DE318141C - - Google Patents
Info
- Publication number
- DE318141C DE318141C DENDAT318141D DE318141DA DE318141C DE 318141 C DE318141 C DE 318141C DE NDAT318141 D DENDAT318141 D DE NDAT318141D DE 318141D A DE318141D A DE 318141DA DE 318141 C DE318141 C DE 318141C
- Authority
- DE
- Germany
- Prior art keywords
- aluminum
- lime
- coating
- carbonate
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 29
- 229910052782 aluminium Inorganic materials 0.000 claims description 28
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 9
- 235000015450 Tilia cordata Nutrition 0.000 claims description 9
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 9
- 239000004571 lime Substances 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 claims description 4
- 238000003825 pressing Methods 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 235000013305 food Nutrition 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000002378 acidificating Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 210000003278 Egg Shell Anatomy 0.000 description 1
- FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000009924 canning Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000004653 carbonic acids Chemical class 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000003000 nontoxic Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 229960001367 tartaric acid Drugs 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
Description
Aluminium wird bekanntlich von sauren und alkalischen Flüssigkeiten mehr oder minder stark angegriffen, wodurch die Verwendbarkeit dieses Metalls namentlich zu Gefäßen zum Aufbewahren von derartigen Flüssigkeiten sehr beschränkt ist. Es war daher bis jetzt auch nicht möglich, das Aluminium zu Gefäßen zur Konservierung von Lebensmitteln zu verwenden. Das Aluminium wird von denAs is well known, aluminum is more or less exposed to acidic and alkaline liquids heavily attacked, making this metal usable especially for vessels for storing such liquids is very limited. It was therefore up Now it is also not possible to use aluminum to preserve food to use. The aluminum is used by the
ίο hier in Betracht kommenden, natürlich sehr verdünnten Säuren, wie Essigsäure, Milchsäure, Zitronensäure und Weinsäure, sowie von mehr oder minder konzentrierten Kochsalzlösungen bei längerer Dauer der Einwirkung angriffen, und es treten hierbei Wasserstoffentwicklungen irii Gestalt von Bläschen an den Metallwänden auf, welche naturgemäß die Konservierung von Nahrungsmitteln sehr beeinträchtigen oder auch gänzlich hindern.ίο eligible here, of course very much dilute acids, such as acetic acid, lactic acid, citric acid, and tartaric acid, as well of more or less concentrated saline solutions for longer periods of exposure attacked, and hydrogen evolution occurs in the form of bubbles the metal walls, which naturally affect the preservation of food very much or hinder it entirely.
Konservendosen aus Aluminium oder mit Aluminium überzogenem Eisenblech konnten daher für die meisten Nahrungsmittel nicht angewandt werden.Tin cans made of aluminum or sheet iron coated with aluminum could therefore cannot be used for most foods.
Diesen Nachteil zu beseitigen und das Aluminium auch für Konservenzwecke in weitem Umfang nutzbar zu machen, bezweckt die vorliegende Erfindung.To eliminate this disadvantage and to use the aluminum for canning purposes by far The present invention aims to make the scope useful.
Die Grundlage des Verfahrens bildet die Erkenntnis, daß Kreidestriche auf Aluminiumblechen sich ohne Veränderung ihrer Qualität auf die Schweißtemperatur des Alumniums (etwa 550° C) erhitzen und ia diesem Zustand unter Walzendruck aufwalzen lassen und dann derartig fest auf dem Aluminium haften, daß sie weiteren Bearbeitungsprozessfen der Bleche durch Walzen, Stanzen, Falien usw. standhalten und auch durch den bei Aluminium bekannten Beizprozeß mittels Ätznatronlösung nicht zu entfernen sind. Diese Eigentümlichkeit der Kreidestriche beim Aluminium wurde, bisher beim Plattieren vpn Eisenblech mit Aluminium, angewandt, indem man beim Aufschweißen von ungleich starken Aluminiumblechen auf Eisenplatinen die eine Blechseite mit einem Kreidestrich yersah, und dann später bei der Verarbeitung, der.mit Ajuminium überzogenen Bleche die stärker. pläi- ' ,· tierte Blechseite von der schwächer plattiertfen unterscheiden konnte. P . -The basis of the process is the knowledge that chalk lines on aluminum sheets on the welding temperature of the aluminum without changing their quality (about 550 ° C) and generally this state Let it roll on under roller pressure and then so firmly on the aluminum adhere to the fact that they are further processing the sheet metal by rolling, punching, felling etc. and cannot be removed by the pickling process known from aluminum using caustic soda solution. These The peculiarity of the chalk lines in aluminum has been vpn, so far in plating Sheet iron with aluminum, applied by welding on unequal thicknesses Aluminum sheets on iron plates yersah one side of the sheet with a chalk line, and then later during processing, der.mit Ajuminium coated sheets the stronger. pläi- ', · tied sheet metal side could be distinguished from the weaker plated side. P. -
Die Envägung, daß- Kreide kohlensaurer Kalk ist, der. hauptsächlich nur in Wasser, ' welches reich an Kohlensäuren·.ist, löslich ist, sonst aber von den hier in Betracht kommejiden schwach sauren. und alkalischen Flüssigkeiten nicht angegriffen wird, führte nun zu 55'. dem Verfahren nach der Erfindung, das darin besteht, das Aluminium mit einem möglichst dichten Überzug von kohlensaurem Kalk zu versehen, der dann in erhitztem Zustande (bei : etwa. 550° C) durch Einwalzen, Einpressen oder Einhämmern mit dem Aluminium verbunden wird. Derartige Überzüge aus kohlen-The consideration that chalk is carbonate of lime that. mainly only in water, ' which is rich in carbonic acids, is soluble, but otherwise of the here considered weakly acidic. and alkaline liquids is not attacked, now resulted in 55 '. the method according to the invention, which consists in the aluminum with a possible to provide a dense coating of carbonate of lime, which then in a heated state (in: approximately. 550 ° C) bonded to the aluminum by rolling, pressing or hammering will. Such coatings made of carbon
'M ■ 'M ■
saurem Kalk schützen das darunter liegende Aluminium.-gegen die Einwirkung genannter Flüssigkeiten, verhindern namentlich die Wassef Stoff entwicklung'".übd eignen sich somit, da der kohlensaure Kalk sowie das Aluminium ungiftig sind, vorzüglich zu Gefäßen zur Aufbewahrung von Lebensmitteln aller Art. Die Anwendung des Aluminiums sowie von mit Aluminium überzogenem Eisenblechacid lime protect the underlying aluminum.-against the effects of the named Liquids, in particular, prevent the development of water. Since the carbonate of lime and the aluminum are non-toxic, ideal for vessels for the storage of food of all kinds. The application of aluminum as well of sheet iron covered with aluminum
ίο für Konservendosen ist durch diesen widerstandsfähigen kohlensauren Kalküberzug möglich.ίο for tin cans is tough because of this Carbonate lime coating possible.
Das Verfahren zur Herstellung derartiger Überzüge auf Aluminium geschieht folgendermaßen: The process for producing such coatings on aluminum is as follows:
Das Aluminium wird an seiner Oberfläche mit gemahlenem, feinem kohlensauren Kalk (Kreide, Muschelschalen, Eierschalen usw.) eingepudert und dann in einem Ofen auf etwa 55°° C erhitzt, worauf es in diesem Zustand unter schwachem Druck (Walzen, Pressen, Hämmern) mit. dem Kalküberzug fest ver-. bunden wird. Nach dem Erkalten empfiehlt es sich, das Aluminium noch mit einer schwachen Säurelösung (Weinstein oder Milchsäure) zu beizen, um es rein und sauber zu erhalten.The aluminum is coated on its surface with ground, fine carbonate of lime (Chalk, clamshells, eggshells, etc.) powdered and then in an oven to about 55 ° C, whereupon it is in this state with light pressure (rolling, pressing, hammering). firmly attached to the lime coating. is bound. After cooling, it is advisable to wash the aluminum with a weak acid solution (Weinstein or Lactic acid) to keep it pure and clean.
Um das Aufpudern des Kalkes zu erleichtern, sind die Aluminiumflächen vorher zu mattieren.To make it easier to powder the lime, the aluminum surfaces must be closed beforehand mattify.
Das Verfahren ist anwendbar außer auf Aluminium auch auf alle Gegenstände aus anderen Metallen, die mit einem Aluminiumüberzug versehen sind. Ebenso erstreckt es sich auf alle Aluminiumlegierungen, welche die hier notwendigen Eigenschaften des Aluminiums besitzen.The procedure is applicable to all objects apart from aluminum other metals with an aluminum coating. Likewise, it extends on all aluminum alloys that have the properties of aluminum that are required here own.
Claims (1)
Publications (1)
Publication Number | Publication Date |
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DE318141C true DE318141C (en) |
Family
ID=570746
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT318141D Active DE318141C (en) |
Country Status (1)
Country | Link |
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DE (1) | DE318141C (en) |
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0
- DE DENDAT318141D patent/DE318141C/de active Active
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