DE3248033A1 - Pesticides - Google Patents

Abstract

The present invention relates to novel pesticide compositions and to a process for their preparation, which comprise one or more pesticide active ingredients and one or more phosphates of the formula I <IMAGE> in addition to conventional carriers, diluents, solvents and/or other inert auxiliaries.

Description

description

The invention relates to the subject matter shown in claims 1-48.

To reduce crop losses in crop cultivation caused by weeds, Weeds, eating and sucking insects, fungi, mites, spider mites, nematodes and other scapegoats can be seen today on the use of chemical pesticides (Pesticides) no longer do without.

A large number of chemical has been used to combat pests Substances enforced.

However, there are some of the pesticides in use Problems still resolved. The pesticides often need to be in high concentrations can be used and can become toxic for the environment.

The most important requirements for a pesticide are as much as possible high selectivity and activity against the pests, as low as possible Activity towards the useful plants as well as a single reef as small as possible in the biological environment.

There are therefore high demands on the selectivity of a pesticide posed. To reduce the burden on the environment, the amount of pesticide used should the per hectare to control the pests is needed, if possible oering, which, however, often leads to a loss of activity.

Another requirement is the ease of use with both the production as well as the application.

Surprisingly, it has now been found that the amount of pesticide required to control pests (weeds, insects, fungi, etc.) per hectare of cultivated area can be reduced by up to 40-60t, in some cases by up to 80X, if one the pesticide active ingredients or the mixture of several pesticide active ingredients one or more phosphates of the general formula I where X = OH or O ~ R1 = H, saturated or unsaturated, branched or straight-chain alkyl or acyl group with 1 - 22 carbon atoms, a straight-chain or branched alkylene group, optionally with a primary, secondary or tertiary amino group, one or several hydroxyl groups, an alkoxy group, halogen, phosphate, a sugar residue, an acylamino group or an acyloxy group can be substituted R2 = a straight-chain or branched, saturated or unsaturated alkyl or acyl group with 12-22 carbon atoms, a group of the general formula II, III, IV, V or VI - (CH 2) nY-R3 II Y = O, S, NH n = 1-8 m = 1 - 4 R3 = H, straight-chain or branched, saturated or unsaturated alkyl or acyl group with 1 - 22 carbon atoms R4 = H, straight-chain or branched, saturated or unsaturated alkyl or Acyl group with 1 - 22 carbon atoms R5, R6 = identical or different, mean H or alkyl with 1 - 4 carbon atoms, preferred groups for R1 are H, where R7, R8, Rg are identically or differently H or methyl, preferred groups for R2 are saturated or unsaturated alkyl or acyl groups with 12-22 carbon atoms, (CH2) nOR3 and -CH (CH2OR3) 2 are particularly preferred phosphates of the general formula I where X = OH or 0 R1 = H, -CH2-CH2-NH2, -CH2-CH2-N (CH3) 2, -CH2-CH2-N (CH3) 3 -CH2-CH (OH) -CH2-OH, -CH2-CH (NH2) -COOH R2 = C12-22 saturated or unsaturated alkyl or acyl -CH2-CH (OR3) -CH2-OR4, -CH2-OR4, -CH (CH2OR4) 2 in which R3 and R4 are identical or different , H or saturated or unsaturated alkyl or acyl group with 1 to 22 carbon atoms. The phosphates are mixed with the pesticides in a weight ratio of 1: 0.2 to 1:20, preferably 1: 0.8 to 1: 5.

The phosphates of the general formula I are known compounds, which are obtained by conventional methods, e.g. DE-OS 20 09 341, DE-OS 20 09 342, DE-OS 20 09 343, DE-OS 20 33 357, DE-OS 20 33 358, DE-OS 20 33 359, DE-OS 20 33 360, DE-OS 20 33 361, DE-OS 23 45 057, DE-OS 23 45 059, DE-OS 23 45 060, DE-OS 24 37 832, DE-OS 24 37 833, DE-OS 27 17 547, DE-OS 27 52 553, DE-OS 30 10 185, DE-OS 30 11 738, DE-OS 28 20 893, US-PS 35 77 446, EP 32622, DE-OS 27 45 810, EP 50327, EP 50460, EP 61872, EP 40039, DE-OS 30 08 082, EP 40039 or H. Eibl in Research Monographs in Cell and Tissue Physiology, Vol. 7, pages 19-50.

The new pesticide compositions are not only very economical the advantage of the treatment that the degradation, especially in the useful plants, accelerates and no more pesticide residues in the crops during harvest available. Quick dismantling can also shorten waiting times.

In addition, the new pesticidal compositions show an essential feature better adhesion to the plants or stored goods to be protected.

By adding the phosphates, the absorption of the pesticide will continue accelerated by the pests, so that also the one needed to protect the plants Pesticide amount can be reduced significantly.

The pesticides are used to manufacture the new pesticide compositions with one or more of the phosphates of the general formula I in a weight ratio 1: 0.2 to 1:20, preferably 1: 0.5 to 1:10, but especially in a weight ratio 1: 1 to 1: 5, mixed.

The following compounds in particular are suitable as phosphates of the formula I in question: dodecyl 2-trimethylammonioethyl phosphate hexadecyl 2-trimethylammonioethyl phosphate octadecen-9-yl 2-trimethylammonioethyl phosphate hexadecanoyl 2-trimethylammonioethyl phosphate hexadecyl 2-dimethylaminoethyl phosphate hexadecyl (2-amino-2-carboxy) -ethyl phosphate hexadecyl 2,3-dihydroxypropyl phosphate eicosyl 2-aminoethyl phosphate tetradecanoyl 2-trimethylammonioethyl phosphate tridecyl 2-methylaminoethyl phosphate hexadecyl 3-trimethylammoniopropyl phosphate Hexadecanoyl 4-trimethylammoniobutyl phosphate Hexadecyl phosphate 2-dodecyloxyethyl 2-trimethylammonioethyl phosphate 2-hexadecyloxyethyl 2-trimethyl ammonioethyl phosphate 2-hexadecylthioethyl 2-trimethylammonioethyl phosphate 2-octadecanoyloxyethyl 2-trimethylammonioethyl phosphate 2- (9,12,15-octatridecenoyloxycthyl phosphate 2-tetradecyloxyethyl-2-acylaminoethyl phosphate 2-tetradecanoyloxyethyl 2-dimethylaminoethyl phosphate 2- (5,8,11,14-eicosatetraenyloxy) ethyl 2-aminoethyl phosphate 2- (9,12,15-octadecatrienoyloxy) ethyl phosphate 2-hexadecanoyloxyethyl 2-dimethyl aminoethyl phosphate 3-octadecyloxypropyl 2-trimethylammonioethyl phosphate (3-0ctadecyloxy-2-hydroxy) propyl 2-trimethylammonioethyl phosphate 3-octadecanoyloxypropyl 2-trimethylammonioethyl phosphate (3-octadecyloxy-2-methyl) propyl 2-trimethylammonioethyl phosphate (3-octadecyloxy-2,2-dimethyl) propyl 2-trimethylammonioethyl phosphate 3-tetradecyloxypropyl 2-trimethylammonioethyl phosphate 3-hexadecyloxypropyl 2-trimethylammonioethyl phosphate 3-hexadecyloxypropyl 2-dimethyl aminoethyl phosphate 3-hexadecyloxypropyl 2-acetylaminoethyl phosphate 3-tridecylpropyl 4-trimethylammoniobutyl phosphate 3-tridecylpropyl 3-trimethylammoniopropyl phosphate 6-hexadecylhexyl-3-trimethylammoniopropyl phosphate 6-octadecen-9-yl-hexyl isopropyl phosphate 3-hexadecylpropyl hexadecyl phosphate (3-hexadecyloxy-2-methoxy) propyl 2-trimethylammonioethyl phosphate 2,3-di-tetradecanoylpropyl 2-trimethylammonioethyl phosphate 2,3-di-tetradecanoyloxypropyl 2-hydroxyethyl phosphate 2,3-di-hexadecanoyloxypropyl 2-fluoroethyl phosphate (1-hexadecyloxymethyl-2-hexadecyloxy) -ethyl 2-trimethylammonioethyl phosphate (3-octadecycloxy-2-hydroxy) propyl 2,3-dihydroxypropyl phosphate 3-hexadecanoyloxypropyl 2,2-dimethylaminoethyl phosphate 3-hexadecanoyloxypropyl (2,2-dimethylaminoethyl) dimethylammonioethyl phosphate 3-octadecyl 2- (2-aminoethyl) aminoethyl phosphate 2,3-dihexadecylpropyl (trimethylammonioethyl) -dimethylammonioethyl phosphate 3-hexadecanoyloxypropyl phosphate (3-hexadecyloxy-2-octadecyloxy) propyl 2-aminoethyl phosphate (3-hexadecanoyloxy-2-octadecanoyloxy) propyl 2-trimethylammonioethyl phosphate (2,3-di-hexadecyloxy) propyl 2-trimethylammonioethyl phosphate (2,3-di-hexadecyloxy) propyl phosphate (2,3-di-hexadecanoyloxy) propyl phosphate (2,3-Di-hexadecanoylamino) propyl phosphate 3-tetradecyloxypropyl 2-trimethylammonioethyl phosphate 3,6,9,12-tetraoxatetracosanyl 2-aminoethyl phosphate 2- 2- (dodecyloxy) ethoxy -ethyl 2-aminoethyl phosphate (2-hexadecyloxy-1-hexadecyloxymethyl) -ethyl phosphate (2-hexadecanoyloxy-1-hexadecanoyloxymethyl) -ethyl phosphate (2-hexadecyloxy-1-hexadecyloxymethyl) -ethyl 2-trimethylammonioethyl phosphate (2-hexadecyloxy-1-hexadecyloxymethyl) -ethyl 2-dimethylaminoethyl phosphate (2-hexadecanoyloxy-1-hexadecanoyloxymethyl) -ethyl-2-trimethylammonioethyl phosphate (2W0ctadecyloxy-1-octadecyloxymethyl) ethyl 2-trimethylammonioethyl phosphate (2-octadecanoyloxy-1-octadecanoyloxymethyl) ethyl 2-trimethylammonioethyl phosphate (2,3-di-tetradecyloxy) propyl phosphate (2,3-di-tetradecyloxy) propyl 2-ami noethyl phosphate (2,3-di-tetradecyloxy) propyl 2,3-dihydroxypropyl phosphate (2,3-di-tetradecyloxy) propyl 2-dimethyl aminoethyl phosphate (2,3-di-tetradecanoyloxy) propyl 2-aminoethyl phosphate (2,3-Di-tetradecanoyloxy) propyl 2-dimethyl aminoethyl phosphate (2,3-di-tetradecanoyloxy) propyl 2-trimethyl ammonioethyl phosphate (2,3-di-tetradecanoyloxy) propyl 3-trimethylammoniopropyl phosphate (2,3-di-dodecyloxy) propyl 4-trimethylammoniobutyl phosphate (2,3-di-dodecanoyloxy) propyl phosphate (2-dodecyloxy-3-hexadecyloxy) propyl 2-acetylaminoethyl phosphate (2-dodecanoyloxy-3-hexadecyloxy) propyl 2-trimethylammonioethyl phosphate bis - [(2,3-dihexadecanoyloxy) propyl | phosphate (2,3-dihexadecanoyloxy) propyl inositol phosphate (2,3-dioctadecanoyloxy) -propyl inositol phosphate come as pesticides in particular herbicides, insecticides, fungicides, acaricides or nematicides are suitable.

Virtually any herbicide can be used as the herbicide. Compounds from the group of photosynthesis inhibitors, respiratory inhibitors, the growth substances, the Milose inhibitor and the germ inhibitor in question.

Particularly suitable examples are: 1. Phenoxycarboxylic acid derivatives of the general formula I in which a) R1, R2 and R3, which can be the same or different from one another, = H, CH3 or halogen, in particular chlorine, but with a maximum of two radicals being H, R4 = H or CH3 n = 0-2, Y = 0 or SX = O, NH or S R5, when X = 0, = H, straight-chain or branched C1-12-alkyl, hydroxyalkyl, such as hydroxyethyl, or alkali or alkaline earth cations and, in particular, ammonium cations, ie salts of acids with ammonia or organic amines, such as, for example, hydroxyethylamine or trihydroxyethylamine, or R5, if X = NH, = H, NH2, optionally phenyl inhibited by 1-3 halogen atoms, heterocyclic groups, such as, for example, 2-thiazolyl, or b) R1 and R3 = R4 and R5 have the same meaning as in a), R6 = CH3n halogen or trifluoromethyl and m = 1-3.

The substances are known compounds like them are described in the following patents: US 3,352,897, US 2,390,942, DE-PS 915 876, DE-AS 1 115 515, FR-PS 1 222 916, GB-PS 8 22 199, GB-PS 57 34 77, DE-AS 11 24 296, GB-PS 10 41 982, CA-PS 570 065, US-PS 30 76 025.

Examples of compounds of general formula I are: 4-chloro-phenoxyacetic acid-N, O-methylamide, 2,4-dichlorophenoxyacetic acid, 2,4-dichlorophenoxyacetic acid hydrazide, 2-methyl-4-chlorophenoxyacetic acid hydrazide, 2-chloro-4-fluorophenoxyacetic acid, 2-chloro-4-fluorophenoxyacetic acid butyl ester, 4-chloro-2-methyl-phenoxyacetic acid, 4-chloro-2-methyl-phenoxythioacetic acid, N- (2-chlorophenyl) -4-chloro-2-methyl-phenoxyacetic acid amide, N- (3-trifluoromethylphenyl) -2,4-dimethyl-phenoxyacetic acid amide, 2,4-dimethylphenoxyacetic acid, 2,4,5-trichlorophenoxyessic acid, 2- (4-chlorophenoxy) propionic acid, 2- (2-methylphenoxy) propionic acid, 2- (2-Methyl-4-chloro-phenoxy) -propionic acid (Mecoprop) 2- (2-methyl-4-chloro-phenoxy} -propionic acid-N- (tri fluoromethylphenyl) amide, 2- (2,4,5-trichlorophenoxy) propionic acid (fenoprop), 2- [4- (2,4-dichlorophenoxy) phenoxy] propionic acid, 2- [4- (4-chlorophenoxy) phenoxy]] propionic acid, 4- (4-chlorophenoxy) butyric acid, 4- (4- Chloro-2-methylphenoxy) butyric acid (MCPB), 4- (2,4,5-trichlorophenoxy) butyric acid, but in particular 2,4-dichlorophenoxyacetic acid (2,4-D) and its salts and esters, like the sodium or ammonium salt or salts with ethanolamine or triethanolamine, 2,4,5-Trichlorophenoxyacetic acid (2,4,5-Trlphenac) and its salts and esters, which can be combined with a phosphate especially as selective Foliar herbicide for combating dicotyledonous weeds such as knotweed species, Use chamomile and thistle in cereals, maize, rice, sugar cane or grassland permit.

2. Urea derivatives of the general formula II in which R1, R2 = H, straight-chain or branched C1-4-alkyl, cycloalkyl, containing compounds, in particular chlorine, trifluoromethyl, nitro, alkoxy, optionally halogen-substituted phenoxy, where at most one of the groups R1 and R2 is H, R3 = H, CH3, C2H5, R4 = H, cycloalkyl, C1-4 alkyl, methoxy.

The compounds of general formula II are known compounds as described in the following patents: U.S. Patent 2 655 447, DE-PS 935 165, DE-PS 951 181, DE-OS 20 39 041, DE-OS 21 07 774, DE-OS 21 37 992, DE-OS 20 50 776, DE-PS 968 273, DE-OS 19 05 598.

Compounds of the formula II are, for example: 3-phenyl-1,1-dimethylurea (Fenuron), 1. (2-methyl-cyclohexyl) -3-phenylurea (Siduron), 3- (4-isopropyl-phenyl) -1,1-dimethylurea (Isoproturon), 3- (4-t-butyl-phenyl) -1,1-dimethylurea, 3- (4-chlorophenyl) -1,1-dimethylurea (Monuron), 3- (3,4-dichlorophenyl) -l, l-dimethyl urea (Diuron), N- (3,4-dichlorophenyl) -N-diethylurea, 1-n-Butyl-1-methyl-3- (3,4-dichlorophenyl) urea. (Neburon), N- (3-trifluoromethylphenyl) -1, l-d.lmethylurea (Fluometuron), 3- (3-chloro-4-methylphenyl) -1,1-dimethylurea (chlorotoluron), 3- (4-Chlorophenyl) -1-methyl-1- (1-methyl-prop-2-ynyl) -urea (Butoron), 1- (α, α-Dimethylbenzyl) -3- (4-methylphenyl) -urea , 3- (3-Chloro-4-methoxyphenyl) -1,1-dimethylurea (Metoxuron), 3-f (4-chlorophenoxy) -phenyl7-1,1-dimethylurea (Chloroxuron), 3- (4-chlorophenyl) -1-methoxy-1-methylurea (monolinuron), 3- (4-bromophenyl) -1-methoxy-1-methylurea (Metobromuron), 3- {3,4-dichlorophenyl) - ^ 1-methoxy-1-methylurea (linuron), 3- (3-chloro-4-bromophenyl ) -1-methoxy-1-methylurea (chlorobromuron), 3- [3-chloro-4- (chlorodifluoromethylthio) phenyl] -1,1-dimethylurea (Thiochloromethyl), but in particular: 3- (4-isopropyl-phenyl) -1,1-dimethylurea (Isoproturon) or 3- (3,4-dichlorophenyl) -1-methocy-1-methylurea (Linuron), which, in combination with phosphates, are particularly effective as selective pre- and post-emergence herbicides to combat grass weeds, such as Alopercurus myosuroides, Apera spicaventi, Poa spp., Avena fatura and annual weeds in winter wheat, winter barley and rye or weeds in vegetables, fruit and wine growing 3. Organic phosphorus and arsenic compounds such as 0,0-di-isopropyl-S [2- (phenylsulfonylamino) -ethyl] -dithiophosphate (Bensulide), n- (Phosphonomethyl) -glycine (Glyphosate), Ethylcarbamoylphosphoric acid salts, Methyl arsenic acid disodium salt, dimethyl arsenic acid.

4. Alcohols and aldehydes, such as ethyl xanthogen disulfide, alcyl alcohol, Acrolein.

5. Substituted alkanecarboxylic acid, e.g.

Monochloroacetic acid, N, N-diallylchloracetamine (allidochlor), 2,3,6-trichlorophenylacetic acid (chlorfenac), benzamidooxyacetic acid (benzadox), 4-chloro-2-oxobenzothiazolin-3-yl-acetic acid (benazolin), N, N-dimethyl- 2,2-diphenylacetamide (diphenamide), trichloroacetic acid, ethylglycol bis (trichloroacetate), methyl 2-chloro-3- (4-chlorophenyl) propionate (chlorophenprop), 2,2-dichloropropionic acid, methyl B-naphthyloxyacetate, 2- (1- Naphthyloxy) propionic acid-N, N-dimethylamide (naproamid) 6. Aromatic carboxylic acid derivatives of the general formula in which R1-R5, which can be the same or different, = halogen, NH2, methoxy, -COOH3, -COONH-naphthyl, NO2, with a maximum of 4 groups being H, A = -COOR6> -CONR7R8, -CSNR7R8, - COSR6, R6 = H, alkali, alkaline earth, alkyl, hydroxyalkyl, R7 = H, alkyl, R8 = H, alkyl, hydroxyalkyl, benzyl.

mean.

The substances of the general formula III are known compounds described in, for example, the following patents: U.S. Patent 3 027 248, GB-PS 987 253, US-PS 3,534,098, US-PS 3,013,054, US-PS 3,081,162, US-PS 2 923 634, GB-PS 671 153.

Compounds of the formula III are, for example: 2,6-dichlorobenzonitrile (dichlorbenil), 2,6-dichlorobenzoic acid thioamide (chlorothiamide), N- (1,1-dimethylpropynyl) -3,5-dichlorobenzamide (propyzamide), 3-amino-2, 5-dichlorobenzoic acid (chloramben), 3,6-dichloro-2-methoxy-benzoic acid (dicamba), 2,3,6-trichlorobenzoic acid, dimethyl-2,3,4,6-tetrachloroteraphthalate (chlorothal), N- (2- Naphthyl) phthalamic acid (naptalam); 7. Phenol derivatives of the general formula IV in which R1 5, which can be the same or different = H, NO2, straight-chain or branched C14-alkyl, halogen, nitrile, trifluoromethyl, where a maximum of 4 groups are H, and R4 = H, -COCH3, -CSOalkyl, -COCH2- Cl, -COO-alkyl, -N = CH-aryl, phenyl, optionally substituted by trifluoromethyl, nitro, alkyl, NH2, alkoxy, halogen.

The substances are known compounds such as they are described in the following patents: GB-PS 1,067,031, US-PS 2,192,197, GB-PS 1 096 037, DE-PS 10 88 757, US-PS 3 080 225, US-PS 3 652 645, DE-OS 14 93 512.

Examples of compounds of the general formula IV are: 3,5-dibromo-4-hydroxy-benzonitrile (Bromoxynil), 4-hydroxy-3,5-diiodobenzonitrile (ioxynil), 6-methyl-2,4-dinitro-phenol (DNOC), 2-sec-butyl-4,6-dinitro-phenol (Dinoseb), 3,5-dibromo-4-hydroxy-benzaldehyde-0- (2,4-dinitrophenyl) -oxime (Bromofenoxine) 2-sec-Butyl-4,6-dinitro-phenyl acetate (Dinosebacetet), 2,4-dichlorophenyl-4'-nitrophenyl ether (Nitrofen), 5- (2,4-dichlorophenoxy) -2-nitrobenzoic acid methyl ester (Bifenox), 2,4'-dinitro-4-trifluoromethyl-diphenylether (Fluorodifen), pentachlorophenol (PCP), 2,4-dinitro-3-methyl-6-tert-butylphenol acetate, 2,4-dinitro-6-sec-amylphenyl, 2,4,6-trichloro-4'-nitrodiphenyl ether, -3-methyl-4'-nitro-diphenyl ether, 2,4'-dinitro-4-trifluoromethyl-diphenyl ether, 2,4-dichlorophenyl-3'-methoxy-4'-nitrophenyl ether, but in particular 2,4-dinitro-6-methylphenol, which is in combination with Phosphates especially for combating seed herbs like E.g. chickweed, climbing rennet, chamomile, knotweed, speedwell, dead nettle and Saatwuchsblume, with cereals, maize or viticulture, if necessary with the addition of a Growth agent herbicides, or pentachlorophenol or 2,4,6-trichlorophenyl-1'-nitrophenyl ether, especially in the control of barn millet and sedge in rice cultivation.

8. Anilines of the general formula V in which R1 = H, C1-3-alkyl or nitro, R2 = H, halogen or NH2, R3 = C1-3-alkyl, H, -CF3, -SO2CH3 or -SO2NH2, R4 = H or C13-alkyl, R5 = H, NO2 or C1-3-alkyl, R6 = H, C1-3-alkyl, C1-4-alkoxymethyl or cyclopropylmethyl and R7 = branched or straight-chain C1-5-alkyl, or straight-chain or branched C1-7-acyl .

The substances are known compounds like them are described in the following patents: U.S. Patent 3,257,190, U.S. Patent 3,546,295, U.S.P. 2,863,752, DE-AS 11 66 547, US-PS 3,020 142, DE-AS 10 39 779, US-PS 3,442,945, UK-PS 1 164 160, DE-OS 22 41 408.

Examples of the compounds of the formula V are: N, N-dipropyl-2,6-dinitro-4-trifluoromethylanilide (Trifluralin), N-ethyl-N-butyl-2,6-dinitro-4-trifluoromethylaniline (benfluralin), N-Cyclopropylmethyl-N-propyl-2,6-dinitro-4-trifluoromethyl aniline (Profluralin), 3-diethylamine-2,4-dinitro-6-trifluoromethylaniline (Dinitramine), N- (1-ethylpropyl) -3,4-dimethyl-2,6-dinitroaniline (Penoxyn), N, N-dipropyl-4-methylsulfonyl-2,6-dinitroaniline (Nitraline), 4- (dipropylamino) -3,5-dinitro-benzenesulfonamide (Dryzalin), N, N-dipropyl-2,6-dinitro-4-iso-propylaniline (Isopropaline), N-iso-propyl-α-chloroacetanilide (propachlor), α, α-dimethylvaleryl-4-chloroanilide (Monalid), N- (3-chloro-4-methylphenyl) -2-methylvaleric acid amide (pentanochlor), Propionic acid 3,4-dichloroanilide (Propanil), 2,6-diethyl-N- (methoxymethyl) -2-chloroacetanilide (Alachlor), 2,6-diethyl-N- (butoxymethyl) -2-chloroacetanilide (butachlor), 2- (N-benzoyl-3,4-dichloroanilino) propionic acid ethyl ester, but in particular propionic acid-3,4-dchoranilide (Proopanil).

9. Carbamates of the general formula VI in which R1 = H, halogen, in particular chlorine, CH3 or NHCOOC2H5 and R2 = H, straight-chain or branched C1-4-alkyl, haloalkyl, haloalkynyl, alkynyl, 3- (methoxycarbamoyl) -phenyl.

The substances are known compounds like them z. B. are described in the following patents: US-PS 3,334,989, DE-AS 11 59 432, DE-AS 11 88 588, US-PS 3,150,179, GB-PS 574,995, US 2,695,226, DE-OS 15 67 151.

Examples of the compounds of the formula VI: iso-propyl-N-phenylcarbamate (Propham ?, 1-methyl- (ethylcarbamoylmethyl) -N-phenylcarbamate (Carbetamide), iso-propyl-N- (3-chlorophenyl) -carbamate (Chlorpropham), 4-chloro-2-butynyl-N- (3-chlorophenyl) -carbamate (Barban), 1-methylpropargyl-N- (3-chlorophenyl) -carbamate (Chlorbufam), methyl N- (4-aminobenzenesulfonyl) carbamate (Asulam) 2,6-di-tert-butyl-4-methylphenyl-N-methylcarbamate (Terbucarb), 3-MethoxyCarbonylaminophenyl-N- (3-Methylphenyl) -carbamate (Phenmedipham), 3-ethoxycarbonylaminophenyl-N-phenylcarbamate (Desmedipham), but in particular iso-propyl-N-phenylcarbamate, 3-methoxycarbonylamino-phenyl-N- (3-methylphenyl) -carbamate or 3-ethoxycarbonylaminophenyl-N-phenylcarbamate.

10. Triazines of the general formula VII in which R1 = halogen, in particular chlorine, methylthio or methoxy and R2 and R3 = straight-chain or branched C13-alkyl, optionally subst. with a nitrile group or azole group.

The substances are known compounds like them e.g. are described in the following patents: DE-OS 15 42 733, CH-PS 329 277, CH-PS 337 019, DE-AS 16 70 528, DE-AS 11 86 070.

Examples of compounds of the formula VII are: 2-azido-4-methylthio-6-iso-propylamino-1,3,3-triazine (Aziprotryn), 2,4-bis (ethylamino) -6-chloro-1,3,5-triazine (simazine), 2-ethylamino-4-chloro-6-isopropylamino-1,3,5-triazine (Atrazine), 2-methylamino-4-methylthio-6-isopropylamino-1,315-triazine (Desmetryne), 2- (4-ethyl amino-6-chloro-1, 3,5-triazin-2-ylamino) -2-methylpropiononitrile (cyanazine), 2-ethylamino-4-tert-butylamino-6-chloro-1,3,5-triazine (terbutylazine), 2-chloro-4,6-bis (isopropylamino) -1,3,5-triazine (Propazine), 2-ethylamino-4-methylthio-6-isopropylamino-1,3,5-triazine (Ametryne), 2-ethylamino-4-sec-butylamino-6-methoxy-1,3,5-triazine (secbumetone), 2-ethylamino-4-tert-butylamino-6-methoxy-1,3,5-triazine (Terbumetone), 2-methoxy-4,6-bis (isopropylamino) -1,3,5-triazine (Prometon), 2-ethylamino-4-tert-butylamino-6-methylthio-1,3,5-triazine (Terbutryne), 2-methylthio-4,6-bis (isopropylamino) -1,3,5-triazine (Prometryn), 2- (3-methoxypropylamino) -4-methylthio-6-isopropylamino-1,3 , 5-triazine (Methoprotryne), but in particular: 2- (4-ethylamino-6-chloro-1,3,5-triazin-2-ylamino) -2-methylpropiononitrile.

11. Triazinones of the general formula VIII in which R1 = alkyl, subst. Aryl or a cycloaliphatic radical, R2 = NH2, -NH-alkyl or N = CH-alkyl and R3 = C1t4-alkyl, alkoxy or alkylthio.

The substances are known compounds like them are described, for example, in the following patents: US-PS 3,671,523, DE-OS 24 07 144, U.S. Patent 3,847,914.

Examples of compounds of the formula VIII are: 4-Amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5 (4H) -one Metribuzin), 6-tert-butyl-4-iso-butylideneamino-3-methylthio-1,2,4-triazin-5 (4H) -one (Isomethiozine), but especially 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5 (4H) -one (Metamitron), 12. Other herbicides that can be used are, for example: 3,6-epoxy-cyclohexanedicarboxylic acid (Endothal), S-ethyl-N, N-diethyl-thiocarbamate (ethiolate), S-ethyl-N, N-hexane methane thiocarbamate (Molinate), S-ethyl-N, N-dipropyl-thiocarbamate (EPTC), S-ethyl-N-ethyl-N-cyclohexyl-thiocarbamate (Cyclate), S-ethyl-N, N-diisobutylthiocarbamate (butylate), S-propyl-N, N-dipropyl-thiocarbamate (Vernolate), S-propyl-N-ethyl-N-butvl-thiocarbamate (Pebulate) 2-chloroallyl-N, N-diethyl-dithiocarbamate (Sulfallate), S- (2,3,3-Trichlorallyl) -N, N-diisopropylthiocarbamate (Trillate), S- (2,3-D1chlorallyl) -N, N-disopropylthiocarbamate (Dialate), S- (4-chlorobenzyl) -N, N-d-methyl-thiocarbamate (benthiocarb), 1,3-dimethyl-1- (5-trifluoromethyl-1,3,4.thadlazol-2-yl ) -urea (thiazfluron), 1- (5-ethylsulfonyl-1,3,4-thiadiazol-2-yl) -1,3-dimethylurea (Sulfodiazole), 2-oxo-1-imidazolidincarboxylic acid-N-isobutylamide (isocarbamide), 1- (benzothiazolyl) -1 , 3-dimethylurea (methabenzthiazuron), 1,1-ethylene-2,2'-dipyridylium dibromide (Diquat), 1,1'-dimethyl-4,4'-dipyridylium dichloride (Paraquat).

The individual herbicides are used alone or in combination with others Herbicides with the addition of phosphates of the general formula I are used.

The new herbicidal compositions can by customary methods can be used, e.g. as a soil herbicide or leaf herbicide or as a systemic one Herbicides or contact herbicides as needed before sowing, after sowing or after emergence.

It is mainly used to remove weeds and Weed grasses such as

Alopeurus myosuroides, Bromus tectorum, Cyperus rotundus, Digitaria sanguinalis, Echinochlora crus galli, Eleusine indica, Festuca ovina, Lolium perenne, Phleum protense, Setaria italica, Poa annua, Setaria viridis, Sorghum hale pense, Abutilon theophrasti, Amaranthus retroflexus, Anthemis arvensis, Chenopodlum album, Chrysanthemum segetum, Convol utus arvensis, Agropyron repens, Apera pica-venti, Arrhenaterum elastius bulbosum, Pennisetum clandestinum, Ischaemum rugosum, Rottbuellia exaltata, Imperata cylindrica, Poa trivialis, Leptodiloa filiformis, Setaria faberii, Galium aparine, Cirsium arvense, Atriplex spp., Which are the cultivation of useful plants in Hinder or damage monocultures.

Examples of useful plants that protect against weeds and grass weeds are: oats, barley, rice, millet, wheat, maize, sugar beet, cane sugar, potatoes, Soybean, cotton, tobacco, coffee, fruit, vegetables or viticulture.

Virtually any desired insecticide can be used as the insecticide, for example the known chemical pesticides from the following groups: 1. Pyrethroids of the general formula I R1 = CH3, COOH, COOCH3, Cl, Br R2 = CH, Cl, Br R3 = subst. Cyclopentene, subst. Furylmethyl, phthalilimidomethyl, phenoxybenzyl or phenalkenyl groups.

Examples of compounds of the formula I: R1 R2 R3 - 1. -CH3 -CH3 CH3 ~ CL CH2-CH = CH-CH = CH2 pyrethrin I. 2. -COOCH3 -CH3 CH3 CH30CH2-CH = CH-CH = CH2 pyrethrin 11 0 3. -CH3 -CH3 CH3CH2-CH = CH-CH3 cinerine I. 0 4. -COOCH3 -CH3 CH3 <CH2-CH = CH-CH3 cinerine -II 0 5. -CH3 -CH3 CH3 <CH2-CH = CH-C2H5 Jasmolin I. O 6. -COOCH3 -CH3 CH3 -CH = CH-C, H5 Jasmolin II 0 1 R4 R .3. . 7: -CH3 -CHY '" 7 -CH3 CH3; $ i $ / CH2i [7il RO Furethrin urethri n 0 5 CH 8. -CH3 -CH3%) H2CH = CH2 allethrin CH 9. -CH3 CH3 3 cyclethrin OK Cl 10. -CH3 CH3 CH) ¼ bathrin CH 3CH3 ß 1 -CH3 CH3 -CH2 dimethrin 2 12. -C (3 -CH3 -CH2 -) Ö phthalhrin 30th 13. -CH3 -CH3 -CH2 - WCH2-CH = CH2 Japothrin -CH 14. -CH3 CH3 ZH ?? Oo pyresthrin > 5 15. -CM3 CH3 -CH2-CH = C-CH2 - butethrin 1 66 -CH3 -CH3 -CH2 - & - t penothrin 17. -C1 -C1 -CH2 X ° ~ X Permethri n 18. -Br -Br -CH »~ ° ~ t decamethrin ch

The compounds of the formula I are known compounds which have already proven themselves as insecticides (chemistry of plant protection and Pesticides, Sprinqer 1970, p. 87 ff).

The compounds of the formula I are sparingly soluble in water and are sensitive to heat and are easily inactivated in air.

Draw combinations of the compounds of formula I with phosphates in particular that the stability to air and temperature is greatly improved. It is also possible to use aqueous solutions and emulsions without having to use questionable organic solvents. Even the often unpleasant odor of the compounds is due to the addition of phosphates of the general formula I reduced. The killing of the insects is achieved by adding the phosphates increased considerably without increasing the toxicity on warm-blooded animals will. Combinations of permethrin or decamethrin with are particularly preferred Phosphates of formula I.

2. Chlorinated hydrocarbons of the general formula II R1 = halogen, especially chlorine, methoxy, C1-3-alkyl R2 = polychloralkyl, nitroalkyl groups such as: 2,2-Bsi- (p-chlorophenyl) -1,1,1-trichloroethane (DDT), 2,2- Bsi- (p-methoxyphenyl) -1,1,1-trichloroethane (methoxychlor), 2,2-bis- (p-fluorophenyl) -1,1,1-trichloroethane (DFDT), 2,2-bis- (p -chlorphenyl) -1,1-dichloroethane (TDE), 2,2-bis- (p-ethylphenyl) -1,1-dichloroethane (Perthane), 2-nitro-1,1 = bis- (p-chlorophenyl) - butane (Bulan), 2-nitro-1,1-bis (p-chlorophenyl) propane (Prolan).

Mixtures of: 2,2-bis- (p-chlorophenyl-l, l, l-trichloroene) are preferred or 2,2-bis (p-methoxyphenyl) -1-, 1,1-trlchloroethane with alkyl phosphates. advantage This mixture is that through the complex formation of the substances with the alkyl phosphates water-soluble or easily emulsifiable mixtures without the use of questionable organic solvents can be produced.

3. Polychlorocycloalkanes such as: γ-1,2,3,4,5,6-hexachlorocyclohexane (Lindane), 1, 2,4,5,6,7,8-octachloro-4,7-methano-3a, 4 7,7a-tetrahydroindane (chlordane), 1,4,5, 6,7-heptachlor-4,7-methano-3a, 4,7,7a-tetrahydroindane (heptachlor), 2-exo-4,5,6,7,8-heptachlor-4,7 -methano-3a, 4,7,7a-tetrahydro-indane (Dihydroheptachlor), 1,3,4,5,6,7,10,10-octachloro-4,7-endomethylene-4,7,8,9-tetrahydrophthalane (Isobenzane), 6,7,8,9,10,10-hexachloro-1,5,5a, 6,9,9a-hexahydro-6,9-methano-2,4,3-benzodioxathiepin-3-oxide (Endosulfan), 5,6-bis- (chloromethyl) -1,2,3,4,7,7-hexachlorobicyclo 2,2,1-hepten-2- (Alodan), 5-bromomethyl-1,2,3,4,7,7-hexachlorobicyclo-2,21-hepten-2 (bromodane), 1,2,3,4,10,10-hexachloro-1,4,4a , 5,8,8a-hexahydro-endo-1,4-exo-5,8-dimethanophthalene (Aldrine), 1,2,3,4,10,10-hexachloro-6,7-epoxy-1,4,4a, 5,6,7,8,8aocta-hydro-endo-1,4-oxo- 5,8-dimethanophthalene (Dieldrin), 1,2,3,4,10,10-hexachloro-6,7-epoxy-1,4,4a, 5,6,7,8,8aocta-hydro-endo-1,4-endo- 5,8-dimethanonaphthalene (Endrin) Mixtures of lindane, aldrin, dieldrin or endrin are particularly preferred with phosphates. In addition to the significant improvement in the result of exposure Aqueous solutions or emulsions can be produced on the insects without Use of toxic solvents.

4. Phosphoric acid esters of the general formula III in which R1 = C1 4-alkyl, especially CH3 or C2H5, R2 = alkoxy, especially methoxy or ethoxy, C1-4-alkyl, especially ethyl, or aminoalkyl, especially amino-C1 4-alkyl, A = either a) - ( CH2) nZ-R3, where n = 1-3, Z = S, SO or SO2, R3 = straight-chain or branched C14 alkyl, subst. Aryl, especially with chlorine, methyl or nitro subst. Phenyl or a radical of the general formula III, or b) chlorine, methyl or substituted by nitro.

Phenyl, oS-subst. Benzyl, an alkenyl carboxylic acid ester group or an alkenylcarboxamide group, or c) a heteroaryl group, such as subst.

Pyridyl, pyrimidinyl, quinoxalyl, isocalyl, triazolyl, phthalyl, Benztriazinyl, benzoxazolyl, thiadiazolyl, triazinolyl group.

The compounds of the general formula III are known compounds, such as: 0,0-diethyl-0- (ethylthio) -ethyl-thiophosphate (Demeton-0), 0,0-diethyl-S- (ethylthio) -ethyl-thiophosphate (Demeton-S), O, 0-dimethyl-S- (ethylthio) -ethyl-thiophosphate, 0,0-diethyl-S- (2-ethylsulfinyl-1-methyl) -ethyl-thiophosphate, O, O-diethyl-O- (ethylsulfinyl) -ethyl-thiophosphate, 0,0-diethyl-S- (2-ethylthio) ethydithiophosphate (Disulfoton), 0,0-dimethyl-S- (2-ethylthio) -ethyldithiophosphate, O, O -dlethyl-S- (2-ethylthio) -methyldithiophosphate (Phorate), O, O-Diethyl-S- (tertbutylthio) -methyidithiophosphate (Terbufos), 0,0-Diethyl-S - [(4-chlorophenylthio) -methyl] -dithiophosphate, S, S-methylene-bis (0,0-diethyl) -dithiophosphate (ethione), 0,0-dimethyl-S- [1,2-bis- (ethoxycarbonyl) -ethyl] -dithiophosphate (Malthion), 0,0-dimethyl-S - [(N-methyl-carbonyl) -methyl] -dithiophosphate (dimethoate), O, O-Diethyl-S - [(N-isopropyl-carbamoyl) -methyl? -Dithiophosphate (prothoate), 0,0-dimethyl-S - [(N- (1-cyano-1-methyl-ethyl) -carbamoylmethylj thiophosphate (Cyanthoate), O, O-diethyl-S-r (N-ethoxycarbonyl-N-methyl) -carbamoylmethylj-dithiophosphate (Necarbam), 0,0-dimethyl-S- [α- (ethoxycarbonyl) -benzyl] -dithiophosphate (phenthoate), 0,0-Dimethyl-S-Z2- (N-methylcarbamoyl) -ethylthio7-ethylthiophosphate (Vamidothion), 0,0-dimethyl-0- (2,2-dichlorovinyl) -phosphate (dichlorvos), 0, Os-dimethyl-0- (1-methoxycarbonyl-1-propen-2-yl) -phosphate (Mevinphos), tran-O, O-dimethyl-0- (2-methoxycarbonyl-2-methyl-vinyl) -thiophosphate (Methacrifos), 0,0-dimethyl-O-L1-chloro-1- (N, N-diethylcarbamoyl) -1-propen-2-ylj-phosphate (Phosphamidone), 0,0-dimethyl-0- [1- (n, N-dimethylcarbamoyl) -1-propen-2-yl] -phosphate (Dicrotophos), 0,0-diethyl-0-z2-chloro-1- (2,4-dichloro-phenyl) -vinyl7-phosphate (chlorfenvinphos), 0,0-dimethyl-0- [2-chloro-1- (2,4,5-trichlorophenyl) vinyl] phosphate (tetrachlorvinphos), 0,0-dimethyl-0- (4-nitrophenyl) -thiophosphate (parathion), 0,0-dimethyl-0- (3-methyl-4-nitro-phenyl) -thiophosphate (Fenitrothion), 0,0-dimethyl-0- (2,4,5-trichlorophenyl) thiophosphate (Fenchlorphos), 0,0-dimethyl-0- (4-bromo-2,5-dichlorophenyl) thiophosphate (bromophos), 0,0-Dimethyl-0- (3-methyl-4-methylthiohexyl) -thiophosphate (fenthion), O-methyl-0- (4t-butyl-2-chlorophenyl) -N-methyl-phosphamidate- (Crufomat), O-ethyl-S-phenylethanedithiophosphate (Fonofos), 4,4'-bis (methoxy-phosphinothiyloxy) -diphenyl sulfide (Temephos), O, 0-Diethyl-O- (2-isopropyl-6-methyl-4-pyrimidinyl) -thiophosphate (Diazinon), 0,0-Diethyl-0- (2-diethylamino-6-methyl-4-pyrimidinyl) -thiophosphate (Pyrimiphos), 0,0-Diethyl-0- (3,5,6-trichloro-pyridyl-2-thiophosphate (ChJorpyrifos),% 0,0-diethyl-0- (2-quinoxalyl) -thiophosphate (Quinalphos),% 0,0-Diethyl-0- (S-phenyl-3-isoxazolyl) -thiophosphate (isoxathione), 0,0-diethyl-0- (1-phenyl-1,2,4-triazol-3-yl) -thiophosphate (Triazophos), 0,0-diethyl-0- (5-chloro-1-1sopropyl-1, 2,4-triazol-3-yl) thiophosphate (Isazofos), O, O-dimethyl-S- (phthalimido-methyl) -dithiophosphate (Phosmet), 0,0-dimethyl-S - [(1,2,3-benztriazin-4 (3H) on-3-yl ) methyl / dithiophosphate (Azinphosmethyl), 0,0-diethyl-S-r (6-chloro-benzoxazol-2 (3H) on-3-yl) -methyl 7-dithiophosphate (Phosalone), 0,0-Dimethyl-S - [(2-methoxy-1,3,4-thiadiazol-5 (4H) on-4-yl) -methyli-dithiophosphate (Methidathione), 0,0-dimethyl-S - [(6-chloro-oxazolone-4,5-6-pyridin-2 (3H) -on-.3-yl) -methyl-thlophosphate (Azamethiphos), 0,0-Dimethyl-S - [(4,6-diamino-1,3,5-triazin-2-yl) methyl] dithiophosphate (Menazon), 0,0-Di-methyl-S - [(5-methoxy-4H-pyrone-2-yl) -methyly-thiophosphate (Endothion), 0,0-Diethyl-S - [(5,7-dichloro-2-benzoxazolyl) methyl] dithiophosphate (Benoxafos), 0,0-dimethyl-2,2,2-trichloro-1-hydroxy-ethane-phosphonate (trichlorphone), 2,3-bis- (diethoxy-phosphinothioylthio-1,4-dioxane (diocathion), 2- (diethoxyphophinylimino) -1,3, dithiolane (Phosfolane), O, S-dimethyl-thiophosphamidate (Methamidophos), 2-methoxy-4H-1,3,2-benzodiocaph ~ osphorin-2-sulfide, Diethoxyphosphinothioyl-oxyimino) -phenyl-acetonitrile (Phoxim), 0,0-dimethyl-0- (7-chloro-bicyclo- [3,2,0] -hepta-2,6-dien-6-yl) -phosphate (Heptenophos), O-ethyl-S, S-dipropyldithiophosphate (Ethoprophos), O-ethyl-S-propyl-0- (2-chloro-4-bromo-phenyl) -thiophosphate (Profenofos), O-Ethyl-S-propyl-O- (4-methylthio-phenyl) -dithiophosphate (Merpafos), The following phosphoric acid esters are particularly preferred: Heptenophos [0,0-dimethyl-0- (7-chlorobicyclo- [3,2,0] -hepta2,6-dien-6-yl) -phosphate], Demeton-S-methyl [0,0-dimethyl-S- (methylthio) -ethylthiophosphate], Oxydemeton-methyl [0,0-Dimethyl-S- (ethylsulfinyl) -ethylthiophosphate], Etrimphos t0- (6-ethoxy-2-ethyl-4-pyrimidinyl) 0,0-dimethylthiophosphate].

Parathion r0,0-Diethyl-0- (4-nitrophenyl) -thiophosphate, [0,0-Dimethyl-0- (4-nitrophenyl) -thiophosphate, Triazophos [O, O-Diethyl-O- (1-phenyl-1,2,4-triazol-3-yl) -thiophosphateg, in particular however, parathion, especially to combat it of letting and sucking insects, against hayworms and sourworms, spider mites, scale insects, Rube flies, Beetle.

Caterpillars, anal caterpillars, vesicle foot etc.

5. Aryl carbamates of the general formula IV R1 = CH3 or H, R2 = H, dialkylamino, C1-4-alkyl, C1-4-alkoxy or C1-4-alkylthio, R3 = H, straight-chain or branched C1-5-alkyl or dimethylaminomethylimino, R4 = H, C14 -Alkyl, C1-4 alkoxy, C1-4 alcohol, dioxolane, or alkylthiomethyl, where R3 and R4 together are, for example, the groups -OC (CH3) 2-O-, -CH = CH-CH = CH- or -CH2 -C (CH3) 2-0- can mean.

The compounds of the general formula IV are known compounds, such as: 4-diallylamino-3,5-dimethylphenyl-methyl-carbamate (allyxycarb), 4-dimethylamino-3-methylphenyl-methyl-carbamate (Aminocarb), 2,2-dimethyl-1,4-benzodioxol-4-yl-methylcarbamate (bendiocarb), 2-sec-butylphenyl-methylcarbamate (BPMC), 3- (1-methylbutyl) -phenyl-methylcarbamate (Bufencarb I), 3- (1-ethylpropyl) -phenyl-methylcarbamate (Bufencarb II), 1-naphthyl-methylcarbamate (carbaryl), 2,3-dihydro-2,2-dimethylbenrofuran-7-yl- carbamate (carbofuran), 2- (1,3-Dioxolan-2-yl) phenyl methyl carbamate (Dioxacarb), 2-Ethylthio-methylphenyl-methylcarbamate (Ethilfencarb), 3-DimethylamRno-methylenimino-phenylmethyl-carbamate (Formetanate), 3,5-dimethyl-4-methylthiophenyl-methylcarbamate (mercaptodimethur), 4-dimethylamino-3,5-dimethylphenylmethylcarbamate (mexacurbate), 3,4-di- (carbamoylthio) -2-dimethylaminopropane hydrochloride 3-isopropyl-5-methylphenyl-methylcarbamate (Promecarb), 2-isopropoxyphenyl-methylcarbamate (Propoxur), but especially Propoxur (2-isopropoxyphenyl-methylcarbamate).

6. Other known insecticides that can be used are e.g.

2-methyl-2- (methylthio) -propylideneamino-methylcarbamate (Aldicarb) , 1- (methylthio) -ethylideneamino-methylcarbamate (methomyl), N, N-dimethyl - -met hylcarba moyloxyimino-d - (methylthio), acetamide (oxamyl), 1,3-di- (carbamoylthio) -2-dimethylaminopropane hydrochloride (Cartap), 2-dimethylamino-5,6-dimethylpyrimidin-4-yl-dimethylcarbamate (pirimicarb), 4- (4-chloro-2-methylphenyl) -N'-dimethylformamidine (Chlordimeform), N, N-di- (2,4-xylyliminomethyl) -methylamine (Amitraz), but in particular: Aldicarb 2-methyl-2- (methylthio) -propylideneamino7-methylcarbamate.

Of the insecticides mentioned in the individual groups 1-6 are the following preferred: permethrin, decamethrin, DDT, methoxychlor, lindane, aldrin, dieldrin, Endrin, Heptenophos, Demeton-S-methyl, Oxydemeton-methyl, Etrimphos, Parathi on, Triazophos, Propoxur, Aldicarb.

The individual insecticides are used alone or in combination with others Insecticides with the addition of phosphates of the general formula I are used.

The new insecticide compositions can help combat dormant stages of insects and mites (winter spray), to combat all stages on the growing plant (leaf application), to combat insect larvae (soil application), and used to combat insect infestation on harvested goods (storage protection) will.

Areas of application for the new isecticidal compositions are e.g. the control of locusts, ground insects, spider mites, scale insects, cicadas, Thrips, such as wireworms, grubs, leaf hoppers, larvae of weevils, earthworms, Cabbage fly larvae; Fallow fly larvae, particularly in the case of cereals; Frit fly. in particular with corn, oats, barley; Mole bugs, ants, springtails, millipedes, Termites, woodlice, aphids, capsule beetles, especially with cotton; Stem drill especially with rice and corn; Flies and mosquitoes, especially in the case of cereals; Colorado potato beetle, Beetle beetles, pollen beetles, weevils, caterpillars and flies, in particular in vegetable growing; Fruit maggots, caterpillars, leaf mammals, in particular in fruit growing; Grape moth, phylloxera, Beetles and caterpillars, in particular in viticulture; Caterpillars and bugs, in particular when growing tea; Caterpillars, bugs, mealybugs in cocoa cultivation; all types of beetles in banana cultivation; Fruit flies, in particular in citrus fruit cultivation; Olive fly, olive moth in particular in olive growing; Caterpillars, beetles and leaf wasps in forestry.

Practically any fungicide can be used as the fungicide, for example the known fungicides from the following groups: 1. Aromatic nitro compounds of the general formula I in which R1 = C2 is 4-alkenyl or branched alkoxy, in particular C1-4-alkoxy, R2 "is C2-6-alkyl.

The compounds of the formula I are known compounds.

Suitable examples are: 2,4-dinitro-6- (2-butyl) -phenyl-3 ', 3'-dimethylacrylic acid ester (Binapacryl), 2,4-dinitro-6- (2-butyl) -phenyl-isopropyl-oxy -carboxylic acid ester (dinobutone), 2,4-dinitro-6- (2-octyl) -phenyl-crotonic acid ester (dinocap) 2. Chlorobenzenes of the general formula II in which R1 = Cl or H; R2 = Cl, -OCH3 or H; R3 = Cl or -CN, R4 = C1 or H and R5 = -CN, -OCH3 or -NO2.

The compounds of the formula II are known compounds.

Suitable examples are: hexachlorobenzene, petachloronitrobenzene (quintozen), 1,3-dicyan-2,4,5,6-tetrachlorobenzene (chlorothalonil), 1,4-dichloro-2,5-dimethoxybenzene (Chloroneb), 2,3,5,6-tetrachloronitrobenzene (Teenazen).

3. Phthalic acid derivatives of the general formula III in which R = alkylthio, especially C1-4-alkylthio, especially methylthio, haloalkyl, especially C1-4-haloalkyl, especially trichloromethyl or thionophosphoryl.

The compounds of the formula III are known compounds. In question come e.g.

Ditalimphos [N- (diethoxy-thiophosphoryl) -phthalimide], captan [N- (trichloromethylthio) -tetrahadrophthali-folpet [N- (Trichloromethylthio) phthalimide], Captafol LN- (1,1,2,2-tetrachloroethylthio) phthalimide7, Chlorothalonil or nitrothal.

4. A fungicide from the series of thiocarbamates: Ferbam, Macozeb, Maneb = manganese-ethylene-1,2-bis-dithiocarbamate, metiram, methylmetiram, propamocarb, Propineb = tin-propenyl-1,2-bis-dithiocarbamidate, prothiocarb = S-ethyl-N- (3-dimethylaminopropyl) -thiocarb amat-hydrochlird, Vondozeb, Zineb = zinc-ethylene-1,2-bis-dithiocarbamidate, Zinoc = N-methylene-bis- (zinc-ethylene-bis-duthiocarbamidate), Ziram = zinc-dimethyldithiocarbamate, Thiram = bis (dimethylthiocarbamoyl) disulfide.

5. A fungicide from the benzimidazole series, such as benomyl = 1- (n-butylcarbamoyl) -2-methoxycarbonylamino) benzimidazole, carbendazine = 2- (methoxycarbonyl-amino) -benzylimidazole, fuberidazole = 2- (2-furyl) -benzimidazole, rabenzazole, thiabendazole = 2- (4-thiazolyl) -benzimidazole, 6. A fungicide from the group of aniline derivatives, e.g .: benodanil = 2-iodobenzoic acid anilide, Carboxin = 2,3-dihydro-2-methyl-1,4-oxathiin-3-carboxanilide chloraniformethyn = N-Formyl-N'-3,4-dichlorophenyltrichloroacetate aldehyde aminal, diclorane = 2,6-dichloro-4-nitroaniline Fenfuram, Furaloxyl, Methfuroxam Oxycarboxin "2,3-Dihydro-6-methyl-1,4-oxathiin-5-carboxylic acid anilide-S-dioxide 7. Other fungicides that can be used: Thiophanate = 1,2-bis- (3-methoxycarbonyl-2-thioureide) -benzene, Dodemorph = N-cyclododecyl-morpholinium acetate, Tridemorph = N-tridecyl-2,6-dimethylmorpholine, Anilazine = 2,4-dichloro-6- (o-chlornailino) -S-triazine, bupirimate = 2-ethylamino-4-dimethylaminosulfonate-S-butyl-6-methyl-pyrimidine, Cetactaelate, quinomethionate = 6-methylquinoxaline-2,3-dithiocyclocarbonate, chloromethionate, Dichlorofluanide = N, N-dimethyl-N'-phenyl-N'-fluorodichloromethylthio-sulfamide, dimethirimol = 5n-butyl-2-dimethylamino-4-hydroxy-6-methyl-pyrimidine, Dithianon = 2,3-dicyana-1,4-dithia-anthrquinone, dodine = n-dodeylquanidine acetate, ethirimol = 2-ethylamino-5n-butyl-4-hydroxy-6-methylpyrimidine, fenaminsulf = p-dimethylaminobenzene disulfonate sodium salt, Fenarimol 5 A / - (2-chlorophenyl) -PC / -I4-chlorophenyl) -5-pyrimidine-meth'hanol, iprodione = 1-isopropylcarbamoyl -3- (3,5-dichlorophenyl) hydantoin, pyrazophos = 0, 0-diethyl-O- (5-methyl-6-ethyloxycarbon pyrazolo- [1,5-a] -pyrimidin-2-yl) thiophosphate, tolylfluanid = N, N-dimethyl-N '- (4-methylphenyl) -N'-fluorodichloromethylthio-sulfamide, Triadimefon = 1- (4-chlorophenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) -2-butanone, Triadimenol, triflorine = 1,4- (2,2,2-trichloro-1-formamidocityl) -piperazine, vinclozoline = 3- (3'5'-dichlorophenyl) -5-methyl-5-vinyl-1,3-oxazolidine-2,4-dione.

The individual fungicides are used alone or in combination with others Fungicides with the addition of phosphates of the general formula 1 are used. the New fungicide compositions can be used to combat a wide variety of fungal diseases can be used. For example, in potato and tomato blight spots (Alternaria solani); Gray mold rot of onion (Botrytis allil); Gray mold rot, Botrytis rot of strawberries and grapes; Dutch elm disease (Ceratocystis ulmi); Leaf spot disease of beets (Cercospprabeticola); Banana spot disease (Cercospora musae); Peach scab (Cladosporium carpophilum); Cucumber scabies (Cladosporium cucumcrinum); Brown or Velvet spots of tomato (Cladosporium fulvum); Shotgun disease of stone fruit (Clasterosporium carpophilum); Rye ergot (Clavicep purpurea); Spray stains sick on cherries (Coccomyces hiemalis); Burning spot disease of beans (Colletotrichum lindemuthianum); Leaf spot disease of rose t Diplocarpon rosae); Soot in roses (Marssonia rosae); Cucumber powdery mildew (Erysiphe cichoracearum); Grain powdery mildew (Erysiphe graminis); Bladder disease on tea (Exobasidium vexans); Stem rot (Fusarium culmorum); Wilt disease of tomatoes (Fusarium oxysporum); Panama Disease of Bananas; Snow mold of the grain (Fusarium nivale); Cherry scab (Fusicladium cerasi); Pear grate (Gymnosporangium sabinae); Streak disease the barley (Helminthosporium gramineum); Coffee rust (Hemileia vastatrix); Black-leaved (Mycena.citricolor); Blue mold disease on tobacco (Pernospora tabaclna); root burn of beets (Phomabetae) ;, rose rust; Apple collar rot, late blight and tuber rot the potato, brown rot of the tomato (Phytophthora infestans); Brusone disease on rice (Pyricularia oryzae); Leaf fall disease; Leather berry disease; Apple powdery mildew (Podosphaera leucotricha); Hop powdery mildew (Spaerotheca humuli); Rose powdery mildew (Spaerotheca pannosa); Potato cancer (Synchytrium endobioticum); Stink brand; Wheat stone brandy (Tilletia caries); Open oat brandy (Ustilago avenae); Barley blight (Ustilago nuda); Wheat blight (Ustilago tritici); Apple scab; Pear scab; Verticillim wilt; Wilting diseases of the potato; Cotton and other crops.

Practically any acaricide can be used as the acidic agent, for example the known chemical acaricides of the following groups: 1. Compounds of the general formula I in which R1 s H, CH3, alkoxy, alkoxymethyl, alkoxycarbomyl, alkynyl, R2 = CM3, CF3 CC13; OH, H, mean.

The compounds of formula I are, for example: 1,1-bis- (4-chlorophenyl) -2,2,2-trichloroethane, 1,1-bis- (4-chloro-phenyl) -2,2,2-triflurethane, 1,1-bis- (4-chloro-phenyl) -ethane, bis- (4-chloro-phenyl) -methane, 1,1-bis- (4-chloro-phenyl) -ethanol (chlorfenethol), 1,1-bis- (4-chloro-phenyl) -2,2-dichloroethanol, 1,1-bis- (4-chloro-phenyl) -2-chloroethanol, 1,1-bis- (4-chloro-phenyl) -2,2,2-trichloroethanol (Dicofol), 1,1-bis- (4-chloro-phenyl) -2-ethoxyethanol, 4,4'-dichloro-benzilic acid ethyl ester (Chlorobenzilate), 1,1-bis- (4-chlorophenyl) -propinol, 4,4'-dichlorobenzilic acid isopropyl ester (Chloropropylate).

2. Compounds of the general formula II in which R1 = N02, straight-chain or branched alkyl, R2 = H, alkenylcarbonyl, Alko.xyzarbonal and R3 = cycloalkyl, branched C1-8-alkyl.

The compounds of formula II are known Acarizlde, such as: 4,6-Dinitro-2-cyclohexylphenol, 4,6-dinitro-2-cyclohexylphenol salts, 4-nitro-2,6-di-tert-butylphenol, 4,6-dinitro-2- (1-methyl-heptyl) -phenyl-crotonate (Dinocap), 4,6-dinitro-2-sec-butyl-phenyl-β-B-dimethylacrylate (Binapacryl), ethyl- (4,6-dinitro-2-tert-butyl-phenyl) -carbonate, Isopropyl (4,6-dinitro-2-sec-butyl-phenyl) carbonate (dinobutone).

3. Compounds of the general formula III in which X = S, SO or SO2, n = 0, O or 1, R1 to Rg = H, NO2, halogen, in particular Cl or F, R1 9 can be identical or different).

The compounds of the formula III are known acaricides, such as: 2,4,5,4'-tetrachlorodiphenyl sulfide (Tetrasul), diphenyl sulfone, 4-chloro-diphenyl sulfone, 2,4,5,4'-tetrachlorodiphenyl sulfone (Tetradifon), (4-chlorophenyl) - (4-chlorobenzyl) sulfide (chlorine surfactant), (4-fluorophenyl) - (4-chlorobenzyl ) sulfide (fluorosurfactant).

The following preparations, for example, can be used as other known acaricides are: quinoxaline-2,3-trithio-cyclic carbonate (thioquinox), 6-methyl-quinoxaline-2,3-dithio-cyclic carbonate (Quinomethionate), N-methyl-carbamic acid- (4-methylmercapto-3,5-dimethyl-phenyl) -ester (M-ethiocarb) N- (2-MEthyl-4-chloro-phenyl) -N ', N'-dimethyl-formamidine (Chlordimeform), 2,4,5-trichloro-phenylaza-4-chloro-phenylsulphide (chlorofensulphide), 4-chloro-benzenesulphonic acid (Chlorfenson).

N- (3-methylaminocarboxy) -N'N'-dimethyl-formamidine (formetanate), preferred but are Dinoc, Benapacryl, Dinobuton, Tetrasul, Chlorobensid, Tetradifon, Propargit, Chlorfenethol, dicofol, chlorobenzilate, chloropropylate, bromopropylate, chlorodimephone, Formetarate, quinomethioate, or thiquinox.

The individual acaricides can be used alone or in combination with others Acaricides or if necessary, also insecticides with the addition of phosphates of the general Formula I can be used.

The new acaricide compositions can be used, for example, in fruit, vegetable, Ornamental plants, vines and hops are used, e.g. to control spider mites, such as Tetranychus urticae, Tetranychus telarius, Panonychus ulmi, Panonychus ci tri, or from the most varied of Bryobia species of 'false spider mites', e.g. the most varied Brevipalpus species; from soft skin mites such as Hemitarsonemus catus, Tarsonemus pallidus; or from gall mites such as Phyllocoptruta oleivora and numerous species the genera Eriophyes, Phyllocoptes, Aceria and Vasates.

Practically any nematicide can be used as a nematicide, see above such as: 0- (2,4-dichlorophenyl) -O, O-diethylthiophosphate (dichlofenthione), thiophosphoric acid-O, O-diethyl-O-2-pyrazinyl ester (Zinophos), 0, O-Diethyl-0- (4-methyl-sulfinyl-phenyl) -thlophosphoric acid ester (Fensulfothion), 2-methyl -2- (methylthlo) -proplonaldehyde-o- (methylcarbonyl) -oxime (aldicarb), 3,5-dimethyl-1,3,5-2H-tetrahydrothiadizin-thione- (2) (Dazomet), dichloropropene (dichloropropane / dichloropropene mixture), the individual nematicides can be used alone or in combination with other nematicides or, if necessary, herbicides or acaricides with the addition of phosphates of the general formula 1 are used will.

The new nematicidal compositions can be used, for example, on the following nematodes are used: for free-living root nematodes, such as Pratylenchus, Rotylenchus, Tylenchorhynchus, Trichodorus, Longidorus, Xiphinema species everything on the roots of cereals, beets, potatoes, vegetables, carrots, fruit growing, banana growing, Coffee or tea growing; in root knot nematodes such as Meloidogyne species especially for tobacco, cotton, vegetables and ornamentals; in cyst nematodes, e.g. Heterodera species, with potatoes, oats, hops, clover, vegetables, etc. in stem nematodes, in particular Ditylenchus species, in rye, tobacco, beets, onions, maize, oats, clover, ornamental plants; and in Battnematoden, especially Aphelenchoides species, mainly in rice, Coconut, strawberries and ornamental plants.

The preparation of the new pesticide compositions can be as follows Wise done: the phosphate or a mixture of several phosphates is in organic Solvents such as toluene, ethyl acetate, xylene, gasoline, ethanol or methanol or Mixture of these solvents, dissolved. The selection of the solution means or solvent Mixing takes place depending on the dissolving behavior of the pesticide used. In the Phosphate solution is added. the pesticide is dissolved by heating. After the termination During the dissolving process, the solvent is distilled off in vacuo with warming.

The product obtained in this way is made by adding suitable auxiliaries, such as fillers, carriers, diluents, wetting agents, stabilizers, Gelling agents, evaporation accelerators, gelling agents and extenders or auxiliaries, the spraying or misting of the pesticide compositions according to the invention promote, converted into a customary, suitable form of trade.

The new pesticidal compositions can also be prepared in this way that the pesticide with the phosphate or phosphates and the necessary auxiliary and fillers are mixed, the mixture in an organic solvent is dissolved or slurried and then the solvent is drawn off again. A ready-to-use mixture is obtained.

For pesticides that are soluble in water or water-alcohol mixtures the pesticide is advantageously first in water or the water-alcohol mixture dissolved and the phosphate or alkyl phosphate mixture added and the product under Stirring or processed into a solution or emulsion by the application of ultrasound. The emulsifiers usually required can be used before or after this stirring process can be added. The emulsion or solution thus obtained is usually such as e.g. by distillation, spray drying or lyophilization of the solvent mixture or freed from the water. The resulting product can then be used as a finished product or may be used with the addition of suitable auxiliaries. Also the product can re-emulsified or dissolved in water and used as a spray preparation. Phosphate solutions or emulsions with organic or aqueous-organic can also be used Solvents or water prior to liquid discharge to those on the market Means are added.

The new pesticide compositions can by conventional methods be applied to the soil or plants in the form of sticks, Litter, granules or as an aqueous preparation in the form of soluble concentrates, emulsifiable concentrates or dispersible concentrates.

For the application of the pesticides you need in most cases Carriers or auxiliaries in order to convert relatively small amounts of active ingredient to large Distribute units of area evenly. In addition to carrier substances, thinners, Wetting agents, stabilizers, gelling agents, evaporation accelerators, Penetrlermi ttel or extenders can be used.

Carriers are e.g .: talc, kaolin, bentonite, silica gel, lime or rock flour. Further aids are e.g. surface-active compounds, such as soaps (fatty acid salts), fatty alcohol sulfonates or alkyl sulfonates. As satilizers or protective colloids can be gelatin, casein, albumin, starch, or methyl cellulose can be used. The phosphates can also with the addition of herbal Ule, such as soybean oil, can be used. - Example 1 Manufacture of 1 liter. of a herbicide emulsion concentrate (95 g / 1) with 2-methyl-4-chlorophenoxyacetic acid as an active ingredient.

95 g of 2-methyl-4-chlorophenoxyacetic acid, 150 g of (2,3-di-hexadecanoyloxy) propyl 2-trimethylammonioethyl phosphate 8 g Tween 80 2 g Span 80 100 g N- (2-hydroxyethyl) caproic acid amide 150 ml of xylene and 150 ml of isophorone are combined and dissolved with stirring.

The effectiveness against two-leaved weeds of 1 kg of this formulation with 95 g of active ingredient / liter is the same as 1 kg of a conventional commercial product 190 g / l.

Example 2 1 kg of herbicidal emulsion clay concentrate with flampropmethyl as Active ingredient is produced as follows: 160 g flampropmethyl 160 g 3-octadecy10xypropyl 2-trimethylammonioethyl phosphate 15 g N- (2-hydroxyethyl) -heptanoic acid amide 90 g Cremophor 170 g of isophorone are mixed with a xylene-toluene mixture to 1 kg filled up.

0.5 kg of this concentrate are usually diluted with water, As effective against wild oats as 1 kg of the commercial product.

This emulsion concentrate can also be used with ULV or LV technology when diluting with the same amount of water.

This mixture is a clear solution, while the commercial product, diluted with the same amount of water, results in an inhomogeneous, thick emulsion, which cannot be splashed.

Example 3 1 liter of herbicidal emulsifiable spray (25X) with propionic acid-3,4-dichloroanilide as an active ingredient is produced.

250 g of propionic acid 3,4-dichloroanilide 250N octadecanoyl 2-trimethylammonioethyl phosphate 5 g Tagat D 5 g Tegomuls O 30 g Cellosolve with Shellsol A on 1 Liters filled up and dissolved.

0.5 liters of this formulation is used against broad-leaved weeds E.g. Potato cultivation is just as effective as 1 kg of a common commercial product the same concentration.

Example 4 Production of 1 kg of herbicide spray powder (14 Z) with 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5- (4H) -one as an active ingredient.

140 g of 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5- (4H) -one 160 g of 2-hexadecanoyloxyethyl 2-trimethylammonioethyl phosphate 8 g Tween 80 2 g Span 80 50 g Cellosolve 100 ml Propylene glycol 1 1 of methanol are dissolved with heating.

400 June of this solution are kneaded with 650 a of bentonite (colloidal) and the paste dried. This process is repeated with 400 ml each time all of the solution is applied to the bentonite. The dry product will be under Addition of 5 g of ground aerosol.

1 kg of this wettable powder (with 14 Z) is against weeds in the sugar beet just as effective as 0.4 kg of a commercial product with 7q X content of active ingredient, Example 5 Production of 400 g HeF; Tbicide spray powder (40 X) with 2 - [[4-chloro-6- (ethylamino) -1,3,5-triazin-2-yl] -amino] -2-methyl-propionitrile as an active ingredient.

1360 g of 2 - [[4-chloro-6- (ethylamino) -1,3,5-triazin-2-yl] amino] -2-methyl-propionitrile 160 g 2-octadecyl 2-trimethylammonioethyl phosphate 2 g Marlowet IHF 70 g dry glycose 8 g of Bentone EW are stirred into 1220 g of water and homogenized. The mixture is spray dried.

0.2 kg of this wettable powder (40 X) is effective against weeds and grass weeds in maize equivalent to 0.5 kg of a commercially available wettable powder with 50% content of Active ingredient.

Example 6 Production of 1 kg herbicide emulsion concentrate with 80 g / l desmedipham and 80 g / l phenmedipham as active ingredients.

809 Desmedipham 809 Phenmedipham 160g 2-octadecanoyl 2-trimethylammonioethyl phosphate 2309 toluene 1709 isophorone 150g N- (2-hydroxyethyl) -heptanoic acid amide 1109 Cremaphor EL 209 PEG 600 are mixed into the emulsion concentrate.

1 liter of this formulation with 160g / 1 active ingredient concentrate is against dicot weeds in sugar beet are just as effective as 1.8 liters of a commercial product with the same concentration of active ingredients.

Example 7 Preparation of 1 liter of herbicide emulsion concentrate with 3-m-Tolylcarbamoyloxyphenylcarbamate as the active ingredient.

80 g of 3-m-tolylcarbamoyloxyphenylcarbamate 100 9 of a mixture approx. 50 g (2,3-di-hexadecvloxy) -propyl 2-trimethylammonioethyl phosphate and approx. 50 q (2,3-Di-hexadecyloxy) propyl phosphate 2 g Ligninsulfonate 30 g Cellosolve 150 g Propylene glycol is made up to 1 liter with cyclohexanone and dissolved.

1 liter of this formulation with a concentration of 80 a / l is against weeds just as effective in sugar beet as 1 liter of a common commercial product 157 g / l content of active ingredient.

Example 8 Preparation of 1 liter, emulsifiable herbicide concentrate with isopropylphenyl carbamate as the active ingredient.

250 g isopropylphenyl carbamate 200 g (2,3-di-tetradecyloxy) propyl 2-trimethylammonioethyl phosphate in a mixture of 50 g soybean oil and 15 ml ethanol 8 g Tween 80 2 g Span 80 20 g Cellosove 100 ml ethyl acetate are mixed with isopropanol made up to 1 liter and dissolved.

0.5 liters of this formulation are used as a precursor herbicide against weeds just as effective as 1 kg of a standard commercial product in the same concentration.

Example 9 Preparation of 1 liter of insecticide emulsion concentrate, which contains as active ingredient 12,5 (S) -α-cyano-3-phenoxyphenyl- (1R) -cis-3- (2,2-dibromovinyl) -2,2-dimethylcyclopropanecarboxyl at 150 g (2-hexadecyloxy-1-hexadecyloxymethyl) -ethyl 2-trimethylammonioethyl phosphate 30 g ethanol 50 g xylene 2 g polyethylene glycol glycerine monooleate 5 g glycerine monodioleate 23 g Cellosolve made up to 1 liter with Shel.lsol N.

The mixture is e.g. suitable for the treatment of 1 hectare of a Corn field against European corn borer.

Example 10 Production of 1 liter of insecticide emulsion concentrate, which as the active ingredient 2-chloro-6'-ethyl-N- (2-methoxy-1-methylethyl) acetate-o-toluidide contains.

100 g of 2-chloro-6'-ethyl-N- (2-methoxymethylethyl) -acet-o-toluidide 220 g of 2-octadecyloxyethyl 2-trimethylammonioethyl phosphate and 2-octadecyloxyethyl 2-acetylaminoethyl phosphate in a ratio of 1: 1 dissolved in 50 ml of ethanol 50 ml of xylene 10 g Marlowet IHF 10 9 Cellosove made up to 1 liter with Shellsol A.

The mixture is e.g. suitable for treating 1 hectare of one Oilseed rape field against green rapeseed beetle.

The same effect is achieved with this mixture of 100 g / l active ingredient as with usual formulations containing 200 g / l.

Example 11 Preparation of 1 liter of insecticide emulsion concentrate, which as the active ingredient 7-chlorobicyclo [3,2,0] -hepta-2,6-dien-6-yl-dimethylphosphate contains.

120 g of 7-chlorobicyclo [3,2,0] -hepta-2,6-dien-6-yldimethylphosphate 200 g 2- (octadecen-9-yl) -ethyl 2-trimethylammonioethyl phosphate 40 ml ethanol 70 ml Xylene 10 g Tween 80 2 g Span 80 60 g Cellosolve to 1 liter made up with Shellsol A.

65.Qml of the mixture are suitable e.g. for treating 1 hectare of a Leaf vegetable field against aphid, d. H.

80 g instead of the usual 170 g.

The mixture is also suitable for combating ectoparasites Pets.

Example 12 Preparation of 1 liter of an insecticide emulsion concentrate, which as the active ingredient 0-6-ethoxy-2-ethylpirimidin-4-yl-0,0-dimethyl-phosphorothioate contains.

250 g of 0-6-ethoxy-2-ethylpirimidin-4-yl-0,0-dimethyl-phosphorothioate 300 g of 3-hexadecyloxypropyl 2-trimethylammonioethyl phosphate in a mixture of 1: 1 with (3-hexadecyl-2-hydroxy) propyl 2-dimethylaminoethyl phosphate in 50 ml of ethanol dissolved 7 g Cellosolve 9 g Tween 80 2 g Span 80 made up to 1 liter made up with Shellsol N.

1 liter of this mixture is suitable e.g. for treating 1 hectare a white cabbage field oegen biting and sucking insects.

When using commercially available preparations, double the amount of Active ingredient needed.

Example 13 Preparation of 1 liter of insecticide emulsion spray, which contains 0,0-diethyl-0,4-nitrophenylphosphorothioate as the active ingredient.

230g 0,0-diethyl-0,4-nitrophenyl-phosphorothioate ca.300a 2-dodecyloxyethyl 2-trimethylammonioethyl phosphate dissolved in 100 ml of ethanol 50 ml of xylene 10 g of Marlowet 1HF made up to 1 liter with Shellsol A.

650 ml (150 active ingredient) of this mixture are suitable e.g.

for the treatment of 1 hectare of a rapeseed field against rapeseed beetle.

When using commercially available preparations, double the amount of active ingredient needed.

Example 14 Production of 1 liter of emulsion concentrate, which is used as contains active ingredient 2-Icopropoxyphenylmethvlcarbamat.

150 g 2-isopropoxyphenylmethyl carbamate 200 g (3-octadecyloxy-2-methyl) propyl 2-trimethylammonioethyl phosphate 150 ml ethanol 100 ml isopropanol 5 9 Tagat O 5 g Tegomuls O 10 g Cellosolve made up to 1 liter with Shellsol N.

2 liters of this mixture (300 q active ingredient) eionen z ^ B. for treatment of 1 hectare of a stone fruit field.

When using commercially available preparations, double the amount of Active ingredient needed.

Example 15 Production of 1 kg of fungicide spray powder (20Z) with 1,2,3,6-tetrahydro-N- (trichloromethylthio) phthalimide as active ingredient 200 g of 1,2,3,6-tetrahydro-N- (trichloromethylthio) phthalimide 200 g of 3-hexadecyloxypropyl 2-trimethylammonioethyl phosphate in a 1: 1 mixture with 3-hexadecyloxypropyl 2-aminoethyl phosphate in 50 ml of ethanol 10 g of dioctyl sodium sulfosuccinate are in 3 liters of toluene dissolved. 400 ml of this solution are kneaded with 600 g of bentonite and the paste dried in vacuo. This process is repeated until the whole toluene solution is absorbed by the bentonite. The end product is ground.

1 kg of this 20% wettable powder, 0.15% dissolved in water, against Scab applied to pomaceous fruit has the same effect as 0.5 kg of a proprietary commercial preparation.

Example 16 1 kg of fungicide spray powder with N- (trichloromethylthio) phthalimide 125 g of N- (Trichtoromethylthio) -phthalimide are produced as the active ingredient 200 g of hexadecanoyl 2-trimethylammonioethyl phosphate in 50 ml of ethanol 29 dioctyl sodium sulfosuccinate are dissolved in 400 ml of toluene while warming and mixed with 673 9 bentonite (colloidal) kneaded homogeneously and dried the paste. With the addition of 4 g of Aerosil, the Grind the product.

1 kg of this wettable powder (12.54) is just as effective as a foliar fungicide like 0.5 kg of a customary commercial product with 50% active ingredient content.

Example 17 Production of 1 kg Funciizid spray powder (12.5X) with 1- (4-chlorophenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) butanone as an active ingredient 125 g of 1- (4-chlorophenoxy) -3,3-dimethyl-1- (1,2,4 triazol-1-yl) butanol, 200 g of (2,3-di-hexadecanoyloxy) propyl 2,3-dihydroxypropyl phosphate in 50 ml of ethanol 10 g of dioctyl sodium sulfosuccinate dissolved in 250 ml of toluene. The solution becomes homogeneous on 655 g bentonite (colloidal) upset. The product is dried, ground and sieved.

Against powdery mildew in cereals, 1 kg of this formulation is in Effect is the same as 1 kg of a commercial product with 25% active ingredient.

Example 18 1 kg of acaricide spray powder with 2-sec-butyl-4,4-dinitrophenyl isopropyl carbonate The active E ingredient is: 125 g of 2-sec-butyl-4,4-dinitrophenyl isopropyl carbonate 160 g of (2,3-di-tetradecyloxy) propyl 3-trimethylammoniopropyl phosphate in 80 ml of ethanol 85 q PEG 4000/6000 dissolved in ethanol are dissolved in 350 ml xylene with heating.

The solution is kneaded homogeneously with 628o bentonite (colloidal) and the paste dried. The product is ground by adding 4 g of Aerosil.

1 kg of this wettable powder (12.5) is used to protect spider mites in fruit growing just as effective as 1 kg of a conventional commercial product with 25% active ingredient content.

Example 19 1 liter of acarbide emulsion concentrate (12.5%) with 4-chlorophenyl-2,4,5-trichlorophenyl sulfone 125 g of 4-chlorophenyl-2,4,5-trichlorophenyl sulfone are produced as the active ingredient 200 c (2,3-Dl-tetradecanoyloxy) propyl 2-trimethylanephosphate and (2,3-di-tetradecanoyloxy) propyl (2-amino-2-carboxy) ethyl phosphate in a ratio of 2: 1 5 g Tween 80 5 g Span 80 made up to 1 liter with cyclohexanone and dissolved.

1 liter of this emulsion concentrate with 125 g / l is against summer eggs and Junn larvae in fruit, vegetable and wine growing are just as effective as 1 liter of one usual commercial product with 250 g / l content of active ingredient.

Example 20 Preparation of 1 kg of nematicidal spreading agent against wandering Root nematodes in ornamental plants, which is 2-methyl-2- (methylthio) -propionaldehyde as the active ingredient contains.

50 g of 2-methyl-2- (methylthio) propanoldehyde 120 g of bis [(2,3-dihexadecanoyl) propyl] phosphate 0.1 g ascorbic palmitate are dissolved in 500 ml toluene at 300-35 ° C. This solution is kneaded with 804 g CaCO3 (quality: calcium carbonate precipitated), the paste dried and ground.

The powder is dissolved in water with 1) 15.0 g of lignin sulfonate and 2) 100 ml of a 10X gelatin solution mixed.

The resulting pellets become one in the fluidized bed dryer Powder dried.

The product thus obtained is equivalent in effectiveness against nematodes to the commercial product with 10 X active ingredient.

Claims (48)

1. Pesticide compositions, characterized in that they consist of a) one or more pesticide active ingredients and b) one or more phosphates of the general formula ---- mel 1 where X = OH or O ~ R1 = H, saturated or unsaturated, branched or straight-chain alkyl or acyl group with 1 - 22 carbon atoms, a straight-chain or branched alkylene group, optionally with a primary, secondary or tertiary amino group, one or several hydroxyl groups, an alkoxy group, halogen, phosphate, a sugar residue, an acylamino group or an acyloxy group can be substituted R2 = a straight-chain or branched, saturated or unsaturated alkyl or acyl group with 12-22 carbon atoms, a group of the general formula II, III, IV, V or Vt (CH2) n -Y-R3 II Y = O, S, NH n = 1-8 m = 1-4 R3 = H, straight-chain or branched, saturated or unsaturated alkyl or acyl group with 1 - 22 carbon atoms. R4 = H, straight-chain or branched, saturated or unsaturated Alkyl or acyl group with 1 - 22 carbon atoms. R5, R6 = identical or different, H or alkyl with 1 - 4 carbon atoms in a weight ratio a: b of 1: 0.5 to 1:20 in addition to the usual carrier, dilution, Solvent, spray and / or other inert auxiliaries exist. 2. Pesticide compositions according to claim 1, characterized in that that components a) and b) are present in a weight ratio of 1: 0.5 to 1:10. 3. Pesticide compositions according to claim 1 or 2, characterized in that that components a) and b) are present in a weight ratio of 1: 1 to 1: 5. 4. Pesticide compositions according to one or more of claims 1-3, characterized in that one or more of the compounds of general formula I is used as the phosphate where X = OH or O ~ R7, R8, Rg = identically or differently H or C14-alkyl and n, R2 and R3 have the same meaning as in claim 1, can be used. 5. Pesticide compositions according to one or more of claims 1-3, characterized in that one or more compounds of general formula I as the phosphate wherein R2 = -CH2-CH (OR3) -CH2-OR3 -CH2-OR3 -CH2-CH2-OR3 or -CH (CH2OR3) and R1, R, X have the same meaning as in claim 4, are used. 6. Pesticide composition according to one or more of claims 1-3, characterized in that one or more of the compounds of general formula I is used as the phosphate where X = OH or O R2 = saturated or unsaturated alkyl or acyl group with 12-22 carbon atoms, R7, R8, Rg = identically or differently denote H or methyl. 7. Pesticide composition according to one or more of claims 1-3, characterized in that one or more of the compounds of general formula I is used as the phosphate where X = OH or O- R2 = - (CH2) NO-R3 R3 = saturated or unsaturated alkyl or acyl group with 12-22 carbon atoms R7, R8, Rg = identically or differently denote H or methyl n = 1-2. 8. Pesticide compositions according to one or more of claims 1-3, characterized in that one or more of the compounds of general formula I is used as the phosphate where X = OH or O ~ R2 = -CH2-CH (OR3) -CH2-0R4 R3, R4 = identical or different, H or saturated or unsaturated C1-22 alkyl or acyl group R7, R8, R9 = identical or different, denote H or methyl . 9. Pesticide compositions according to one or more of claims 1-3, characterized in that one or more of the compounds of general formula I is used as the phosphate where X = OH or O R2 = -CH (CH2OR3) 2 and R3, R7, R8, Rg have the same meaning as in claim 8, can be used. 10. Pesticide composition according to one or more of Expectations 1-9, characterized in that a herbicide is used as the pesticide. 11. Pesticide composition according to one or more of the claims 1 - 9, characterized in that as a pesticide an insecticide is used. 12. Pesticide composition according to one or more of the claims 1 - 9, characterized in that a fungicide is used as the pesticide. 13. Pesticide composition according to claim 10, characterized in that one or more compounds from the groups are used as the herbicidal active ingredient: A. Phenoxycarboxylic acid derivatives of the general formula I in which a) R1 'R2, R3 = H, CH3 or halogen, with at most 2 radicals being H, R = H or CH3 n = 0-2 Y = 0 or S, X = O, NH, or S and R5, if X = 0, = H, straight-chain or branched C1-12-alkyl, hydroxyalkyl, an alkali or alkaline earth cation or an ammonium cation of an organic amine or R5, if X = NH, = H, -NR2, optionally phenyl substituted with 1-3 halo atoms or a heterocyl group, or b) R1 and R3 = R4 and R5 have the same meaning as in a) and R6 ~CH3> halogen or trifluoromethyl and n = 1-3; B. Urea derivatives of the general formula II where R1 and R2, which can be the same or different, are H, straight-chain or branched C1-4-alkyl, cycloalkyl, halogen, trifluoromethyl, nitro, alkoxy, optionally halogen-substituted phenoxy, with at most one of the groups R1 and R2 being H. . R3 = H, OH3 or C2H5 and R4 = H, cycloalkyl, C1-4 alkyl or methoxy; C. Herbicidal, organic phosphorus or arsenic compounds; D. Herbicidal alcohols or aldehydes; E. Herbicidally active substituted alkanecarboxylic acids; F. Aromatic carboxylic acid derivatives of the general formula III in which R1 - R5, which can be identical or different, are H, halogen, NH2, methoxy, -COOCH3, -COONH-naphthyl or -N02, with at most 4 of the groups R1 - R5 being, and A = -COOR6 -CONR7R8, -CSNR7R8 or COSR6 mean, in which R6 = H, alkali, alkaline earth, alkyl or hydroxyalkyl R7 = H or alkyl and R8 = H, alkyl, hydroxyalkyl or benzyl; G. Phenol derivatives of the general formula IV in which R1 - R5, which can be identical or different, are H, NO2, straight-chain or branched C1-4-alkyl, halogen, nitrile or trifluoromethyl, with at most 4 of the groups R1-R5 being H, and R4 = H, -COCH3 , -CSO-alkyl, -COCH2Cl, -COO-alkyl, -N = CH-aryl or optionally phenyl substituted by trifluoromethyl, nitro, alkyl, NR2, alkoxy and / or halogen; H. Anilines of the general formula V where R1 = H, C1-3-alkyl or nitro, R2 = H, halogen or NH2, R3 = C1-3-alkyl, H, CCF3, -SO2CH3 or -SO2NH2 R4 = H, or C1 3 -alkyl, R5 = H, NO2 or C1-3-alkyl, R6 = H, C1-13-alkyl, C1-4-alkoxymethyl or cyclopropylmethyl and R7 = branched or straight-chain alkyl or straight-chain or branched C1 5-acyl. J. Carbamates of the general formula .VI where R1 = H, halogen, CH3 or -NHCOOC2H5 and R2 = H, straight-chain or branched C14-alkyl, haloalkyl, haloalkynyl or 3- (methoxycarbamoyl) -phenyl. K. Triazines of the general formula VII where R1 = halogen, methylthio or methoxy and R2 and R3, which can be identical or different, = straight-chain or branched C1 3 -alkyl, which is optionally substituted with a nitrile group or azole group. L. Triazinones of the general formula VIII where R1 = an alkyl group, a substituted aryl group or a cycloaliphatic radical R2 = NH2, NH-alkyl or -N = CH-alkyl and R3 = alkyl, alkoxy or alkylthio. M. Other herbicides that can be used are, for example: 3,6-epoxy-cyclohexanedicarboxylic acid, S-ethyl-N, N-diethyl-thiocarbamate, S-ethyl-N, N-hexamethylene-thiocarbamate, S-ethyl-N, N-dipropyl-thiocarbamate, S-ethyl-N-ethyl-N-cyclohexyl-thiocarbamate, S-ethyl-N, N-diisobutylthiocarbamate, S-propyl-N, N-dipropyl-thiocarbamate, S-propyl-N-ethyl-N-butyl-thiocarbamate, 2-chlorallyl-N, N-diethyl-dithiocarbamate, S- (2,3,3-Trichloral lyl) -N, N-diisopropylthiocarbamate, S- (2,3-dichloroallyl) -N, N-diisopropylthiocarbamate, S- (4-chlorobenzyl) -N, N-w diethyl thiocarbamate, 1,3-dimethyl-1- (5-trifluoromethyl-1,3,4-thiadiazol-1-yl) urea, 1- (5-Ethylsulfonyl-1,3,4-thiadiazol-2-yl) -1,3-dimethylurea, 2-Oxi-1-imidazolidinecarboxylic acid-N-isobutylamide, 1- (benzothiazolyl) -1,3-dimethylurea, 1,1-ethylene-2,2'-dipyridylium dibromide, 1,1'-dimethyl-4,42-dipyridylium dichloride. 14. Pesticide compositions according to one or more of the claims 10 to 13, characterized in that the herbicidal active ingredient is one or more Compounds from the group consisting of the following compounds are used becomes: 2,4-dichlorophenoxyacetic acid or a salt or an ester thereof, 2,4,5-trichlorophenoxyacetic acid or a salt or an ester thereof, 3- (4-isopropyl-phenyl) -1,1-dimethylurea, 3-t3,4-dichlorophenyl) -1-methoxy-1-methylurea, 2,4-dinitro-6-methylphenol, pentachlorophenol, 2,4,6-trichlorophenyl-4'-nitrophenyl ether, Propionic acid-3,4-dichloroanilide, Iso-propyl-N-phenylcarbamate, 3-methoxycarbonylaino-phenyl-N- (3-methylphenyl) -carbamate, 3-ethoxycarbonylamino-phenyl-N-phenylcarbamate, 2- (4-ethylamino-6-chloro-1,3,5-triazin-2-ylamino) -2-methyl-propiononitrile, 4-Amino-3-methyl-6-phenyl-1,2,4-triazin-5 (4H) -one. 15. Pestlzi d composition according to claim 11, characterized in that a Pvrethroid of the general formula I as an insecticide where R1 = CH3, COOH, COOCH3, Cl, Br, R2 = CH3, Cl, Br R3 = subst. Cyclopentene, subst. Furylmethyl, phthalimidomethyl, phenoxybenzyl or a phenalkenyl group is used. 16. Pesticide composition according to claim 15, characterized in that that as pyrethroid pyrethrin, cinerin, josmolin, furethrin, allethrin, cyclethrin, Bathrin, Dimethrin, Phthalthrin, Japothrin, Pyresthrin, Butethrin, Penothrin, Permethrin or decamethrin is used. 17. Pesticide composition according to claim 15 or 16, characterized in that that permethrin is used as the pyrethroid. 18. Pesticide composition according to claim 15 or 16, characterized in that that decamethrin is used as the pyrethroid. 19. Pesticide composition according to claim 11, characterized in that the insecticide is a chlorinated hydrocarbon of the general formula II in which R1 = halogen, methoxy or C1-3-alkyl and a polychloroalkyl or nitroalkyl is used. 20. Pesticide composition according to claim 11, characterized in that that 2,2-bis- (p-chlorophenyl) -l, 1,1-trichloroethane is used as an insecticide. 21. Pesticide composition according to claim 11, characterized in that that 2,2-bis- (p-methoxyphenyl) -1,1,1-trichloroethane is used as an insecticide. 22. Pesticide composition according to claim 11, characterized in that that is used as an insecticide'DFDT, TDE, Perthane, Bulan or Prolan. 23. Pesticide composition according to claim 11, characterized in that that as an insecticide chlordane, heptachlor, dihydroheptachlor, isobenzane, endosulfan or bromadane is used. 24. Pesticide composition according to claim 11, characterized in that that the insecticide used is lindane, aldrin, dieldrin or endrin. 25. Pesticide composition according to claim 11, characterized in that the insecticide is a phosphoric acid ester of the general formula III in which R1 = C1-4-alkyl, R2 = alkoxy, C1-4-alkyl or aminoalkyl, A = either a) - (CH2) n Z-R3. where n = 1-3, Z = S, SO or SO2 or b) denotes chlorine, methyl, nitro-phenyl, 4-substituted-benzyl, an alkenylcarboxylic ester or alkenylcarboxamide group or c) heteroaryl group, wjrd are used. 26. Pesticide composition according to claim 25, characterized in that that as an insecticide Demeton-O, Demeton-S, Disulfobon, Phorat, Terbufos, Ethion, Malathion, Dimethoat, Prothoat, Cyanathiat, Mercarbam, Phenthoat, Vamidothion, Dichlorvos, Mevinphos, Methacrifos, Phosphamidon, Dicrotophos, Chlorfenvinphos, Tetrachlorvinphos, Parathion, Fenitrothion, Fenchlorphos, Bromophos, Fenthion ,. Crufomat, Fonofos, Temephos, Diazinon, Pirimiphos, Chlorpyrifos, Quinalphos, Isoxathion, Triazophos, Isazofos, Phosmet, Azinphosmethvl, Phosalon, Methidathion, Azamethiphos, Menazon, Endothion, Benoxafos, Trichlorphon, Dioxathion, Phosfolan, Methamidophos, Phoxim, Heptenophos, Ethoprophos, Profenofos or Merpafos is used. 27. Pesticide composition according to claim 25, characterized in that that as an insecticide Heptenophos, Demeton-S-methyl, Oxydemeton-methyl, Etrimphos, Parathion or Triazophos is used. 28. Pesticide composition according to claim 27, characterized in that that parathion is used as an insecticide. 29. Pesticide composition according to claim 11, characterized in that an aryl carbamate of the general formula IV as the insecticide in which R1 = CH3 or H, R2 = H, dialkylamino, C1 4 -alkyl, alkoxy or alkthio, R3 = H, straight-chain or branched C1-5-alkyl or dimethylate-ninomethylimino, R4 = H, alkyl, C1 4-alkoxy, C1 -4-Alktio, dioxolane or alkylthiomethyl, where R3 and R4 together can also form the groups -OC- (CH3) 2-O- or -CH = CH-CH = CH- is used. 30. Pesticide composition according to claim 29, characterized in that that the insecticide allyxycarb, aminocarb, bendiocarb, BPMC, bufencarb, carbaryl, Carbofuran, Dioxacarb, Ethiofencarb, Formetanate, Mercaptodimethur, Mexacarb, MPMC or Promecarb is used. 31. Pesticide composition according to claim 29, characterized in that that Propoxur is used as an insecticide. 32. pesticide composition according to claim 11, characterized in that that as an insecticide Aldicarb, ethyl, Oxamyl, Captap, Pirlmicarb, Chlordimeform or Amitraz is used. 33. Pesticide composition according to claim 11, characterized in that that aldicarb is used as an insecticide. 34. Pesticide composition according to claim 12, characterized in that one or more compounds from the groups of: A. Aromatic nitro compounds of the general formula I are used as the fungicidal active ingredient in which R1 = C2-4-alkenyl or branched alkoxy and R2 = C2-6-alkyl; B. Chlorobenzenes of the general formula II in which R1 = Cl or H, R2 = Cl, -OCH3 or H, R3 = Cl or - CN, R4 = Cl or H and Rs = -CN, -OCH3 or -NO2; C. Phthalic acid derivatives of the general formula III in which R = an alkylthio, haloalkyl or thionophosphoryl group; D. The fungicidally active thiocarbamates; E. The fungicidally active benzimidazoles; F. The funqicidally active aniline derivatives; G. The fungicides: thiophanate, dodemorph, tridemorph, anilazine, bupirimate, cetactaelate, quinomethionate, chloromethionate, dichlorofluanide, dimethirimol, dithianon, dodine, ethirimol, fenaminsulf, fenarimol, iprodione, pyrazetuanidol, triadimetuanidol, triadimetuanidol, triadimetylenol, triadimetylenol, triadi 35. Pesticide composition according to one or more of the claims 1-9, indicated that the pesticide used is an acaricide. 36. Pesticide composition according to claim 35, characterized in that that one or more compounds from the group are used as acari zi d active ingredient will. A. The compounds of the general formula I in which R1 = H, CH3, alkoxy, alkoxymethyl, alkoxycarbonyl or alkynyl R2 = CH3, CF3, C13, OH or H. B. The compounds of general formula II in which R1 = NO2, straight-chain or branched alkyl, R2 = H, alkenylcarbonyl or alkoxycarbonyl, R3 = cycloalkyl or branched C1-8-alkyl. C. The compounds of general formula III in which X = S or SO2, n = 0 or 1 R1 to t, which can be identical to or different from one another, are H, NO2 or halogen. D. The acaricides: thioquinox, quinomethionate, methiocarb, chlordimeform, Formetanate, chlorofensulfide and chlorofenson. 37. Acarlzid compositions according to claim 35, characterized in that that one or more of the compounds Dinoc, Benapacryl, Dinobuton, Tetrasul, chlorine surfactant, tetradifon, propargite, chlorfenethol, dicofol, Chlorobenzilate, chloropropylate, bromopropylate, chlorodimephone, formetanate, quinomethionate or Thiquinox. 38. Pesticide composition according to one or more of the claims 1-9, characterized in that a nematicide is used as the pesticide. 39. Pesticide composition according to claim 38, characterized in that that as a nematicide Dichlofenthion, Zinophos, Fensulfothion, Aldicarb, Dazomet and / or Dichloropropene is used. 40. Process for the preparation of pesticidal compositions according to one or more of claims 1-39, characterized in that the phosphate or mixtures of the phosphates according to formula I in an organic solvent or solvent mixture is dissolved and, if necessary, in this solution by heating and / or stirring the pesticide dissolves, and then the solvent or solvent mixture is drawn off in vacuo. The mixture obtained becomes more customary with the addition Filler and auxiliaries converted into a customary application form. 41. A method for the preparation of Pestlz.i d compositions according to one or more of claims 1-39, characterized in that the Pesticides with one or more phosphates of the general formula I with addition Usual fillers and auxiliaries dissolved or slurried in an organic solvent and the solvent will then be abaezooen. 42. Process for the production of pesticide compositions according to one or more of claims 1-39, characterized in that one or more, Pesticides soluble in water or alcohol in water or water-alcohol mixtures together with one or more phosphates of the general formula I with stirring and / or slight heating and / or ultrasound dissolves and the solvent or Solvent mixture is withdrawn. 43. Use of pesticidal compositions according to one or more of claims 1-39 for combating weeds and / or pests. 44. Use of pesticide compositions generally one or more of claims 10-14 for the control of weeds and weeds. 45. Use of pesticide compositions according to one or more of claims 15-33 for the control of insects. 46. Use of pesticide compositions according to one or more of claims 12 or 34 for combating fungi. 47. Use of pesticidal compositions according to one or more of claims 35-37 for combating mites or spider mites. 48. Use of pesticide compositions according to one or more of claims 38-39 for controlling nematodes.