DE3169218D1 - Process for removal of sulfur from moisture-bearing, sulfur-containing hydrocarbon process streams - Google Patents

Process for removal of sulfur from moisture-bearing, sulfur-containing hydrocarbon process streams

Info

Publication number
DE3169218D1
DE3169218D1 DE8181306172T DE3169218T DE3169218D1 DE 3169218 D1 DE3169218 D1 DE 3169218D1 DE 8181306172 T DE8181306172 T DE 8181306172T DE 3169218 T DE3169218 T DE 3169218T DE 3169218 D1 DE3169218 D1 DE 3169218D1
Authority
DE
Germany
Prior art keywords
sulfur
moisture
removal
bearing
containing hydrocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8181306172T
Other languages
English (en)
Inventor
Paul Earl Eberly
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of DE3169218D1 publication Critical patent/DE3169218D1/de
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3408—Regenerating or reactivating of aluminosilicate molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
    • C10G25/05—Removal of non-hydrocarbon compounds, e.g. sulfur compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00—Gas separation: processes
    • Y10S95/90—Solid sorbent
    • Y10S95/902—Molecular sieve

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Industrial Gases (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
DE8181306172T 1981-01-02 1981-12-30 Process for removal of sulfur from moisture-bearing, sulfur-containing hydrocarbon process streams Expired DE3169218D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/222,054 US4358297A (en) 1980-01-02 1981-01-02 Removal of sulfur from process streams

Publications (1)

Publication Number Publication Date
DE3169218D1 true DE3169218D1 (en) 1985-04-11

Family

ID=22830598

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8181306172T Expired DE3169218D1 (en) 1981-01-02 1981-12-30 Process for removal of sulfur from moisture-bearing, sulfur-containing hydrocarbon process streams

Country Status (6)

Country Link
US (1) US4358297A (de)
EP (1) EP0056197B1 (de)
JP (1) JPS57135029A (de)
AU (1) AU553900B2 (de)
CA (1) CA1172178A (de)
DE (1) DE3169218D1 (de)

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DE3228270A1 (de) * 1982-07-29 1984-02-02 Degussa Ag, 6000 Frankfurt Katalysator fuer die herstellung von kohlenwasserstoffen und das verfahren zu dessen herstellung
US4449991A (en) * 1982-12-20 1984-05-22 Exxon Research And Engineering Co. Removal of sulfur from process streams
US4686775A (en) * 1983-12-16 1987-08-18 Union Oil Company Of California Absorbent drying method by contacting with a hydrocarbon
GB8407842D0 (en) * 1984-03-27 1984-05-02 Shell Int Research Removing hydrogen sulphide from gases
CA1252451A (en) * 1984-07-04 1989-04-11 Taisuke Nishida Method of separating carbon monoxide and carbon monoxide adsorbent used in this method
GB8517333D0 (en) * 1985-07-09 1985-08-14 Ici Plc Purification of hydrocarbon mixture
GB8520353D0 (en) * 1985-08-14 1985-09-18 Ici Plc Gas purification
GB2180848A (en) * 1985-09-25 1987-04-08 Shell Int Research Removing hydrogen sulphide from a gaseous mixture
GB8630846D0 (en) * 1986-12-24 1987-02-04 Ici Plc Desulphurisation
US4846962A (en) * 1987-02-12 1989-07-11 Exxon Research And Engineering Company Removal of basic nitrogen compounds from extracted oils by use of acidic polar adsorbents and the regeneration of said adsorbents
US4831208A (en) * 1987-03-05 1989-05-16 Uop Chemical processing with an operational step sensitive to a feedstream component
DE3825169A1 (de) * 1988-07-23 1990-02-01 Huels Chemische Werke Ag Verfahren zur feinentschwefelung von kohlenwasserstoffen
US5013337A (en) * 1988-12-06 1991-05-07 Uop Process for separating a mixture of molecular species using crystalline microporous metal sulfide compositions
US5174979A (en) * 1989-10-06 1992-12-29 Uop Mixed ion-exchanged zeolites and processes for the use thereof in gas separations
US5120516A (en) * 1990-01-08 1992-06-09 Physical Sciences, Inc. Process for removing nox emissions from combustion effluents
US5171333A (en) * 1990-01-09 1992-12-15 Uop Methane purification by pressure swing adsorption
US5013334A (en) * 1990-01-09 1991-05-07 Uop Methane purification by pressure swing adsorption
US5057473A (en) * 1990-04-12 1991-10-15 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Regenerative Cu La zeolite supported desulfurizing sorbents
US5346535A (en) * 1991-08-23 1994-09-13 Engelhard Corporation Use of crystalline molecular sieves containing charged octahedral sites in removing volatile organic compounds from a mixture of the same
US5424051A (en) * 1992-01-14 1995-06-13 Uop Process for the removal of carbon dioxide and mercaptans from a gas stream
FR2691375B1 (fr) * 1992-05-20 1994-09-09 Inst Francais Du Petrole Procédé de traitement de gaz malodorants et/ou toxiques.
US5919354A (en) * 1997-05-13 1999-07-06 Marathon Oil Company Removal of sulfur from a hydrocarbon stream by low severity adsorption
US6579347B1 (en) * 1998-04-28 2003-06-17 Matsushita Electric Industrial Co., Ltd. Method for removing sulfur compound present in city gas
EP1171229A1 (de) * 1999-03-24 2002-01-16 University of Wyoming System zur wiedergewinnung von schwefel und wasserstoff aus korrosiven gasen
AU5130500A (en) * 1999-05-21 2000-12-12 Zeochem Llc Molecular sieve adsorbent-catalyst for sulfur compound contaminated gas and liquid streams and process for its use
US6096194A (en) * 1999-12-02 2000-08-01 Zeochem Sulfur adsorbent for use with oil hydrogenation catalysts
US6391815B1 (en) 2000-01-18 2002-05-21 Süd-Chemie Inc. Combination sulphur adsorbent and hydrogenation catalyst for edible oils
JP4609961B2 (ja) * 2000-01-28 2011-01-12 Ｊｘ日鉱日石エネルギー株式会社 硫黄化合物の除去方法
EP1121977B1 (de) * 2000-02-01 2007-04-25 Tokyo Gas Co., Ltd. Verfahren zur Entfernung von Schwefelverbindungen aus Brenngasen
US6875410B2 (en) * 2000-02-01 2005-04-05 Tokyo Gas Co., Ltd. Adsorbent for removing sulfur compounds from fuel gases and removal method
US6911569B1 (en) * 2000-08-07 2005-06-28 The Regents Of The University Of Michigan Sulfur resistant adsorbents
US20020043154A1 (en) * 2000-08-25 2002-04-18 Engelhard Corporation Zeolite compounds for removal of sulfur compounds from gases
DE10155643A1 (de) * 2001-11-08 2003-05-28 Ipc Process Ct Gmbh Körper für die Separation einer in einem Gasgemisch enthaltenen Komponente
US6736879B2 (en) * 2002-05-01 2004-05-18 Chevron Phillips Chemical Company Lp Process to prepare low carbon disulfide containing dimethyl sulfide
US20040007130A1 (en) * 2002-07-11 2004-01-15 Gislason Jason J. Desulfurization and novel compositions for same
WO2004039926A1 (en) * 2002-10-29 2004-05-13 Shell Internationale Research Maatschappij B.V. Removal of sulphur compounds from hydrocarbon streams using adsorbents and regeneration of the loaded adsorbents
CA2507355C (en) * 2002-11-28 2012-02-21 Jolinde Machteld Van De Graaf Process for removing sulphur compounds including hydrogen sulphide and mercaptans from gas streams
US7651550B2 (en) * 2003-06-06 2010-01-26 Zeochem Ag Method for sulfur compounds removal from contaminated gas and liquid streams
EP1732679B1 (de) 2003-12-05 2012-03-07 Intercat, Inc. Verfahren zur Reduktion con SOx-, NOx- und CO-Emissionen in Gasströmen
US7431825B2 (en) 2003-12-05 2008-10-07 Intercat, Inc. Gasoline sulfur reduction using hydrotalcite like compounds
TWI342335B (en) 2004-06-02 2011-05-21 Intercat Inc Mixed metal oxide additives
US8323603B2 (en) * 2004-09-01 2012-12-04 Sud-Chemie Inc. Desulfurization system and method for desulfurizing a fuel stream
US20060043001A1 (en) * 2004-09-01 2006-03-02 Sud-Chemie Inc. Desulfurization system and method for desulfurizing afuel stream
US20060283780A1 (en) * 2004-09-01 2006-12-21 Sud-Chemie Inc., Desulfurization system and method for desulfurizing a fuel stream
CA2578233A1 (en) * 2004-09-01 2006-03-16 Sued-Chemie Inc. A desulfurization system and method for desulfurizing a fuel stream
US7780846B2 (en) * 2004-09-01 2010-08-24 Sud-Chemie Inc. Sulfur adsorbent, desulfurization system and method for desulfurizing
KR100634535B1 (ko) * 2005-01-24 2006-10-13 삼성에스디아이 주식회사 탈황용 제올라이트 흡착제 및 그것의 제조방법
EP1700630B1 (de) * 2005-03-08 2011-05-25 Institut Français du Pétrole Verfahren zur Entfernung von Schwefelverbindungen aus gasförmigen Kohlenwasserstoffen mittels Adsorptionsmitteln
WO2007018677A1 (en) 2005-07-26 2007-02-15 Exxonmobil Upstream Research Company Method of purifying hydrocarbons and regeneration of adsorbents used therein
CN102099332B (zh) 2008-07-15 2014-02-12 巴斯夫欧洲公司 提纯二烷基硫醚的方法
DE102010003880A1 (de) 2010-04-12 2011-10-13 Durtec Gmbh Mineralische Gasadsorber zur Beseitigung von Ozon aus Abluft/Abgas, Verfahren zu deren Herstellung und Regenerierung
TW201444617A (zh) * 2013-05-30 2014-12-01 Hua Feng Applied Equipment Co Ltd 可中和酸性物質之沸石觸媒製程

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US2882243A (en) * 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
GB871076A (en) 1956-10-16 1961-06-21 Azote Office Nat Ind Improvements in or relating to the desulphurization of gases
US3085380A (en) * 1959-10-23 1963-04-16 Engineers & Fabricators Inc Adsorption process
NL127140C (de) * 1959-11-30
US3078634A (en) * 1959-11-30 1963-02-26 Union Carbide Corp Sweetening and drying of natural gas
US3070639A (en) * 1959-12-15 1962-12-25 Pure Oil Co Separation of aromatic hydrocarbons using surface-modified solid adsorbent
US3078640A (en) * 1959-12-18 1963-02-26 Union Carbide Corp Separation of sulfur compounds from vapor mixtures
NL259188A (de) * 1959-12-31
NL262414A (de) * 1960-03-15
US3087291A (en) * 1960-06-22 1963-04-30 C B Southern Inc Gas sweetening process and apparatus
US3300324A (en) * 1963-05-20 1967-01-24 Mobil Oil Corp Hydrogen sulfide detection method and control system
BE759979A (fr) * 1965-02-10 1971-06-07 Grillo Werke Ag Procede d'elimination du soufre dans les gaz residuaires
GB1173388A (en) * 1967-06-30 1969-12-10 Leuna Werk Walter Ulbricht Veb Process for the Isolation of Hydrocarbon Groups
US3620969A (en) * 1969-10-15 1971-11-16 Union Carbide Corp Desulfurization by selective adsorption with a crystalline zeolitic molecular sieve
US3725299A (en) * 1970-08-06 1973-04-03 Union Carbide Corp Regeneration of molecular sieves having sulfur compounds adsorbed thereon
US3816975A (en) * 1972-11-14 1974-06-18 Union Carbide Corp Purification of hydrocarbon feedstocks
US4028069A (en) * 1976-08-30 1977-06-07 Uop Inc. Purification and drying of hydrocarbon streams with adsorbents

Also Published As

Publication number Publication date
US4358297A (en) 1982-11-09
AU553900B2 (en) 1986-07-31
EP0056197B1 (de) 1985-03-06
EP0056197A1 (de) 1982-07-21
JPS57135029A (en) 1982-08-20
AU7907081A (en) 1982-07-08
CA1172178A (en) 1984-08-07
JPH0147216B2 (de) 1989-10-12

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Legal Events

Date Code Title Description
8339 Ceased/non-payment of the annual fee