, DE-OS 14 93 512.

Examples of compounds of the general formula IV are: 3,5-dibromo-4-hydroxy-benzonitrile (Bromoxynil), 4-hydroxy-3,5-diiodobenzonitrile (ioxynil), 6-methyl-2,4-dinitro-phenol (DNOC), 2-sec-butyl-4,6-dinitro-phenol (Dinoseb), 3,5-dibromo-4-hydroxy-benzaldehyde-0- (2,4-dinitrophenyl) -oxime (Bromofenoxine) 2-sec-Butyl-4,6-dinitro-phenyl acetate (Dinosebacetet), 2,4-dichlorophenyl-4'-nitrophenyl ether (Nitrofen), 5- (2,4-dichlorophenoxy) -2-nitrobenzoic acid methyl ester (Bifenox), 2,4'-dinitro-4th-trifluoromethyl-diphenylether (Fluorodif.en), pentachlorophenol (PCP), 2,4-dinitro-3-methyl-6-tert-butylphenol acetate, 2,4-dinitro-6-sec-amylphenyl, 2,4,6-trichloro-4'-nitrodiphenyl ether, 3-methyl-4'-nitro-diphenyl ether, 2,4'-Dinitro-4-trifluoromethyl-diphenylether, 2,4-dichlorophenyl-3'-methoxy-4'-nftrophenylether, but in particular 2,4-dinotro-6-methylphenol, which is in combination with alkylene phosphates especially for combating seed weeds, such as chickweed, Climbing herb, chamomile, knotweed, speedwell, dead nettle and seed herb, for grain, maize or viticulture, if necessary with the addition of a growth agent herbicide, or pentachlorophenol or 2,4,6-trichlorophenyl-4'-nitrophenyl ether, in particular in the control of barnyard millet and marsh corn in rice cultivation.

8. Anilines of the general formula V in which R1 = H, C1-3-alkyl or nitro, R2 = H, halogen or NH2, R3 = C1-3-alkyl, H, -CF3, -S02CH3 or -SO2NH2, R4 = H or C13-alkyl, R5 = H, NO2 or C1-3-alkyl, R6 = H, C1-3-alkyl, C1-4-alkoxymethyl or cyclopropylmethyl and R7 = branched or straight-chain C1-5-alkyl or straight-chain or branched C1-7-acyl.

The substances are known compounds like them are described in the following patents: U.S. Patent 3,257,190, U.S. Patent 3,546,295, U.S.P. 2,863,752, DE-AS 11 66 547, US-PS 3,020 142, DE-AS 10 39 779, US-PS 3,442,945, UK-PS 1 164 160, DE-OS 22 41 408.

Examples of the compounds of the formula V are: N, N-dipropyl-2,6-dinitro-4-trifluoromethylanilide (Trifluralin), N-ethyl-N-butyl-2,6-dinitro-4-trifluoromethylaniline (benfluralin), N-Cyclopropylmethyl-N-propyl-2,6-dinitro-4-trifluoromethylaniline (Profluralin), 3-diethyl amino-2,4-dinitro-6-trifluoromethyl aniline (Dinitram5ne), N- (1-Ethylpropyl) -3,4-dimethyl-2,6-dinitroaniline (Penoxyn), N, N-Dipropyl-4-methylsulfonyl-2,6-dinitroaniline (Nitraline), 4- (dipropylamino) -3,5-dinitro-benzenesulfonamide (oryzaline), N, N-dipropyl-2,6-dinitro-4-iso-propylaniline (Isopropaline), N-iso-propyl-α-chloroacetanilide (propachlor) d, d-dimethylvaleyl-4-chloroanilide (Monalid), N- (3-chloro-4-methylphenyte) -2-methylvaleric acid amide (pentanochlor), Propionic acid 3,4-dichloranilide (Propanil), 2,6-diethyl-N- (methoxymethyl) -2-chloroacetanilide (Alachlor), 2,6-diethyl-N- (butoxymethyl) -2-chloroacetanilide (butachlor), 2- (N-benzoyl-3,4-dichloroanilino) -propionic acid ethyl ester, but in particular propionic acid-3,4-dichloroanilide (Propani 1).

9. Carbamates of the general formula VI in which R1 = H, halogen, in particular chlorine, CH3 or NHCOOC2H5 and R2 = H, straight-chain or branched C1-4-alkyl, haloalkyl, haloalkynyl, alkynyl, 3- (methoxycarbamoyl) -phenyl. The substances are known compounds how they z. B. in the following patents: US-PS 3,334,989, DE-AS 11 59 432, DE-AS 11 88 588 US-PS 3,150,179, GB-PS 574 995, US 2,695,226, DE-OS 15 67 151.

Example of the compounds of the formula VI: iso-propyl-N-phenylcarbamate (Propham), 1-methyl- (ethylcarbamoylmethyl) -N-phenylcarbamate (Carbetamide), iso-propyl-N- (3-chlorophenyl) -carbamate (Chlorpropham), 4-chloro-2-butynyl-N- (3-chlorophenyl) -carbamate (Barban), 1-methylpropargyl-N- (3-chlorophenyl) -carbamate (Chlorbufam), methyl N- (4-aminobenzenesulfonyl) carbamate (Asulam), 2,6-di-tert-butyl-4-methylphenyl-N-methylcarbamate (Terbucarb) 3-MethoxyCarbonylaminophenyl-N- (3-MethYlphenNYl) -carbamate (Phenmedipham), 3-ethoxycarbonylaminophenyl-N-phenylcarbamate (Desmedipham), but in particular iso-propyl-N-phenyl-carhamate, 3-methoxy-carbonylamino-phenyl-N- (3-methylphenyl) -carbamate or 3-ethoxycarbonylaminophenyl-N-phenylcarbamate.

10. Triazines of the general formula VII In the = halogen, especially. Chlorine, methylthio or methoxy and R2 and R3 = straight-chain or branched C1-3-alkyl, optionally subst. with a nitrile group or azole group.

The substances are known compounds like them e.g. are described in the following patents: DE-OS 15 42 733, CH-PS 329 277, CH-PS 337 019, DE-AS 16 70 528, DE-AS 11 86 070.

Examples of compounds of the formula YII are: 2-azido-4-methylthio-6-iso-propylamino-1,3,3-triazine (Aziprotryn), 2,4-bis (ethylamino) -6-chloro-1,3,5-triazine (simazine), 2-ethylamino-4-chloro-6-isopropylamino-1,3,5-triazine (Atrazine), 2-methylamino-4-methylthio-6-isopropylamino-1,3,5-triazine (Desmetryne), 2- (4-Ethylamino-6-chloro-1,3,5-triazin-2-ylamino) -2-methylpropiononitrile (cyanazine), 2-ethylamino-4-tert-butylamino-6-chloro-1,3,5-triazine (terbutylazine), 2-chloro-4,6-bis (isopropylamino) -1,3,5-triazine (Propazine), 2-ethylamino-4-methylthio-6-isopropylamino-1,3,5-triazine (Ametryne), 2-ethylamino-4-sec-butylamino-6-methoxy-1,3,5-triazine (secbumetone), 2-ethylamino-4-tert-butylamino-6-methoxy-1,3,5-triazine (Terbtlmeton), 2-methoxy-4s6-bis (isopropylamino) -1,3,5-triazine (Prometon), 2-ethylamino-4-tert-butylamino + 6-methylthio-1,3,5-triazine (Terbutryne), 2-methylthio-4,6-bis (isopropylamino) -1,3,5-triazine (Prometryn), 2- (3-methoxypropylamino) -4-methylthio-6-isopropylamino-1,3 , 5-triazine (Methoprotryne), but in particular: 2- (4-Ethylamino-6-chloro-1,3,5-triazin-2-ylamino) -2-methylpropi ononi tri 1.

11. Triazynones of the general formula VIII in which R1 = alkyl, subst. Aryl or a cycloaliphatic radical, R2 = NH2, -NH-alkyl or N = CH-alkyl and R3 = Ci 4-alkyl, alkoxy or alkylthio.

The substances are known compounds like them are described, for example, in the following patents: US-PS 3,671,523, DE-OS 24 07 144, U.S. Patent 3,847,914.

Examples of compounds of the formula VIII are: 4-amino-6-tert-butyl-3-methylthio-1,2,4 triazin-5 (4H) -one (metribuzin), 6-tert-butyl-4-iso-butylideneamino-3-methylthio-1,2,4-triazin-5 (4H) -one (Isomethfozin), but especially 4-amino-3-methy1-6-phenyl-1,2,4-triazin-5 (4H) -one (Metamitron), 12. Other herbicides that can be used are, for example: 3,6-epoxy-cyclohexanedicarboxylic acid (Endothal), S-ethyl-N, N-diethyl-thiocarbamate (ethiolate), S-ethyl-N, N-hexanemethylene thiocarbamate (Molinate), S-ethyl-N, N-dipropyl-thiocarbamate (EPTC), S-ethyl-N-ethyl-N-cyclohexyl-thiocarbamate (Cyclate) S-ethyl-N, N-diisobutylthiocarbamate (butylate), S-propyl-N, N-dipropyl-thiocarbamate (Vernolate), S-propyl-N-ethyl-N-butyl-thiocarbamate (Pebulate), 2-chloroallyl-N, N-diethyl-dithiocarbamate (Sulfallate), S- (2,3,3-Trichlorally) -N, N-diisopropylthiocarbamate (Trillate), S- (2,3-dichloroallyl ) -N, N-disopropylthiocarbamate (diallate), S- (4-chlorobenzyl) -N, N-diethylthiocarbamate (Benthiocarb), 1,3-dimethyl-1- (5-trifluoromethyl-1,3,4-thiadiazo-2-yl) urea (Thiazfluron), 1- (5-ethylsulfonyl-1,3,4-thiadiazol-2-yl) -l, 3-dimethylurea (sulfodiazole), 2-Oxo-1-imidazolidinecarbomic acid-N-isobutylamide (isocarbamide), 1- (benzothiazolyl) -1,3-dimethylurea (Methabenzthiazuron), 1,1-ethylene-2,2'-dipyridylium dibromide (Diquat), 1,1'-dimethyl-4,4'-dipyridylium dichloride (Paraquat) Individual herbicides are used alone or in combination with others Herbicides with the addition of alkyl phosphates of the general formula I are used.

The new herbicidal compositions can by customary methods can be used, e.g. as a soil herbicide or leaf herbicide or as a systemic one Herbicides or contact herbicides as needed before sowing, after sowing or after emergence.

It is mainly used to remove weeds and Weed grasses such as

Alopeurus myosuroides, Bromus tectorum, Cyperus rotundus, Digitaria sanguinalis, Echinochlora crus galli, Eleusine indica, Festuca ovina, Lolium perenne, Phleum protense, Setaria italica, Poa annua, Setarla viridis, sorghum hale pense, Abutilon theophrasti, Amaranthus retroflexus, Anthemis arvensis, Chenopodium album, Chrysanthemum segetum, Convolutus arvensîs, Agropyron repens, Apera picä-venti, Arrhenaterum elastius bulbosum, Pennisetum clandestinum, Ischaemum rugosum, Rottbuellia exaltata, Imperata cylindrica, Poa trivialis, Leptochloa filiformis, Setaria faberii, Galium aparine, Cirsium arvense, Atriplex spp., Which are the cultivation of useful plants in Hinder or damage monocultures.

Examples of crops that protect from weeds and grass weeds are: oats, barley, rice, millet, wheat, maize, sugar beet, cane sugar, potatoes, Soybeans, cotton, tobacco, coffee, fruits, vegetables or viticulture.

Virtually any desired insecticide can be used as the insecticide, for example the known chemical pesticides from the following groups: 1. Pyrethroids of the general formula I R1 = CH3, COOH, COOCH3, Cl, Br R2 = CH3, Cl, Br R3 "substituted cyclopentene, substituted furylmethyl, phthalilimidomethyl, phenoxybenzyl or phenalkenyl groups.

Examples of compounds of the formula I: R1 R2 R3 ,. . 1. -CH3 -CH3 CH, - CH2-CH = CH-CH = CH2 pyrethrin 1 2. -COOCH3 -CH3 CH3> oCH2-CH = CH-CH = CH2 pyrethrin II J 3. "CH3 -CH3 CH3gaCH2-cH = cH-cH3 cinerin 1 0 4. -COOCH3 -CH3 GH3 <CH2-CH = CH-CH3 Cinerin II 3 I-0 5. -CH3 -CH3 CH30CH2-CH = CH-C2H5 jasmoline 1 0 2 6. -COOCH3 -CH3 CH3 <CH2-CH = CH-C2H5 Jasmolin II O 1 .RR t .2. . 3 7. -CH3 -CH3 / CHZ CH2 ^ g furethrin 58. -CH3 -CH3 W H2-CH = CH2 allethrin CH 9. -CH3 CH3 <C cyclethrin 10 Cl 10, -CH3 -CH3 Cl X Bathrin CH; -CH -CH3 -CH3 CH 3tCH3 dimethrin -CH2 12. -CH3 -CH 3 -CH2-t phthalhrin 20th 13. -CH3 -CH3 CH2 vCH2-CH = CH2 japothrin 14. -CH3 -CH3 2v-CH2 ~ - pyresthrin 25th 15. -CH3 -CH3 -CHZ-CH = C-CH2 butethrin 3 & 6 -CH3 CH3 CH2 penothrin 17. -Cl -Cl -CH2 »~ ° ~ t permethrin -CH2 18. -Br -Br -CH t ~ ° ~ decamethrin ch The compounds of the formula 1 are known compounds which have already proven their worth as insecticides (chemistry of pesticides and pest control agents, Springer 1970, p. 87 ff).

The compounds of the formula I are sparingly soluble in water and are sensitive to heat and are easily inactivated in air.

Draw combinations of compounds of formula 1 with alkyl phosphates in particular that the stability to air and temperature is greatly improved. It is also possible to use aqueous solutions and emulsions without having to use questionable organic solvents. Even the often unpleasant odor of the compounds is caused by the addition of alkyl phosphates of the general formula I reduced. The killing of the insects is through addition the alkyl phosphates increased considerably without increasing the toxicity to warm-blooded animals will. Combinations of permethrin or decamethrin with are particularly preferred Alkyl phosphates of the formula I.

2. Chlorinated hydrocarbons of the general formula II R1 = halogen, especially chlorine, methoxy, C1-3-alkyte R2 = polychloralkyl, nitroalkyl groups such as: 2,2-bis- (p-chlorophenyl) -1,1,1-trichloroethane (DDT), 2,2- Bis- (p-methoxyphenyl) -1,1,1-trichloroethane (methoxychlor), 2,2-bis- (p-fluorophenyl) -1,1,1-trichloroethane (DFDT), 2,2-bis- (p -chlorphenyl) -1,1-dichloroethane (TDE), 2,2-bis- (p-ethylphenyl) -1,1-dlchloroethane (Perthane), 2-nitro-1,1-bis- (p-chlorophenyl) - butane (Bulan), 2-nitro-1,1-bis (p-chlorophenyl) propane (Prolan).

Mixtures of: 2,2-bis- (p-chlorophenyl) -1,1,1-trichloroethane are preferred or 2,2-bis (p-methoxyphenyl) -1,1,1-trlchloroethane with alkyl phosphates. advantage This mixture is that through the complex formation of the substances with the alkyl phosphates water-soluble or easily emulsifiable mixtures without the use of questionable organic solvents can be produced.

3. Polychlorocycloalkanes such as: γ-1,2,3,4,5,6-hexachlorocyclohexane (Lindane), 1, 2,4,5,6,7,8-octachloro-4,7-methano-3a, 4,7,7a-tetrahydroindane (chlordane), 1,4,5,6,7-heptachlor-4,7-methano-3a, 4,7,7a-tetrahydroindane (heptachlor), 2-exo-4,5,6,7,8-heptachlor-4,7 -methano-3a, 4,7,7a-tetrahydro-indane (Dihydroheptachlor), 1,3,4,5,6,7,10,10-octachloro-4,7-endomethylene-4,7,8 tetrahydrophthalane (Isobenzane), 6,7,8,9,10,10-hexachloro-1,5,5a, 6,9,9arhexahydrow6,9 * methano-2,4,3-benzodioxathiepin-3-oxide (Endosulfan), 5,6-bis (chloromethyl) -1,2,3,4,7,7-hexachlorobicyclo-2,2,1-hepten-2 (Alodan) 5-bromomethyl-1,2,3,4,7,7-hexachlorobicyclo-2,2,1-hepten-2 (bromodan) 1,2,3,4,10,10-hexachloro-1 , 4,4a, 5,8,8a-hexahydro-endoZ 1,4-exo-5,8-dimethanophthalene (Aldrine), 1, 2,3,4'10,10-hexachloro-6,7-epoxy-1,4,4a, 5,6 , 7,8,8aocta-hydro-endo-1,4-oxo-5,8-dimethanophthalene (Dieldrin), 1,2,3,4,10,1O-hexachloro-6,7-epoxy-1,4, 4a, 5,6,7,8,8a octa-hydro-endo-1,4-endo-5,8-dimethanonaphthalene (endrin).

Mixtures of lindane, aldrin and dieldrin are particularly preferred or endrin with alkyl phosphates. In addition to the significant improvement in the result the action on the insects, aqueous solutions or emulsions can be produced, without the use of toxic solvents.

4. Phosphoric acid esters of the general formula III in which R1 ~ C14-alkyl, in particular CH3 or C2H5, R2 = alkoxy, in particular methoxy or ethoxy, C1 4 -alkyl, in particular ethyl, or aminoalkyl, in particular amino-C1-4-alkyl, A = either a) - (CH2 ) nZ-R3, where n = 1-3, Z = S, SO or SO2, R3 = straight-chain or branched C14 alkyl, subst. Aryl, especially with chlorine, methyl or nitro subst. Phenyl or a radical of the general formula III, or b) chlorine, methyl or substituted by nitro.

Phenyl, α-subst. Benzyl, an alkenyl carboxylic acid ester group or an alkenyl carboxamide group, or c) a heteroaryl group, such as, for example, B, subst.

.Pyridyl, pyrimidinyl, quinoxalyl, isocalyl, triazolyl, phthalyl, Benztriazinyl, benzoxazolyl, thiadiazolyl, triazinolylo group is.

The compounds of the general formula III are known compounds, such as: 0,0-diethyl-0- (ethylthio) -ethyl-thiophosphate (Demeton-0), O, O-diethyl-S- (ethylthio) -ethyl-thiophosphate (Demeton-S), O, O-dimethyl-S- (ethylthio) -ethyl-thiophosphate, O, O-diethyl-S (2-ethylsulfinyl-1-methyl) -ethyl-thiophosphate, 0,0-diethyl-0- (ethylsulfinyl) -ethyl-thiophosphate, 0,0-Diethyl-S- (2-ethylthio) -ethyldithiophosphate (Disulfoton), 0,0-diethyl-S- (2-ethylthio) -ethyldithiophosphate, O, O-diethyl-S- (2-ethylthio) -methyldithiophosphate (Phorate) O, O-Diethyl-S- (tertbutylthio) -methyidithiophosphat (Terbufos), 0,0-Diethyl-S - [(4-chlorophenylthio) -methyl] -dithiophosphate, S, S-methylene-bis- (O, O-diethyl) -dithiophosphate (ethion), 0,0-dimethyl-S- / 1,2-bis- (ethoxycarbonyl) -ethyl7-dithiophosphate (Malthion), 0,0-dimethyl-S - [(N-methyl-carbamoyl) -methyl] -dithiophosphate (dimethoate), O, O-diethyl-S-IN- (1-cyano-1-methyl-ethyl) -carbamoylmethyl-thiophosphate (Cyanthoate), 0,0-diethyl-S - [(N-ethoxycarbonyl-N-methyl) -carbamoylmethyl-7-dithiophosphate (Necarbam) 0,0-Dimethyl-S- [α- (ethoxycarbonyl) -benzyl] -dithiophosphate (phenthoate), 0,0-Dimethyl-S-12- (N-methylcarbamoyl) -ethylthio7-ethylthiophosphate (Vamidothion), O, O-Dimethyl-O- (2,2-dichlorovinyl) -phosphate (dichlorvos) O, O "Dimethyl-O- (i-methoxycarbonyl-1-propen-2-yl) -phosphate (Mevinphos), tran-O, O-dimethyl-0- (2-metlloxycarbonyl-2-methyl-vinyl) thiophosphate (Methacrifos), 0,0-dimethyl-0- [1-chloro-1- (N, N-diethylcarbamoyl) -1-propen-2-yli-phosphate (Phosphamidon), 0,0-dimethyl-0- [n, N-dimethylcarbamoyl) -1-propen-2-yl] -phosphate (Dicrotophos), 0,0-diethyl-0- [2-chloro-1- (2,4-dichlorophenyl) vinyl] phosphate (chlorfenvinphos), O, O-Dimethyl-O-L2-chloro * 1- (2,4,5-trichlorophenyl) -vinyl7F phosphate tetrachlorvinphos), 0,0-Diethyl-0- (4-nitrophenyl) -thiophosphate (parathion) 0,0-Dimethyl-0- (3-methyl-4-nitro-phenyl) -thiophosphate (Fenitrothion) 0,0-dimethyl-0- (2,4,5-trichlorophenyl) thiophosphate (Fenchlorphos), 0,0-dimethyl-0- (4-bromo-2,5-dichlorophenyl) thiophosphate (bromophos), 0,0-Dimethyl-0- (3-methyl-4-methylthiohexyl) -thiophosphate (fenthion), O-methyl-0- (4t-butyl-2-chlorophenyl) -N-methyl-phosphamidate (Crufomat), 0-ethyl-S-phenylethanedithiophosphate (Fonofos), 4,4'-bis (methoxy-phosphinothiloxy) -diphenyl sulfide (Temephos), O, O-Diethyl-O- (2-isopropyl-6-methyl-4-pyrimidinyl) -thiophosphate (Diazinon), 0,0-Diethyl-0- (2-diethylamino-6-methyl-4-pyrimidinyl) -thiophosphate (Pyrimiphos), 0,0-diethyl-0- (3,5,6-trichloropyridyl2-thiopllosphat (chlorpyrifos), 0,0-diethyl-0- (2-quinoxaly) -thiophosphate (Quinalphos), 0,0-diethyl-0- (S-phenyl-3-isoxazolyl) -thiophosphate (isoxathione), 0,0-diethyl-0- (1-phenylb1,2,4-triazol-3-yl) thiophosphate (Triazophos), 0,0-Diethyl-0- (5-chloro-1-isopropyl-1,2,4-triazol-3-yl) thiophosphate (Isazofos), 0,0-dimethyl-S- (phthalimido-methyl) -dithiophosphate (Phosmet), 0,0-dimethyl-S - [(1,2,3-benztriazin-4 (3H) on-3-yl ) methyl] dithiophosphate (Azinphosmethyl), 0,0-diethyl-S-r (6-chloro-benzoxazol-2 (3H) one "3-yl) methyl 7-dithiophosphate (Phosalone), 0,0-Dimethyl-S-E (2-methoxy-1,3,4-thiadiazol-5 (4H) on-4-yl) methyl] dithiophosphate (Methidathione), 0,0-dimethyl-S - [(6-chloro-oxazolone-4,5-6-pyridin-2 (3H) -on-3-yl) -methyl7-thiophosphate (Azamethiphos), OtO-Dimethyl-S- | (4,6-diamino-1,3,5-triazin-2-yl) -methyl2-dithiophosphate (Menazon), 0,0-Dimethyl -S-i (5-methoxy-4H-pyrone-2-yl) -methylj-thiophosphate (Endothion), 0,0-Diethyl-S-C (5,7-dichloro-2-benzox-azolyl) -methyl 7-dithiophosphate (Benoxafos), 0,0-dimethyl-2,2,2-trichlor-1-hydroxy-ethane-phosphonate (trichlorophone), 2,3-bis- (diethoxy-phosphinothioylthio) -1,4-dioxane (diocathion), 2- (diethoxyphosphinylimino) -1,3, dithiolane (Phosfolan) O, S-dimethyl-thiophosphamidate (Methamidophos), 2-methoxy-4H-1,3,2-benzodiocaph-osophorin-2-sulfide, Diethoxyphosphinothioyl-oxyimino) -phenyl-acetonitrile (Phoxim), 0,0-dimethyl-0-dimethyl-0- (7-chlorobicyclo- [3,2,0] -hepta-2,6-dien-6-yl )-phosphate (Heptenophos), 0-ethyl-S, S-dipropyldithiophosphate (Ethoprophos), 0-ethyl-S-propyl-0- (2-chloro-4-bromophenyl) thiophosphate (Profenofos) O-Ethyl S-propyl-0- (4-methylthio-phenyl) -dithiophosphate (Merpafos), The following phosphoric acid esters are particularly preferred: Heptenophos La, O-dimethyl-O- (7-chlorobicyclo-63,2,0) -hepta-2,6-dien-6-yl) -phosphate, Demeton-S-methyl [0,0-dimethyl-S- (methylthio) -ethylthiophosphate], Oxydemeton-methyl [0,0-Dimethyl-S- (ethylsulfinyl) -ethylthlophosphatl, Etrimphos [0- (6-ethoxy-2-ethyl-4-pyrimidinyl) -O, O-dimethylthiophosphatel, Parathion fO, O-diethyl-0- (4-nitrophenyl) -thiophosphate, [0,0-dimethyl-0- (4-nitrophenyl) -thiophosphate, Triazophos [0,0-diethyl-0- (1-phenyl-1,2,4-triazol-3-yl) thiophosphate], in particular however, parathion, especially to combat it of letting and sucking insects, against hayworms and sourworms, spider mites, scale insects, robber flies, Beetles, caterpillars, anal caterpillars, larch vesicles, etc.

5. Aryl carbamates of the general formula IV R1 = CH3 or H, R2 = H, dialkylamino, C1-4-alkyl, C1-4-alkoxy or C1-4-alcohol, R3 = H, straight-chain or branched C1-5-alkyl or dimethylaminomethylimino, R4 = H, C1 -4-alkyl, C1-4-alkoxy, C1-4-alcohol, dioxolane, or alkylthiomethyl, where R3 and R4 together are, for example, the groups -0-C (CH3) 2-0-, -CH = CH-CH = CH - or -CH2-C (CH3) 2-O- can mean.

The compounds of the general formula IV are known compounds, such as: 4-diallylamino-3,5-dimethylphenyl-methyl-carbamate (allyxycarb), 4-dimethylamino-3-methylphenyl-methyl-carbamate (Aminocarb), 2,2-dimethyl-1,3-benzodioxol-4-yl-methylcarbamate (Bendiocarb), 2-sec-butylphenyl-methylcarbamate (BPMC), 3- (1-methylbutyl) -phenyl-methylcarbamate (Bufencarb I), 3- (1-ethylpropyl) -phenyl-methylcarbamate (Bufencarb II), 1-naphthyl-methyl carbamate (carbaryl), 2,3-dihydro "2b2-dimethylbenzofuran-7-yl-methyl carbamate (Carbofuran), 2- (1,3-Dioxolan-2-yl) -phenyl-methylcarbamate (Dioxacarb), 2-Ethylthio-methylphenyl-methylcarbamate (Ethiofencarb), 3-dimethyl aminomethylenimi no-phenylmethyl-carbamate (formetanate), 3,5-dimethyl-4-methylthiophenyl-methyl carbamate (Mercaptodimethur), 4-dimethylamino-3,5-dimethylphenylmethylcarbamate (mexacurbate), 3,4-dimethylphenyl-methylcarbamate (MPMC), 3-isopropyl-5-methylphenyl-methylcarbamate (Promecarb), 2-isopropoxyphenyl methylcarbamate (Propoxur), but especially Propoxur (2-isopropoxyphenyl methyl carbamate).

6, Other known insecticides that may be used are e.g.

2-methyl-2- (methylthio) -propylideneamino-methylcarbamate (Aldicarb), 1- (methylthio) -ethylideneamino-methylcarbamate (methomyl), N, N-dimethyl- »-methylcarbamovyloxyimino- g - (methylthio), acetamide (oxamyl), 1,3-di "(carbamoylthio) -2-dimethylaminopropane hydrochloride (Cartap), 2-dimethylamino-5,6-dimethylpyrimidin-4-yl-dimethylcarbamate (pirimicarb) 4- (4-chloro-2-methylphenyl) -N'-dimethylforniamidine (chlorodimeform), N, N-di- (2,4-xylyliminomethyl) -methylamine (Amitraz), but in particular: Aldicarb 12-methyl-2- (methylthio) "propylideneamino-methylcarbamate.

Of the insecticides mentioned in the individual groups 1-6 are the following preferred: permethrin, decamethrin, DDT, methoxychlor, lindane, aldrin, dieldrin, Endrin, Heptenophos, Demeton-S-methyl, Oxydemeton-methyl, Etrimphos, Parathion, Triazophos, Propoxur, Aldicarb.

The individual insecticides are used alone or in combination with others Insecticides with the addition of alkyl phosphates of the general formula 1 are used.

The new insecticide compositions can help combat dormant stages of insects and mites (winter spray), to combat all stages on the growing plant (leaf application), to combat insect larvae (soil application), and used to combat insect infestation on harvested crops (storage protection) will.

Areas of application for the new isecticidal compositions are e.g. the control of locusts, ground insects, spider mites, scale insects, cicadas, Thrips, such as wire warmers, grubs, leaf hoppers, larvae of weevil beetles, groundworms * Cabbage fly larvae; Fallow fly larvae, especially in cereals;, frit fly. especially with corn, oats and barley; Mole crickets, ants, springtails, millipedes, Termites, woodlice, aphids, capsule beetles, especially with cotton; Stem borer especially with rice and corn; Flies and mosquitoes, especially in the case of cereals; Colorado potato beetle, Beetle fly, pollen beetle, weevil, caterpillars and flies, especially in vegetable growing Fruit maggots, caterpillars, leaf mammals, in particular in fruit growing; Grape moth, phylloxera, Beetles and caterpillars, in particular in viticulture; Caterpillars and bugs, in particular when growing tea; Caterpillars, bugs, mealybugs in cocoa cultivation; all types of beetles in banana cultivation; Fruit flies, in particular in citrus fruit cultivation; Olive fly, olive moth in particular in olive growing; Caterpillars, beetles and leaf aspen species in forestry.

Practically any fungicide can be used as a fungicide4 such as the known fungicides from the following groups: 1. Aromatic nitro compounds of the general formula I in which R1 = C24-alkenyl or branched alkoxy, in particular C1-4-alkoxy, R2 "is C2 6-alkyl.

The compounds of the formula I are known compounds, suitable examples are: 2,4-dinitro-6- (2-butyl) -phenyl-3 ', 3'-dimethylacrylic acid ester (Binapacryl), 2,4-dinitro-6- (2 -butyl) -phenyNl-isopropyl-oxy-carboxylic acid ester (dinobutone), 2,4-dinitro-6- (2-octyl) -phenyl-crotonic acid ester (Dinocap) 2. Chlorobenzenes of the general formula II in which R1 = Cl or H; R2 = Cl, -OCH3 or H; R3 = Cl or -CN, R4 = Cl or H and R5 = -CN, -OCH3 or -N02.

The compounds of the formula II are known compounds.

Suitable examples are: hexachlorobenzene, petachloronitrobenzene (quintozen), 1,3-dicyan-2,4,5,6-tetrachlorobenzene (chlorothalonil), 1,4-dichloro-2,5-dimethoxybenzene (Chloroneb), 2,3,5,6-tetrachloronitrobenzene (Teenazen).

3. Phthalic acid derivatives of the general formula III in which R = alkylthio, especially C1-4-alkylthios, especially methylthio, haloalkyl, especially C1-4-haloalkyl, especially trichloromethyl or thionophosphoryl.

The compounds of the formula III are known compounds. In question come e.g.

Ditalimphos [N- (diethoxy-thiophosphoryl) -phthalimide], captan [N- (trichloromethylthio) -tetrahydrophthali-folpet [N- (trichloromethylthio) phthalimide], captafol [N- (1,1,2,2-tetrachloroethylthio) phthalimide], Chlorothalonil or nitrothal.

4. A fungicide from the thiocarbamate series: Ferbams Macozeb, Maneb = Manganese-ethylene-1,2-bis-dithiocarbamate, Metiram, Methylmeti ram, Propamocarb, Propineb = tin-propylene-1,2-bis-dithiocarbamidate, prothiocarb = S-ethyl-N- (3-dimethylaminopropyl) thiocarbamate hydrochloride, Vondozeb, Zineb = zinc-ethylene-1,2-bis-dithiocarbamidate, Zinoc = N-methylene-bis- (zinc-ethylene-bis-dithiocarbamidate), Ziram = zinc dimethyldithiocarbamate, thiram = bis (dimethylthiocarbamoyl) disulfide.

5. A fungicide from the series of benzimidazoles, such as benomyl = 1- (n-butylcarbomyl) -2-methoxycarbonylamino) benzimidazole, Carbendazin = 2- (methoxycarbonyl-amino) -benzimidazole, Fuberizadol = 2- (2-furyl) -benzimidazole, Rabenzazol, Thiabendazol = 2- (4-thiazolyl) -benzimidazol, 6. A fungicide from the Group of aniline derivatives, e.g .: benodanil = 2-iodobenzoic acid anilide, carboxi = 2,3-dihydro-2-methyl-1,4-oxathiin-3-carboxanilide Chloraniformethyn = N-formyl-N'-3,4-dichlorophenyltrichloroacetate aldehyde aminal, diclorane = 2,6-dichloro-4-nitroaniline fenfuram, furaloxyl, methfuroxam oxycarboxin = 2,3-dihydro-6-methyl-1,4-oxathiine-5-carboxylic acid anilide-S-dioxide 7. Other fungicides that can be used: Thiophanate = 1,2-bis- (3-methoxycarbonyl-2-thioureide) -benzene, Dodemorph = N-cyclododecyl-morpholinium acetate, Tridemorh = N-tridecyl-2,6-dimethylmorpholine, Anilazine = 2,4-dichloro-6- (o-chloroanilino) -S-triazine, Bupl \ -imat = 2-ethylamino-4-dimethylamidosulfonate-S-butyl-6-methyl-pyrimidine, Cetactael at, quinomethionate = 6-methylquinoxaline-2,3-dithiocyclocarbonate, chloromethionate, Dichlorofluanide = N, N-dimethyl-N'-phenyl-N'-fluorodichloromethylthio-sulfamide, dimethirimol = 5n-butyl-2-dimethylamino-4-hydroxy-6-methyl-pyrimidine, Dithianon = 2,3-dicyana-1,4-dithia-anthrquinone, dodine = n-dodeylquanidine acetate, ethirimol = 2-ethylamino-5n-butyl-4-hydroxy-6-methylpyrimidine, fenaminsulf = p-dimethyl aminobenzene disulfonate sodium salt, Fernarimol = # - (2-chlorophenyl) - # - (4-chlorophenyl) -5-pyrimidine-methanol, Iprodione = 1-isopropylcarbamoyl-3- (3,5-dichlorophenyl) hydantoin, pyrazophos = 0,0-diethyl-0- (5-methyl-6-ethyloxycarbonylpyrazole- [1,5-a] -pyrimidin-2-yl -) - thiophosphate, Tolyfluanid = N, N-dimethyl-N '- (4-methylphenyl) -N'-fluorodichloromethylthio-sulfamide, Triadimefon = 1- (4-chlorophenoxy) -3,3-dimethyl-1- (1,2,4-tri azol -1-yl) -2-butanone, Triadimenol, triforine = 1,4-di- (2,2,2-trichloro-1-formamidocityl) -piperazine, vinclozoline = 3- (3'5'-dichlorophenyl) -5-methyl-5-vinyl-1,3-oxazolidine-2,4-dione.

The individual fungicides are used alone or in combination with others Fungicides with the addition of alkyl phosphates of the general formula I are used. The new fungicide compositions can be used to combat a wide variety of fungal diseases can be used. For example, in potato and tomato blight spots (Alternaria solani) ;. Gray mold rot of onion (Botrytis allii); Gray mold rot, Botrytis rot of strawberries and grapes; Dutch elm disease (Ceratocystis ulmi); Leaf spot disease of beets (Cercospora beticola); Banana spot disease (Cercospora musae); Peach scab (Cladosporium carpophilum); Cucumber scabies (Cladosporium cucumcrinum); Brown or Velvet mottling of tomato (Cladosporium fulvum); Shotgun disease of stone fruit (Clasterosporium carpophilum); Rye ergot (Clavicep purpurea); Spotted disease on cherries (Coccomyces hiemalis); Burning spot disease of beans (Colletotrichum lindemuthianum); Rose leaf spot disease (Diplocarpon rosae); Soot in roses (Marssonia rosae); Cucumber powdery mildew (Erysiphe cichoracearum); Powdery mildew (Erysiphe graminis); Bladder disease on tea (Exobasidium vexans); Stem rot (Fusarium culmorum); Wilt disease of tomatoes (Fusarium oxysporum); Panama Disease of Bananas; Snow mold of the grain, (Fusarium nivale); Cherry scab (Fusicladium cerasi); Pear grate (Gymnosporangium sabinae); Streak disease the barley (Helminthosporium gramineum); Coffee rust (Hemileia vastatrix); Black foliage (Mycena citricolor); Blue mold disease on tobacco (Pernospora tabacina); Root burn of beets (Phomabetae) ;, rose rust; Collar rot, leaf rot and tuber rot of the Potato, tomato brown rot (Ph, ytophthora infestans); Brusone's disease on Rice (Pyricularia oryzae); Leaf fall disease; Leather berry disease; Apple powdery mildew (Podosphaera leucotricha); Hop powdery mildew (Spaerotheca humuli); Rose powdery mildew (Spaerotheca pannosa); Potato canker (Synchytrium endobioticum); Stink brand; Wheat stone brandy (Tilletia caries); Open oat brandy (Ustilago avenae); Barley blight (Ustilago nuda); Wheat blight (Ustilago tritici); Apple scab; Pear scab; Verticillim wilt; Wilting diseases of the potato; Cotton and other crops.

Practically any acaricide can be used as the acidic agent, for example the known chemical acaricides of the following groups: 1. Compounds of the general formula I in which R1 = H, CH3, alkoxy, alkoxymethyl, alkoxycarbomyl, alkynyl, R2 = CH3, CF3 CCl3, OH, 1 <, mean. The compounds of the formula I are, for example: 1,1-bis- (4-chloro-phenyl) -2,2,2-trichloroethane, 1,1-bis- (4-chloro-phenyl) -2,2,2- trifluorethane, 1,1-bis- (4-chloro-phenyl) -ethane, bis- (4-chloro-phenyl) -methane, 1,1-bis- (4-chloro-phenyl) -ethanol (chlorfenethol), 1 , 1-bis- (4-chloro-phenyl) -2,2-dichloroethanol 1,1-bis- (4-chloro-phenyl) -2-chloroethanol, 1,1-bis- (4-chloro-phenyl) - 2,2,2-trichloroethanol (Dicofol), 1,1-bis- (4-chlorophenyl) -2-ethoxyethanol, 4,4'-dichlorobenzilic acid ethyl ester (chlorobcilate) 1,1-bis- (4-chloro -phenyl) -propinol, 4,4'-Dichtor-benzilic acid isopropyl ester (chloropropylate).

2. Connections of the general formula II in which R1 = NO2, straight-chain or branched alkyl, R2 = H, alkenylcarbonyl, alkoxycarbonal and R3 = cycloalkyl, branched C1-8-alkyl.

The compounds of the formula II are known acaricides, such as: 4,6-dinitro-2-cyclohexylphenol 4,6-dinitro-2-cyclohexylphenol salts, 4-nitro-2,6-di-tert-butylphenol, 4,6-dinitro-2- (1-methyl-heptyl) -phenyl-crotonate (Dinocap), 4,6-dinitro-2-sec-butyl-phenyl-ß, ß-dimethylacrylate (Binapacryl), ethyl- (4,6-dinitro-2-tert, - 'ßutqyl-phenyl) -carbonate, Isopropyl (4,6-dinitro-2-sec-butyl-phenyl) carbonate (dinobutone).

3. Compounds of the general formula III in which X = S, SO or SO2, n = 0, O or 1, R1 to R9 - H, NO2, halogen, in particular Cl or F, R1 9 can be identical or different).

The compounds of the formula III are known acaricides, such as: 2,4,5,4'-tetrachlorodiphenyl sulfide (Tetrasul), diphenyl sulfone, 4-chloro-diphenyl sulfone, 2,4,5,4'-tetrachlorodiphenyl sulfone (Tetradifon), (4-chlorophenyl) - (4-chlorobenzyl) sulfide (chlorine surfactant) (4-fluorophenyl) - (4-chlorobenzyl) sulfide (Fluorosurfactant).

The following preparations, for example, can be used as other known acaricides are: quinoxaline-2,3-trithio-cyclic carbonate (thioquinox), 6-methyl-quinoxaline-2,3-dithio-cyclic carbonate (Quinomethionate), N-methyl-carbamic acid- (4-methylmercapto-3,5-dimethyl-phenyl) -ester (Methiocarb) N- (2-methyl-4-chloro-phenyl) -N ', N'-dimethyl-formamidine (Chlordimeform), 2,4,5-Trichloro-phenylaza-4-chloro-phenylsulphide (chlorofensulphide) 4-chloro-benzenesulphonic acid (Chlorfenson).

N- (3-methylaminocarboxy) -N, N'-dimethylformamidine (formetanate), preferred but are Dinoc, Benapacryl, Dinobuton, Tetrasul, Chlorobensid, Tetradifon, Propargit, Chlorfenethol, Dicofoi, Chlorbenzi lat, Chlorpropylat, Bromopropylat, Chlordimefon, Formetarats quinomethioate or thiquinox.

The individual acaricides can be used alone or in combination with others Acaricides or possibly also insecticides with the addition of alkyl phosphates of the general Formula 1 are used.

The new acaricide compositions can be used, for example, in fruit, vegetable, Ornamental plants, vines and hops are used, e.g. to control spider mites, such as Tetranychus urticae, Tetranychus telarius, Panonychus ulmi, Panonychus citri, or from the most varied of Bryobia species of 'false spider mites', e.g. the most varied Brevipalpus species; from soft skin mites such as Hemitarsonemus catus, Tarsonemus pallidus; or from gall milks such as Phyllocoptruta oleivora and numerous species the genera Eriophyes, Phyllocoptes, Aceria and Vasates.

Practically any nematicide can be used as a nematicide, see above such as: 0- (2,4-dichlorophenyl) -O, O-diethylthiophosphate (dichlofenthione), thiophosphoric acid-O, O-diethyl -0-2-pyrazinyl ester (Zinophos), 0,0-diethyl-0- (4-methyl-sulfinyl-phenyl) -thiophosphoric acid ester (Fensulfothione), 2-methyl-2- (methylthio) propionaldehyde-o- (methylcarbonyl) oxime (Aldicarb), 3,5-Dimethyl-1,3t5-2H-tetrahydrothiadizin-thione- (2) (Dazomet) dichloropropene (Dichloropropane / dichloropropene mixture), the individual nematicides can be used alone or in combination with other nematicides or, if necessary, herbicides or acaricides with the addition of alkyl phosphates of the general formula I are used.

The new nematicidal compositions can be used, for example, on the following nematodes are used: for free-living root nematodes, such as Pratylenchus, Rotylenchus, Tylenchorhynchus, Trichodorus, Longidorus, Xiphinema species everything on the roots of cereals, beets, potatoes, vegetables, carrots, fruit growing, banana growing, Coffee or tea cultivation; in root knot nematodes such as Meloidogyne species especially for tobacco, cotton, vegetables and ornamentals; in cyst nematodes, e.g. Heterodera species, with potatoes, oats, hops, clover, vegetables, etc. in stem nematodes, in particular Ditylenchus species, in rye, tobacco, beets, onions, maize, oats, clover, ornamental plants; and in leaf nematodes, especially Aphelenchoides species, mainly in rice, Coconut, strawberries and ornamental plants.

The preparation of the new pesticide compositions can be as follows Wise done: The alkyl phosphate or a mixture of several alkyl phosphates is in organic solvents such as toluene, ethyl acetate, xylene, gasoline, ethanol or methanol or mixtures of these solvents. The selection of the solvent or solvent mixture takes place depending on the dissolving behavior of the one used Pesticide. If necessary, the pesticide is added to the alkyl phosphate solution by heating dissolved. After the dissolution process has ended, the solvent is reduced in vacuo distilled off with heating.

The product obtained in this way is made by adding suitable auxiliaries, such as fillers, carriers, diluents, wetting agents, stabilizers, Gelling agents, evaporation accelerators, gelling agents and extenders or auxiliaries, the spraying or misting of the pesticide compositions according to the invention promote, transferred into a usual, suitable form of trade.

The new pesticidal compositions can also be prepared in this way that the pesticide with the alkyl phosphate or the alkyl phosphates and the necessary auxiliaries and fillers are mixed, the mixture in an organic Solvent is dissolved or slurried and then the solvent is drawn off again will. A ready-to-use mixture is obtained.

For pesticides that are soluble in water or mixed water and alcohol the pesticide is advantageously first in water or the water-alcohol mixture dissolved and the alkyl phosphate or alkyl phosphate mixture added and the product with stirring or by applying ultrasound to form a solution or emulsion processed. The emulsifiers usually required can be used before or after this Rtihrvornang can be added. The emulsion or solution thus obtained is usually e.g. by distillation, spray drying or lyophilization of the solvent mixture or freed from the water. The resulting product can then be used as a finished product or may be used with the addition of suitable auxiliaries. Also the product can re-emulsified or dissolved in water and used as a spray preparation. Alkyl phosphate solutions or emulsions with organic or aqueous-organic can also be used Solvents or water before the liquid discharge to those available on the market Means are added.

The new pesticide compositions can by conventional methods be applied to the ground or to the plants in the form of sticks, Litter, granules or as an aqueous preparation in the form of soluble concentrates, emulsifiable concentrates or dispersible concentrates.

For the application of the pesticides you need in most cases Carriers or auxiliaries in order to convert relatively small amounts of active ingredient to large Distribute units of area evenly. In addition to carrier substances, thinners, Wetting agents, stabilizers, gelling agents, evaporation accelerators, penetrants or extenders can be used.

Carriers are e.g .: talc, kaolin, bentonite, silica gel, lime or rock flour. Further aids are e.g. surface-active compounds, such as soaps (fatty acid salts), fatty alcohol sulfonates or alkyl sulfonates. As satilizers or protective colloids can be gelatin, casein, albumin, starch, or methyl cellulose can be used. The alkyl phosphates can also be added vegetable oils such as soybean oil can be used.

Example 1 Preparation of 1 liter of a herbicidal emulsion concentrate es (95 g / l) with 2-methyl-4-chlorophenoxyacetic acid as the active ingredient.

95 g of 2-methyl-4-chlorophenoxessic acid 150 g of 4-hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxo-9 octadecenyl) oxy] -3,5,9-trioxa-4-phosphaheptacos-18-en-1-ammonium hydroxide-4-oxide 8 g Tween 80 2 g Span 80 100 g N- (2-hydroxyethyl) -caproic acid amide 150 ml xylene 150 ml of isophorone are combined and dissolved with stirring.

The effectiveness against two-leaved weeds of 1 kg of this formulation with 95 g of active ingredient / liter is the same as 1 kg of a customary commercial product 190 g / l.

Example 2 1 kg herbicide emulsion concentrate with flampropmethyl as Active ingredient is produced as follows: 160 g of flampropmethyl 160 g of 4-hydroxy-N, NN-trimethyl-9-oxo-6 - [((1-oxo-9-octadecenyl) -oxy) -methyl] -3,5,8- trioxa-4-phosphahexacos-17-en-1-ammonium hydroxide-4-oxide 15 g of N- (2-hydroxyethyl) heptanoic acid amide 90 g of Cremophor EL 170 g of isophorone mixed and made up to 1 kg with a xylene-toluene mixture.

0.5 kg of this concentrate are usually diluted with water, As effective against wild oats as 1 kg of the commercial product.

This emulsion concentrate can also be used with ULV or LV technology apply when diluted with the same amount of water This mixture is a clear solution, while the commercial product is diluted with the same amount of water, results in an inhomogeneous, thick emulsion that cannot be splashed.

Example 3 1 liter of herbicidal emulsifier spray (25%) with propion acid-3,4-dichloroanilide is produced as an active ingredient.

250 g propionic acid-3,4-dichloroanilide 250 g 4-hydroxy-N, N, N-trimethyl-9-oxo-6 - [((1-oxo-9,12-oct-adecadienyl) -oxy) -methyl7- 3,5,8-trioxa; 4-phosphahexacosa-17,19-diene-1-ammonium hydroxide-4-oxide in 250 ml of ethanol 5 g of Tagat D 5 g Tegomuls O 30 g Cellosolve are made up to 1 liter with Shellsol A and solved.

0.5 liters of this formulation is used against broad-leaved weeds E.g. potato cultivation is just as effective as 1 kg of a pale commercial product the same concentration.

Example 4 Production of 1 kg of herbicide wettable powder (14%) with 4-amino-3-methyl-6-phenyl-1,2,4-triazine-5- (4H) -on as an active ingredient.

140 g of 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5- (4H) -one 160 g of 4-hydroxy-N, N, N-trimethyl-10-oxo-7- [ (1-oxo-9-octadecenyl) oxy] -3,5,9-trioxa-4-phosphaheptacos-18-en-1-ammonium hydroxide d-4-oxide 8 g Tween 80 2 g Span 80 50 g Cellosolve 100 ml propylene glycol 1 1 methanol are dissolved with heating.

400 ml of this solution are kneaded with 650 9 bentonite (colloidal) and the paste dried. This process is repeated with 400 ml each time until the whole solution is applied to the bentonite. The dry product is added ground by 5 g aerosol.

1 kg of this wettable powder (with 14%) is against weeds in the sugar beet just as effective as 0.4 kg of a common commercial product with a 70% content of active ingredient Example 5 Preparation of 400 g of herbicide wettable powder (40 X) with 2 - [[4-chloro-6- (ethylamino) -1,3,5-triazin-2-yl] -amino] -2-methyl-propionitrile as an active ingredient.

160 g of 2 - [[4-chloro-6- (ethylamino) -1,3,5-triazin-2-yl] -aminod-2-methyl-propionitrile 160 g of 4-hydroxy-N, N, N-trimethyl-10-oxo-7- £ (1-oxooctadecyl) -oxXy7-3,5,9-trioxa-4-phosphaheptacosane-1-ammonium hydroxide-4-oxide 2 g of Marlowet IHF 70 g of dry glycose 8 g of Bentone E are stirred into 1220 Stir in g of water and homogenize. The mixture is spray dried.

0.2 kg of this wettable powder (40%) is effective against weeds and grass weeds in maize equivalent to 0.5 kg of a commercially available wettable powder with 50% content Active ingredient.

Example 6 Production of 1 kg herbicide emulsion concentrate with 80 g / l desmedipham and 80 g / l phenmedipham as active ingredients.

80g Desmedipham 80g Phenmedipham 160g 4-Hydroxy-N, N, N-trimethyl-9-oxo-6-f ((1-oxooctadecyl) -oxy) -methyl7-3.5 , 8-trioxa-4-phosphahexacosane-1-ammonium hydroxide-4-oxide 230g toluene 170g isophorone 150g N- (2-hydroxyethyl) -heptanoic acid amide 110g Cremaphor EL 20g PEG 600 become mixed with the emulsion concentrate.

1 liter of this formulation with 160g / l active ingredient concentrate is against dicot weeds in sugar beet are just as effective as 1.8 liters of a commercial product with the same concentration of active ingredients.

Example 7 Preparation of 1 liter of herbicide emulsion concentrate with 3-m-Tolylcarbamoyloxyphenylcarbamate as the active ingredient.

80 g of 3-m-tolylcarbamoyloxyphenylcarbamate 100 g of a mixture of approx. 50 g of 4-hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxo-9,12-octadecadienyl) -oxy] -3,5,9-trioxa-4-phosphaheptacosa- 18,21-diene-1-ammonium hydroxide-4-oxide and approx. 50 c; 4-Hydroxy-10-oxo-7 - [(1-oxo-9,12-octadecadienyl) -oxy] -3,5,9-trioxa-4-phosphate-heptacosa-18,21-diene-1-ammonium hydroxide-4- oxide 2 g of lignosulfonate 30 g of cellosolve 150 g of propylene glycol are added to 1 liter with cyclohexanone filled up and released.

1 liter of this formulation with a concentration of 80 gil is against weeds just as effective in sugar beet as 1 liter of a common commercial product 157 q / l content of active ingredient.

Example 8 Preparation of 1 liter of emulsifiable herbicide concentrate with isopropylphenyl carbamate as the active ingredient.

250 g isopropylphenyl carbamate 200 g 4-hydroxy-N, N, N-trimethyl-9-oxo-6 £ ((i-oxohexadexyl) -oxy) -methyl] -3,5,8-trioxa-4-phosphatetracosane-1- ammonium hydroxide-4-oxide in a mixture of 50 9 soybean oil and 15 ml ethanol 8 g Tween 80 2 g Span 80 20 g Cellosove 100 ml of ethyl acetate are made up to 1 liter with isopropanol and dissolved.

0.5 liters of this formulation are used as a precursor herbicide against weeds just as effective as 1 kg of a standard commercial product in the same concentration.

Example 9 Preparation of 1 liter of insecticide emulsion concentrate, which as active ingredient contains 12.5 g (S) - α-cyano-3-phenoxyphenyl- (1R) -cis-3- (2,2-dibromovinyl) -2,2-dimethylcyclopropanecarboxyl at 150 g of 4-hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxohexadecyl) -oxy] -3,5,9-trioxa-4-phosphapentacosane-1-ammonium hydroxide-4-oxide 30 g ethanol 50 g xylene 2 g polyethylene glycol glycerine monooleate 5 g glycerine monodioleate 23 g Cellosolve made up to 1 titer with Shellsol N.

The mixture is e.g. suitable for the treatment of 1 hectare of a Corn field against European corn borer.

Example 10 Preparation of 1 liter of insecticide emulsion concentrate, which as the active ingredient 2-chloro-6'-ethyl-N- (2-methoxy-1-methylethyl) acetate-o-toluidide contains.

100 g of 2-chloro-6'-ethyl-N- (2-methoxy-1-methylethyl) -acet-o-toluidide 220 g of 4-hydroxy-N, N, N-trimethyl-9-oxo-6 - [((1-oxo-9-octadecenyl) -oxy) -methyl] -3,5,8-trioxa-4-phosphahexacos- 17-en-1-ammonium hydroxide-4-oxide and 4-hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxo-9-octadecenyl) -oxy] -3,5,9-trioxa-4-phosphaheptacos-18-en-1 -ammonium hydroxide-4-oxide Dissolved in a ratio of 1: 1 in 50 ml of ethanol 50 ml of xylene 10 g of Marlowet IHF 10 g of Cellosove made up to 1 liter with Shellsol A.

The mixture is suitable e.g. for the treatment of 1 hectare Oilseed rape field against green rapeseed beetle.

The same effect is achieved with this mixture of 100 g / l active ingredient as with the usual formulation containing 200 g / l.

Example 11 Preparation of 1 liter of insecticide emulsion concentrate, which as the active ingredient 7-chlorobicyclo [3,2,0] -hepta-2,6-dien-6-yl-dimethylphosphate contains.

120 g of 7-chlorobicyclo [3,2,0] -hepta-2,6-dien-6-yldimethylphosphate 200 g of 4-hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxooctadecyl) -oxy] -3,5,9-trioxa-4-phosphahepta cosan-1-ammonium hydroxide-4-oxide 40 ml ethanol 70 ml xylene 10 g Tween 80 2 g span 80 60 g Cellosolve made up to 1 liter with Shellsol A.

650 ml of the mixture are suitable e.g. for treating 1 hectare of one Leaf vegetable field against aphids, i.e.

80 g instead of the usual amount of 170 q.

The mixture is also suitable for combating ectoparasites Pets.

Example 12 Preparation of 1 liter of an insecticide emulsion concentrate, which as the active ingredient O-6-ethoxy-2-ethylpirimidin-4-yl-0,0-dimethyl-phosphoreothioate contains.

250 g of 0-6-ethoxy-2-ethylpirimidin-4-yl-0,0-dimethyl-phosphorothioate 300 g of 4-hydroxy-N, N, N-trimethyl-9-oxo-6 - [((1-oxooctadecyl) oxy) methyl] -3,5,8-trioxa-4-phosphahexacosane-1-ammonium hydroxide 4-oxide in a mixture of 1: 1 with 4-hydroxy-9-oxo-6-phosphahexacosane-1-ammonium hydroxide-4-oxide dissolved in 50 ml of ethanol 7 9 cellosolve 9 g Tween 80 2 g Span 80 made up to 1 liter with Shellsol N.

1 liter of this mixture is suitable e.g. for treating 1 hectare a white cabbage field against biting and sucking insects.

When using commercially available preparations, double the amount of Active ingredient needed.

Example 13 Preparation of 1 liter of insecticide emulsion spray, which contains 0,0-diethyl-0,4-nitrophenylphosphorothioate as the active ingredient.

230 g of 0,0-diethyl-0,4-nitrophenyl-phosphorothioate approx. 300 g of 4-hydroxy-N, N, N-trimethyl-10-oxo-7 [(1-oxo-9,12-octadecadienyl ) -oxy j-3,5,9-trioxa-4-phosphaheptacosa-18,21-diene-1-ammonium hydroxide-4-oxide dissolved in 100 ml of ethanol 50 ml of xylene 10 g of Marlowet IHF made up to 1 liter with Shellsol A.

650 nil (150 active ingredient) of this mixture are suitable e.g.

for the treatment of 1 hectare of a rapeseed field against rapeseed beetle.

When using commercially available preparations, double the amount of active ingredient needed.

Example 14 Preparation of 1 liter emulsion concentrate, which is used as contains active ingredient 2-isopropoxyphenylmethylcarbamate.

150 g of 2-isopropoxyphenylmethyl carbamate, 200 g of 4-hydroxy-N, N, N-trimethyl-9-oxo-6 [((1-oxo-9,12-octadecadienyl) oxy-methyl] -3,5,8-trioxa -4-phosphahexacosa-17,19-diene-1-ammonium hydroxide-4-oxide 150 ml ethanol 100 nil isopropanol 5 g Tagat O 5 g Tegomuls O 10 g Cellosolve 1 liter made up with Shellsol N.

2 liters of this mixture (300 g of active ingredient) are suitable, for example. for treatment of 1 hectare of a stone fruit field.

When using commercial preparations, double the amount of Active ingredient needed.

Example 15 Production of 1 kg of fungicide spray powder (20%) with 1,2,3,6-tetrahydro-N- (trichloromethylthio) phthalimide as active ingredient 200 g of 1,2,3,6-tetrahydro-N- (trichloromethylthio) phthalimide 200 g of 4-hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxo-9-octadecenyl) -oxy] -3,5,9-trioxa-4-phosphaheptacos-18-en- 1-ammonium hydroxide-4-oxide in a mixture 1: 1 with 4-hydroxy-10-oxo-7 - [(1-oxo-9-octadecenyl) -oxy] -3,5,9-trioxaphosphahcptacos-18-en-1-ammonium hydroxide-4-oxide in 50 ml of ethanol 10 g of dioctyl sodium sulfosuccinate are dissolved in 3 liters of toluene. 400 ml of this solution are kneaded with 600 g of bentonite and the paste in a vacuum dried. This process is repeated until all of the toluene solution is up the bentonite is raised. The end product is ground.

1 kg of this 20% wettable powder has, dissolved in water for 15 days, against Scab applied to pomaceous fruit has the same effect as 0.5 kg of an 80% commercial preparation.

Example 16 1 kg of fungicide spray powder with N- (trichloromethylthio) phthalimide 125 g of N- (trichloromethylthio) phthalimide are produced as the active ingredient 200 g of 4-hydroxy-N, N, N-trimethyl-9-oxo-6 - [((1-oxo-9-octadecenyl) methyl] -3,5,8-trioxa-4-phosphahexacos-17-ene -1-ammonium hydroxide-4-oxide in 50 ml of ethanol 2 g of dioctyl sodium sulfosuccinate are heated in 400 ml Toluene dissolved and kneaded homogeneously with 673 g bentonite (colloidal) and the paste dried. The product is ground by adding 4 g of Aerosil.

1 kg of this wettable powder (12.54) is just as effective as a foliar fungicide like 0.5 kg of a conventional commercial product with 50% active ingredient content.

Example 17 Production of 1 kg of funnitide wettable powder (12.5%) with 1- (4-chlorophenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) butanone as an active ingredient 125 g of 1- (4-chlorophenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) butanone, 200 g of 4-hydroxy-N, N, N-trimethyl-10-oxo -7 - [(1-oxo-hexadecyl) -oxy] -3,5,9-trioxa-4-phosphapentacosane-1-ammonium hydroxide-4-oxide in 50 ml of ethanol 10 g of dioctyl sodium sulfosuccinate are dissolved in 250 ml of toluene. The solution is applied in high amounts to 655 g of bentonite (colloidal). The product is dried, ground and sieved.

Against powdery mildew in cereals, 1 kg of this formulation is in Effect is the same as 1 kg of a commercial product with 25% active ingredient.

Example 18 1 kg of acaricide spray powder with 2-sec-butyl-4,4-dinitrophenyl isopropyl carbonate The active ingredient produced is: 125 g of 2-sec-butyl-4,4-dinitrophenyl isopropyl carbonate 160 g of 4-hydroxy-N, N, N-trimethyl-9-oxo-6-f ((1-oxo hexadecyl) -oxy) -methyl] -3,5,8-trioxa-4-phosphatetracosane-1-ammonium hydroxide -4-oxide in 80 ml of ethanol 85 g of PEG 4000/6000 dissolved in ethanol are added to 350 ml of xylene Heating dissolved.

The solution is kneaded and homoqen with 6289 bentonite (colloidal) the paste dried. The product is ground by adding 4 g of Aerosil.

1 kg of this wettable powder (12.5%) is against spider mils in fruit growing just as effective as 1 kg of a conventional commercial product with 25% active ingredient content.

Example 19 1 liter of acaricide emulsion concentrate (12.5%) with 4-chlorophenyl-2,4,5-trichlorophenyl sulfone 125 g of 4-chlorophenyl-2,4,5-trichlorophenyl sulfone are produced as the active ingredient 200 g of 4-hydroxy-N, N, N-trimethyl-10-oxo-7 - [(1-oxooctadecyl) -oxy] -3,5,9-trioxa-4-phosphaheptacosane-1-ammonium hydroxide-4-oxide 5 g Tween 80 5 g Span 80 are made up to 1 liter with cyclohexanone and dissolved.

1 liter of this emulsion concentrate with 125 g / l is against summer eggs and Jun-ol larvae are just as effective in growing fruit, vegetables and vines as 1 liter of one Usual commercial product with 250 g / l content of active ingredient.

Example 20 Preparation of 1 kg of nematicidal anti-wandering spreading agent de root nematodes in ornamental plants, which is 2-methyl-2- (methyl thio) propionaldehyde.

50 g of 2-methyl-2- (methylthio) propionaldehyde, 120 g of 4-hydroxy-N, N, N-trimethyl-9-oxo-6 - [((1-oxo-octadecyl) oxy) methyl] -3 , 5,8-trioxa-4-phosphahexacosan- 1-ammonium hydroxide-4-oxide 0.1 g of ascorbic palmitate are dissolved in 500 ml of toluene at 30 ° 35 0C resolved. This solution is precipitated with 804 g CaCO3 (quality: calcium carbonate) kneaded, the paste dried and ground.

The powder is dissolved in water with 1) 15.0 g of lignin sulfonate and 2) 100 ml of a 10% gelatin solution mixed together.

The resulting pellets are turned into a powder in the fluidized bed dryer dried.

The product thus obtained is equivalent in effectiveness against nematodes to the commercial product with 10 C / active substance.

Claims (48)

Claims 1. Pesticide composition, characterized in that it consists of a) one or more pesticide active ingredients and b) one or more alkyl phosphates of the general formula I. where R1 = -CH2NH3 + or CH2N + (CH3) 3 and either R2 = -CH2OR4 and R3 - -CH2OR5 or R2 = -CH (OR4) CH2OR5 and R3 = H and for both possibilites R4 and R5, which are the same or different can be, a straight-chain or branched, saturated or unsaturated alkyl or acyl group with 3-22 carbon atoms, in a weight ratio a: b of 1: O to 1:20 in addition to the usual carrier, dilution, solution, spraying and / or other inert auxiliaries. 2. Pesticide composition according to claim 1, characterized in that that the components a) and b) are present in a weight ratio of 1: 0.5 to 1:10. 3. Pesticide composition according to claim 1 or 2, characterized in that that components a) and b) are present in a weight ratio of 1: 1 to 1: 5. 4. Pesticide composition according to one or more of claims 1-3, characterized in that a compound of general formula I is used as the alkyl phosphate where R1 = -CH2NH3 or CH2N + (CH3) 3 R2 = -CH2OR4, R3 = -CH2OR5 and R4, R5 = identical or different, a straight-chain or branched, saturated or unsaturated alkyl or acyl group with 3-22 carbon atoms * is used 5. pesticide composition according to one or more of claims 1-3, characterized in that a compound of general formula I as the alkyl phosphate wherein R1 = -CH2NH3 + or CH2N + (CH3) 3 R2 -CH (OR4) -CM2OR 5, R3 R4, R5 - same or variously a straight chain or branched, saturated or unsaturated alkyl or acyl group with 3-22 carbon atoms is used will. 6. Pesticide composition according to one or more of claims 1-3, characterized in that a compound of general formula I is used as the alkyl phosphate where R1 = -CH2NH3 or -CH2N (CH3) 3 R2 = CH20R4, R3 -CFt2OR5 R4, R5 = identical or different, a straight-chain or branched, saturated or unsaturated acyl group with 3-22 carbon atoms is used. 7. Pesticide composition according to one or more of claims 1-3, characterized in that a compound of general formula I is used as the alkyl phosphate where R1 = -CH2NH3 + or CH2N + (CH3) 3, R2 = -CH (OR4) -CH2OR5 R4, R5 = identical or different, a straight-chain or branched, saturated or unsaturated acyl group with 3-22 carbon atoms is used. 8. Pesticide composition according to. one or more of the claim 1 - 7, characterized in that R4, R5 are a saturated or unsaturated acyl group means having 14-18 carbon atoms. 9. Pesticide composition according to one or more of the claims 1-8, characterized in that R4, R5 is an acyl group from the palmitoyl series, Mean oleyl, linolyl, stearyl or linolenyl. 10. Pesticide composition according to one or more of the claims 1-9, characterized in that a herbicide is used as the pesticide. 11. Pesticide composition according to claim 10, characterized in that one or more compounds from the groups are used as the herbicidal active ingredient: 1. Phenoxycarboxylic acid derivatives of the general formula I in which a) R1, R2, R3 = H. CH3 or halogen, with a maximum of 2 radicals being H, R4 = H or CH3 n = 0 - 2, Y = O or S, X = O, NH or S, and R5, when X = O, = H, straight-chain or branched C1-12-alkyl, hydroxyalkyl, an alkali or alkaline earth metal cation or an ammonium cation of an organic amine or R5, when X = NIl, = H, -NR2 . possibly with 1-3 halo atoms subst. Is phenyl or a heterocyl group, or b) R1 and R3 @ H, R4 and R5 have the same meaning as in a) and R6 = CH3, halogen or trifluoromethyl and n = 1-3; 2, urea derivatives of the general formula II wherein R1 and R2, which can be the same or different, are H, straight-chain or branched C1-4-alkyl, cycloalkyl, halogen, trifluoromethyl, nitro, alkoxy, optionally substituted by halogen. Is phenoxy, where at most one of the groups R1 and R2 is H, R3 = H, CH3 or C2M5 and R4 = H, cycloalkyl, C1-4-alkyl or methoxy; 3. Herbicidal, organic phosphorus or arsenic compounds; 4. Herbicidal alcohols or aldehydes; 5. Herbicidal Subst. Alkanecarboxylic acids; 6. aromatic carboxylic acid derivatives of the general formula III where R1 - R5, which can be the same or different, are H, halogen, NH2, methoxy, -COOCH3, -COONH-naphthyl or -NO2 * where at most 4 of the groups R1-R5 are H, and A = -COOR6, - CONR7R8, -CSNR7R8 or -COSR6 denote, in which R6 = H, alkali, alkaline earth, alkyl or hydroxyalkyl, R7 = H or alkyl and R8 = H, alkyl, hydroxyalkyl or benzyl; 7. Phenol derivatives of the general formula IV wherein R1-R5, which can be the same or different, are H, NO2, straight-chain or branched C1-4 alkyl, halogen, nitrile or trifluoromethyl, with at most four of the groups R1-R5 being H, and R4 = H, -COCH3, -CSO-alkyl, -COCH2Cl, -COO-alkyl, -N = CH-aryl or optionally substituted by trifluoromethyl, nitro, alkyl, NR2, alkoxy and / or halogen. Is phenyl; 8. Anilines of the general formula V where R1 = H, C1 ~ 3-alkyl or nitro, R2 = H, halogen or NH2, R3 = C1 3 -alkyl, H, CCF3 * -S02CH3 or -SO2NH2 R4 = H, or C1-3-alkyl, R5 = H, NO2 or C1-3-alkyl, R6 = H, C1-3-alkyl, C14-alkoxymethyl or cyclopropylmethyl and R7 = branched or straight-chain C1-5-alkyl or straight-chain or branched C1-5-acyl. 9. Carbamates of the general formula VI where R1 = H, halogen, CH3 or -NHCOOC2H5 and R2 = H, straight or branched C1-4-alkyl, haloalkyl, haloalkyl or 3- (methoxycarbamoyl) -phenyl. 10. Triazines of the general formula VII where R1 = halogen, methylthio or methoxy and R2 and R3, which can be identical or different, = straight-chain or branched C1-3-alkyl, which is optionally substituted with a nitrile group or azole group; 11. Triazinones of the general formula VIII where R1 = an alkyl group, a substituted aryl group or a cycloaliphatic radical, R2 = NH2, -NH-alkyl or -N = CH-alkyl and R3 = C1 4-alkyl, alkoxy or alkylthio; 12. Other herbicides that can be used are, for example: 3,6-epoxy-cyclohexanedicarboxylic acid, S-ethyl-N, N-diethylthiocarbamate, S-ethyl-N, N-hexanemethylene thiocarbamate, S-ethyl-N, N-dipropyl- thiocarbamate, S-ethyl-N-ethyl-N-cyclohexyl-thiocarbamate, S-ethyl-N, N-diisobutylthiocarbamate, S-propyl-N, N-dipropyl-thiocarbamate, S-propyl-N-ethyl-N-butyl thiocarbamate, 2-chloroallyl-N, N-diethyl-dithiocarbamate, S- (2,3,4-trichloroallyl) - N, N-diisopropylthiocarbamate, S- (2,3-chloroal lyl) -N, N-diisopropylthiocarbamate, S- (4-chlorobenzyl) -N, N-di ethyl thiocarbamate, 1,3-dimethyl-1- (5-trifluoromethyl-1,3,4-thiadiazol-1-yl) urea, 1- (5 -Ethyl sulfonyl -1, 3,4-thiadiazol-2-yl) -1,3-dimethylurea, 2-oxo-1-imidazolidinecarboxylic acid-N-isobutylamide, 1- (benzothiazolyl) -1,3-dimethylurea, 1, 1-ethylene-2,2'-dipyridylium dibromide, 1,1'-dimethyl-4,4'-dipyridylium dichloride. 12. Pesticide compositions according to one or more of Expectations 10-11, characterized in that one or more compounds are used as the herbicidal active ingredient from the group consisting of the following compounds is used: 2,4-dichlorophenoxyacetic acid or a salt or an ester thereof, 2,4,5-trichlorophenoxyacetic acid or a salt or an ester thereof, 3- (4-isopropyl-phenyl) -1,1-dimethylurea, 3- (3,4-dichlorophenyl) -1-methoxy-1-methylurea, 2,4-dinitro-6-methylphenyol, pentachlorophenol, 2,4,6-trichlorophenyl-4'-nitrophenyl ether, Propionic acid-3,4-dichloroanilide, iso-propyl-N-phenylcarbamate, 3-methoxycarbonylamino-phenyl-N- (3-methylphenyl) -carbamate, 3-ethoxycarbonylamino-phenyl-N-phenylcarbamate, 2- (4-ethylamino-6-chloro-1,3,5-triazin-2-ylamino) -2-methyl-propiononitrile, 4-Amino-3-methyl-6-phenyl-1,2,4-triazin-5 (4H) -one. 13. Pesticide composition according to one or more of the claims 1-9, characterized in that an insecticide is used as the pesticide. 14. Pesticide composition according to claim 13, characterized in that that the insecticide is a pyrethroid of the general formula I O R1 # C = CH-C-O-R3 R2 I CH3 CH3 where R1 = CH3, COOH, COOCH3, Cl, Br, R2 = CH3, Cl, Br, R3 = subst. Cyclopentene, subst. Furylmethyl, phthalimidomethyl, phenoxybenzyl or a phenalkenyl group is used. 15. Pesticide composition according to claim 14, characterized in that that as pyrethroid pyrethrin, cinerin, josmolin, furethrin, allethrin, cyclethrin, Bathrin, Dimethrin, Phthalthrin, Japothrin, Pyresthrin, Butethrin, Penothrin, Permethrin or decamethrin is used. 16. Pesticide composition according to claim 14 or 15, characterized in that that permethrin is used as the pyrethroid. 17. Pesticide composition according to claim 14 or 15, characterized in that that decamethrin is used as the pyrethroid. 18. Pesticide composition according to claim 13, characterized in that a chlorinated hydrocarbon of the general formula II is used as the isecticide in which R1 = halogen, methoxy or C1-3 alkyl and R2 = a polychloroalkyl or nitroalkyl is used. 19. Pesticide composition according to claim 13, characterized in that that 2,2-bis- (p-chlorophenyl) -1,1,1-trichloroethane is used as an insecticide. 20. Pesticide composition according to claim 13, characterized in that that 2,2-bis- (p-methoxyphenyl) -1,1,1-trichloroethane is used as an insecticide. 21. Pesticide composition according to claim 13, characterized in that that DFDT, TDE, Perthane, Bulan or Prolan is used as an insecticide. 22. Pesticide composition according to claim 13D, characterized in that that as an insecticide chlordane, heptachlor, dihydroheptachlor, isobenzane, endosulfan or bromadane is used. 23. Pesticide composition according to claim 13, characterized in, that the insecticide used is lindane, aldrin, dieldrin or endrinie. 24. Pesticide composition according to claim 13, characterized in that a phosphoric acid ester of the general formula III as the insecticide in which R1 = C1-4-alkyl, R2 = alkoxy, C1-4-alkyl or aminoalkyl, A: either a) - (CH2) nZ-R3, where n = 1-3, Z = 5, SO or SO2 or b) chlorine, methyl, nitro-phenyl, α-substituted-benzyl, an alkenylcarboxylic acid ester or alkenylcarboxamide group or c) a heteroaryl group is used. 25. Pesticide composition according to claim 24, characterized in that that as an insecticide Demeton-O, Demeton-S, Disulfobon, Phorat, Terbufos, Ethion, Malathions Dimethoat, Prothoat, Cyanathiat, Mercarbam, Phenthoat, Vamidothion, Dichlorvos, Mevinphos t Methacrifos, Phosphamidon, Dicrotophos, Chlorfenvinphos, Tetrachlorvinphos, Parathion, Fenitrothion, Fenchlorphos, Bromophos, Fenthion, Crufomat, Fonofos, Temephos, Diazinon, Pirimiphos Chlorpyrifos, Quinalphoss Isoxathion, Triazophos, Isazofos, Phosmet, Azinphosmethyl, Phosalon, Methidathion, Azamethiphos, Menazon, Endothion, Benoxafoss Trichlorphon, Dioxathion, Phosfolan, Methamidophos, Phoxim, Heptenophos, Ethoprophos, Profenofos or Merpafos is used. 26. Pesticide composition according to claim 24, characterized in that that as an insecticide Heptenophos, Demeton-S-methyl, Oxydemeton-methyl, Etrimphos, Parathion or Triazophos is used. 27. Pesticide composition according to claim 26, characterized in, that parathion is used as an insecticide. 28. Pesticide composition according to claim 13, characterized in that an aryl carbamate of the general formula IV as the insecticide in which R1 = CH3 or H, R2 = H, dialkylamino, C14-alkyl, alkoxy or Alkthio, R3 = H, straight-chain or branched C1-5-alkyl or dimethylaminomethylimino, R4 = H, C1 4-alkyl, C14-alkoxy, C1-4-Alktio, dioxolane or alkylthiomethyl, where R3 and R4 together can also form the groups -OC- (CH3) 2-O- or -CH- = CH-CH = CH- is used. 29. Pesticide composition according to claim 28, characterized in, that the insecticide Allyxycarb, Aminocarb, Bendiocarb, BPMC, Bufencarb, Carharyl, Carbofuran, Dioxacarb, Ethiofencarb, Formetanate, Mercaptodimethur, Mexacarb, MPMC or Promecarb is used. 30. Pesticide composition according to claim 28, characterized in that that Propoxur is used as an insecticide. 31. Pesticide composition according to claim 13, characterized in that that as an insecticide Aldicarb, Methomyl, Oxamyl, Captap, Pirimicarb, Chlordimeform or Amitraz is used. 32. Pesticide composition according to claim 1S, characterized in that that aldicarb is used as an insecticide. 33. Pesticide composition according to one or more of the claims 1-9, characterized in that a fungicide is used as the pesticide. 34. Pesticide composition according to claim 33, characterized in that one or more compounds from the groups of: 1. Aromatic nitro compounds of the general formula I are used as the fungicidal active ingredient in which R1 = C2-4-alkenyl or branched alkoxy and R2 = C2-6-alkyl; 2. Chlorobenzenes of the general formula II in which R1 = C1 or H, R2. = C1, -OCH3 or H, R3 = Cl or -CN, R4 = Cl or H and R5 = -CN, -OCH3 or -NO2 is 3. Phthalic acid derivatives of the general formula III in which R = an alkylthio, haloalkyl or thionophosphoryl group; 4. The fungicidally effective thiocarbamates; 5. The fungicidal omens benzimidazoles; 6. The fungicidally effective aniline derivatives; 7, The fungicides: thiophanate, dodemorph, tridemorph, anilazine, bupirimate, cetactaelate, quinomethionate, chloromethionate, dichlorofluanide, dimethirimol, dithianon, dodinb ethirimol, fenaminsulf, fenarimol, iprodione, tri-dimerol, pyrazolimen, tri-dione, pyrazuanid, tri 35. Pesticide composition according to one or more of the claims 1-9, indicated that the pesticide used is an acaricide. 36. Pesticide composition according to claim 35, characterized in that that one or more compounds from the group are used as acaricide active ingredient will. 1. The compounds of the general formula I in which R1 is H, CH3, alkoxy, alkoxymethyl, alkoxycarbonyl or kynyl R2 = CH3, CF3, Cl3, OH or H. 2, The compounds of the general formula II in which R1 = NO2, straight-chain or branched alkyl, R2 = H., alkenylcarbonyl or alkoxycarbonyl, R3 = cycloalkyl or branched C1-8-alkyl. 3. The compounds of the general formula III in which = = S or SO2, n = 0 or 1 R1 to Rg, which can be identical to or different from one another, are H, NO2 or halogen. 4. The acaricides: thioquinox, quinomethionate, methiocarb, chlordimeform, Formetanat, Chlorfensulfjd and Chlorfenson. 37 * Acari-zid compositions according to claim 5, characterized in that that one or more of the compounds Dinoc, Benapacryl, Dinobuton, Tetrasul, Chlorbensidf Tetradifon, Propargit, Chtorfenethol, Dlcofol, Chlorobenzilate> chloropropylate, bromopropylate, chlorodimephone, formetanate, quinomethionate or Thiquinox. 38. Pesticide composition according to one or more of the claims 1-9, characterized in that a nematicide is used as the pesticide. 39. Pesticide composition according to claim 38, characterized in that that as Nematizld Dichlofenthion, Zinophos, Fensulfothion, Aldicarb, Dazomet and / or Dichloropropene is used. 40. Process for the preparation of pesticidal compositions according to one or more of claims 1-39, characterized in that the alkyl phosphate, or mixtures of the alkyl phosphates according to formula I in an organic solvent or solvent mixture is dissolved and, if necessary, in this solution by heating and / or stirring the pesticide dissolved, and then the solvent or solvent mixture is removed in vacuo. The mixture obtained is with the addition of customary filling and aids converted into a customary application form. 41. Process for the preparation of pesticidal compositions according to one or more of claims 1-39, characterized in that the Pesticides with one or more alkyl phosphates of the general formula I below Addition of customary fillers and auxiliaries dissolved in an organic solvent or slurried and the solvent is then removed. 42. Process for the preparation of pesticide compositions according to one or more of claims I-39, characterized in that one or more, Pesticides soluble in water or alcohol in water or water-alcohol mixtures together with one or more alkyl phosphates of the general formula I below Stirring and / or slight heating and / or ultrasound dissolved and the solvent or solvent mixture is withdrawn. 43. Use of pesticidal compositions according to one or more of claims 1-39 for combating weeds and / or pests. 44. Use of pesticide compositions according to one or more of claims 10-12 for combating grass weeds and weeds. 45. Use of pesticide compositions according to one or more of claims 13-32 for the control of insects. 46. Use of pesticidal compositions according to one or more of claims 33-34 for combating fungi. 47. Use of pesticidal compositions according to one or more of claims 35-37 for combating mites or spider mites. 48. Use of pesticide compositions according to one or more of claims 38-39 for controlling nematodes.